Electrically isolating insulated conductor heater

ABSTRACT

A heating system for a subsurface formation includes an electrical conductor and an insulation layer at least partially surrounding the electrical conductor. A jacket that includes ferromagnetic material at least partially surrounds the insulation layer. The outside surface of the jacket is configured to be at little or no electric potential while the electrical conductor is conducting electricity and while the jacket is at temperatures below the Curie temperature of the ferromagnetic material.

PRIORITY CLAIM

This patent application claims priority to U.S. Provisional Patent No.60/925,685 entitled “SYSTEMS AND PROCESSES FOR USE IN SITU HEATTREATMENT PROCESSES” to Vinegar et al. filed on Apr. 20, 2007, which isincorporated by reference in its entirety, and to U.S. ProvisionalPatent No. 60/999,839 entitled “SYSTEMS AND PROCESSES FOR USE INTREATING SUBSURFACE FORMATIONS” to Vinegar et al. filed on Oct. 19,2007, which is incorporated by reference in its entirety.

RELATED PATENTS

This patent application incorporates by reference in its entirety eachof U.S. Pat. Nos. 6,688,387 to Wellington et al.; 6,991,036 toSumnu-Dindoruk et al.; 6,698,515 to Karanikas et al.; 6,880,633 toWellington et al.; 6,782,947 to de Rouffignac et al; 6,991,045 toVinegar et al.; 7,073,578 to Vinegar et al.; 7,121,342 to Vinegar et al;and 7,320,364 to Fairbanks. This patent application incorporates byreference in its entirety each of U.S. Patent Application Publication2007-0133960 to Vinegar et al., U.S. Patent Application Publication2007-0221377 to Vinegar et al., and U.S. Patent Application Publication2008-0017380 to Vinegar et al. This patent application incorporates byreference in its entirety U.S. patent application Ser. No. 11/975,676 toVinegar et al.

GOVERNMENT INTEREST

The Government has certain rights in the invention pursuant to AgreementNos. SD 10634 and NFE 062050824 between Sandia National Laboratories(operating under Agreement DE-AC04-94AL85000Sa for the U.S. Departmentof Energy) and Shell Exploration and Production Company.

BACKGROUND

1. Field of the Invention

The present invention relates generally to methods and systems forproduction of hydrocarbons, hydrogen, and/or other products from varioussubsurface formations such as hydrocarbon containing formations.

2. Description of Related Art

Hydrocarbons obtained from subterranean formations are often used asenergy resources, as feedstocks, and as consumer products. Concerns overdepletion of available hydrocarbon resources and concerns over decliningoverall quality of produced hydrocarbons have led to development ofprocesses for more efficient recovery, processing and/or use ofavailable hydrocarbon resources. In situ processes may be used to removehydrocarbon materials from subterranean formations. Chemical and/orphysical properties of hydrocarbon material in a subterranean formationmay need to be changed to allow hydrocarbon material to be more easilyremoved from the subterranean formation. The chemical and physicalchanges may include in situ reactions that produce removable fluids,composition changes, solubility changes, density changes, phase changes,and/or viscosity changes of the hydrocarbon material in the formation. Afluid may be, but is not limited to, a gas, a liquid, an emulsion, aslurry, and/or a stream of solid particles that has flow characteristicssimilar to liquid flow.

During some in situ processes, wax may be used to reduce vapors and/orto encapsulate contaminants in the ground. Wax may be used duringremediation of wastes to encapsulate contaminated material. U.S. Pat.No. 7,114,880 to Carter, and U.S. Pat. No. 5,879,110 to Carter, each ofwhich is incorporated herein by reference, describe methods fortreatment of contaminants using wax during the remediation procedures.

In some embodiments, a casing or other pipe system may be placed orformed in a wellbore. U.S. Pat. No. 4,572,299 issued to Van Egmond etal., which is incorporated by reference as if fully set forth herein,describes spooling an electric heater into a well. In some embodiments,components of a piping system may be welded together. Quality of formedwells may be monitored by various techniques. In some embodiments,quality of welds may be inspected by a hybrid electromagnetic acoustictransmission technique known as EMAT. EMAT is described in U.S. Pat. No.5,652,389 to Schaps et al.; U.S. Pat. No. 5,760,307 to Latimer et al.;U.S. Pat. No. 5,777,229 to Geier et al.; and U.S. Pat. No. 6,155,117 toStevens et al., each of which is incorporated by reference as if fullyset forth herein.

In some embodiments, an expandable tubular may be used in a wellbore.Expandable tubulars are described in U.S. Pat. No. 5,366,012 to Lohbeck,and U.S. Pat. No. 6,354,373 to Vercaemer et al., each of which isincorporated by reference as if fully set forth herein.

Heaters may be placed in wellbores to heat a formation during an in situprocess. Examples of in situ processes utilizing downhole heaters areillustrated in U.S. Pat. No. 2,634,961 to Ljungstrom; U.S. Pat. No.2,732,195 to Ljungstrom; U.S. Pat. No. 2,780,450 to Ljungstrom; U.S.Pat. No. 2,789,805 to Ljungstrom; U.S. Pat. No. 2,923,535 to Ljungstrom;and U.S. Pat. No. 4,886,118 to Van Meurs et al.; each of which isincorporated by reference as if fully set forth herein.

Application of heat to oil shale formations is described in U.S. Pat.No. 2,923,535 to Ljungstrom and U.S. Pat. No. 4,886,118 to Van Meurs etal. Heat may be applied to the oil shale formation to pyrolyze kerogenin the oil shale formation. The heat may also fracture the formation toincrease permeability of the formation. The increased permeability mayallow formation fluid to travel to a production well where the fluid isremoved from the oil shale formation. In some processes disclosed byLjungstrom, for example, an oxygen containing gaseous medium isintroduced to a permeable stratum, preferably while still hot from apreheating step, to initiate combustion.

A heat source may be used to heat a subterranean formation. Electricheaters may be used to heat the subterranean formation by radiationand/or conduction. An electric heater may resistively heat an element.U.S. Pat. No. 2,548,360 to Germain, which is incorporated by referenceas if fully set forth herein, describes an electric heating elementplaced in a viscous oil in a wellbore. The heater element heats andthins the oil to allow the oil to be pumped from the wellbore. U.S. Pat.No. 4,716,960 to Eastlund et al., which is incorporated by reference asif fully set forth herein, describes electrically heating tubing of apetroleum well by passing a relatively low voltage current through thetubing to prevent formation of solids. U.S. Pat. No. 5,065,818 to VanEgmond, which is incorporated by reference as if fully set forth herein,describes an electric heating element that is cemented into a wellborehole without a casing surrounding the heating element.

U.S. Pat. No. 6,023,554 to Vinegar et al., which is incorporated byreference as if fully set forth herein, describes an electric heatingelement that is positioned in a casing. The heating element generatesradiant energy that heats the casing. A granular solid fill material maybe placed between the casing and the formation. The casing mayconductively heat the fill material, which in turn conductively heatsthe formation.

U.S. Pat. No. 4,570,715 to Van Meurs et al., which is incorporated byreference as if fully set forth herein, describes an electric heatingelement. The heating element has an electrically conductive core, asurrounding layer of insulating material, and a surrounding metallicsheath. The conductive core may have a relatively low resistance at hightemperatures. The insulating material may have electrical resistance,compressive strength, and heat conductivity properties that arerelatively high at high temperatures. The insulating layer may inhibitarcing from the core to the metallic sheath. The metallic sheath mayhave tensile strength and creep resistance properties that arerelatively high at high temperatures.

U.S. Pat. No. 5,060,287 to Van Egmond, which is incorporated byreference as if fully set forth herein, describes an electrical heatingelement having a copper-nickel alloy core.

Obtaining permeability in an oil shale formation between injection andproduction wells tends to be difficult because oil shale is oftensubstantially impermeable. Many methods have attempted to link injectionand production wells. These methods include: hydraulic fracturing suchas methods investigated by Dow Chemical and Laramie Energy ResearchCenter; electrical fracturing by methods investigated by Laramie EnergyResearch Center; acid leaching of limestone cavities by methodsinvestigated by Dow Chemical; steam injection into permeable nahcolitezones to dissolve the nahcolite by methods investigated by Shell Oil andEquity Oil; fracturing with chemical explosives by methods investigatedby Talley Energy Systems; fracturing with nuclear explosives by methodsinvestigated by Project Bronco; and combinations of these methods. Manyof these methods, however, have relatively high operating costs and lacksufficient injection capacity.

Large deposits of heavy hydrocarbons (heavy oil and/or tar) contained inrelatively permeable formations (for example in tar sands) are found inNorth America, South America, Africa, and Asia. Tar can be surface-minedand upgraded to lighter hydrocarbons such as crude oil, naphtha,kerosene, and/or gas oil. Surface milling processes may further separatethe bitumen from sand. The separated bitumen may be converted to lighthydrocarbons using conventional refinery methods. Mining and upgradingtar sand is usually substantially more expensive than producing lighterhydrocarbons from conventional oil reservoirs.

In situ production of hydrocarbons from tar sand may be accomplished byheating and/or injecting a gas into the formation. U.S. Pat. Nos.5,211,230 to Ostapovich et al. and U.S. Pat. No. 5,339,897 to Leaute,which are incorporated by reference as if fully set forth herein,describe a horizontal production well located in an oil-bearingreservoir. A vertical conduit may be used to inject an oxidant gas intothe reservoir for in situ combustion.

U.S. Pat. No. 2,780,450 to Ljungstrom describes heating bituminousgeological formations in situ to convert or crack a liquid tar-likesubstance into oils and gases.

U.S. Pat. No. 4,597,441 to Ware et al., which is incorporated byreference as if fully set forth herein, describes contacting oil, heat,and hydrogen simultaneously in a reservoir. Hydrogenation may enhancerecovery of oil from the reservoir.

U.S. Pat. No. 5,046,559 to Glandt and U.S. Pat. No. 5,060,726 to Glandtet al., which are incorporated by reference as if fully set forthherein, describe preheating a portion of a tar sand formation between aninjector well and a producer well. Steam may be injected from theinjector well into the formation to produce hydrocarbons at the producerwell.

As outlined above, there has been a significant amount of effort todevelop methods and systems to economically produce hydrocarbons,hydrogen, and/or other products from hydrocarbon containing formations.At present, however, there are still many hydrocarbon containingformations from which hydrocarbons, hydrogen, and/or other productscannot be economically produced. Thus, there is still a need forimproved methods and systems for production of hydrocarbons, hydrogen,and/or other products from various hydrocarbon containing formations.

SUMMARY

Embodiments described herein generally relate to systems, methods, andheaters for treating a subsurface formation. Embodiments describedherein also generally relate to heaters that have novel componentstherein. Such heaters can be obtained by using the systems and methodsdescribed herein.

In certain embodiments, the invention provides one or more systems,methods, and/or heaters. In some embodiments, the systems, methods,and/or heaters are used for treating a subsurface formation.

In certain embodiments, the invention provides a heating system for asubsurface formation, comprising: an electrical conductor; an insulationlayer at least partially surrounding the electrical conductor; and ajacket comprising ferromagnetic material, the jacket at least partiallysurrounding the insulation layer, wherein the outside surface of thejacket is configured to be at little or no electric potential while theelectrical conductor is conducting electricity and while the jacket isat temperatures below the Curie temperature of the ferromagneticmaterial.

In certain embodiments, the invention provides a heating system for asubsurface formation, comprising: an electrical conductor; an insulationlayer at least partially surrounding the electrical conductor; and ajacket comprising ferromagnetic material, the jacket at least partiallysurrounding the insulation layer, wherein the jacket is configured togenerate a majority of the heat in the heating system when atime-varying electrical current is applied to the heating system.

In certain embodiments, the invention provides a method for heating asubsurface formation, comprising: providing electrical power to a heaterlocated in an opening in the formation, the heater comprising: anelectrical conductor; an insulation layer at least partially surroundingthe electrical conductor; and a jacket comprising ferromagneticmaterial, the jacket at least partially surrounding the insulationlayer, wherein the outside surface of the jacket is configured to be atlittle or no electrical potential while the electrical conductor isconducting electricity and while the jacket is at temperatures below theCurie temperature of the ferromagnetic material; and allowing heat totransfer from the heater to at least a portion of the subsurfaceformation.

In further embodiments, features from specific embodiments may becombined with features from other embodiments. For example, featuresfrom one embodiment may be combined with features from any of the otherembodiments.

In further embodiments, treating a subsurface formation is performedusing any of the methods, systems, or heaters described herein.

In further embodiments, additional features may be added to the specificembodiments described herein.

BRIEF DESCRIPTION OF THE DRAWINGS

Advantages of the present invention may become apparent to those skilledin the art with the benefit of the following detailed description andupon reference to the accompanying drawings in which:

FIG. 1 depicts an illustration of stages of heating a hydrocarboncontaining formation.

FIG. 2 shows a schematic view of an embodiment of a portion of an insitu heat treatment system for treating a hydrocarbon containingformation.

FIG. 3 depicts a schematic representation of an embodiment of a systemfor treating the mixture produced from an in situ heat treatmentprocess.

FIG. 4 depicts a schematic representation of an embodiment of a systemfor treating in situ heat conversion process gas.

FIG. 5 depicts a schematic representation of an embodiment of a systemfor treating in situ heat treatment process gas.

FIG. 6 depicts a schematic representation of an embodiment of a systemfor treating in situ heat treatment process gas.

FIG. 7 depicts a schematic representation of an embodiment of a systemfor treating in situ heat treatment process gas.

FIG. 8 depicts a schematic representation of an embodiment of a systemfor treating in situ heat treatment process gas.

FIG. 9 depicts a schematic representation of an embodiment of a systemfor treating a liquid stream produced from an in situ heat treatmentprocess.

FIG. 10 depicts a schematic representation of an embodiment of a systemfor forming and transporting tubing to a treatment area.

FIG. 11 depicts time versus rpm (revolutions per minute) for aconventional steerable motor bottom hole assembly during a drill bitdirection change.

FIG. 12 depicts an embodiment of a drilling string with dual motors on abottom hole assembly.

FIG. 13 depicts time versus rpm for a dual motor bottom hole assemblyduring a drill bit direction change.

FIG. 14 depicts an embodiment for assessing a position of a firstwellbore relative to a second wellbore using multiple magnets.

FIG. 15 depicts an embodiment for assessing a position of a firstwellbore relative to a second wellbore using a continuous pulsed signal.

FIG. 16 depicts an embodiment for assessing a position of a firstwellbore relative to a second wellbore using a radio ranging signal.

FIG. 17 depicts an embodiment for assessing a position of a plurality offirst wellbores relative to a plurality of second wellbores using radioranging signals.

FIGS. 18 and 19 depict an embodiment for assessing a position of a firstwellbore relative to a second wellbore using a heater assembly as acurrent conductor.

FIGS. 20 and 21 depict an embodiment for assessing a position of a firstwellbore relative to a second wellbore using two heater assemblies ascurrent conductors.

FIG. 22 depicts an embodiment of an umbilical positioning control systememploying a wireless linking system.

FIG. 23 depicts an embodiment of an umbilical positioning control systememploying a magnetic gradiometer system.

FIG. 24 depicts an embodiment of an umbilical positioning control systememploying a combination of systems being used in a first stage ofdeployment.

FIG. 25 depicts an embodiment of an umbilical positioning control systememploying a combination of systems being used in a second stage ofdeployment.

FIG. 26 depicts two examples of the relationship between power receivedand distance based upon two different formations with differentresistivities.

FIG. 27 depicts an embodiment of a drilling string with a non-rotatingsensor.

FIG. 28A depicts an embodiment of a drilling string including cuttingstructures positioned along the drilling string.

FIG. 28B depicts an embodiment of a drilling string including cuttingstructures positioned along the drilling string.

FIG. 28C depicts an embodiment of a drilling string including cuttingstructures positioned along the drilling string.

FIG. 29 depicts an embodiment of a drill bit including upward cuttingstructures.

FIG. 30 depicts an embodiment of a tubular including cutting structurespositioned in a wellbore.

FIG. 31 depicts a schematic drawing of an embodiment of a drillingsystem.

FIG. 32 depicts a schematic drawing of an embodiment of a drillingsystem for drilling into a hot formation.

FIG. 33 depicts a schematic drawing of an embodiment of a drillingsystem for drilling into a hot formation.

FIG. 34 depicts a schematic drawing of an embodiment of a drillingsystem for drilling into a hot formation.

FIG. 35 depicts an embodiment of a freeze well for a circulated liquidrefrigeration system, wherein a cutaway view of the freeze well isrepresented below ground surface.

FIG. 36 depicts a representation of a portion of a freeze wellembodiment.

FIG. 37 depicts an embodiment of a wellbore for introducing wax into aformation to form a wax barrier.

FIG. 38A depicts a representation of a wellbore drilled to anintermediate depth in a formation.

FIG. 38B depicts a representation of the wellbore drilled to the finaldepth in the formation.

FIGS. 39, 40, and 41 depict cross-sectional representations of anembodiment of a temperature limited heater with an outer conductorhaving a ferromagnetic section and a non-ferromagnetic section.

FIGS. 42, 43, 44, and 45 depict cross-sectional representations of anembodiment of a temperature limited heater with an outer conductorhaving a ferromagnetic section and a non-ferromagnetic section placedinside a sheath.

FIGS. 46A and 46B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 47A and 47B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 48A and 48B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 49A and 49B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIGS. 50A and 50B depict cross-sectional representations of anembodiment of a temperature limited heater.

FIG. 51 depicts a cross-sectional representation of an embodiment of acomposite conductor with a support member.

FIG. 52 depicts a cross-sectional representation of an embodiment of acomposite conductor with a support member separating the conductors.

FIG. 53 depicts a cross-sectional representation of an embodiment of acomposite conductor surrounding a support member.

FIG. 54 depicts a cross-sectional representation of an embodiment of acomposite conductor surrounding a conduit support member.

FIG. 55 depicts a cross-sectional representation of an embodiment of aconductor-in-conduit heat source.

FIG. 56 depicts a cross-sectional representation of an embodiment of aremovable conductor-in-conduit heat source.

FIG. 57 depicts a cross-sectional representation of an embodiment of atemperature limited heater in which the support member provides amajority of the heat output below the Curie temperature of theferromagnetic conductor.

FIGS. 58 and 59 depict cross-sectional representations of embodiments oftemperature limited heaters in which the jacket provides a majority ofthe heat output below the Curie temperature of the ferromagneticconductor.

FIGS. 60A and 60B depict cross-sectional representations of anembodiment of a temperature limited heater component used in aninsulated conductor heater.

FIG. 61 depicts a top view representation of three insulated conductorsin a conduit.

FIG. 62 depicts an embodiment of three-phase wye transformer coupled toa plurality of heaters.

FIG. 63 depicts a side view representation of an end section of threeinsulated conductors in a conduit.

FIG. 64 depicts an embodiment of a heater with three insulated cores ina conduit.

FIG. 65 depicts an embodiment of a heater with three insulatedconductors and an insulated return conductor in a conduit.

FIG. 66 depicts a cross-sectional representation of an embodiment ofthree insulated conductors banded together.

FIG. 67 depicts a cross-sectional representation of an embodiment ofthree insulated conductors banded together with a support member betweenthe insulated conductors.

FIG. 68 depicts an embodiment of an insulated conductor in a conduitwith liquid between the insulated conductor and the conduit.

FIG. 69 depicts an embodiment of an insulated conductor heater in aconduit with a conductive liquid between the insulated conductor and theconduit.

FIG. 70 depicts an embodiment of an insulated conductor in a conduitwith liquid between the insulated conductor and the conduit, where aportion of the conduit and the insulated conductor are orientedhorizontally in the formation.

FIG. 71 depicts a cross-sectional representation of a ribbed conduit.

FIG. 72 depicts a perspective representation of a portion of a ribbedconduit.

FIG. 73 depicts an embodiment of a portion of an insulated conductor ina bottom portion of an open wellbore with a liquid between the insulatedconductor and the formation.

FIG. 74 depicts a schematic cross-sectional representation of a portionof a formation with heat pipes positioned adjacent to a substantiallyhorizontal portion of a heat source.

FIG. 75 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with the heat pipe located radially around anoxidizer assembly.

FIG. 76 depicts a cross-sectional representation of an angled heat pipeembodiment with an oxidizer assembly located near a lowermost portion ofthe heat pipe.

FIG. 77 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with an oxidizer located at the bottom of the heatpipe.

FIG. 78 depicts a cross-sectional representation of an angled heat pipeembodiment with an oxidizer located at the bottom of the heat pipe.

FIG. 79 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with an oxidizer that produces a flame zoneadjacent to liquid heat transfer fluid in the bottom of the heat pipe.

FIG. 80 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with a tapered bottom that accommodates multipleoxidizers.

FIG. 81 depicts a cross-sectional representation of a heat pipeembodiment that is angled within the formation.

FIG. 82 depicts an embodiment of a three-phase temperature limitedheater with a portion shown in cross section.

FIG. 83 depicts an embodiment of temperature limited heaters coupledtogether in a three-phase configuration.

FIG. 84 depicts an embodiment of three heaters coupled in a three-phaseconfiguration.

FIG. 85 depicts a cross-sectional representation of an embodiment of acentralizer on a heater.

FIG. 86 depicts a cross-sectional view representation as viewed from theside of an embodiment of a centralizer on a heater.

FIG. 87 depicts a side view representation as viewed from the top of anembodiment of a substantially u-shaped three-phase heater in aformation.

FIG. 88 depicts a top view representation of an embodiment of aplurality of triads of three-phase heaters in a formation.

FIG. 89 depicts a top view representation of an embodiment of aplurality of triads of three-phase heaters in a formation withproduction wells.

FIG. 90 depicts a top view representation of an embodiment of aplurality of triads of three-phase heaters in a hexagonal pattern.

FIG. 91 depicts a top view representation of an embodiment of a hexagonfrom FIG. 90.

FIG. 92 depicts an embodiment of triads of heaters coupled to ahorizontal bus bar.

FIG. 93 depicts an embodiment of two temperature limited heaters coupledtogether in a single contacting section.

FIG. 94 depicts an embodiment of two temperature limited heaters withlegs coupled in a contacting section.

FIG. 95 depicts an embodiment of three diads coupled to a three-phasetransformer.

FIG. 96 depicts an embodiment of groups of diads in a hexagonal pattern.

FIG. 97 depicts an embodiment of diads in a triangular pattern.

FIG. 98 depicts a cross-sectional representation of an embodiment ofsubstantially u-shaped heaters in a formation.

FIG. 99 depicts a representational top view of an embodiment of asurface pattern of heaters depicted in FIG. 98.

FIG. 100 depicts a cross-sectional representation of substantiallyu-shaped heaters in a hydrocarbon layer.

FIG. 101 depicts a side view representation of an embodiment ofsubstantially vertical heaters coupled to a substantially horizontalwellbore.

FIG. 102 depicts an embodiment of pluralities of substantiallyhorizontal heaters coupled to bus bars in a hydrocarbon layer

FIG. 103 depicts an embodiment of pluralities of substantiallyhorizontal heaters coupled to bus bars in a hydrocarbon layer.

FIG. 104 depicts an embodiment of a bus bar coupled to heaters withconnectors.

FIG. 105 depicts an embodiment of a bus bar coupled to heaters withconnectors and centralizers.

FIG. 106 depicts a cross-sectional representation of a connectorcoupling to a bus bar.

FIG. 107 depicts a three-dimensional representation of a connectorcoupling to a bus bar.

FIG. 108 depicts an embodiment of three u-shaped heaters with commonoverburden sections coupled to a single three-phase transformer.

FIG. 109 depicts a top view representation of an embodiment of a heaterand a drilling guide in a wellbore.

FIG. 110 depicts a top view representation of an embodiment of twoheaters and a drilling guide in a wellbore.

FIG. 111 depicts a top view representation of an embodiment of threeheaters and a centralizer in a wellbore.

FIG. 112 depicts an embodiment for coupling ends of heaters in awellbore.

FIG. 113 depicts a schematic of an embodiment of multiple heatersextending in different directions from a wellbore.

FIG. 114 depicts a schematic of an embodiment of multiple levels ofheaters extending between two wellbores.

FIG. 115 depicts an embodiment of a u-shaped heater that has aninductively energized tubular.

FIG. 116 depicts an embodiment of an electrical conductor centralizedinside a tubular.

FIG. 117 depicts an embodiment of an induction heater with a sheath ofan insulated conductor in electrical contact with a tubular.

FIG. 118 depicts an embodiment of an induction heater with a tubularhaving radial grooved surfaces.

FIG. 119 depicts an embodiment of a heater divided into tubular sectionsto provide varying heat outputs along the length of the heater.

FIG. 120 depicts an embodiment of three electrical conductors enteringthe formation through a first common wellbore and exiting the formationthrough a second common wellbore with three tubulars surrounding theelectrical conductors in the hydrocarbon layer.

FIG. 121 depicts a representation of an embodiment of three electricalconductors and three tubulars in separate wellbores in the formationcoupled to a transformer.

FIG. 122 depicts an embodiment of a multilayer induction tubular.

FIG. 123 depicts a cross-sectional end view of an embodiment of aninsulated conductor that is used as an induction heater.

FIG. 124 depicts a cross-sectional side view of the embodiment depictedin FIG. 123.

FIG. 125 depicts a cross-sectional end view of an embodiment of atwo-leg insulated conductor that is used as an induction heater.

FIG. 126 depicts a cross-sectional side view of the embodiment depictedin FIG. 125.

FIG. 127 depicts a cross-sectional end view of an embodiment of amultilayered insulated conductor that is used as an induction heater.

FIG. 128 depicts an end view representation of an embodiment of threeinsulated conductors located in a coiled tubing conduit and used asinduction heaters.

FIG. 129 depicts a representation of cores of insulated conductorscoupled together at their ends.

FIG. 130 depicts an end view representation of an embodiment of threeinsulated conductors strapped to a support member and used as inductionheaters.

FIG. 131 depicts an embodiment of a casing having an axial grooved orcorrugated surface.

FIG. 132 depicts an embodiment of a single-ended, substantiallyhorizontal insulated conductor heater that electrically isolates itselffrom the formation.

FIGS. 133A and 133B depict cross-sectional representations of anembodiment of an insulated conductor that is electrically isolated onthe outside of the jacket.

FIG. 134 depicts a side view representation with a cut out portion of anembodiment of an insulated conductor inside a tubular.

FIG. 135 depicts a cross-sectional representation of an embodiment of aninsulated conductor inside a tubular taken substantially along line A-Aof FIG. 134.

FIG. 136 depicts a cross-sectional representation of an embodiment of adistal end of an insulated conductor inside a tubular.

FIG. 137 depicts an embodiment of a wellhead.

FIG. 138 depicts an embodiment of a heater that has been installed intwo parts.

FIG. 139 depicts an embodiment of a dual continuous tubular suspensionmechanism including threads cut on the dual continuous tubular over abuilt up portion.

FIG. 140 depicts an embodiment of a dual continuous tubular suspensionmechanism including a built up portion on a continuous tubular.

FIGS. 141A and 141B depict embodiments of dual continuous tubularsuspension mechanisms including slip mechanisms.

FIG. 142 depicts an embodiment of a dual continuous tubular suspensionmechanism including a slip mechanism and a screw lock system.

FIG. 143 depicts an embodiment of a dual continuous tubular suspensionmechanism including a slip mechanism and a screw lock system withcounter sunk bolts.

FIG. 144 depicts an embodiment of a pass-through fitting used to suspendtubulars.

FIG. 145 depicts an embodiment of a dual slip mechanism for inhibitingmovement of tubulars.

FIGS. 146A and 146B depict embodiments of split suspension mechanismsand split slip assemblies for hanging dual continuous tubulars.

FIG. 147 depicts an embodiment of a dual slip mechanism for inhibitingmovement of tubulars with a reverse configuration.

FIG. 148 depicts an embodiment of a two-part dual slip mechanism forinhibiting movement of tubulars.

FIG. 149 depicts an embodiment of a two-part dual slip mechanism forinhibiting movement of tubulars with separate locks.

FIG. 150 depicts an embodiment of a dual slip mechanism locking platefor inhibiting movement of tubulars.

FIG. 151 depicts an embodiment of a segmented dual slip mechanism withlocking screws for inhibiting movement of tubulars.

FIG. 152 depicts a top view representation of an embodiment of atransformer showing the windings and core of the transformer.

FIG. 153 depicts a side view representation of the embodiment of thetransformer showing the windings, the core, and the power leads.

FIG. 154 depicts an embodiment of a transformer in a wellbore.

FIG. 155 depicts an embodiment of a transformer in a wellbore with heatpipes.

FIG. 156 depicts a schematic for a conventional design of a tap changingvoltage regulator.

FIG. 157 depicts a schematic for a variable voltage, load tap changingtransformer.

FIG. 158 depicts a representation of an embodiment of a transformer anda controller.

FIG. 159 depicts a side view representation of an embodiment forproducing mobilized fluids from a tar sands formation with a relativelythin hydrocarbon layer.

FIG. 160 depicts a side view representation of an embodiment forproducing mobilized fluids from a tar sands formation with a hydrocarbonlayer that is thicker than the hydrocarbon layer depicted in FIG. 159.

FIG. 161 depicts a side view representation of an embodiment forproducing mobilized fluids from a tar sands formation with a hydrocarbonlayer that is thicker than the hydrocarbon layer depicted in FIG. 160.

FIG. 162 depicts a side view representation of an embodiment forproducing mobilized fluids from a tar sands formation with a hydrocarbonlayer that has a shale break.

FIG. 163 depicts a top view representation of an embodiment forpreheating using heaters for the drive process.

FIG. 164 depicts a perspective representation of an embodiment forpreheating using heaters for the drive process.

FIG. 165 depicts a side view representation of an embodiment of a tarsands formation subsequent to a steam injection process.

FIG. 166 depicts a side view representation of an embodiment using atleast three treatment sections in a tar sands formation.

FIG. 167 depicts a representation of an embodiment for producinghydrocarbons from a tar sands formation.

FIG. 168 depicts a representation of an embodiment for producinghydrocarbons from multiple layers in a tar sands formation.

FIG. 169 depicts an embodiment for heating and producing from aformation with a temperature limited heater in a production wellbore.

FIG. 170 depicts an embodiment for heating and producing from aformation with a temperature limited heater and a production wellbore.

FIG. 171 depicts an embodiment of a first stage of treating a tar sandsformation with electrical heaters.

FIG. 172 depicts an embodiment of a second stage of treating a tar sandsformation with fluid injection and oxidation.

FIG. 173 depicts an embodiment of a third stage of treating a tar sandsformation with fluid injection and oxidation.

FIG. 174 depicts a schematic representation of an embodiment of adownhole oxidizer assembly.

FIG. 175 depicts a schematic representation of an embodiment of a systemfor producing fuel for downhole oxidizer assemblies.

FIG. 176 depicts a schematic representation of an embodiment of a systemfor producing oxygen for use in downhole oxidizer assemblies.

FIG. 177 depicts a schematic representation of an embodiment of a systemfor producing oxygen for use in downhole oxidizer assemblies.

FIG. 178 depicts a schematic representation of an embodiment of a systemfor producing hydrogen for use in downhole oxidizer assemblies.

FIG. 179 depicts a cross-sectional representation of an embodiment of adownhole oxidizer including an insulating sleeve.

FIG. 180 depicts a cross-sectional representation of an embodiment of adownhole oxidizer with a gas cooled insulating sleeve.

FIG. 181 depicts a perspective view of an embodiment of a portion of anoxidizer of a downhole oxidizer assembly.

FIG. 182 depicts a cross-sectional representation of an embodiment of anoxidizer shield.

FIG. 183 depicts a cross-sectional representation of an embodiment of anoxidizer shield.

FIG. 184 depicts a cross-sectional representation of an embodiment of anoxidizer shield.

FIG. 185 depicts a cross-sectional representation of an embodiment of anoxidizer shield.

FIG. 186 depicts a cross-sectional representation of an embodiment of anoxidizer shield with multiple flame stabilizers.

FIG. 187 depicts a cross-sectional representation of an embodiment of anoxidizer shield.

FIG. 188 depicts a perspective representation of an embodiment of aportion of an oxidizer of a downhole oxidizer assembly with louveredopenings in the shield.

FIG. 189 depicts a cross-sectional representation of a portion of ashield with a louvered opening.

FIG. 190 depicts a perspective representation of an embodiment of asectioned oxidizer.

FIG. 191 depicts a perspective representation of an embodiment of asectioned oxidizer.

FIG. 192 depicts a perspective representation of an embodiment of asectioned oxidizer.

FIG. 193 depicts a cross-sectional representation of an embodiment of afirst oxidizer of an oxidizer assembly.

FIG. 194 depicts a cross-sectional representation of an embodiment of acatalytic burner.

FIG. 195 depicts a cross-sectional representation of an embodiment of acatalytic burner with an igniter.

FIG. 196 depicts a cross-sectional representation of an oxidizerassembly.

FIG. 197 depicts a cross-sectional representation of an oxidizer of anoxidizer assembly.

FIG. 198 depicts a schematic representation of an oxidizer assembly withflameless distributed combustors and oxidizers.

FIG. 199 depicts a schematic representation of an embodiment of adownhole oxidizer assembly.

FIG. 200 depicts a schematic representation of an embodiment of adownhole oxidizer assembly.

FIG. 201 depicts a schematic representation of an embodiment of a heaterthat uses coal as fuel.

FIG. 202 depicts a schematic representation of an embodiment of a heaterthat uses coal as fuel.

FIG. 203 depicts a schematic representation of an embodiment of adownhole fluid heating system.

FIG. 204 depicts an embodiment of a wellbore for heating a formationusing a burning fuel moving through the formation.

FIG. 205 depicts a top view representation of a portion of the fueltrain used to heat the treatment area.

FIG. 206 depicts a side view representation of a portion of the fueltrain used to heat the treatment area.

FIG. 207 depicts an aerial view representation of a system that heatsthe treatment area using burning fuel that is moved through thetreatment area.

FIG. 208 depicts a schematic representation of a closed loop circulationsystem for heating a portion of a formation.

FIG. 209 depicts a plan view of wellbore entries and exits from aportion of a formation to be heated using a closed loop circulationsystem.

FIG. 210 depicts a representation of piping of a circulation system withan insulated conductor heater positioned in the piping.

FIG. 211 depicts a side view representation of an embodiment of a systemfor heating the formation that can use a closed loop circulation systemand/or electrical heating.

FIG. 212 depicts a schematic representation of an embodiment of a systemfor heating the formation using gas lift to return the heat transferfluid to the surface.

FIG. 213 depicts a schematic representation of an embodiment of an insitu heat treatment system that uses a nuclear reactor.

FIG. 214 depicts an elevational view of an in situ heat treatment systemusing pebble bed reactors.

FIG. 215 depicts a side view representation of an embodiment for an insitu staged heating and production process for treating a tar sandsformation.

FIG. 216 depicts a top view of a rectangular checkerboard patternembodiment for the in situ staged heating and production process.

FIG. 217 depicts a top view of a ring pattern embodiment for the in situstaged heating and production process.

FIG. 218 depicts a top view of a checkerboard ring pattern embodimentfor the in situ staged heating and production process.

FIG. 219 depicts a top view an embodiment of a plurality of rectangularcheckerboard patterns in a treatment area for the in situ staged heatingand production process.

FIG. 220 depicts an embodiment of varied heater spacing around aproduction well.

FIG. 221 depicts a side view representation of embodiments for producingmobilized fluids from a hydrocarbon formation.

FIG. 222 depicts a side view representation of an embodiment forproducing mobilized fluids from a hydrocarbon formation heated byresidual heat.

FIG. 223 depicts a schematic representation of a system for inhibitingmigration of formation fluid from a treatment area.

FIG. 224 depicts an embodiment of a windmill for generating electricityfor subsurface heaters.

FIG. 225 depicts an embodiment of a solution mining well.

FIG. 226 depicts a representation of a portion of a solution miningwell.

FIG. 227 depicts a representation of a portion of a solution miningwell.

FIG. 228 depicts an elevational view of a well pattern for solutionmining and/or an in situ heat treatment process.

FIG. 229 depicts a representation of wells of an in situ heatingtreatment process for solution mining and producing hydrocarbons from aformation.

FIG. 230 depicts an embodiment for solution mining a formation.

FIG. 231 depicts an embodiment of a formation with nahcolite layers inthe formation before solution mining nahcolite from the formation.

FIG. 232 depicts the formation of FIG. 231 after the nahcolite has beensolution mined.

FIG. 233 depicts an embodiment of two injection wells interconnected bya zone that has been solution mined to remove nahcolite from the zone.

FIG. 234 depicts an embodiment for heating a formation with dawsonite inthe formation.

FIG. 235 depicts a representation of an embodiment for solution miningwith a steam and electricity cogeneration facility.

FIG. 236 depicts an embodiment of treating a hydrocarbon containingformation with a combustion front.

FIG. 237 depicts a representation of an embodiment for treating ahydrocarbon containing formation with a combustion front.

FIG. 238 depicts a schematic representation of a system for producingformation fluid and introducing sour gas into a subsurface formation.

FIG. 239 depicts a schematic representation of a circulated fluidcooling system.

FIG. 240 depicts a perspective view of an embodiment of an undergroundtreatment system.

FIG. 241 depicts a perspective view of tunnels of an embodiment of anunderground treatment system.

FIG. 242 depicts a perspective of an embodiment of an undergroundtreatment system having heat wellbores spanning between to two tunnelsof the underground treatment system.

FIG. 243 depicts a perspective of an embodiment of an undergroundtreatment system having wellbores extending from the surface thatintersect tunnels of the underground treatment system.

FIG. 244 depicts a schematic of tunnel sections of an embodiment of anunderground treatment system.

FIG. 245 depicts a schematic view of an embodiment of an undergroundtreatment system with surface production.

FIG. 246 depicts electrical resistance versus temperature at variousapplied electrical currents for a 446 stainless steel rod.

FIG. 247 shows resistance profiles as a function of temperature atvarious applied electrical currents for a copper rod contained in aconduit of Sumitomo HCM12A.

FIG. 248 depicts electrical resistance versus temperature at variousapplied electrical currents for a temperature limited heater.

FIG. 249 depicts raw data for a temperature limited heater.

FIG. 250 depicts electrical resistance versus temperature at variousapplied electrical currents for a temperature limited heater.

FIG. 251 depicts power versus temperature at various applied electricalcurrents for a temperature limited heater.

FIG. 252 depicts electrical resistance versus temperature at variousapplied electrical currents for a temperature limited heater.

FIG. 253 depicts data of electrical resistance versus temperature for asolid 2.54 cm diameter, 1.8 m long 410 stainless steel rod at variousapplied electrical currents.

FIG. 254 depicts data of electrical resistance versus temperature for acomposite 1.9 cm, 1.8 m long alloy 42-6 rod with a copper core (the rodhas an outside diameter to copper diameter ratio of 2:1) at variousapplied electrical currents.

FIG. 255 depicts data of power output versus temperature for a composite1.9 cm, 1.8 m long alloy 42-6 rod with a copper core (the rod has anoutside diameter to copper diameter ratio of 2:1) at various appliedelectrical currents.

FIG. 256 depicts data for values of skin depth versus temperature for asolid 2.54 cm diameter, 1.8 m long 410 stainless steel rod at variousapplied AC electrical currents.

FIG. 257 depicts temperature versus time for a temperature limitedheater.

FIG. 258 depicts temperature versus log time data for a 2.5 cm solid 410stainless steel rod and a 2.5 cm solid 304 stainless steel rod.

FIG. 259 depicts experimentally measured resistance versus temperatureat several currents for a temperature limited heater with a copper core,a carbon steel ferromagnetic conductor, and a 347H stainless steelsupport member.

FIG. 260 depicts experimentally measured resistance versus temperatureat several currents for a temperature limited heater with a copper core,an iron-cobalt ferromagnetic conductor, and a 347H stainless steelsupport member.

FIG. 261 depicts experimentally measured power factor versus temperatureat two AC currents for a temperature limited heater with a copper core,a carbon steel ferromagnetic conductor, and a 347H stainless steelsupport member.

FIG. 262 depicts experimentally measured turndown ratio versus maximumpower delivered for a temperature limited heater with a copper core, acarbon steel ferromagnetic conductor, and a 347H stainless steel supportmember.

FIG. 263 depicts examples of relative magnetic permeability versusmagnetic field for both the found correlations and raw data for carbonsteel.

FIG. 264 shows the resulting plots of skin depth versus magnetic fieldfor four temperatures and 400 A current.

FIG. 265 shows a comparison between the experimental and numerical(calculated) AC resistances for currents of 300 A, 400 A, and 500 A.

FIG. 266 shows the AC resistance per foot of the heater element as afunction of skin depth at 1100° F. calculated from the theoreticalmodel.

FIG. 267 depicts the power generated per unit length in each heatercomponent versus skin depth for a temperature limited heater.

FIGS. 268A-C compare the results of theoretical calculations withexperimental data for resistance versus temperature in a temperaturelimited heater.

FIG. 269 displays temperature of the center conductor of aconductor-in-conduit heater as a function of formation depth for a Curietemperature heater with a turndown ratio of 2:1.

FIG. 270 displays heater heat flux through a formation for a turndownratio of 2:1 along with the oil shale richness profile.

FIG. 271 displays heater temperature as a function of formation depthfor a turndown ratio of 3:1.

FIG. 272 displays heater heat flux through a formation for a turndownratio of 3:1 along with the oil shale richness profile.

FIG. 273 displays heater temperature as a function of formation depthfor a turndown ratio of 4:1.

FIG. 274 depicts heater temperature versus depth for heaters used in asimulation for heating oil shale.

FIG. 275 depicts heater heat flux versus time for heaters used in asimulation for heating oil shale.

FIG. 276 depicts accumulated heat input versus time in a simulation forheating oil shale.

FIG. 277 depicts a plot of heater power versus core diameter.

FIG. 278 depicts power, resistance, and current versus temperature for aheater with core diameters of 0.105″.

FIG. 279 depicts actual heater power versus time during the simulationfor three different heater designs.

FIG. 280 depicts heater element temperature (core temperature) andaverage formation temperature versus time for three different heaterdesigns.

FIG. 281 depicts plots of power versus temperature at the three currentsfor an induction heater.

FIG. 282 depicts temperature versus radial distance for a heater withair between an insulated conductor and conduit.

FIG. 283 depicts temperature versus radial distance for a heater withmolten solar salt between an insulated conductor and conduit.

FIG. 284 depicts temperature versus radial distance for a heater withmolten tin between an insulated conductor and conduit.

FIG. 285 depicts simulated temperature versus radial distance forvarious heaters of a first size, with various fluids between theinsulated conductors and conduits, and at different temperatures of theouter surfaces of the conduits.

FIG. 286 depicts simulated temperature versus radial distance forvarious heaters wherein the dimensions of the insulated conductor arehalf the size of the insulated conductor used to generate FIG. 285, withvarious fluids between the insulated conductors and conduits, and atdifferent temperatures of the outer surfaces of the conduits.

FIG. 287 depicts simulated temperature versus radial distance forvarious heaters wherein the dimensions of the insulated conductor is thesame as the insulated conductor used to generate FIG. 286, and theconduit is larger than the conduit used to generate FIG. 286 withvarious fluids between the insulated conductors and conduits, and atvarious temperatures of the outer surfaces of the conduits.

FIG. 288 depicts simulated temperature versus radial distance forvarious heaters with molten salt between insulated conductors andconduits of the heaters and a boundary condition of 500° C.

FIG. 289 depicts a temperature profile in the formation after 360 daysusing the STARS simulation.

FIG. 290 depicts an oil saturation profile in the formation after 360days using the STARS simulation.

FIG. 291 depicts the oil saturation profile in the formation after 1095days using the STARS simulation.

FIG. 292 depicts the oil saturation profile in the formation after 1470days using the STARS simulation.

FIG. 293 depicts the oil saturation profile in the formation after 1826days using the STARS simulation.

FIG. 294 depicts the temperature profile in the formation after 1826days using the STARS simulation.

FIG. 295 depicts oil production rate and gas production rate versustime.

FIG. 296 depicts weight percentage of original bitumen in place(OBIP)(left axis) and volume percentage of OBIP (right axis) versustemperature (° C.).

FIG. 297 depicts bitumen conversion percentage (weight percentage of(OBIP))(left axis) and oil, gas, and coke weight percentage (as a weightpercentage of OBIP)(right axis) versus temperature (° C.).

FIG. 298 depicts API gravity (°)(left axis) of produced fluids, blowdown production, and oil left in place along with pressure (psig)(rightaxis) versus temperature (° C.).

FIG. 299A-D depict gas-to-oil ratios (GOR) in thousand cubic feet perbarrel ((Mcf/bbl)(y-axis) versus temperature (° C.)(x-axis) fordifferent types of gas at a low temperature blow down (about 277° C.)and a high temperature blow down (at about 290° C.).

FIG. 300 depicts coke yield (weight percentage)(y-axis) versustemperature (° C.)(x-axis).

FIG. 301-D depict assessed hydrocarbon isomer shifts in fluids producedfrom the experimental cells as a function of temperature and bitumenconversion.

FIG. 302 depicts weight percentage (Wt %)(y-axis) of saturates from SARAanalysis of the produced fluids versus temperature (° C.)(x-axis).

FIG. 303 depicts weight percentage (Wt %)(y-axis) of n-C₇ of theproduced fluids versus temperature (° C.)(x-axis).

FIG. 304 depicts oil recovery (volume percentage bitumen in place (vol %BIP)) versus API gravity (°) as determined by the pressure (MPa) in theformation in an experiment.

FIG. 305 depicts recovery efficiency (%) versus temperature (° C.) atdifferent pressures in an experiment.

While the invention is susceptible to various modifications andalternative forms, specific embodiments thereof are shown by way ofexample in the drawings and may herein be described in detail. Thedrawings may not be to scale. It should be understood, however, that thedrawings and detailed description thereto are not intended to limit theinvention to the particular form disclosed, but on the contrary, theintention is to cover all modifications, equivalents and alternativesfalling within the spirit and scope of the present invention as definedby the appended claims.

DETAILED DESCRIPTION

The following description generally relates to systems and methods fortreating hydrocarbons in the formations. Such formations may be treatedto yield hydrocarbon products, hydrogen, and other products.

“Alternating current (AC)” refers to a time-varying current thatreverses direction substantially sinusoidally. AC produces skin effectelectricity flow in a ferromagnetic conductor.

“API gravity” refers to API gravity at 15.5° C. (60° F.). API gravity isas determined by ASTM Method D6822 or ASTM Method D1298.

“ASTM” refers to American Standard Testing and Materials.

In the context of reduced heat output heating systems, apparatus, andmethods, the term “automatically” means such systems, apparatus, andmethods function in a certain way without the use of external control(for example, external controllers such as a controller with atemperature sensor and a feedback loop, PID controller, or predictivecontroller).

“Bare metal” and “exposed metal” refer to metals of elongated membersthat do not include a layer of electrical insulation, such as mineralinsulation, that is designed to provide electrical insulation for themetal throughout an operating temperature range of the elongated member.Bare metal and exposed metal may encompass a metal that includes acorrosion inhibiter such as a naturally occurring oxidation layer, anapplied oxidation layer, and/or a film. Bare metal and exposed metalinclude metals with polymeric or other types of electrical insulationthat cannot retain electrical insulating properties at typical operatingtemperature of the elongated member. Such material may be placed on themetal and may be thermally degraded during use of the heater.

Boiling range distributions for the formation fluid and liquid streamsdescribed herein are as determined by ASTM Method D5307 or ASTM MethodD2887. Content of hydrocarbon components in weight percent forparaffins, iso-paraffins, olefins, naphthenes and aromatics in theliquid streams is as determined by ASTM Method D6730. Content ofaromatics in volume percent is as determined by ASTM Method D1319.Weight percent of hydrogen in hydrocarbons is as determined by ASTMMethod D3343.

“Bromine number” refers to a weight percentage of olefins in grams per100 gram of portion of the produced fluid that has a boiling range below246° C. and testing the portion using ASTM Method D1159.

“Carbon number” refers to the number of carbon atoms in a molecule. Ahydrocarbon fluid may include various hydrocarbons with different carbonnumbers. The hydrocarbon fluid may be described by a carbon numberdistribution. Carbon numbers and/or carbon number distributions may bedetermined by true boiling point distribution and/or gas-liquidchromatography.

“Cenospheres” refers to hollow particulates that are formed in thermalprocesses at high temperatures when molten components are blown up likeballoons by the volatilization of organic components.

“Chemically stability” refers to the ability of a formation fluid to betransported without components in the formation fluid reacting to formpolymers and/or compositions that plug pipelines, valves, and/orvessels.

“Clogging” refers to impeding and/or inhibiting flow of one or morecompositions through a process vessel or a conduit.

“Column X element” or “Column X elements” refer to one or more elementsof Column X of the Periodic Table, and/or one or more compounds of oneor more elements of Column X of the Periodic Table, in which Xcorresponds to a column number (for example, 13-18) of the PeriodicTable. For example, “Column 15 elements” refer to elements from Column15 of the Periodic Table and/or compounds of one or more elements fromColumn 15 of the Periodic Table.

“Column X metal” or “Column X metals” refer to one or more metals ofColumn X of the Periodic Table and/or one or more compounds of one ormore metals of Column X of the Periodic Table, in which X corresponds toa column number (for example, 1-12) of the Periodic Table. For example,“Column 6 metals” refer to metals from Column 6 of the Periodic Tableand/or compounds of one or more metals from Column 6 of the PeriodicTable.

“Condensable hydrocarbons” are hydrocarbons that condense at 25° C. andone atmosphere absolute pressure. Condensable hydrocarbons may include amixture of hydrocarbons having carbon numbers greater than 4.“Non-condensable hydrocarbons” are hydrocarbons that do not condense at25° C. and one atmosphere absolute pressure. Non-condensablehydrocarbons may include hydrocarbons having carbon numbers less than 5.

“Coring” is a process that generally includes drilling a hole into aformation and removing a substantially solid mass of the formation fromthe hole.

“Cracking” refers to a process involving decomposition and molecularrecombination of organic compounds to produce a greater number ofmolecules than were initially present. In cracking, a series ofreactions take place accompanied by a transfer of hydrogen atoms betweenmolecules. For example, naphtha may undergo a thermal cracking reactionto form ethene and H₂.

“Curie temperature” is the temperature above which a ferromagneticmaterial loses all of its ferromagnetic properties. In addition tolosing all of its ferromagnetic properties above the Curie temperature,the ferromagnetic material begins to lose its ferromagnetic propertieswhen an increasing electrical current is passed through theferromagnetic material.

“Cycle oil” refers to a mixture of light cycle oil and heavy cycle oil.“Light cycle oil” refers to hydrocarbons having a boiling rangedistribution between 430° F. (221° C.) and 650° F. (343° C.) that areproduced from a fluidized catalytic cracking system. Light cycle oilcontent is determined by ASTM Method D5307. “Heavy cycle oil” refers tohydrocarbons having a boiling range distribution between 650° F. (343°C.) and 800° F. (427° C.) that are produced from a fluidized catalyticcracking system. Heavy cycle oil content is determined by ASTM MethodD5307.

“Diad” refers to a group of two items (for example, heaters, wellbores,or other objects) coupled together.

“Diesel” refers to hydrocarbons with a boiling range distributionbetween 260° C. and 343° C. (500-650° F.) at 0.101 MPa. Diesel contentis determined by ASTM Method D2887.

“Enriched air” refers to air having a larger mole fraction of oxygenthan air in the atmosphere. Air is typically enriched to increasecombustion-supporting ability of the air.

“Fluid pressure” is a pressure generated by a fluid in a formation.“Lithostatic pressure” (sometimes referred to as “lithostatic stress”)is a pressure in a formation equal to a weight per unit area of anoverlying rock mass. “Hydrostatic pressure” is a pressure in a formationexerted by a column of water.

A “formation” includes one or more hydrocarbon containing layers, one ormore non-hydrocarbon layers, an overburden, and/or an underburden.“Hydrocarbon layers” refer to layers in the formation that containhydrocarbons. The hydrocarbon layers may contain non-hydrocarbonmaterial and hydrocarbon material. The “overburden” and/or the“underburden” include one or more different types of impermeablematerials. For example, the overburden and/or underburden may includerock, shale, mudstone, or wet/tight carbonate. In some embodiments of insitu heat treatment processes, the overburden and/or the underburden mayinclude a hydrocarbon containing layer or hydrocarbon containing layersthat are relatively impermeable and are not subjected to temperaturesduring in situ heat treatment processing that result in significantcharacteristic changes of the hydrocarbon containing layers of theoverburden and/or the underburden. For example, the underburden maycontain shale or mudstone, but the underburden is not allowed to heat topyrolysis temperatures during the in situ heat treatment process. Insome cases, the overburden and/or the underburden may be somewhatpermeable.

“Formation fluids” refer to fluids present in a formation and mayinclude pyrolyzation fluid, synthesis gas, mobilized hydrocarbons, andwater (steam). Formation fluids may include hydrocarbon fluids as wellas non-hydrocarbon fluids. The term “mobilized fluid” refers to fluidsin a hydrocarbon containing formation that are able to flow as a resultof thermal treatment of the formation. “Produced fluids” refer to fluidsremoved from the formation.

“Freezing point” of a hydrocarbon liquid refers to the temperature belowwhich solid hydrocarbon crystals may form in the liquid. Freezing pointis as determined by ASTM Method D5901.

“Gasoline hydrocarbons” refer to hydrocarbons having a boiling pointrange from 32° C. (90° F.) to about 204° C. (400° F.). Gasolinehydrocarbons include, but are not limited to, straight run gasoline,naphtha, fluidized or thermally catalytically cracked gasoline, VBgasoline, and coker gasoline. Gasoline hydrocarbons content isdetermined by ASTM Method D2887.

“Heat of Combustion” refers to an estimation of the net heat ofcombustion of a liquid. Heat of combustion is as determined by ASTMMethod D3338.

A “heat source” is any system for providing heat to at least a portionof a formation substantially by conductive and/or radiative heattransfer. For example, a heat source may include electric heaters suchas an insulated conductor, an elongated member, and/or a conductordisposed in a conduit. A heat source may also include systems thatgenerate heat by burning a fuel external to or in a formation. Thesystems may be surface burners, downhole gas burners, flamelessdistributed combustors, and natural distributed combustors. In someembodiments, heat provided to or generated in one or more heat sourcesmay be supplied by other sources of energy. The other sources of energymay directly heat a formation, or the energy may be applied to atransfer medium that directly or indirectly heats the formation. It isto be understood that one or more heat sources that are applying heat toa formation may use different sources of energy. Thus, for example, fora given formation some heat sources may supply heat from electricresistance heaters, some heat sources may provide heat from combustion,and some heat sources may provide heat from one or more other energysources (for example, chemical reactions, solar energy, wind energy,biomass, or other sources of renewable energy). A chemical reaction mayinclude an exothermic reaction (for example, an oxidation reaction). Aheat source may also include a heater that provides heat to a zoneproximate and/or surrounding a heating location such as a heater well.

A “heater” is any system or heat source for generating heat in a well ora near wellbore region. Heaters may be, but are not limited to, electricheaters, burners, combustors that react with material in or producedfrom a formation, and/or combinations thereof.

“Heavy hydrocarbons” are viscous hydrocarbon fluids. Heavy hydrocarbonsmay include highly viscous hydrocarbon fluids such as heavy oil, tar,and/or asphalt. Heavy hydrocarbons may include carbon and hydrogen, aswell as smaller concentrations of sulfur, oxygen, and nitrogen.Additional elements may also be present in heavy hydrocarbons in traceamounts. Heavy hydrocarbons may be classified by API gravity. Heavyhydrocarbons generally have an API gravity below about 20°. Heavy oil,for example, generally has an API gravity of about 10-20°, whereas targenerally has an API gravity below about 10°. The viscosity of heavyhydrocarbons is generally greater than about 100 centipoise at 15° C.Heavy hydrocarbons may include aromatics or other complex ringhydrocarbons.

Heavy hydrocarbons may be found in a relatively permeable formation. Therelatively permeable formation may include heavy hydrocarbons entrainedin, for example, sand or carbonate. “Relatively permeable” is defined,with respect to formations or portions thereof, as an averagepermeability of 10 millidarcy or more (for example, 10 or 100millidarcy). “Relatively low permeability” is defined, with respect toformations or portions thereof, as an average permeability of less thanabout 10 millidarcy. One darcy is equal to about 0.99 squaremicrometers. An impermeable layer generally has a permeability of lessthan about 0.1 millidarcy.

Certain types of formations that include heavy hydrocarbons may alsoinclude, but are not limited to, natural mineral waxes, or naturalasphaltites. “Natural mineral waxes” typically occur in substantiallytubular veins that may be several meters wide, several kilometers long,and hundreds of meters deep. “Natural asphaltites” include solidhydrocarbons of an aromatic composition and typically occur in largeveins. In situ recovery of hydrocarbons from formations such as naturalmineral waxes and natural asphaltites may include melting to form liquidhydrocarbons and/or solution mining of hydrocarbons from the formations.

“Hydrocarbons” are generally defined as molecules formed primarily bycarbon and hydrogen atoms. Hydrocarbons may also include other elementssuch as, but not limited to, halogens, metallic elements, nitrogen,oxygen, and/or sulfur. Hydrocarbons may be, but are not limited to,kerogen, bitumen, pyrobitumen, oils, natural mineral waxes, andasphaltites. Hydrocarbons may be located in or adjacent to mineralmatrices in the earth. Matrices may include, but are not limited to,sedimentary rock, sands, silicilytes, carbonates, diatomites, and otherporous media. “Hydrocarbon fluids” are fluids that include hydrocarbons.Hydrocarbon fluids may include, entrain, or be entrained innon-hydrocarbon fluids such as hydrogen, nitrogen, carbon monoxide,carbon dioxide, hydrogen sulfide, water, and ammonia.

An “in situ conversion process” refers to a process of heating ahydrocarbon containing formation from heat sources to raise thetemperature of at least a portion of the formation above a pyrolysistemperature so that pyrolyzation fluid is produced in the formation.

An “in situ heat treatment process” refers to a process of heating ahydrocarbon containing formation with heat sources to raise thetemperature of at least a portion of the formation above a temperaturethat results in mobilized fluid, visbreaking, and/or pyrolysis ofhydrocarbon containing material so that mobilized fluids, visbrokenfluids, and/or pyrolyzation fluids are produced in the formation.

“Insulated conductor” refers to any elongated material that is able toconduct electricity and that is covered, in whole or in part, by anelectrically insulating material.

“Karst” is a subsurface shaped by the dissolution of a soluble layer orlayers of bedrock, usually carbonate rock such as limestone or dolomite.The dissolution may be caused by meteoric or acidic water. The Grosmontformation in Alberta, Canada is an example of a karst (or “karsted”)carbonate formation.

“Kerogen” is a solid, insoluble hydrocarbon that has been converted bynatural degradation and that principally contains carbon, hydrogen,nitrogen, oxygen, and sulfur. Coal and oil shale are typical examples ofmaterials that contain kerogen. “Bitumen” is a non-crystalline solid orviscous hydrocarbon material that is substantially soluble in carbondisulfide. “Oil” is a fluid containing a mixture of condensablehydrocarbons.

“Kerosene” refers to hydrocarbons with a boiling range distributionbetween 204° C. and 260° C. at 0.101 MPa. Kerosene content is determinedby ASTM Method D2887.

“Modulated direct current (DC)” refers to any substantiallynon-sinusoidal time-varying current that produces skin effectelectricity flow in a ferromagnetic conductor.

“Naphtha” refers to hydrocarbon components with a boiling rangedistribution between 38° C. and 200° C. at 0.101 MPa. Naphtha content isdetermined by ASTM Method D5307.

“Nitride” refers to a compound of nitrogen and one or more otherelements of the Periodic Table. Nitrides include, but are not limitedto, silicon nitride, boron nitride, or alumina nitride.

“Nitrogen compound content” refers to an amount of nitrogen in anorganic compound. Nitrogen content is as determined by ASTM MethodD5762.

“Octane Number” refers to a calculated numerical representation of theantiknock properties of a motor fuel compared to a standard referencefuel. A calculated octane number is determined by ASTM Method D6730.

“Olefins” are molecules that include unsaturated hydrocarbons having oneor more non-aromatic carbon-carbon double bonds.

“Olefin content” refers to an amount of non-aromatic olefins in a fluid.Olefin content for a produced fluid is determined by obtaining a portionof the produce fluid that has a boiling point of 246° C. and testing theportion using ASTM Method D1159 and reporting the result as a brominefactor in grams per 100 gram of portion. Olefin content is alsodetermined by the Canadian Association of Petroleum Producers (CAPP)olefin method and is reported in percent olefin as 1-decene equivalent.

“Orifices” refer to openings, such as openings in conduits, having awide variety of sizes and cross-sectional shapes including, but notlimited to, circles, ovals, squares, rectangles, triangles, slits, orother regular or irregular shapes.

“P (peptization) value” or “P-value” refers to a numerical value, whichrepresents the flocculation tendency of asphaltenes in a formationfluid. P-value is determined by ASTM method D7060.

“Pebble” refers to one or more spheres, oval shapes, oblong shapes,irregular or elongated shapes.

“Periodic Table” refers to the Periodic Table as specified by theInternational Union of Pure and Applied Chemistry (IUPAC), November2003. In the scope of this application, weight of a metal from thePeriodic Table, weight of a compound of a metal from the Periodic Table,weight of an element from the Periodic Table, or weight of a compound ofan element from the Periodic Table is calculated as the weight of metalor the weight of element. For example, if 0.1 grams of MoO₃ is used pergram of catalyst, the calculated weight of the molybdenum metal in thecatalyst is 0.067 grams per gram of catalyst.

“Physical stability” refers the ability of a formation fluid to notexhibit phase separation or flocculation during transportation of thefluid. Physical stability is determined by ASTM Method D7060.

“Pyrolysis” is the breaking of chemical bonds due to the application ofheat. For example, pyrolysis may include transforming a compound intoone or more other substances by heat alone. Heat may be transferred to asection of the formation to cause pyrolysis.

“Pyrolyzation fluids” or “pyrolysis products” refers to fluid producedsubstantially during pyrolysis of hydrocarbons. Fluid produced bypyrolysis reactions may mix with other fluids in a formation. Themixture would be considered pyrolyzation fluid or pyrolyzation product.As used herein, “pyrolysis zone” refers to a volume of a formation (forexample, a relatively permeable formation such as a tar sands formation)that is reacted or reacting to form a pyrolyzation fluid.

“Residue” refers to hydrocarbons that have a boiling point above 537° C.(1000° F.).

“Rich layers” in a hydrocarbon containing formation are relatively thinlayers (typically about 0.2 m to about 0.5 m thick). Rich layersgenerally have a richness of about 0.150 L/kg or greater. Some richlayers have a richness of about 0.170 L/kg or greater, of about 0.190L/kg or greater, or of about 0.210 L/kg or greater. Lean layers of theformation have a richness of about 0.100 L/kg or less and are generallythicker than rich layers. The richness and locations of layers aredetermined, for example, by coring and subsequent Fischer assay of thecore, density or neutron logging, or other logging methods. Rich layersmay have a lower initial thermal conductivity than other layers of theformation. Typically, rich layers have a thermal conductivity 1.5 timesto 3 times lower than the thermal conductivity of lean layers. Inaddition, rich layers have a higher thermal expansion coefficient thanlean layers of the formation.

“Smart well technology” or “smart wellbore” refers to wells thatincorporate downhole measurement and/or control. For injection wells,smart well technology may allow for controlled injection of fluid intothe formation in desired zones. For production wells, smart welltechnology may allow for controlled production of formation fluid fromselected zones. Some wells may include smart well technology that allowsfor formation fluid production from selected zones and simultaneous orstaggered solution injection into other zones. Smart well technology mayinclude fiber optic systems and control valves in the wellbore. A smartwellbore used for an in situ heat treatment process may be WestbayMultilevel Well System MP55 available from Westbay Instruments Inc.(Burnaby, British Columbia, Canada).

“Subsidence” is a downward movement of a portion of a formation relativeto an initial elevation of the surface.

“Sulfur compound content” refers to an amount of sulfur in an organiccompound. Sulfur content is as determined by ASTM Method D4294.

“Superposition of heat” refers to providing heat from two or more heatsources to a selected section of a formation such that the temperatureof the formation at least at one location between the heat sources isinfluenced by the heat sources.

“Synthesis gas” is a mixture including hydrogen and carbon monoxide.Additional components of synthesis gas may include water, carbondioxide, nitrogen, methane, and other gases. Synthesis gas may begenerated by a variety of processes and feedstocks. Synthesis gas may beused for synthesizing a wide range of compounds.

“TAN” refers to a total acid number expressed as milligrams (“mg”) ofKOH per gram (“g”) of sample. TAN is as determined by ASTM Method D3242.

“Tar” is a viscous hydrocarbon that generally has a viscosity greaterthan about 10,000 centipoise at 15° C. The specific gravity of targenerally is greater than 1.000. Tar may have an API gravity less than10°.

A “tar sands formation” is a formation in which hydrocarbons arepredominantly present in the form of heavy hydrocarbons and/or tarentrained in a mineral grain framework or other host lithology (forexample, sand or carbonate). Examples of tar sands formations includeformations such as the Athabasca formation, the Grosmont formation, andthe Peace River formation, all three in Alberta, Canada; and the Fajaformation in the Orinoco belt in Venezuela.

“Temperature limited heater” generally refers to a heater that regulatesheat output (for example, reduces heat output) above a specifiedtemperature without the use of external controls such as temperaturecontrollers, power regulators, rectifiers, or other devices. Temperaturelimited heaters may be AC (alternating current) or modulated (forexample, “chopped”) DC (direct current) powered electrical resistanceheaters.

“Thermally conductive fluid” includes fluid that has a higher thermalconductivity than air at standard temperature and pressure (STP) (0° C.and 101.325 kPa).

“Thermal conductivity” is a property of a material that describes therate at which heat flows, in steady state, between two surfaces of thematerial for a given temperature difference between the two surfaces.

“Thermal fracture” refers to fractures created in a formation caused byexpansion or contraction of a formation and/or fluids in the formation,which is in turn caused by increasing/decreasing the temperature of theformation and/or fluids in the formation, and/or byincreasing/decreasing a pressure of fluids in the formation due toheating.

“Thermal oxidation stability” refers to thermal oxidation stability of aliquid. Thermal Oxidation Stability is as determined by ASTM MethodD3241.

“Thickness” of a layer refers to the thickness of a cross section of thelayer, wherein the cross section is normal to a face of the layer.

“Time-varying current” refers to electrical current that produces skineffect electricity flow in a ferromagnetic conductor and has a magnitudethat varies with time. Time-varying current includes both alternatingcurrent (AC) and modulated direct current (DC).

“Triad” refers to a group of three items (for example, heaters,wellbores, or other objects) coupled together.

“Turndown ratio” for the temperature limited heater in which current isapplied directly to the heater is the ratio of the highest AC ormodulated DC resistance below the Curie temperature to the lowestresistance above the Curie temperature for a given current. Turndownratio for an inductive heater is ratio of the highest heat output belowthe Curie temperature to the lowest heat output above the Curietemperature for a given current applied to the heater.

A “u-shaped wellbore” refers to a wellbore that extends from a firstopening in the formation, through at least a portion of the formation,and out through a second opening in the formation. In this context, thewellbore may be only roughly in the shape of a “v” or “u”, with theunderstanding that the “legs” of the “u” do not need to be parallel toeach other, or perpendicular to the “bottom” of the “u” for the wellboreto be considered “u-shaped”.

“Upgrade” refers to increasing the quality of hydrocarbons. For example,upgrading heavy hydrocarbons may result in an increase in the APIgravity of the heavy hydrocarbons.

“Visbreaking” refers to the untangling of molecules in fluid during heattreatment and/or to the breaking of large molecules into smallermolecules during heat treatment, which results in a reduction of theviscosity of the fluid.

“Viscosity” refers to kinematic viscosity at 40° C. unless specified.Viscosity is as determined by ASTM

Method D445.

“VGO” or “vacuum gas oil” refers to hydrocarbons with a boiling rangedistribution between 343° C. and 538° C. at 0.101 MPa. VGO content isdetermined by ASTM Method D5307.

A “vug” is a cavity, void or large pore in a rock that is commonly linedwith mineral precipitates.

“Wax” refers to a low melting organic mixture, or a compound of highmolecular weight that is a solid at lower temperatures and a liquid athigher temperatures, and when in solid form can form a barrier to water.Examples of waxes include animal waxes, vegetable waxes, mineral waxes,petroleum waxes, and synthetic waxes.

The term “wellbore” refers to a hole in a formation made by drilling orinsertion of a conduit into the formation. A wellbore may have asubstantially circular cross section, or another cross-sectional shape.As used herein, the terms “well” and “opening,” when referring to anopening in the formation may be used interchangeably with the term“wellbore.”

Hydrocarbons in formations may be treated in various ways to producemany different products. In certain embodiments, hydrocarbons informations are treated in stages. FIG. 1 depicts an illustration ofstages of heating the hydrocarbon containing formation. FIG. 1 alsodepicts an example of yield (“Y”) in barrels of oil equivalent per ton(y axis) of formation fluids from the formation versus temperature (“T”)of the heated formation in degrees Celsius (x axis).

Desorption of methane and vaporization of water occurs during stage 1heating. Heating of the formation through stage 1 may be performed asquickly as possible. For example, when the hydrocarbon containingformation is initially heated, hydrocarbons in the formation desorbadsorbed methane. The desorbed methane may be produced from theformation. If the hydrocarbon containing formation is heated further,water in the hydrocarbon containing formation is vaporized. Water mayoccupy, in some hydrocarbon containing formations, between 10% and 50%of the pore volume in the formation. In other formations, water occupieslarger or smaller portions of the pore volume. Water typically isvaporized in a formation between 160° C. and 285° C. at pressures of 600kPa absolute to 7000 kPa absolute. In some embodiments, the vaporizedwater produces wettability changes in the formation and/or increasedformation pressure. The wettability changes and/or increased pressuremay affect pyrolysis reactions or other reactions in the formation. Incertain embodiments, the vaporized water is produced from the formation.In other embodiments, the vaporized water is used for steam extractionand/or distillation in the formation or outside the formation. Removingthe water from and increasing the pore volume in the formation increasesthe storage space for hydrocarbons in the pore volume.

In certain embodiments, after stage 1 heating, the formation is heatedfurther, such that a temperature in the formation reaches (at least) aninitial pyrolyzation temperature (such as a temperature at the lower endof the temperature range shown as stage 2). Hydrocarbons in theformation may be pyrolyzed throughout stage 2. A pyrolysis temperaturerange varies depending on the types of hydrocarbons in the formation.The pyrolysis temperature range may include temperatures between 250° C.and 900° C. The pyrolysis temperature range for producing desiredproducts may extend through only a portion of the total pyrolysistemperature range. In some embodiments, the pyrolysis temperature rangefor producing desired products may include temperatures between 250° C.and 400° C. or temperatures between 270° C. and 350° C. If a temperatureof hydrocarbons in the formation is slowly raised through thetemperature range from 250° C. to 400° C., production of pyrolysisproducts may be substantially complete when the temperature approaches400° C. Average temperature of the hydrocarbons may be raised at a rateof less than 5° C. per day, less than 2° C. per day, less than 1° C. perday, or less than 0.5° C. per day through the pyrolysis temperaturerange for producing desired products. Heating the hydrocarbon containingformation with a plurality of heat sources may establish thermalgradients around the heat sources that slowly raise the temperature ofhydrocarbons in the formation through the pyrolysis temperature range.

The rate of temperature increase through the pyrolysis temperature rangefor desired products may affect the quality and quantity of theformation fluids produced from the hydrocarbon containing formation.Slowly raising the temperature of the formation through the pyrolysistemperature range for desired products may allow for the production ofhigh quality, high API gravity hydrocarbons from the formation. Slowlyraising the temperature of the formation through the pyrolysistemperature range for desired products may allow for the removal of alarge amount of the hydrocarbons present in the formation as hydrocarbonproduct.

In some in situ heat treatment embodiments, a portion of the formationis heated to a desired temperature instead of slowly heating through atemperature range. In some embodiments, the desired temperature is 300°C., 325° C., or 350° C. Other temperatures may be selected as thedesired temperature. Superposition of heat from heat sources allows thedesired temperature to be relatively quickly and efficiently establishedin the formation. Energy input into the formation from the heat sourcesmay be adjusted to maintain the temperature in the formationsubstantially at the desired temperature. The heated portion of theformation is maintained substantially at the desired temperature untilpyrolysis declines such that production of desired formation fluids fromthe formation becomes uneconomical. Parts of the formation that aresubjected to pyrolysis may include regions brought into a pyrolysistemperature range by heat transfer from only one heat source.

In certain embodiments, formation fluids including pyrolyzation fluidsare produced from the formation. As the temperature of the formationincreases, the amount of condensable hydrocarbons in the producedformation fluid may decrease. At high temperatures, the formation mayproduce mostly methane and/or hydrogen. If the hydrocarbon containingformation is heated throughout an entire pyrolysis range, the formationmay produce only small amounts of hydrogen towards an upper limit of thepyrolysis range. After all of the available hydrogen is depleted, aminimal amount of fluid production from the formation will typicallyoccur.

After pyrolysis of hydrocarbons, a large amount of carbon and somehydrogen may still be present in the formation. A significant portion ofcarbon remaining in the formation can be produced from the formation inthe form of synthesis gas. Synthesis gas generation may take placeduring stage 3 heating depicted in FIG. 1. Stage 3 may include heating ahydrocarbon containing formation to a temperature sufficient to allowsynthesis gas generation. For example, synthesis gas may be produced ina temperature range from about 400° C. to about 1200° C., about 500° C.to about 1100° C., or about 550° C. to about 1000° C. The temperature ofthe heated portion of the formation when the synthesis gas generatingfluid is introduced to the formation determines the composition ofsynthesis gas produced in the formation. The generated synthesis gas maybe removed from the formation through a production well or productionwells.

Total energy content of fluids produced from the hydrocarbon containingformation may stay relatively constant throughout pyrolysis andsynthesis gas generation. During pyrolysis at relatively low formationtemperatures, a significant portion of the produced fluid may becondensable hydrocarbons that have a high energy content. At higherpyrolysis temperatures, however, less of the formation fluid may includecondensable hydrocarbons. More non-condensable formation fluids may beproduced from the formation. Energy content per unit volume of theproduced fluid may decline slightly during generation of predominantlynon-condensable formation fluids. During synthesis gas generation,energy content per unit volume of produced synthesis gas declinessignificantly compared to energy content of pyrolyzation fluid. Thevolume of the produced synthesis gas, however, will in many instancesincrease substantially, thereby compensating for the decreased energycontent.

FIG. 2 depicts a schematic view of an embodiment of a portion of the insitu heat treatment system for treating the hydrocarbon containingformation. The in situ heat treatment system may include barrier wells200. Barrier wells are used to form a barrier around a treatment area.The barrier inhibits fluid flow into and/or out of the treatment area.Barrier wells include, but are not limited to, dewatering wells, vacuumwells, capture wells, injection wells, grout wells, freeze wells, orcombinations thereof. In some embodiments, barrier wells 200 aredewatering wells. Dewatering wells may remove liquid water and/orinhibit liquid water from entering a portion of the formation to beheated, or to the formation being heated. In the embodiment depicted inFIG. 2, the barrier wells 200 are shown extending only along one side ofheat sources 202, but the barrier wells typically encircle all heatsources 202 used, or to be used, to heat a treatment area of theformation.

Heat sources 202 are placed in at least a portion of the formation. Heatsources 202 may include heaters such as insulated conductors,conductor-in-conduit heaters, surface burners, flameless distributedcombustors, and/or natural distributed combustors. Heat sources 202 mayalso include other types of heaters. Heat sources 202 provide heat to atleast a portion of the formation to heat hydrocarbons in the formation.Energy may be supplied to heat sources 202 through supply lines 204.Supply lines 204 may be structurally different depending on the type ofheat source or heat sources used to heat the formation. Supply lines 204for heat sources may transmit electricity for electric heaters, maytransport fuel for combustors, or may transport heat exchange fluid thatis circulated in the formation. In some embodiments, electricity for anin situ heat treatment process may be provided by a nuclear power plantor nuclear power plants. The use of nuclear power may allow forreduction or elimination of carbon dioxide emissions from the in situheat treatment process.

When the formation is heated, the heat input into the formation maycause expansion of the formation and geomechanical motion. The heatsources may be turned on before, at the same time, or during adewatering process. Computer simulations may model formation response toheating. The computer simulations may be used to develop a pattern andtime sequence for activating heat sources in the formation so thatgeomechanical motion of the formation does not adversely affect thefunctionality of heat sources, production wells, and other equipment inthe formation.

Heating the formation may cause an increase in permeability and/orporosity of the formation. Increases in permeability and/or porosity mayresult from a reduction of mass in the formation due to vaporization andremoval of water, removal of hydrocarbons, and/or creation of fractures.Fluid may flow more easily in the heated portion of the formationbecause of the increased permeability and/or porosity of the formation.Fluid in the heated portion of the formation may move a considerabledistance through the formation because of the increased permeabilityand/or porosity. The considerable distance may be over 1000 m dependingon various factors, such as permeability of the formation, properties ofthe fluid, temperature of the formation, and pressure gradient allowingmovement of the fluid. The ability of fluid to travel considerabledistance in the formation allows production wells 206 to be spacedrelatively far apart in the formation.

Production wells 206 are used to remove formation fluid from theformation. In some embodiments, production well 206 includes a heatsource. The heat source in the production well may heat one or moreportions of the formation at or near the production well. In some insitu heat treatment process embodiments, the amount of heat supplied tothe formation from the production well per meter of the production wellis less than the amount of heat applied to the formation from a heatsource that heats the formation per meter of the heat source. Heatapplied to the formation from the production well may increase formationpermeability adjacent to the production well by vaporizing and removingliquid phase fluid adjacent to the production well and/or by increasingthe permeability of the formation adjacent to the production well byformation of macro and/or micro fractures.

More than one heat source may be positioned in the production well. Aheat source in a lower portion of the production well may be turned offwhen superposition of heat from adjacent heat sources heats theformation sufficiently to counteract benefits provided by heating theformation with the production well. In some embodiments, the heat sourcein an upper portion of the production well may remain on after the heatsource in the lower portion of the production well is deactivated. Theheat source in the upper portion of the well may inhibit condensationand reflux of formation fluid.

In some embodiments, the heat source in production well 206 allows forvapor phase removal of formation fluids from the formation. Providingheating at or through the production well may: (1) inhibit condensationand/or refluxing of production fluid when such production fluid ismoving in the production well proximate the overburden, (2) increaseheat input into the formation, (3) increase production rate from theproduction well as compared to a production well without a heat source,(4) inhibit condensation of high carbon number compounds (C6 and above)in the production well, and/or (5) increase formation permeability at orproximate the production well.

Subsurface pressure in the formation may correspond to the fluidpressure generated in the formation. As temperatures in the heatedportion of the formation increase, the pressure in the heated portionmay increase as a result of thermal expansion of in situ fluids,increased fluid generation and vaporization of water. Controlling rateof fluid removal from the formation may allow for control of pressure inthe formation. Pressure in the formation may be determined at a numberof different locations, such as near or at production wells, near or atheat sources, or at monitor wells.

In some hydrocarbon containing formations, production of hydrocarbonsfrom the formation is inhibited until at least some hydrocarbons in theformation have been pyrolyzed. Formation fluid may be produced from theformation when the formation fluid is of a selected quality. In someembodiments, the selected quality includes an API gravity of at leastabout 20°, 30°, or 40°. Inhibiting production until at least somehydrocarbons are pyrolyzed may increase conversion of heavy hydrocarbonsto light hydrocarbons. Inhibiting initial production may minimize theproduction of heavy hydrocarbons from the formation. Production ofsubstantial amounts of heavy hydrocarbons may require expensiveequipment and/or reduce the life of production equipment.

In some hydrocarbon containing formations, hydrocarbons in the formationmay be heated to pyrolysis temperatures before substantial permeabilityhas been generated in the heated portion of the formation. An initiallack of permeability may inhibit the transport of generated fluids toproduction wells 206. During initial heating, fluid pressure in theformation may increase proximate heat sources 202. The increased fluidpressure may be released, monitored, altered, and/or controlled throughone or more heat sources 202. For example, selected heat sources 202 orseparate pressure relief wells may include pressure relief valves thatallow for removal of some fluid from the formation.

In some embodiments, pressure generated by expansion of pyrolysis fluidsor other fluids generated in the formation may be allowed to increasealthough an open path to production wells 206 or any other pressure sinkmay not yet exist in the formation. The fluid pressure may be allowed toincrease towards a lithostatic pressure. Fractures in the hydrocarboncontaining formation may form when the fluid approaches the lithostaticpressure. For example, fractures may form from heat sources 202 toproduction wells 206 in the heated portion of the formation. Thegeneration of fractures in the heated portion may relieve some of thepressure in the portion. Pressure in the formation may have to bemaintained below a selected pressure to inhibit unwanted production,fracturing of the overburden or underburden, and/or coking ofhydrocarbons in the formation.

After pyrolysis temperatures are reached and production from theformation is allowed, pressure in the formation may be varied to alterand/or control a composition of formation fluid produced, to control apercentage of condensable fluid as compared to non-condensable fluid inthe formation fluid, and/or to control an API gravity of formation fluidbeing produced. For example, decreasing pressure may result inproduction of a larger condensable fluid component. The condensablefluid component may contain a larger percentage of olefins.

In some in situ heat treatment process embodiments, pressure in theformation may be maintained high enough to promote production offormation fluid with an API gravity of greater than 20°. Maintainingincreased pressure in the formation may inhibit formation subsidenceduring in situ heat treatment. Maintaining increased pressure mayfacilitate vapor phase production of fluids from the formation. Vaporphase production may allow for a reduction in size of collectionconduits used to transport fluids produced from the formation.Maintaining increased pressure may reduce or eliminate the need tocompress formation fluids at the surface to transport the fluids incollection conduits to treatment facilities.

Maintaining increased pressure in a heated portion of the formation maysurprisingly allow for production of large quantities of hydrocarbons ofincreased quality and of relatively low molecular weight. Pressure maybe maintained so that formation fluid produced has a minimal amount ofcompounds above a selected carbon number. The selected carbon number maybe at most 25, at most 20, at most 12, or at most 8. Some high carbonnumber compounds may be entrained in vapor in the formation and may beremoved from the formation with the vapor. Maintaining increasedpressure in the formation may inhibit entrainment of high carbon numbercompounds and/or multi-ring hydrocarbon compounds in the vapor. Highcarbon number compounds and/or multi-ring hydrocarbon compounds mayremain in a liquid phase in the formation for significant time periods.The significant time periods may provide sufficient time for thecompounds to pyrolyze to form lower carbon number compounds.

Generation of relatively low molecular weight hydrocarbons is believedto be due, in part, to autogenous generation and reaction of hydrogen ina portion of the hydrocarbon containing formation. For example,maintaining an increased pressure may force hydrogen generated duringpyrolysis into the liquid phase within the formation. Heating theportion to a temperature in a pyrolysis temperature range may pyrolyzehydrocarbons in the formation to generate liquid phase pyrolyzationfluids. The generated liquid phase pyrolyzation fluids components mayinclude double bonds and/or radicals. Hydrogen (H₂) in the liquid phasemay reduce double bonds of the generated pyrolyzation fluids, therebyreducing a potential for polymerization or formation of long chaincompounds from the generated pyrolyzation fluids. In addition, H₂ mayalso neutralize radicals in the generated pyrolyzation fluids.Therefore, H₂ in the liquid phase may inhibit the generated pyrolyzationfluids from reacting with each other and/or with other compounds in theformation.

Formation fluid produced from production wells 206 may be transportedthrough collection piping 208 to treatment facilities 210. Formationfluids may also be produced from heat sources 202. For example, fluidmay be produced from heat sources 202 to control pressure in theformation adjacent to the heat sources. Fluid produced from heat sources202 may be transported through tubing or piping to collection piping 208or the produced fluid may be transported through tubing or pipingdirectly to treatment facilities 210. Treatment facilities 210 mayinclude separation units, reaction units, upgrading units, fuel cells,turbines, storage vessels, and/or other systems and units for processingproduced formation fluids. The treatment facilities may formtransportation fuel from at least a portion of the hydrocarbons producedfrom the formation. In some embodiments, the transportation fuel may bejet fuel, such as JP-8.

Formation fluid may be hot when produced from the formation through theproduction wells. Hot formation fluid may be produced during solutionmining processes and/or during in situ heat treatment processes. In someembodiments, electricity may be generated using the heat of the fluidproduced from the formation. Also, heat recovered from the formationafter the in situ process may be used to generate electricity. Thegenerated electricity may be used to supply power to the in situ heattreatment process. For example, the electricity may be used to powerheaters, or to power a refrigeration system for forming or maintaining alow temperature barrier. Electricity may be generated using a Kalinacycle, Rankine cycle or other thermodynamic cycle. In some embodiments,the working fluid for the cycle used to generate electricity is aquaammonia.

FIG. 3 and depicts a schematic representation of a system for producingcrude products and/or commercial products from the in situ heattreatment process liquid stream and/or the in situ heat treatmentprocess gas stream. Formation fluid 212 enters fluid separation unit 214and is separated into in situ heat treatment process liquid stream 216,in situ heat treatment process gas 218 and aqueous stream 220. In someembodiments, fluid separation unit 214 includes a quench zone. Asproduced formation fluid enters the quench zone, quenching fluid such aswater, nonpotable water, hydrocarbon diluent, and/or other componentsmay be added to the formation fluid to quench and/or cool the formationfluid to a temperature suitable for handling in downstream processingequipment. Quenching the formation fluid may inhibit formation ofcompounds that contribute to physical and/or chemical instability of thefluid (for example, inhibit formation of compounds that may precipitatefrom solution, contribute to corrosion, and/or fouling of downstreamequipment and/or piping). The quenching fluid may be introduced into theformation fluid as a spray and/or a liquid stream. In some embodiments,the formation fluid is introduced into the quenching fluid. In someembodiments, the formation fluid is cooled by passing the fluid througha heat exchanger to remove some heat from the formation fluid. Thequench fluid may be added to the cooled formation fluid when thetemperature of the formation fluid is near or at the dew point of thequench fluid. Quenching the formation fluid near or at the dew point ofthe quench fluid may enhance solubilization of salts that may causechemical and/or physical instability of the quenched fluid (for example,ammonium salts). In some embodiments, an amount of water used in thequench is minimal so that salts of inorganic compounds and/or othercomponents do not separate from the mixture. In separation unit 214, atleast a portion of the quench fluid may be separated from the quenchmixture and recycled to the quench zone with a minimal amount oftreatment. Heat produced from the quench may be captured and used inother facilities. In some embodiments, vapor may be produced during thequench. The produced vapor may be sent to gas separation unit 222 and/orsent to other facilities for processing.

In situ heat treatment process gas 218 may enter gas separation unit 222to separate gas hydrocarbon stream 224 from the in situ heat treatmentprocess gas. The gas separation unit is, in some embodiments, arectified adsorption and high pressure fractionation unit. Gashydrocarbon stream 224 includes hydrocarbons having a carbon number ofat least 3.

In situ heat treatment process gas 218 enters gas separation unit 222.In gas separation unit 222, treatment of in situ heat conversiontreatment gas 218 removes sulfur compounds, carbon dioxide, and/orhydrogen to produce gas stream 224. In some embodiments, in situ heattreatment process gas 218 includes 20 vol % hydrogen, 30% methane, 12%carbon dioxide, 14 vol % C₂ hydrocarbons, 5 vol % hydrogen sulfide, 10vol % C₃ hydrocarbons, 7 vol % C₄ hydrocarbons, 2 vol % C₅ hydrocarbons,with the balance being heavier hydrocarbons, water, ammonia, COS,mercaptans and thiophenes.

Gas separation unit 222 may include a physical treatment system and/or achemical treatment system. The physical treatment system includes, butis not limited to, a membrane unit, a pressure swing adsorption unit, aliquid absorption unit, and/or a cryogenic unit. The chemical treatmentsystem may include units that use amines (for example, diethanolamine ordi-isopropanolamine), zinc oxide, sulfolane, water, or mixtures thereofin the treatment process. In some embodiments, gas separation unit 222uses a Sulfinol gas treatment process for removal of sulfur compounds.Carbon dioxide may be removed using Catacarb® (Catacarb, Overland Park,Kans., U.S.A.) and/or Benfield (UOP, Des Plaines, Ill., U.S.A.) gastreatment processes. The gas separation unit is, in some embodiments, arectified adsorption and high pressure fractionation unit. In someembodiments, in suit heat treatment process gas is treated to remove atleast 50%, at least 60%, at least 70%, at least 80% or at least 90% byvolume of ammonia present in the gas stream.

As depicted in FIG. 4, in situ heat treatment process gas 218 may entercompressor 232 of gas separation unit 222 to form compressed gas stream234 and heavy stream 236. Heavy stream 236 may be transported to one ormore liquid separation units described herein for further processing.Compressor 232 may be any compressor suitable for compressing gas. Incertain embodiments, compressor 232 is a multistage compressor (forexample 2 to 3 compressor trains) having an outlet pressure of about 40bars. In some embodiments, compressed gas stream 234 may include atleast 1 vol % carbon dioxide, at least 10 vol % hydrogen, at least 1 vol% hydrogen sulfide, at least 50 vol % of hydrocarbons having a carbonnumber of at most 4, or mixtures thereof. Compression of in situ heattreatment process gas 218 removes hydrocarbons having a carbon number ofleast 4 and water. Removal of water and hydrocarbons having a carbonnumber of at least 4 from the in situ process allows compressed gasstream 234 to be treated cryogenically. Cryogenic treatment ofcompressed gas stream 234 having small amounts of high boiling materialsmay be done more efficiently. In certain embodiments, compressed gasstream 234 is dried by passing the gas through a water adsorption unit.

As shown in FIGS. 4 through 8, gas separation unit 222 includes one ormore cryogenic units. Cryogenic units described herein may include oneor more distillation stages. In FIGS. 4 through 8, one or more heatexchangers may be positioned prior or after cryogenic units and/orseparation units described herein to assist in removing and/or addingheat to one or more streams described herein. At least a portion or allof the separated hydrocarbons streams and/or the separated carbondioxides streams may be transported to the heat exchangers.

In some embodiments, distillation stages may include from 1 to about 100stages, from about 5 to about 50 stages, or from about 10 to about 40stages. Stages of the cryogenic units may be cooled to temperaturesranging from about −110° C. to about 0° C. For example, stage 1 (topstage) in a cryogenic unit is cooled to about −110° C., stage 5 iscooled to about −25° C., and stage 10 is cooled to about −1° C. Totalpressures in cryogenic units may range from about 1 bar to about 50 bar,from about 5 bar to about 40 bar, or from about 10 bar to about 30 bar.Cryogenic units described herein may include condenser recycle conduits238 and reboiler recycle conduits 240. Condenser recycle conduits 238allow recycle of the cooled separated gases so that the feed may becooled as it enters the cryogenic units. Temperatures in condensationloops may range from about −110° C. to about −1° C., from about −90° C.to about −5° C., or from about −80° C. to about −10° C. Temperatures inreboiler loops may range from about 25° C. to about 200° C., from about50° C. to about 150° C., or from about 75° C. to about 100° C. Reboilerrecycle conduits 240 allow recycle of the stream exiting the cryogenicunit to heat the stream as it exits the cryogenic unit. Recycle of thecooled and/or warmed separated stream may enhance energy efficiency ofthe cryogenic unit.

As shown in FIG. 4, compressed gas stream 234 enters methane/hydrogencryogenic unit 242. In cryogenic unit 242, compressed gas stream 234 maybe separated into a methane/hydrogen stream 244 and a bottoms stream246. Bottoms stream 246 may include, but is not limited to carbondioxide, hydrogen sulfide, and hydrocarbons having a carbon number of atleast 2. Methane/hydrogen stream 244 may include a minimal amount of C₂hydrocarbons and carbon dioxide. For example, methane/hydrogen stream244 may include about 1 vol % C₂ hydrocarbons and about 1 vol % carbondioxide. In some embodiments, the methane/hydrogen stream is recycled toone or more heat exchangers positioned prior to cryogenic unit 242. Insome embodiments, the methane/hydrogen stream is used as a fuel fordownhole burners and/or an energy source for surface facilities.

In some embodiments, cryogenic unit 242 may include one distillationcolumn having 1 to about 30 stages, about 5 to about 25 stages, or about10 to about 20 stages. Stages of cryogenic unit 242 may be cooled totemperatures ranging from about −150° C. to about 10° C. For example,stage 1 (top stage) is cooled to about −138° C., stage 5 is cooled toabout −25° C., stage 10° C. is cooled to at about −1° C. At temperatureslower than −79° C. cryogenic separation of the carbon dioxide from othergases may be difficult due to the freezing point of carbon dioxide. Insome embodiments, cryogenic unit 242 is about 17 ft. tall and includesabout 20 distillation stages. Cryogenic unit 242 may be operated at apressure of 40 bar with distillation temperatures ranging from about−45° C. to about −94° C.

Compressed gas stream 234 may include sufficient hydrogen and/orhydrocarbons having a carbon number of at least 1 to inhibit solidcarbon dioxide formation. For example, in situ heat treatment processgas 218 may include from about 30 vol % to about 40 vol % of hydrogen,from about 50 vol % to 60 vol % of hydrocarbons having a carbon numberfrom 1 to 2, from about 0.1 vol % to about 3 vol % of carbon dioxidewith the balance being other gases such as, but not limited to, carbonmonoxide, nitrogen, and hydrogen sulfide. Inhibiting solid carbondioxide formation may allow for better separation of gases and/or lessfouling of the cryogenic unit. In some embodiments, hydrocarbons havinga carbon number of at least five may be added to cryogenic unit 242 toinhibit formation of solid carbon dioxide. The resultingmethane/hydrogen gas stream 244 may be used as an energy source. Forexample, methane/hydrogen gas stream 244 may be transported to surfacefacilities and burned to generate electricity.

As shown in FIG. 4, bottoms stream 246 enters cryogenic separation unit248. In cryogenic separation unit 248, bottoms stream 246 is separatedinto gas stream 250 and liquid stream 252. Gas stream 250 may includehydrocarbons having a carbon number of at least 3. In some embodiments,gas stream 250 includes at least 0.9 vol % of C₃-C₅ hydrocarbons, and atmost 1 ppm of carbon dioxide and about 0.1 vol % of hydrogen sulfide. Insome embodiments, gas stream 250 includes hydrogen sulfide in quantitiessufficient to require treatment of the stream to remove the hydrogensulfide. In some embodiments, gas stream 250 is suitable fortransportation and/or use as an energy source without further treatment.In some embodiments, gas stream 250 is used as an energy source for insitu heat treatment processes.

A portion of liquid stream 252 may be transported via conduit 254 to oneor more portions of the formation and sequestered. In some embodiments,all of liquid stream 252 is sequestered in one or more portions of theformation. In some embodiments, a portion of liquid stream 252 enterscryogenic unit 256. In cryogenic unit 256, liquid stream 252 isseparated into C₂ hydrocarbons/carbon dioxide stream 258 and hydrogensulfide stream 260. In some embodiments, C₂ hydrocarbons/carbon dioxidestream 258 includes at most 0.5 vol % of hydrogen sulfide.

Hydrogen sulfide stream 260 includes, in some embodiments, about 0.01vol % to about 5 vol % of C₃ hydrocarbons. In some embodiments, hydrogensulfide stream 260 includes hydrogen sulfide, carbon dioxide, C₃hydrocarbons, or mixtures thereof. For example, hydrogen sulfide stream260 includes, about 32 vol % of hydrogen sulfide, 67 vol % carbondioxide, and 1 vol % C₃ hydrocarbons. In some embodiments, hydrogensulfide stream 260 is used as an energy source for an in situ heattreatment process and/or sent to a Claus plant for further treatment.

C₂ hydrocarbons/carbon dioxide stream 258 may enter separation unit 262.In separation unit 262 C₂ hydrocarbons/carbon dioxide stream 258 isseparated into C₂ hydrocarbons stream 264 and carbon dioxide stream 266.Separation of C₂ hydrocarbons from carbon dioxide is performed usingseparation methods known in the art, for example, pressure swingadsorption units, and/or extractive distillation units. In someembodiments, C₂ hydrocarbons are separated from carbon dioxide usingextractive distillation methods. For example, hydrocarbons having acarbon number from 3 to 8 may be added to separation unit 262. Additionof a higher carbon number hydrocarbon solvent allows C₂ hydrocarbons tobe extracted from the carbon dioxide. C₂ hydrocarbons are then separatedfrom the higher carbon number hydrocarbons using distillationtechniques. In some embodiments, C₂ hydrocarbons stream 264 istransported to other process facilities and/or used as an energy source.Carbon dioxide stream 266 may be sequestered in one or more portions ofthe formation. In some embodiments, carbon dioxide stream 266 containsat most 0.005 grams of non-carbon dioxide compounds per gram of carbondioxide stream. In some embodiments, carbon dioxide stream 266 is mixedwith one or more oxidant sources supplied to one or more downholeburners.

In some embodiments, a portion or all of C₂ hydrocarbons/carbon dioxidestream 258 are sequestered and/or transported to other facilities viaconduit 268. In some embodiments, a portion or all of C₂hydrocarbons/carbon dioxide stream 258 is mixed with one or more oxidantsources supplied to one or more downhole burners.

As depicted in FIG. 5, bottoms stream 246 enters cryogenic separationunit 270. In cryogenic separation unit 270, bottoms stream 246 may beseparated into C₂ hydrocarbons/carbon dioxide stream 258 and hydrogensulfide/hydrocarbon gas stream 272. In some embodiments, C₂hydrocarbons/carbon dioxide stream 258 contains hydrogen sulfide.Hydrogen sulfide/hydrocarbon gas stream 272 may include hydrocarbonshaving a carbon number of at least 3.

In some embodiments, a portion or all of C₂ hydrocarbons/carbon dioxidestream 258 are transported via conduit 268 to other processes and/or toone or more portions of the formation to be sequestered. In someembodiments, a portion or all of C₂ hydrocarbons/carbon dioxide stream258 are treated in separation unit 262. Separation unit 262 is describedabove with reference to FIG. 4.

Hydrogen sulfide/hydrocarbon gas stream 272 may enter cryogenicseparation unit 274. In cryogenic separation unit 274, hydrogen sulfidemay be separated from hydrocarbons having a carbon number of at least 3to produce hydrogen sulfide stream 260 and C₃ hydrocarbon stream 250.Hydrogen sulfide stream 260 may include, but is not limited to, hydrogensulfide, C₃ hydrocarbons, carbon dioxide, or mixtures thereof. In someembodiments, hydrogen sulfide stream 260 may contain from about 20 vol %to about 80 vol % of hydrogen sulfide, from about 4 vol % to about 18vol % of propane and from about 2 vol % to about 70 vol % of carbondioxide. In some embodiments, hydrogen sulfide stream 260 is burned toproduce SO_(x). The SO_(x) may be sequestered and/or treated using knowntechniques in the art.

In some embodiments, C₃ hydrocarbon stream 250 includes a minimal amountof hydrogen sulfide and carbon dioxide. For example, C₃ hydrocarbonstream 250 may include about 99.6 vol % of hydrocarbons having a carbonnumber of at least 3, about 0.4 vol % of hydrogen sulfide and at most 1ppm of carbon dioxide. In some embodiments, C₃ hydrocarbon stream 250 istransported to other processing facilities as an energy source. In someembodiments, C₃ hydrocarbon stream 250 needs no further treatment.

As depicted in FIG. 6, bottoms stream 246 may enter cryogenic separationunit 276. In cryogenic separation unit 276, bottoms stream 246 may beseparated into C₂ hydrocarbons/hydrogen sulfide/carbon dioxide gasstream 278 and hydrogen sulfide/hydrocarbon gas stream 272. In someembodiments, cryogenic separation unit 276 is 12 ft tall and includes 45distillation stages. A top stage of cryogenic separation unit 276 may beoperated at a temperature of −31° C. and a pressure of about 20 bar.

A portion or all of C₂ hydrocarbons/hydrogen sulfide/carbon dioxide gasstream 278 and hydrocarbon stream 280 may enter cryogenic separationunit 282. Hydrocarbon stream 280 may be any hydrocarbon stream suitablefor use in a cryogenic extractive distillation system. In someembodiments, hydrocarbon stream 280 is n-hexane. In cryogenic separationunit 282, C₂ hydrocarbons/hydrogen sulfide/carbon dioxide gas stream 278is separated into carbon dioxide stream 266 and hydrocarbon/H₂S stream284. In some embodiments, carbon dioxide stream 266 includes about 2.5vol % of hydrocarbons having a carbon number of at most 2. In someembodiments, carbon dioxide stream 266 may be mixed with diluent fluidfor downhole burners, may be used as a carrier fluid for oxidizing fluidfor downhole burners, may be used as a drive fluid for producinghydrocarbons, may be vented, and/or may be sequestered. In someembodiments, cryogenic separation unit 282 is 4 m tall and includes 40distillation stages. Cryogenic separation unit 282 may be operated at atemperature of about −19° C. and a pressure of about 20 bar.

Hydrocarbon/hydrogen sulfide stream 284 may enter cryogenic separationunit 286. Hydrocarbon/hydrogen stream 284 may include solventhydrocarbons, C₂ hydrocarbons and hydrogen sulfide. In cryogenicseparation unit 286, hydrocarbon/hydrogen sulfide stream 284 may beseparated into C₂ hydrocarbons/hydrogen sulfide stream 288 andhydrocarbon stream 290. Hydrocarbon stream 290 may contain hydrocarbonshaving a carbon number of at least 3. In some embodiments, separationunit 286 is about 6.5 m. tall and includes 20 distillation stages.Cryogenic separation unit 286 may be operated at temperatures of about−16° C. and a pressure of about 10 bar.

Hydrogen sulfide/hydrocarbon gas stream 272 may enter cryogenicseparation unit 274. In cryogenic separation unit 274, hydrogen sulfidemay be separated from hydrocarbons having a carbon number of at least 3to produce hydrogen sulfide stream 260 and C₃ hydrocarbon stream 250.Hydrogen sulfide stream 260 may include, but is not limited to, hydrogensulfide, C₂ hydrocarbons, C₃ hydrocarbons, carbon dioxide, or mixturesthereof. In some embodiments, hydrogen sulfide stream 260 contains about31 vol % hydrogen sulfide with the balance being C₂ and C₃ hydrocarbons.Hydrogen sulfide stream 260 may be burned to produce SO_(x). The SO_(x)may be sequestered and/or treated using known techniques in the art.

In some embodiments, cryogenic separation unit 274 is about 4.3 m talland includes about 40 distillation stages. Temperatures in cryogenicseparation unit 274 may range from about 0° C. to about 10° C. Pressurein cryogenic separation unit 274 may be about 20 bar.

C₃ hydrocarbon stream 250 may include a minimal amount of hydrogensulfide and carbon dioxide. In some embodiments, C₃ hydrocarbon stream250 includes about 50 ppm of hydrogen sulfide. In some embodiments, C₃hydrocarbon stream 250 is transported to other processing facilities asan energy source. In some embodiments, hydrocarbon stream C₃ hydrocarbonstream 250 needs no further treatment.

As depicted in FIG. 7, compressed gas stream 234 may be treated using aRyan/Holmes process to recover the carbon dioxide from the compressedgas stream 234. Compressed gas stream 234 enters cryogenic separationunit 292. In some embodiments cryogenic separation unit 292 is about 7.6m tall and includes 40 distillation stages. Cryogenic separation unit292 may be operated at a temperature ranging from about 60° C. to about−56° C. and a pressure of about 30 bar. In cryogenic separation unit292, compressed gas stream 234 may be separated into methane/carbondioxide/hydrogen sulfide stream 294 and hydrocarbon/H₂S stream 296.

Methane/carbon dioxide/hydrogen sulfide stream 294 may includehydrocarbons having a carbon number of at most 2 and hydrogen sulfide.Methane/carbon dioxide/hydrogen sulfide stream 294 may be compressed incompressor 298 and enter cryogenic separation unit 300. In cryogenicseparation unit 300, methane/carbon dioxide/hydrogen sulfide stream 294is separated into carbon dioxide stream 266 and methane/hydrogen sulfidestream 244. In some embodiments, cryogenic separation unit 300 is about2.1 m tall and includes 20 distillation stages. Temperatures incryogenic separation unit 300 may range from about −56° C. to about −96°C. at a pressure of about 45 bar.

Carbon dioxide stream 266 may include some hydrogen sulfide. Forexample, carbon dioxide stream 266 may include about 80 ppm of hydrogensulfide. At least a portion of carbon dioxide stream 266 may be used asa heat exchange medium in heat exchanger 302. In some embodiments, atleast a portion of carbon dioxide stream 266 is sequestered in theformation and/or at least a portion of the carbon dioxide stream is usedas a diluent in downhole oxidizer assemblies.

Hydrocarbon/hydrogen sulfide stream 296 may include hydrocarbons havinga carbon number of at least 2 and hydrogen sulfide. Hydrocarbon/hydrogensulfide stream 296 may pass through heat exchanger 302 and enterseparation unit 304. In separation unit 304, hydrocarbon/hydrogensulfide stream 296 may be separated into hydrocarbon stream 306 andhydrogen sulfide stream 260. In some embodiments, separation unit 304 isabout 7 m tall and includes 30 distillation stages. Temperatures inseparation unit 304 may range from about 60° C. to about 27° C. at apressure of about 10 bar.

Hydrocarbon stream 306 may include hydrocarbons having a carbon numberof at least 3. Hydrocarbon stream 306 may pass through expansion unit308 and form purge stream 310 and hydrocarbon stream 312. Purge stream310 may include some hydrocarbons having a carbon number greater than 5.Hydrocarbon stream 312 may include hydrocarbons having a carbon numberof at most 5. In some embodiments, hydrocarbon stream 312 includes 10vol % n-butanes and 85 vol % hydrocarbons having a carbon number of 5.At least a part of hydrocarbon stream 312 may be recycled to cryogenicseparation unit 292 to maintain a ratio of about 1.4:1 of hydrocarbonsto compressed gas stream 234.

Hydrogen sulfide stream 260 may include hydrogen sulfide, C₂hydrocarbons, and some carbon dioxide. In some embodiments, hydrogensulfide stream 260 includes about 13 vol % hydrogen sulfide, about 0.8vol % carbon dioxide with the balance being C₂ hydrocarbons. At least aportion of the hydrogen sulfide stream 260 may be burned as an energysource. In some embodiments, hydrogen sulfide stream 260 is used as afuel source in downhole burners.

In some embodiments, substantial removal of all the hydrogen sulfidefrom the C₂ hydrocarbons is desired. C₂ hydrocarbons may be used as anenergy source in surface facilities. Recovery of C₂ hydrocarbons mayenhance the energy efficiency of the process. Separation of hydrogensulfide from C₂ hydrocarbons may be difficult because C₂ hydrocarbonsboil at approximately the same temperature as a hydrogen sulfide/C₂hydrocarbons mixture. Addition of higher molecular weight (higherboiling) hydrocarbons does not enable the separation between hydrogensulfide and C₂ hydrocarbons as the addition of higher molecular weighthydrocarbons decreases the volatility of the C₂ hydrocarbons. It hasbeen advantageously found that the addition of carbon dioxide to thehydrogen sulfide/C₂ hydrocarbons mixture allows separation of hydrogensulfide from the C₂ hydrocarbons.

As shown in FIG. 8, bottoms stream bottoms stream 246 and carbon dioxidestream 314 enter cryogenic separation unit 316. In cryogenic separationunit 316, bottoms stream 246 may be separated into C₂hydrocarbons/carbon dioxide gas stream 258 and hydrogensulfide/hydrocarbon gas stream 318 by addition of sufficient carbondioxide to form a C₂ hydrocarbons/carbon dioxide azeotrope (for examplea C₂ hydrocarbons/carbon dioxide vol ratio of 0.17:1 may be used). TheC₂ hydrocarbons/carbon dioxide azeotrope has a boiling point lower thanthe boiling point of C₂ hydrocarbons. For example, the C₂hydrocarbons/carbon dioxide azeotrope has a boiling point that is 14° C.lower than C₂ boiling point at 10 bar, and a boiling point that is 22°C. lower than the C₂ boiling point at 40 bar. Use of a C₂hydrocarbons/carbon dioxide azeotrope allows formation of a C₂hydrocarbons/carbon dioxide stream having a minimal amount of hydrogensulfide (for example, a C₂ hydrocarbons/carbon dioxide stream having atmost 30 ppm, at most 25 ppm, at most 20 ppm, or at most 10 ppm ofhydrogen sulfide). In some embodiments, cryogenic separation unit 316 is3.3 m tall and includes 40 distillation stages and may be operated at apressure of about 10 bar.

At least a portion of C₂ hydrocarbons/carbon dioxide stream 258 andhydrocarbon recovery stream 320 may enter separation unit 262.Hydrocarbon recovery stream 320 may include hydrocarbons having a carbonnumber ranging from 4 to 7. In separation unit 262, contact of C₂hydrocarbons/carbon dioxide stream 258 with hydrocarbon recovery stream320 separates hydrocarbons from the C₂ hydrocarbons/carbon dioxidestream to form separated carbon dioxide stream 266 and C₂ richhydrocarbon stream 322. For example, a hydrocarbon recovery stream tocarbon dioxide ratio of 1.25 to 1 may effective extract all thehydrocarbons from the carbon dioxide. Separated carbon dioxide stream266 may be sequestered in the formation, used as a drive fluid, recycledto cryogenic separation unit 316, or used as a cooling fluid in otherprocesses.

C₂ rich hydrocarbon stream 322 may enter hydrocarbon recovery unit 324.In hydrocarbon recovery unit 324, C₂ rich hydrocarbon stream 322 may beseparated into light hydrocarbons stream 326 and bottom hydrocarbonstream 328. In some embodiments, hydrocarbon recovery unit 324 is 4.9 mtall, has 30 distillation stages, and is operated at a pressure of 10bar. Light hydrocarbons stream 326 may include hydrocarbons having acarbon number from 2 to 4, residual amount of hydrogen sulfide,mercaptans, and/or COS. For example, light hydrocarbons stream 326 mayhave about 30 ppm hydrogen sulfide, 280 ppm mercaptans and 260 ppm COS.Light hydrocarbons stream 326 may be treated further (for example,contacted with molecular sieves) to remove the sulfur compounds. In someembodiments, light hydrocarbons stream 326 requires no furtherpurification and is suitable for transportation and/or use as a fuel.

Hydrocarbon stream 328 may include hydrocarbons having a carbon numberranging from 3 to 7. Some of hydrocarbon stream 328 may be directed toseparation unit 330 after passing through heat exchanger 302. Some ofhydrocarbon stream 328 may pass through expansion unit 308 to form purgestream 310 and hydrocarbon recovery stream 320. Passing hydrocarbonstream 328 through to form purge stream 310 may stabilize thecomposition of hydrocarbon recovery stream 320 and avoid build-up ofheavy hydrocarbons and organosulfur compounds. Hydrocarbon recoverystream 320 may pass through second expansion unit 308′ and/or one ormore heat exchangers 302 prior to entering separation units 262, 330.

Hydrogen sulfide/hydrocarbon gas stream 318 from cryogenic separationunit 316 may include, but is not limited to, hydrocarbons having acarbon number of at least 3, hydrocarbons that include sulfurheteroatoms (organosulfur compounds), hydrogen sulfide, or mixturesthereof. A portion or all of hydrogen sulfide/hydrocarbon gas stream 318and hydrocarbon recovery stream 320 enter hydrogen sulfide separationunit 330. Output from cryogenic separation unit 330 may include hydrogensulfide stream 260 and rich C₃ hydrocarbons stream 332. To facilitateseparation of the hydrogen sulfide from rich C₃ hydrocarbon stream 332,a volume ratio of 0.73 to 1 of rich C₃ hydrocarbons stream to hydrogensulfide may be used. In some embodiments, separation unit 330 is about2.7 m tall and includes 30 distillation stages. Cryogenic separationunit 330 may be operated at a temperature of about −16° C. and apressure of about 10 bar. C₃ hydrocarbon stream 332 may containhydrocarbons having a carbon number of at least 3. At least a portion ofC₃ hydrocarbon stream 332 may enter hydrocarbon recovery unit 324.

Hydrogen sulfide stream 260 may include, but is not limited to, hydrogensulfide, C₂ hydrocarbons, C₃ hydrocarbons, carbon dioxide, or mixturesthereof. In some embodiments, hydrogen sulfide stream 260 contains about99 vol % hydrogen sulfide with the balance being C₂ and C₃ hydrocarbons.Hydrogen sulfide stream 260 may be burned to produce SO_(x). In someembodiments, at least a portion of the hydrogen sulfide stream is usedas a fuel in downhole burners. The SO_(x) may be used as a drive fluid,sequestered and/or treated using known techniques in the art.

As shown in FIG. 3, in situ heat treatment process liquid stream 216enters liquid separation unit 226. In some embodiments, liquidseparation unit 226 is not necessary. In liquid separation unit 226,separation of in situ heat treatment process liquid stream 216 producesgas hydrocarbon stream 228 and salty process liquid stream 230. Gashydrocarbon stream 228 may include hydrocarbons having a carbon numberof at most 5. A portion of gas hydrocarbon stream 228 may be combinedwith gas hydrocarbon stream 224.

Salty process liquid stream 230 may be processed through desalting unit336 to form liquid stream 338. Desalting unit 336 removes mineral saltsand/or water from salty process liquid stream 230 using known desaltingand water removal methods. In certain embodiments, desalting unit 336 isupstream of liquid separation unit 226.

Liquid stream 338 includes, but is not limited to, hydrocarbons having acarbon number of at least 5 and/or hydrocarbon containing heteroatoms(for example, hydrocarbons containing nitrogen, oxygen, sulfur, andphosphorus). Liquid stream 338 may include at least 0.001 g, at least0.005 g, or at least 0.01 g of hydrocarbons with a boiling rangedistribution between about 95° C. and about 200° C. at 0.101 MPa; atleast 0.01 g, at least 0.005 g, or at least 0.001 g of hydrocarbons witha boiling range distribution between about 200° C. and about 300° C. at0.101 MPa; at least 0.001 g, at least 0.005 g, or at least 0.01 g ofhydrocarbons with a boiling range distribution between about 300° C. andabout 400° C. at 0.101 MPa; and at least 0.001 g, at least 0.005 g, orat least 0.01 g of hydrocarbons with a boiling range distributionbetween 400° C. and 650° C. at 0.101 MPa. In some embodiments, liquidstream 338 contains at most 10% by weight water, at most 5% by weightwater, at most 1% by weight water, or at most 0.1% by weight water.

In some embodiments, the separated liquid stream may have a boilingrange distribution between about 50° C. and about 350° C., between about60° C. and 340° C., between about 70° C. and 330° C. or between about80° C. and 320° C. In some embodiments, the separated liquid stream hasa boiling range distribution between 180° C. and 330° C.

In some embodiments, at least 50%, at least 70%, or at least 90% byweight of the total hydrocarbons in the separated liquid stream have acarbon number from 8 to 13. About 50% to about 100%, about 60% to about95%, about 70% to about 90%, or about 75% to 85% by weight of liquidstream may have a carbon number distribution from 8 to 13. At least 50%by weight of the total hydrocarbons in the separated liquid stream mayhave a carbon number from about 9 to 12 or from 10 to 11.

In some embodiments, the separated liquid stream has at most 15%, atmost 10%, at most 5% by weight of naphthenes; at least 70%, at least80%, or at least 90% by weight total paraffins; at most 5%, at most 3%,or at most 1% by weight olefins; and at most 30%, at most 20%, or atmost 10% by weight aromatics.

In some embodiments, the separated liquid stream has a nitrogen compoundcontent of at least 0.01%, at least 0.1% or at least 0.4% by weightnitrogen compound. The separated liquid stream may have a sulfurcompound content of at least 0.01%, at least 0.5% or at least 1% byweight sulfur compound.

After exiting desalting unit 336, liquid stream 338 enters filtrationsystem 342. In some embodiments, filtration system 342 is connected tothe outlet of the desalting unit. Filtration system 342 separates atleast a portion of the clogging compounds from liquid stream 338. Insome embodiments, filtration system 342 is skid mounted. Skid mountingfiltration system 342 may allow the filtration system to be moved fromone processing unit to another. In some embodiments, filtration system342 includes one or more membrane separators, for example, one or morenanofiltration membranes or one or more reverse osmosis membranes.Removal of clogging compositions from liquid stream 338 is described inU.S. Published Patent Application No. 2007-0131428 to den Boestert etal., which is incorporated by reference herein.

In some embodiments, the membrane separation is a continuous process.Liquid stream 338 passes over the membrane due to a pressure differenceto obtain a filtered liquid stream 344 (permeate) and/or recycle liquidstream 346 (retentate). In some embodiments, filtered liquid stream 344may have reduced concentrations of compositions and/or particles thatcause clogging in downstream processing systems. Continuous recycling ofrecycle liquid stream 346 through nanofiltration system can increase theproduction of filtered liquid stream 344 to as much as 95% of theoriginal volume of liquid stream 338. Recycle liquid stream 346 may becontinuously recycled through membrane module for at least 10 hours, forat least one day, or for at least one week without cleaning the feedside of the membrane. Upon completion of the filtration, waste stream348 (retentate) may include a high concentration of compositions and/orparticles that cause clogging. Waste stream 348 exits filtration system342 and is transported to other processing units such as, for example, adelayed coking unit and/or a gasification unit.

In some embodiments, liquid stream 338 is contacted with hydrogen in thepresence of one or more catalysts to change one or more desiredproperties of the crude feed to meet transportation and/or refineryspecifications using known hydrodemetallation, hydrodesulfurization,hydrodenitrofication techniques. Other methods to change one or moredesired properties of the crude feed are described in U.S. PublishedPatent Applications Nos. 2005-0133414; 2006-0231465; and 2007-0000810 toBhan et al.; 2005-0133405 to Wellington et al.; and 2006-0289340 toBrownscombe et al., all of which are incorporated by reference herein.

In some embodiments, the hydrotreated liquid stream has a nitrogencompound content of at most 200 ppm by weight, at most 150 ppm, at most110 ppm, at most 50 ppm, or at most 10 ppm of nitrogen compounds. Theseparated liquid stream may have a sulfur compound content of at most1000 ppm, at most 500 ppm, at most 300 ppm, at most 100 ppm, or at most10 ppm by weight of sulfur compounds.

In some embodiments, the desalting unit may produce a liquid hydrocarbonstream and a salty process liquid stream, as shown in FIG. 9. In situheat treatment process liquid stream 216 enters liquid separation unit226. Separation unit 226 may include one or more distillation units. Inliquid separation unit 226, separation of in situ heat treatment processliquid stream 216 produces gas hydrocarbon stream 228, salty processliquid stream 230, and liquid hydrocarbon stream 350. Gas hydrocarbonstream 228 may include hydrocarbons having a carbon number of at most 5.A portion of gas hydrocarbon stream 228 may be combined with gashydrocarbon stream 224. Salty process liquid stream 230 may be processedas described in FIG. 3. Salty process liquid stream 230 may includehydrocarbons having a boiling point above 260° C. In some embodimentsand as depicted in FIG. 9, salty process liquid stream 230 entersdesalting unit 336. In desalting unit 336, salty process liquid stream230 may be treated to form liquid stream 338 using known desalting andwater removal methods. Liquid stream 338 may enter separation unit 352.In separation unit 352, liquid stream 338 is separated into bottomsstream 354 and hydrocarbon stream 356. In some embodiments, hydrocarbonstream 356 may have a boiling range distribution between about 200° C.and about 350° C., between about 220° C. and 340° C., between about 230°C. and 330° C. or between about 240° C. and 320° C.

In some embodiments, at least 50%, at least 70%, or at least 90% byweight of the total hydrocarbons in hydrocarbon stream 356 have a carbonnumber from 8 to 13. About 50% to about 100%, about 60% to about 95%,about 70% to about 90%, or about 75% to 85% by weight of liquid streammay have a carbon number distribution from 8 to 13. At least 50% byweight of the total hydrocarbons in the separated liquid stream may havea carbon number from about 9 to 12 or from 10 to 11.

In some embodiments, hydrocarbon stream 356 has at most 15%, at most10%, at most 5% by weight of naphthenes; at least 70%, at least 80%, orat least 90% by weight total paraffins; at most 5%, at most 3%, or atmost 1% by weight olefins; and at most 30%, at most 20%, or at most 10%by weight aromatics.

In some embodiments, hydrocarbon stream 356 has a nitrogen compoundcontent of at least 0.01%, at least 0.1% or at least 0.4% by weightnitrogen compound. The separated liquid stream may have a sulfurcompound content of at least 0.01%, at least 0.5% or at least 1% byweight sulfur compound.

Hydrocarbon stream 356 enters hydrotreating unit 358. In hydrotreatingunit 358, liquid stream 338 may be hydrotreated to form compoundssuitable for processing to hydrogen and/or commercial products.

Liquid hydrocarbon stream 350 from liquid separation unit 226 mayinclude hydrocarbons having a boiling point up to 260° C. Liquidhydrocarbon stream 350 may include entrained asphaltenes and/or othercompounds that may contribute to the instability of hydrocarbon streams.For example, liquid hydrocarbon stream 350 is a naphtha/kerosenefraction that includes entrained, partially dissolved, and/or dissolvedasphaltenes and/or high molecular weight compounds that may contributeto phase instability of the liquid hydrocarbon stream. In someembodiments, liquid hydrocarbon stream 350 may include at least 0.5% byweight asphaltenes, 1% by weight asphaltenes or at least 5% by weightasphaltenes.

As properties of the liquid hydrocarbon stream 350 are changed duringprocessing (for example, TAN, asphaltenes, P-value, olefin content,mobilized fluids content, visbroken fluids content, pyrolyzed fluidscontent, or combinations thereof), the asphaltenes and other componentsmay become less soluble in the liquid hydrocarbon stream. In someinstances, components in the produced fluids and/or components in theseparated hydrocarbons may form two phases and/or become insoluble.Formation of two phases, through flocculation of asphaltenes, change inconcentration of components in the produced fluids, change inconcentration of components in separated hydrocarbons, and/orprecipitation of components may cause processing problems (for example,plugging) and/or result in hydrocarbons that do not meet pipeline,transportation, and/or refining specifications. In some embodiments,further treatment of the produced fluids and/or separated hydrocarbonsis necessary to produce products with desired properties.

During processing, the P-value of the separated hydrocarbons may bemonitored and the stability of the produced fluids and/or separatedhydrocarbons may be assessed. Typically, a P-value that is at most 1.0indicates that flocculation of asphaltenes from the separatedhydrocarbons may occur. If the P-value is initially at least 1.0 andsuch P-value increases or is relatively stable during heating, then thisindicates that the separated hydrocarbons are relatively stable.

Liquid hydrocarbon stream 350 may be treated to at least partiallyremove asphaltenes and/or other compounds that may contribute toinstability. Removal of the asphaltenes and/or other compounds that maycontribute to instability may inhibit plugging in downstream processingunits. Removal of the asphaltenes and/or other compounds that maycontribute to instability may enhance processing unit efficienciesand/or prevent plugging of transportation pipelines.

Liquid hydrocarbon stream 350 may enter filtration system 342.Filtration system 342 separates at least a portion of the asphaltenesand/or other compounds that contribute to instability from liquidhydrocarbon stream 350. In some embodiments, filtration system 342 isskid mounted. Skid mounting filtration system 342 may allow thefiltration system to be moved from one processing unit to another. Insome embodiments, filtration system 342 includes one or more membraneseparators, for example, one or more nanofiltration membranes or one ormore reverse osmosis membranes. Use of a filtration system that operatesat below ambient, ambient, or slightly higher than ambient temperaturesmay reduce energy costs as compared to conventional catalytic and/orthermal methods to remove asphaltenes from a hydrocarbon stream.

The membranes may be ceramic membranes and/or polymeric membranes. Theceramic membranes may be ceramic membranes having a molecular weight cutoff of at most 2000 Daltons (Da), at most 1000 Da, or at most 500 Da.Ceramic membranes may not swell during removal of the desired materialsfrom a substrate (for example, asphaltenes from the liquid stream). Inaddition, ceramic membranes may be used at elevated temperatures.Examples of ceramic membranes include, but are not limited to,mesoporous titania, mesoporous gamma-alumina, mesoporous zirconia,mesoporous silica, and combinations thereof.

Polymeric membranes may include top layers made of a dense membrane anda base layers (supports) made of porous membranes. The polymericmembranes may be arranged to allow the liquid stream (permeate) to flowfirst through the dense membrane top layer and then through the baselayer so that the pressure difference over the membrane pushes the toplayer onto the base layer. The polymeric membranes are organophilic orhydrophobic membranes so that water present in the liquid stream isretained or substantially retained in the retentate.

The dense membrane layer of the polymeric membrane may separate at leasta portion or substantially all of the asphaltenes from liquidhydrocarbon stream 350. In some embodiments, the dense polymericmembrane has properties such that liquid hydrocarbon stream 350 passesthrough the membrane by dissolving in and diffusing through thestructure of dense membrane. At least a portion of the asphaltenes maynot dissolve and/or diffuse through the dense membrane, thus they areremoved. The asphaltenes may not dissolve and/or diffuse through thedense membrane because of the complex structure of the asphaltenesand/or their high molecular weight. The dense membrane layer may includecross-linked structure as described in WO 96/27430 to Schmidt et al.,which is incorporated by reference herein. A thickness of the densemembrane layer may range from 1 micrometer to 15 micrometers, from 2micrometers to 10 micrometers, or from 3 micrometers to 5 micrometers.

The dense membrane may be made from polysiloxane, poly-di-methylsiloxane, poly-octyl-methyl siloxane, polyimide, polyaramide,poly-tri-methyl silyl propyne, or mixtures thereof. Porous base layersmay be made of materials that provide mechanical strength to themembrane. The porous base layers may be any porous membranes used forultra filtration, nanofiltration, and/or reverse osmosis. Examples ofsuch materials are polyacrylonitrile, polyamideimide in combination withtitanium oxide, polyetherimide, polyvinylidenedifluoroide,polytetrafluoroethylene, or combinations thereof.

During separation of asphaltenes from liquid stream 350, the pressuredifference across the membrane may range from about 0.5 MPa to about 6MPa, from about 1 MPa to about 5 MPa, or from about 2 MPa to about 4MPa. A temperature of the unit during separation may range from the pourpoint of liquid hydrocarbon stream 350 up to 100° C., from about −20° C.to about 100° C., from about 10° C. to about 90° C., or from about 20°C. to about 85° C. During a continuous operation, the permeate flux ratemay be at most 50% of the initial flux, at most 70% of the initial flux,or at most 90% of the initial flux. A weight recovery of the permeate onfeed may range from about 50% by weight to 97% by weight, from about 60%by weight to 90% by weight, or from about 70% by weight to 80% byweight.

Filtration system 342 may include one or more membrane separators. Themembrane separators may include one or more membrane modules. When twoor more membrane separators are used, the separators may be arranged ina parallel configuration to allow feed (retentate) from a first membraneseparator to flow into a second membrane separator. Examples of membranemodules include, but are not limited to, spirally wound modules, plateand frame modules, hollow fibers, and tubular modules. Membrane modulesare described in Encyclopedia of Chemical Engineering, 4^(th) Ed., 1995,John Wiley & Sons Inc., Vol. 16, pages 158-164. Examples of spirallywound modules are described in, for example, WO/2006/040307 to Boestertet al., U.S. Pat. No. 5,102,551 to Pasternak; U.S. Pat. No. 5,093,002 toPasternak; U.S. Pat. No. 5,275,726 to Feimer et al.; U.S. Pat. No.5,458,774 to Mannapperuma; and U.S. Pat. No. 5,150,118 to Finkle et al,all of which are incorporated by reference herein.

In some embodiments, a spirally wound module is used when a densemembrane is used in filtration system 342. A spirally wound module mayinclude a membrane assembly of two membrane sheets between which apermeate spacer sheet is sandwiched. The membrane assembly may be sealedat three sides. The fourth side is connected to a permeate outletconduit such that the area between the membranes is in fluidcommunication with the interior of the conduit. A feed spacer sheet maybe arranged on top of one of the membranes. The assembly with feedspacer sheet is rolled up around the permeate outlet conduit to form asubstantially cylindrical spirally wound membrane module. The feedspacer may have a thickness of at least 0.6 mm, at least 1 mm, or atleast 3 mm to allow sufficient membrane surface to be packed into thespirally wound module. In some embodiments, the feed spacer is a wovenfeed spacer. During operation, the feed mixture may be passed from oneend of the cylindrical module between the membrane assemblies along thefeed spacer sheet sandwiched between feed sides of the membranes. Partof the feed mixture passes through either one of the membrane sheets tothe permeate side. The resulting permeate flows along the permeatespacer sheet into the permeate outlet conduit.

In some embodiments, the membrane separation is a continuous process.Liquid stream 350 passes over the membrane due to the pressuredifference to obtain filtered liquid stream 360 (permeate) and/orrecycle liquid stream 362 (retentate). In some embodiments, filteredliquid stream 360 may have reduced concentrations of asphaltenes and/orhigh molecular weight compounds that may contribute to phaseinstability. Continuous recycling of recycle liquid stream 362 throughthe filter system can increase the production of filtered liquid stream360 to as much as 95% of the original volume of filtered liquid stream360. Recycle liquid stream 362 may be continuously recycled through aspirally wound membrane module for at least 10 hours, for at least oneday, or for at least one week without cleaning the feed side of themembrane. Upon completion of the filtration, asphaltene enriched stream364 (retentate) may include a high concentration of asphaltenes and/orhigh molecular weight compounds.

At least a portion of filtered liquid stream 360 may be sent tohydrotreating unit 358 for further processing. In some embodiments, atleast a portion of filtered liquid stream 360 may be sent to otherprocessing units.

In some embodiments, at least a portion of or substantially all offiltered liquid stream 360 enters separation unit 368. In separationunit 368, filtered liquid stream 360 may be separated into hydrocarbonstream 370 and liquid hydrocarbon stream 372. Hydrocarbon stream 370 maybe rich in aromatic hydrocarbons. Liquid hydrocarbon stream 372 mayinclude a small amount of aromatic hydrocarbons. Liquid hydrocarbonstream 372 may include hydrocarbons having a boiling point up to 260° C.Liquid hydrocarbon stream 372 may enter hydrotreating unit 358 and/orother processing units.

Hydrocarbon stream 370 may include aromatic hydrocarbons andhydrocarbons having a boiling point up to about 260° C. A content ofaromatics in aromatic rich stream 370 may be at most 90%, at most 70%,at most 50%, or most 10% of the aromatic content of filtered liquidstream 360, as measured by UV analysis such as method SMS-2714. Aromaticrich stream 370 may suitable for use as a diluent for undesirablestreams that may not otherwise be suitable for additional processing.The undesirable streams may have low P-values, phase instability, and/orasphaltenes. Addition of aromatic rich stream 370 to the undesirablestreams may allow the undesirable streams to be processed and/ortransported, thus increasing the economic value of the streamundesirable streams. Aromatic rich stream 370 may be sold as a diluentand/or used as a diluent for produced fluids. All or a portion ofaromatic rich stream 370 may be recycled to separation unit 226.

In some embodiments, membrane separation unit 368 includes one or moremembrane separators, for example, one or more nanofiltration membranesand/or one or more reverse osmosis membranes. The membrane may be aceramic membrane and/or a polymeric membrane. The ceramic membrane maybe a ceramic membrane having a molecular weight cut off of at most 2000Daltons (Da), at most 1000 Da, or at most 500 Da.

The polymeric membrane includes a top layer made of a dense membrane anda base layer (support) made of a porous membrane. The polymeric membranemay be arranged to allow the liquid stream (permeate) to flow firstthrough the dense membrane top layer and then through the base layer sothat the pressure difference over the membrane pushes the top layer ontothe base layer. The dense polymeric membrane has properties such that asliquid hydrocarbon stream 360 passes through the membrane aromatichydrocarbons are selectively separated from the liquid hydrocarbonstream to form aromatic rich stream 370. In some embodiments, the densemembrane layer may separate at least a portion of or substantially allof the aromatics from liquid hydrocarbon stream 360. The dense membranemay be a silicon based membrane, a polyamide based membrane and/or apolyol membrane. Aromatic selective membranes may be purchased from W.R. Grace & Co. (New York, USA), PolyAn (Berlin, Germany), and/or BorsigMembrane Technology (Berlin, Germany).

Liquid stream 374 (retentate) from membrane separation unit 368 may berecycled back to the membrane separation unit. Continuous recycling ofrecycle liquid stream 374 idem through nanofiltration system canincrease the production of aromatic rich stream 370 to as much as 95% ofthe original volume of the filtered liquid stream. Recycle liquid stream374 may be continuously recycled through a spirally wound membranemodule for at least 10 hours, for at least one day, for at least oneweek or until the desired content of aromatics in aromatic rich stream370 is obtained. Upon completion of the filtration, or when theretentate includes an acceptable amount of aromatics, liquid stream 372(retentate) from separation unit 368 may be sent to hydrotreating unit358 and/or other processing units.

Membranes of separation unit 368 may be ceramic membranes and/orpolymeric membranes. During separation of aromatic hydrocarbons fromliquid stream 360 in separation unit 368, the pressure difference acrossthe membrane may range from about 0.5 MPa to about 6 MPa, from about 1MPa to about 5 MPa, or from about 2 MPa to about 4 MPa. Temperature ofseparation unit 368 during separation may range from the pour point ofthe liquid hydrocarbon stream 360 up to 100° C., from about −20° C. toabout 100° C., from about 10° C. to about 90° C., or from about 20° C.to about 85° C. During a continuous operation, the permeate flux ratemay be at most 50% of the initial flux, at most 70% of the initial flux,or at most 90% of the initial flux. A weight recovery of the permeate onfeed may range from about 50% by weight to 97% by weight, from about 60%by weight to 90% by weight, or from about 70% by weight to 80% byweight.

As shown in FIGS. 3, and 9, liquid stream 338 and/or filtered liquidstream 344 may enter hydrotreating unit 358. In some embodiments,hydrogen source 376 enters hydrotreating unit 358 in addition to liquidstream 338 and/or filtered liquid stream 344. In some embodiments, thehydrogen source is not needed. Liquid stream 338 and/or filtered liquidstream 344 may be selectively hydrogenated in hydrotreating unit 358such that di-olefins are reduced to mono-olefins. For example, liquidstream 338 and/or filtered liquid stream 344 is contacted with hydrogenin the presence of DN-200 (Criterion Catalysts & Technologies, HoustonTex., U.S.A.) at temperatures ranging from 100° C. to 200° C. and totalpressures of 0.1 MPa to 40 MPa to produce liquid stream 378. In someembodiments, filtered liquid stream 344 is hydrotreated at a temperatureranging from about 190° C. to about 200° C. at a pressure of at least 6MPa. Liquid stream 378 includes a reduced content of di-olefins and anincreased content of mono-olefins relative to the di-olefin andmono-olefin content of liquid stream 338. The conversion of di-olefinsto mono-olefins under these conditions is, in some embodiments, at least50%, at least 60%, at least 80% or at least 90%. Liquid stream 378 exitshydrotreating unit 358 and enters one or more processing unitspositioned downstream of hydrotreating unit 358. The units positioneddownstream of hydrotreating unit 358 may include distillation units,catalytic reforming units, hydrocracking units, hydrotreating units,hydrogenation units, hydrodesulfurization units, catalytic crackingunits, delayed coking units, gasification units, or combinationsthereof. In some embodiments, hydrotreating prior to fractionation isnot necessary. In some embodiments, liquid stream 378 may be severelyhydrotreated to remove undesired compounds from the liquid stream priorto fractionation. In certain embodiments, liquid stream 378 may befractionated and then produced streams may each be hydrotreated to meetindustry standards and/or transportation standards.

Liquid stream 378 may exit hydrotreating unit 358 and enterfractionation unit 380. In fractionation unit 380, liquid stream 378 maybe distilled to form one or more crude products. Crude products include,but are not limited to, C₃-C₅ hydrocarbon stream 382, naphtha stream384, kerosene stream 386, diesel stream 388, and bottoms stream 354.Fractionation unit 380 may be operated at atmospheric and/or undervacuum conditions.

In some embodiments, hydrotreated liquid streams and/or streams producedfrom fractions (for example, aromatic rich streams, distillates and/ornaphtha) are blended with the in situ heat treatment process liquidand/or formation fluid to produce a blended fluid. The blended fluid mayhave enhanced physical stability and chemical stability as compared tothe formation fluid. The blended fluid may have a reduced amount ofreactive species (for example, di-olefins, other olefins and/orcompounds containing oxygen, sulfur and/or nitrogen) relative to theformation fluid. Thus, chemical stability of the blended fluid isenhanced. The blended fluid may decrease an amount of asphaltenesrelative to the formation fluid. Thus, physical stability of the blendedfluid is enhanced. The blended fluid may be a more a fungible feed thanthe formation fluid and/or the liquid stream produced from the in situheat treatment process. The blended feed may be more suitable fortransportation, for use in chemical processing units and/or for use inrefining units than formation fluid.

In some embodiments, a fluid produced by methods described herein froman oil shale formation may be blended with heavy oil/tar sands in situheat treatment process (IHTP) fluid. Since the oil shale liquid issubstantially paraffinic and the heavy oil/tar sands IHTP fluid issubstantially aromatic, the blended fluid exhibits enhanced stability.In certain embodiments, in situ heat treatment process fluid may beblended with bitumen to obtain a feed suitable for use in refiningunits. Blending the IHTP fluid and/or bitumen with the produced fluidmay enhance the chemical and/or physical stability of the blendedproduct. Thus, the blend may be transported and/or distributed toprocessing units.

As shown in FIGS. 3 and 9, C₃-C₅ hydrocarbon stream 382 produced fromfractionation unit 380 and/or hydrocarbon gas stream 224 enteralkylation unit 396. In alkylation unit 396, reaction of the olefins inhydrocarbon gas stream 224 (for example, propylene, butylenes, amylenes,or combinations thereof) with the iso-paraffins in C₃-C₅ hydrocarbonstream 382 produces hydrocarbon stream 398. In some embodiments, theolefin content in hydrocarbon gas stream 224 is acceptable and anadditional source of olefins is not needed. Hydrocarbon stream 398includes hydrocarbons having a carbon number of at least 4. Hydrocarbonshaving a carbon number of at least 4 include, but are not limited to,butanes, pentanes, hexanes, heptanes, and octanes. In certainembodiments, hydrocarbons produced from alkylation unit 396 have anoctane number greater than 70, greater than 80, or greater than 90. Insome embodiments, hydrocarbon stream 398 is suitable for use as gasolinewithout further processing.

In some embodiments and as depicted in FIGS. 3 and 9, bottoms stream 354may be hydrocracked to produce naphtha and/or other products. Theresulting naphtha may, however, need reformation to alter the octanelevel so that the product may be sold commercially as gasoline.Alternatively, bottoms stream 354 may be treated in a catalytic crackerto produce naphtha and/or feed for an alkylation unit. In someembodiments, naphtha stream 384, kerosene stream 386, and diesel stream388 have an imbalance of paraffinic hydrocarbons, olefinic hydrocarbons,and/or aromatic hydrocarbons. The streams may not have a suitablequantity of olefins and/or aromatics for use in commercial products.This imbalance may be changed by combining at least a portion of thestreams to form combined stream 400 which has a boiling rangedistribution from about 38° C. to about 343° C. Catalytically crackingcombined stream 400 may produce olefins and/or other streams suitablefor use in an alkylation unit and/or other processing units. In someembodiments, naphtha stream 384 is hydrocracked to produce olefins.

Combined stream 400 and bottoms stream 354 from fractionation unit 380enters catalytic cracking unit 402. Under controlled cracking conditions(for example, controlled temperatures and pressures), catalytic crackingunit 402 produces additional C₃-C₅ hydrocarbon stream 382′, gasolinehydrocarbons stream 404, and additional kerosene stream 386′.

Additional C₃-C₅ hydrocarbon stream 382′ may be sent to alkylation unit396, combined with C₃-C₅ hydrocarbon stream 382, and/or combined withhydrocarbon gas stream 224 to produce gasoline suitable for commercialsale. In some embodiments, the olefin content in hydrocarbon gas stream224 is acceptable and an additional source of olefins is not needed.

Many wells are needed for treating the hydrocarbon formation using thein situ heat treatment process. In some embodiments, vertical orsubstantially vertical wells are formed in the formation. In someembodiments, horizontal or U-shaped wells are formed in the formation.In some embodiments, combinations of horizontal and vertical wells areformed in the formation.

A manufacturing approach for the formation of wellbores in the formationmay be used due to the large number of wells that need to be formed forthe in situ heat treatment process. The manufacturing approach may beparticularly applicable for forming wells for in situ heat treatmentprocesses that utilize u-shaped wells or other types of wells that havelong non-vertically oriented sections. Surface openings for the wellsmay be positioned in lines running along one or two sides of thetreatment area. FIG. 10 depicts a schematic representation of anembodiment of a system for forming wellbores of the in situ heattreatment process.

The manufacturing approach for the formation of wellbores mayinclude: 1) delivering flat rolled steel to near site tube manufacturingplant that forms coiled tubulars and/or pipe for surface pipelines; 2)manufacturing large diameter coiled tubing that is tailored to therequired well length using electrical resistance welding (ERW), whereinthe coiled tubing has customized ends for the bottom hole assembly (BHA)and hang off at the wellhead; 3) deliver the coiled tubing to a drillingrig on a large diameter reel; 4) drill to total depth with coil and aretrievable bottom hole assembly; 5) at total depth, disengage the coiland hang the coil on the wellhead; 6) retrieve the BHA; 7) launch anexpansion cone to expand the coil against the formation; 8) return emptyspool to the tube manufacturing plant to accept a new length of coiledtubing; 9) move the gantry type drilling platform to the next welllocation; and 10) repeat.

In situ heat treatment process locations may be distant from establishedcities and transportation networks. Transporting formed pipe or coiledtubing for wellbores to the in situ process location may be untenabledue to the lengths and quantity of tubulars needed for the in situ heattreatment process. One or more tube manufacturing facilities 406 may beformed at or near to the in situ heat treatment process location. Thetubular manufacturing facility may form plate steel into coiled tubing.The plate steel may be delivered to tube manufacturing facilities 406 bytruck, train, ship or other transportation system. In some embodiments,different sections of the coiled tubing may be formed of differentalloys. The tubular manufacturing facility may use ERW to longitudinallyweld the coiled tubing.

Tube manufacturing facilities 406 may be able to produce tubing havingvarious diameters. Tube manufacturing facilities may initially be usedto produce coiled tubing for forming wellbores. The tube manufacturingfacilities may also be used to produce heater components, piping fortransporting formation fluid to surface facilities, and other piping andtubing needs for the in situ heat treatment process.

Tube manufacturing facilities 406 may produce coiled tubing used to formwellbores in the formation. The coiled tubing may have a large diameter.The diameter of the coiled tubing may be from about 4 inches to about 8inches in diameter. In some embodiments, the diameter of the coiledtubing is about 6 inches in diameter. The coiled tubing may be placed onlarge diameter reels. Large diameter reels may be needed due to thelarge diameter of the tubing. The diameter of the reel may be from about10 m to about 50 m. One reel may hold all of the tubing needed forcompleting a single well to total depth.

In some embodiments, tube manufacturing facilities 406 has the abilityto apply expandable zonal inflow profiler (EZIP) material to one or moresections of the tubing that the facility produces. The EZIP material maybe placed on portions of the tubing that are to be positioned near andnext to aquifers or high permeability layers in the formation. Whenactivated, the EZIP material forms a seal against the formation that mayserve to inhibit migration of formation fluid between different layers.The use of EZIP layers may inhibit saline formation fluid from mixingwith non-saline formation fluid.

The size of the reels used to hold the coiled tubing may prohibittransport of the reel using standard moving equipment and roads. Becausetube manufacturing facility 406 is at or near the in situ heat treatmentlocation, the equipment used to move the coiled tubing to the well sitesdoes not have to meet existing road transportation regulations and canbe designed to move large reels of tubing. In some embodiments theequipment used to move the reels of tubing is similar to cargo gantriesused to move shipping containers at ports and other facilities. In someembodiments, the gantries are wheeled units. In some embodiments, thecoiled tubing may be moved using a rail system or other transportationsystem.

The coiled tubing may be moved from the tubing manufacturing facility tothe well site using gantries 408. Drilling gantry 410 may be used at thewell site. Several drilling gantries 410 may be used to form wellboresat different locations. Supply systems for drilling fluid or other needsmay be coupled to drilling gantries 410 from central facilities 412.

Drilling gantry 410 or other equipment may be used to set the conductorfor the well. Drilling gantry 410 takes coiled tubing, passes the coiledtubing through a straightener, and a BHA attached to the tubing is usedto drill the wellbore to depth. In some embodiments, a composite coil ispositioned in the coiled tubing at tube manufacturing facility 406. Thecomposite coil allows the wellbore to be formed without having drillingfluid flowing between the formation and the tubing. The composite coilalso allows the BHA to be retrieved from the wellbore. The compositecoil may be pulled from the tubing after wellbore formation. Thecomposite coil may be returned to the tubing manufacturing facility tobe placed in another length of coiled tubing. In some embodiments, theBHAs are not retrieved from the wellbores.

In some embodiments, drilling gantry 410 takes the reel of coiled tubingfrom gantry 408. In some embodiments, gantry 408 is coupled to drillinggantry 410 during the formation of the wellbore. For example, the coiledtubing may be fed from gantry 408 to drilling gantry 410, or thedrilling gantry lifts the gantry to a feed position and the tubing isfed from the gantry to the drilling gantry.

The wellbore may be formed using the bottom hole assembly, coiled tubingand the drilling gantry. The BHA may be self-seeking to the destination.The BHA may form the opening at a fast rate. In some embodiments, theBHA forms the opening at a rate of about 100 meters per hour.

After the wellbore is drilled to total depth, the tubing may besuspended from the wellhead. An expansion cone may be used to expand thetubular against the formation. In some embodiments, the drilling gantryis used to install a heater and/or other equipment in the wellbore.

When drilling gantry 410 is finished at well site 414, the drillinggantry may release gantry 408 with the empty reel or return the emptyreel to the gantry. Gantry 408 may take the empty reel back to tubemanufacturing facility 406 to be loaded with another coiled tube.Gantries 408 may move on looped path 416 from tube manufacturingfacility 406 to well sites 414 and back to the tube manufacturingfacility.

Drilling gantry 410 may be moved to the next well site. Globalpositioning satellite information, lasers and/or other information maybe used to position the drilling gantry at desired locations. Additionalwellbores may be formed until all of the wellbores for the in situ heattreatment process are formed.

In some embodiments, positioning and/or tracking system may be utilizedto track gantries 408, drilling gantries 410, coiled tubing reels andother equipment and materials used to develop the in situ heat treatmentlocation. Tracking systems may include bar code tracking systems toensure equipment and materials arrive where and when needed.

Directionally drilled wellbores may be formed using steerable motors.Deviations in wellbore trajectory may be made using a slide drillingsystems or using rotary steerable systems (RSS). During use of slidedrilling systems, the mud motor rotates the bit downhole with little orno rotation of the drilling string from the surface during trajectorychanges. The BHA is fitted with a bent sub and/or a bent housing mudmotor for directional drilling. The bent sub and the drill bit areoriented in the desired direction. With little or no rotation of thedrilling string, the drill bit is rotated with the mud motor to set thetrajectory. When the desired trajectory is obtained, the entire drillingstring is rotated and drills straight rather than at an angle. Drill bitdirection changes may be made by utilizing torque/rotary tweaking tonudge the drill bit in the desired direction. FIG. 11 depicts time atdrilling string rotation during direction change versus rotation speed(rpm) of the drilling string for a conventional steerable motor BHAduring a drill bit direction change.

By controlling the amount of wellbore drilled in the sliding androtating modes, the wellbore trajectory can be controlled. Torque anddrag during sliding and rotating modes may limit the capabilities ofslide mode drilling. Steerable motors may produce tortuosity in theslide mode. Tortuosity may make further sliding more difficult. Manymethods have been developed, or are being developed, to improve on slidedrilling systems. Examples of improvements to slide drilling systemsinclude agitators, low weight bits, slippery muds, and torque/toolfacecontrol systems.

Limitations inherent in slide drilling led to the development of rotarysteerable systems (RSS). RSS drilling drills directionally withcontinuous rotation from the surface. There is no need to slide thedrilling string. Continuous rotation transfers weight to the drill bitmore efficiently, thus increasing the rate of penetration. Current RSSsystems may be mechanically and/or electrically complicated with a highcost of delivery due to service companies requiring a high rate ofreturn and due to relatively high failure rates for the systems.

In an embodiment, a dual motor RSS is used. The dual motor RSS allows abent sub and/or bent housing mud motor to change the trajectory of thedrilling while the drilling string remains in rotary mode. The dualmotor RSS uses a second motor in the bottom hole assembly (BHA) torotate a portion of the BHA in a direction opposite to the direction ofrotation of the drilling string. The addition of the second motor mayallow continuous forward rotation of a drilling string whilesimultaneously controlling the drill bit and, thus, the directionalresponse of the BHA. Drill bit control may be achieved with the rotationspeed of the drilling string.

FIG. 12 depicts a schematic representation of an embodiment of drillingstring 418 with dual motors in BHA 420. Drilling string 418 is coupledto BHA 420. BHA 420 includes motor 422A and motor 422B. Motor 422A maybe a bent sub and/or bent housing steerable mud motor that drives drillbit 424. Motor 422B may be a straight motor with a rotation directionthat is opposite to the rotation of drilling string 418 and/or motor422A. Motor 422B may operate at a relatively low rotary speed and havehigh torque capacity as compared to motor 422A. BHA 420 may includesensing array 426 between motors 422A, motor 422B.

Motor 422B may rotate in a direction opposite to the rotation ofdrilling string 418. Thus, portions of BHA 420 beyond motor 422B haveless rotation in the direction of rotation of drilling string 418 due tomotor 422B. The revolutions per minute (rpm) versus differentialpressure relationship for BHA 420 may be assessed prior to runningdrilling string 418 and the BHA 420 in the formation to determine thedifferential pressure at neutral drilling speed (i.e., when the drillingstring speed is equal and opposite to the speed of motor 422B). Measureddifferential pressure may be used by a control system during drilling tocontrol the speed of the drilling string relative to the neutraldrilling speed.

In some embodiments, motor 422B is operated at a substantially fixedspeed. For example, motor 422B may be operated at a speed of 30 rpm.Other speeds may be used as desired.

The rotation speed of drilling string 418 may be used to control thetrajectory of the wellbore being formed. For example, drilling string418 may initially be rotating at 40 rpm, and motor 422B rotates at 30rpm. The counter-rotation of motor 422B and drilling string 418 resultsin a forward rotation speed of 10 rpm in the lower portion of BHA 420(the portion of the BHA below motor 422B). When a directional coursecorrection is to be made, the speed of drilling string 418 is changed tothe neutral drilling speed. Because drilling string 418 is rotating,there is no need to lift drill bit 424 off the bottom of the borehole.Operating at neutral drilling speed may effectively cancel the torque ofthe drilling string so that drill bit 424 is subjected to torque inducedby motor 422A and the formation.

The continuous rotation of drilling string 418 keeps windup of thedrilling string consistent and stabilizes drill bit 424. Directionalchanges of drill bit 424 may be made by changing the speed of drillingstring 418. Using a dual motor RSS system allows the changing of thedirection of the drilling string to occur while the drilling stringrotates at or near the normal operating rotation speed of drillingstring 418. FIG. 13 depicts time at rotation speed during directionalchange versus change in drilling string rotating speed for the dualmotor drilling string during the drill bit direction change. Drill bitcontrol is substantially the same as for conventional slide modedrilling where torque/rotary tweaking is used to nudge the drill bit inthe desired direction, but 0 on the x-axis of FIG. 11 becomes N in FIG.13 (the neutral drilling string speed).

The connection of BHA 420 to drilling string 418 of the dual motor RSSsystem depicted in FIG. 12 may be subjected to the net effect of all thetorque components required to rotate the entire BHA (including torquegenerated at drill bit 424 during wellbore formation). Threadedconnections along drilling string 418 may include profile-matchedsleeves such as those known in the art for utilities drilling systems.

In some embodiments, the control system used to control wellboreformation includes a system that sets a desired rotation speed ofdrilling string 418 when direction changes in trajectory of the wellboreare to be implemented. The system may include fine tuning of the desireddrilling string rotation speed.

In certain embodiments, drilling string 418 is integrated with positionmeasurement and down hole tools (for example, sensing array 426) toautonomously control the hole path along a designed geometry. Anautonomous control system for controlling the path of drilling string418 may utilize at least three domains of functionality: measurement,trajectory, and control. Measurement may be made using sensor systemsand/or other equipment hardware that assess angles, distances, magneticfields and/or other data. Trajectory may include flight path calculationand algorithms that utilize physical measurements to calculate angularand spatial offsets from the design of the drilling string. The controlsystem may implement actions to keep the drilling string in the properpath. The control system may include tools that utilize software/controlinterfaces built into an operating system of in the drilling equipment,drilling string and/or BHA.

In certain embodiments, the control system utilizes position and anglemeasurements to define spatial and angular offsets from the desireddrilling geometry. The defined offsets may be used to determine asteering solution to move the trajectory of the drilling string (thus,the trajectory of the borehole) back into convergence with the desireddrilling geometry. The steering solution may be based on an optimumalignment solution in which a desired rate of curvature of the boreholepath is set and required angle change segments and angle changedirections for the path are assessed (for example, by computation).

In some embodiments, the control system uses a fixed angle change rateassociated with the drilling string, assesses the lengths of thesections of the drilling string, and assesses the desired directions ofthe drilling to autonomously execute and control movement of thedrilling string. Thus, the control system assesses position measurementsand controls of the drilling string to control the direction of thedrilling string.

In some embodiments, differential pressure or torque across motor 422Aand/or motor 422B is used to control the rate of penetration (ROP). Arelationship between ROP, weight-on-bit (WOB) and torque may be assessedfor drilling string 418. Measurements of torque and the ROP-WOB-torquerelationship may be used to control the feed rate (the ROP) of drillingstring 418 into the formation.

FIG. 14 depicts an embodiment for assessing a position of a firstwellbore relative to a second wellbore using multiple magnets. Firstwellbore 428A is formed in a subsurface formation. Wellbore 428A may beformed by directionally drilling in the formation along a desired path.For example, wellbore 428A may be horizontally or vertically drilled inthe subsurface formation.

Second wellbore 428B may be formed in the subsurface formation withdrill bit 424 on drilling string 418. In certain embodiments, drillingstring 418 includes one or more magnets 430. Wellbore 428B may be formedin a selected relationship to wellbore 428A. In certain embodiments,wellbore 428B is formed substantially parallel to wellbore 428A. Inother embodiments, wellbore 428B is formed at other angles relative towellbore 428A. In some embodiments, wellbore 428B is formedperpendicular relative to wellbore 428A.

In certain embodiments, wellbore 428A includes sensing array 426.Sensing array 426 may include two or more sensors 432. Sensors 432 maysense magnetic fields produced by magnets 430 in wellbore 428B. Thesensed magnetic fields may be used to assess a position of wellbore 428Arelative to wellbore 428B. In some embodiments, sensors 432 measure twoor more magnetic fields provided by magnets 430.

Two or more sensors 432 in wellbore 428A may allow for continuousassessment of the relative position of wellbore 428A versus wellbore428B. Using two or more sensors 432 in wellbore 428A may also allow thesensors to be used as gradiometers. In some embodiments, sensors 432 arepositioned in advance (ahead of) magnets 430. Positioning sensors 432 inadvance of magnets 430 allows the magnets to traverse past the sensorsso that the magnet's position (the position of wellbore 428B) ismeasurable continuously or “live” during drilling of wellbore 428B.Sensing array 426 may be moved intermittently (at selected intervals) tomove sensors 432 ahead of magnets 430. Positioning sensors 432 inadvance of magnets 430 also allows the sensors to measure, store, andzero the Earth's field before sensing the magnetic fields of themagnets. The Earth's field may be zeroed by, for example, using a nullfunction before arrival of the magnets, calculating backgroundcomponents from a known sensor attitude, or using a gradiometer setup.

The relative position of wellbore 428B versus wellbore 428A may be usedto adjust the drilling of wellbore 428B using drilling string 418. Forexample, the direction of drilling for wellbore 428B may be adjusted sothat wellbore 428B remains a set distance away from wellbore 428A andthe wellbores remain substantially parallel. In certain embodiments, thedrilling of wellbore 428B is continuously adjusted based on continuousposition assessments made by sensors 432. Data from drilling string 418(for example, orientation, attitude, and/or gravitational data) may becombined or synchronized with data from sensors 432 to continuouslyassess the relative positions of the wellbores and adjust the drillingof wellbore 428B accordingly. Continuously assessing the relativepositions of the wellbores may allow for coiled tubing drilling ofwellbore 428B.

In some embodiments, drilling string 418 may include two or more sensingarrays 426. Sensing arrays 426 may include two or more sensors 432.Using two or more sensing arrays 426 in drilling string 418 may allowfor the direct measurement of magnetic interference of magnets 430 onthe measurement of the Earth's magnetic field. Directly measuring anymagnetic interference of magnets 430 on the measurement of the Earth'smagnetic field may reduce errors in readings (for example, error topointing azimuth). The direct measurement of the field gradient from themagnets from within drill string 418 also provides confirmation ofreference field strength of the field to be measured from withinwellbore 428A.

FIG. 15 depicts an embodiment for assessing a position of a firstwellbore relative to a second wellbore using a continuous pulsed signal.Signal wire 434 may be placed in wellbore 428A. Sensor 432 may belocated in drilling string 418 in wellbore 428B. In certain embodiments,wire 434 provides a reference voltage signal (for example, a pulsed DCreference signal). In one embodiment, the reference voltage signal is a10 Hz pulsed DC signal. In one embodiment, the reference voltage signalis a 5 Hz pulsed DC signal.

The electromagnetic field provided by the voltage signal may be sensedby sensor 432. The sensed signal may be used to assess a position ofwellbore 428B relative to wellbore 428A.

In some embodiments, wire 434 is a ranging wire located in wellbore428A. In some embodiments, the voltage signal is provided by anelectrical conductor that will be used as part of a heater in wellbore428A. In some embodiments, the voltage signal is provided by anelectrical conductor that is part of a heater or production equipmentlocated in wellbore 428A. Wire 434, or other electrical conductors usedto provide the voltage signal, may be grounded so that there is nocurrent return along the wire or in the wellbore. Return current maycancel the electromagnetic field produced by the wire.

Where return current exists, the current may be measured and modeled togenerate a “net current” from which a voltage signal may be resolved.For example, in some areas, a 600 A signal current may only yield a 3-6A net current. Where it is not feasible to eliminate sufficient returncurrent along the wellbore containing the conductor, in someembodiments, two conductors may be installed in separate wellbores. Inthis method, signal wires from each of the existing wellbores areconnected to opposite voltage terminals of the signal generator. Thereturn current path is in this way guided through the earth from thecontactor region of one conductor to the other.

In certain embodiments, the reference voltage signal is turned on andoff (pulsed) so that multiple measurements are taken by sensor 432 overa selected time period. The multiple measurements may be averaged toreduce or eliminate resolution error in sensing the reference voltagesignal. In some embodiments, providing the reference voltage signal,sensing the signal, and adjusting the drilling based on the sensedsignals are performed continuously without providing any data to thesurface or any surface operator input to the downhole equipment. Forexample, an automated system located downhole may be used to perform allthe downhole sensing and adjustment operations.

The signal field generated by the net current passing through theconductors needs to be resolved from the general background fieldexisting when the signal field is “off”. A method for resolving thesignal field from the general background field on a continuous basis mayinclude: 1.) calculating background components based on the knownattitude of the sensors and the known value background field strengthand dip; 2.) a synchronized “null” function to be applied immediatelybefore the reference field is switched “on”; and/or 3.) synchronizedsampling of forward and reversed DC polarities (the subtraction of thesesampled values may effectively remove the background field yielding thereference total current field).

FIG. 16 depicts an embodiment for assessing a position of a firstwellbore relative to a second wellbore using a radio ranging signal.Sensor 432 may be placed in wellbore 428A. Source 436 may be located indrilling string 418 in wellbore 428B. In some embodiments, source 436 islocated in wellbore 428A and sensor 432 is located in wellbore 428B. Incertain embodiments, source 436 is an electromagnetic wave producingsource. For example, source 436 may be an electromagnetic sonde. Sensor432 may be an antenna (for example, an electromagnetic or radioantenna). In some embodiments sensor 432 is located in part of a heaterin wellbore 428A.

The signal provided by source 436 may be sensed by sensor 432. Thesensed signal may be used to assess a position of wellbore 428B relativeto wellbore 428A. In certain embodiments, the signal is continuouslysensed using sensor 432. The continuously sensed signal may be used tocontinuously and/or automatically adjust the drilling of wellbore 428B.The continuous sensing of the electromagnetic signal may be dualdirectional—creating a data link between transceivers. Theantenna/sensor 432 may be directly connected to a surface interfaceallowing a data link between surface and subsurface to be established.

In some embodiments, source 436 and/or sensor 432 are sources andsensors used in a walkover radio locater system. Walkover radio locatersystems are, for example, used in telecommunications to locateunderground lines. In some embodiments, the walkover radio locatedsystem components may be modified to be located in wellbore 428A andwellbore 428B so that the relative positions of the wellbores areassessable using the walkover radio located system components.

In certain embodiments, multiple sources and multiple sensors may beused to assess and adjust the drilling of one or more wellbores. FIG. 17depicts an embodiment for assessing a position of a plurality of firstwellbores relative to a plurality of second wellbores using radioranging signals. Sources 436 may be located in a plurality of wellbores428A. Sensors 432 may be located in one or more wellbores 428B. In someembodiments, sources 436 are located in wellbores 428B and sensors 432are located in wellbores 428A.

In one embodiment, wellbores 428A are drilled substantially verticallyin the formation and wellbores 428B are drilled substantiallyhorizontally in the formation. Thus, wellbores 428B are substantiallyperpendicular relative to wellbores 428A. Sensors 432 in wellbores 428Bmay detect signals from one or more of sources 436. Detecting signalsfrom more than one source may allow for more accurate measurement of therelative positions of the wellbores in the formation. In someembodiments, electromagnetic attenuation and phase shift detected frommultiple sources is used to define the position of a sensor (and thewellbore). The paths of the electromagnetic radio waves may be predictedto allow detection and use of the electromagnetic attenuation and thephase shift to define the sensor position.

FIGS. 18 and 19 depict an embodiment for assessing a position of a firstwellbore relative to a second wellbore using a heater assembly as acurrent conductor. In some embodiments, a heater may be used as a longconductor for a reference current (pulsed DC or AC) to be injected forassessing a position of a first wellbore relative to a second wellbore.If a current is injected onto an insulated internal heater element, thecurrent may pass to the end of heater element 438 where it makes contactwith heater casing 440. This is the same current path when the heater isin heating mode. Once the current passes across to bottom hole assembly420B, one may assume at least some of the current is absorbed by theearth on the current's return trip back to the surface, resulting in anet current (difference in Amps in (A_(i)) versus Amps out (A_(o))).

Resulting electromagnetic field 442 is measured by sensor 432 (forexample, a transceiving antenna) in bottom hole assembly 420A of firstwellbore 428A being drilled in proximity to the location of heater 438.A predetermined “known” net current in the formation may be relied uponto provide a reference magnetic field.

The injection of the reference current may be rapidly pulsed andsynchronized with the receiving antenna and/or sensor data. Access to ahigh data rate signal from the magnetometers can be used to filter theeffects of sensor movement during drilling. The measurement of thereference magnetic field may provide a distance and direction to theheater. Averaging many of these results will provide the position of theactively drilled hole. The known position of the heater and known depthof the active sensors may be used to assess position coordinates ofeasting, northing, and elevation.

The quality of data generated with such a method may depend on theaccuracy of the net current prediction along the length of the heater.Using formation resistivity data, a model may be used to predict thelosses to earth along the bottom hole assembly. The bottom hole assemblymay be in direct contact with the formation and borehole fluids.

The current may be measured on both the element and the bottom holeassembly at the surface. The difference in values is the overall currentloss to the formation. It is anticipated that the net field strengthwill vary along the length of the heater. The field is expected to begreater at the surface when the positive voltage applies to the bottomhole assembly.

If there are minimal losses to earth in the formation, the net field maynot be strong enough to provide a useful detection range. In someembodiments, a net current in the range of about 2 A to about 50 A,about 5 A to about 40 A, or about 10 A to about 30 A, may be employed.

In some embodiments, two heaters are used as a long conductor for areference current (pulsed DC or AC) to be injected for assessing aposition of a first wellbore relative to a second wellbore. Utilizingtwo separate heater elements may result in relatively better control ofreturn current path and therefore better control of reference currentstrength.

A two heater method may not rely on the accuracy of a “model of currentloss to formation”, as current is contained in the heater element alongthe full length of the heaters. Current may be rapidly pulsed andsynchronized with the transceiving antenna and/or sensor data to resolvedistance and direction to the heater. FIGS. 20 and 21 depict anembodiment for assessing a position of first wellbore 428A relative tosecond wellbore 428B using two heater assemblies 438A and 438B ascurrent conductors. Resulting electromagnetic field 442 is measured bysensor 432 (for example, a transceiving antenna) in bottom hole assembly420A of first wellbore 428A being drilled in proximity to the locationof heaters 438A and 438A in second wellbore 428B.

In some embodiments, parallel well tracking may be used for assessing aposition of a first wellbore relative to a second wellbore. Parallelwell tracking may utilize magnets of a known strength and a known lengthpositioned in the pre-drilled second wellbore. Magnetic sensorspositioned in the active first wellbore may be used to measure the fieldfrom the magnets in the second wellbore. Measuring the generatedmagnetic field in the second wellbore with sensors in the first wellboremay assess distance and direction of the active first wellbore. In someembodiments, magnets positioned in the second wellbore may be carefullypositioned and multiple static measurements taken to resolve any general“background” magnetic field. Background magnetic fields may be resolvedthrough use of a null function before positioning the magnets in thesecond wellbore, calculating background components from known sensorattitudes, and/or a gradiometer setup.

In some embodiments, reference magnets may be positioned in the drillingbottom hole assembly of the first wellbore. Sensors may be positioned inthe passive second wellbore. The prepositioned sensors may be nulledprior to the arrival of the magnets in the detectable range to eliminateEarth's background field. This may significantly reduce the timerequired to assess the position and direction of the first wellboreduring drilling as the bottom hole assembly continues drilling with nostoppages. The commercial availability of low cost sensors such as aterrella (utilizing magnetoresistives rather than fluxgates) may beincorporated into the wall of a deployment coil at useful separations.

In some embodiments, multiple types of sources may be used incombination with two or more sensors to assess and adjust the drillingof one or more wellbores. A method of assessing a position of a firstwellbore relative to a second wellbore may include a combination ofangle sensors, telemetry, and/or ranging systems. Such a method may bereferred to as umbilical position control.

Angle sensors may assess an attitude (azimuth, inclination, and roll) ofa bottom hole assembly. Assessing the attitude of a bottom hole assemblymay include measuring, for example, azimuth, inclination, and/or roll.Telemetry may transmit data (for example, measurements) between thesurface and, for example, sensors positioned in a wellbore. Ranging mayassess the position of a bottom hole assembly in a first wellborerelative to a second wellbore. The second wellbore, in some embodiments,may include an existing, previously drilled wellbore.

FIG. 22 depicts a first embodiment of the umbilical positioning controlsystem employing a wireless linking system. Second transceiver 444B maybe deployed from the surface down second wellbore 428B, whicheffectively functions as a telemetry system for first wellbore 428A. Atransceiver may communicate with the surface via wire or fiber optics(for example, wire 446) coupled to the transceiver.

In first wellbore 428A, sensor 432A may be coupled to first transceivingantenna 444A. First transceiving antenna 444A may communicate withsecond transceiving antenna 444B in second wellbore 428B. The firsttransceiving antenna may be positioned on bottom hole assembly 420.Sensors coupled to the first transceiving antenna may include, forexample, magnetometers and/or accelerometers. In certain embodiments,sensors coupled to the first transceiving antenna may include dualmagnetometer/accelerometer sets.

To accomplish data transfer, first transceiving antenna 444A transmits(“short hops”) measured data through the ground to second transceivingantenna 444B located in the second wellbore. The data may then betransmitted to the surface via embedded wires 446 in the deploymenttubular.

Two redundant ranging systems may be utilized for umbilical controlsystems. A first ranging system may include a version of a plasma wavetracker (PWT). FIG. 23 depicts an embodiment of umbilical positioningcontrol system employing a magnetic gradiometer system. A PWT mayinclude a pair of sensors 432B (for example, magnetometer/accelerometersets) embedded in the wall of second wellbore deployment coil (theumbilical). These sensors act as a magnetic gradiometer to detect themagnetic field from reference magnet 430 installed in bottom holeassembly 420 of first wellbore 428A. In a horizontal section of thesecond wellbore, a relative position of the umbilical to the firstwellbore reference magnet(s) may be determined by the gradient. Data maybe sent to the surface through fiber optic cables or wires 446.

FIGS. 24 and 25 depict an embodiment of umbilical positioning controlsystem employing a combination of systems being used in a first stage ofdeployment and a second stage of deployment, respectively. A third setof sensors 432C (for example, magnetometers) may be located on theleading end of wire 446. Sensors 432B, 432C may detect magnetic fieldsproduced by reference magnets 430. The role of sensors 432C may includemapping the Earth's magnetic field ahead of the arrival of the gradientsensors and confirming that the angle of the deployment tubular matchesthat of the originally defined hole geometry. Since the attitude of themagnetic field sensors are known based on the original survey of thehole and the checks of sensors 432B, 432C, the values for the Earth'sfield can be calculated based on current sensor orientation(inclinometers measure the roll and inclination and the model definesazimuth, Mag total, and Mag dip). Using this method, an estimation ofthe field vector due to reference magnets 430 can be calculated allowingdistance and direction to be resolved.

A second ranging system may be based on using the signal strength andphase of the “through the earth” wireless link (for example, radio)established between first transceiving antenna 444A in first wellbore428A and second transceiving antenna 444B in second wellbore 428B.Sensor 432A may be coupled to first transceiving antenna 444A. Given theclose spacing of wellbores 428A, 428B and the variability in electricalproperties of the formation, the attenuation rates for theelectromagnetic signal may be predictable. Predictable attenuation ratesfor the electromagnetic signal allow the signal strength to be used as ameasure of separation between first and second transceiver pairs 444A,444B. The vector direction of the magnetic field induced by theelectromagnetic transmissions from the first wellbore may provide thedirection. A transceiver may communicate with the surface via wire orfiber optics (for example, wire 446) coupled to the transceiver.

With a known resistivity of the formation and operating frequency, thedistance between the source and point of measurement may be calculated.FIG. 26 depicts two examples of the relationship between power receivedand distance based upon two different formations with differentresistivities 448 and 450. If 10 W is transmitted at a 12 Hz frequencyin 20 ohm·m formation 448, the power received amounts to approximately9.10 W at 30 m distance. The resistivity was chosen at random and mayvary depending on where you are in the ground. If a higher resistivitywas chosen at the given frequency, such as 100 ohm·m formation 450, alower attenuation is observed, and a low characterization occurswhereupon it receives 9.58 W at 30 m distance. Thus, high resistivity,although transmitting power desirably, shows a negative affect inelectromagnetic ranging possibilities. Since the main influence inattenuation is the distance itself, calculations may be made solving forthe distance between a source and a point of measurement.

The frequency the electromagnetic source operates on is another factorthat affects attenuation. Typically, the higher the frequency, thehigher the attenuation and vice versa. A strategy for choosing betweenvarious frequencies may depend on the formation chosen. For example,while the attenuation at a resistivity of 100 ohm·m may be good for datacommunications, it may not be sufficient for distance calculations.Thus, a higher frequency may be chosen to increase attenuation.Alternatively, a lower frequency may be chosen for the opposite purpose.

Wireless data communications in ground may allow an opportunity forelectromagnetic ranging and the variable frequency it operates on mustbe observed to balance out benefits for both functionalities. Benefitsof wireless data communication may include, but are not be limitedto: 1) automatic depth sync through the use of ranging and telemetry; 2)fast communications with dedicated hardwired (for example, optic fiber)coil for a transceiving antenna running in, for example, the secondwellbore; 3) functioning as an alternative method for fast communicationwhen hardwire in, for example, the first wellbore is not available; 4)functioning in under balanced and over balanced drilling; 5) providing asimilar method for transmitting control commands to a bottom holeassembly; 6) sensors are reusable reducing costs and waste; 7)decreasing noise measurement functions split between the first wellboreand the second wellbore; and/or 8) multiple position measurementtechniques simultaneously supported may provide real time best estimateof position and attitude.

In some embodiments, it may be advisable to employ sensors able tocompensate for magnetic fields produced internally by carbon steelcasing built in the vertical section of a reference hole (for example,high range magnetometers). In some embodiments, modification may be madeto account for problems with wireless antenna communications betweenwellbores penetrating through wellbore casings.

Increasing the density and quality of directional data during drillingmay increase the accuracy and efficiency in forming wellbores insubsurface formations. The quality of directional data may be diminishedby vibrations and angular accelerations during rotary drilling,especially during rotary drilling segments of wellbore formation usingslide mode drilling.

In certain embodiments, the quality of the data assessed during rotarydrilling is increased by installing directional sensors in anon-rotating housing. FIG. 27 depicts an embodiment of drilling string418 with non-rotating sensor 432. In certain embodiments, non-rotatingsensor 432 is located behind motor 422. Motor 422 may be a steerablemotor. Motor 422 may be located behind drill bit 424. In certainembodiments, sensor 432 is located between non-magnetic components indrilling string 418. In some embodiments, non-rotating sensor 432 islocated in a sleeve over motor 422. In some embodiments, non-rotatingsensor 432 is run on any bottom hole assembly (BHA) for improved dataassessment.

In certain embodiments, non-rotating sensor 432 includes one or moretransceivers for communicating data either into drilling string 418within the BHA or to similar transceivers in nearby boreholes. Thetransceivers may be used for telemetry of data and/or as a means ofposition assessment or verification. In certain embodiments, use ofnon-rotating sensor 432 allows continuous position measurement.Continuous position measurement may be useful in control systems usedfor drilling position systems and/or umbilical position control.

Pieces of formation or rock may protrude or fall into the wellbore dueto various failures including rock breakage or plastic deformationduring and/or after wellbore formation. Protrusions may interfere withdrill string movement and/or the flow of drilling fluids. Protrusionsmay prevent running tubulars into the wellbore after the drill stringhas been removed from the wellbore. Significant amounts of materialentering or protruding into the wellbore may cause wellbore integrityfailure and/or lead to the drill string becoming stuck in the wellbore.Some causes of wellbore integrity failure may be in situ stresses andhigh pore pressures. Mud weight may be increased to hold back theformation and inhibit wellbore integrity failure during wellboreformation. When increasing the mud weight is not practical, the wellboremay be reamed.

Reaming the wellbore may be accomplished by moving the drill string upand down one joint while rotating and circulating. Picking the drillstring up can be difficult because of material protruding into theborehole above the bit or BHA (bottom hole assembly). Picking up thedrill string may be facilitated by placing upward facing cuttingstructures on the drill bit. Without upward facing cutting structures onthe drill bit, the rock protruding into the borehole above the drill bitmust be broken by grinding or crushing rather than by cutting. Grindingor crushing may induce additional wellbore failure.

Moving the drill string up and down may induce surging or pressurepulses that contribute to wellbore failure. Pressure surging orfluctuations may be aggravated or made worse by blockage of normaldrilling fluid flow by protrusions into the wellbore. Thus, attempts toclear the borehole of debris may cause even more debris to enter thewellbore.

When the wellbore fails further up the drill string than one joint fromthe drill bit, the drill string must be raised more than one joint.Lifting more than one joint in length may require that joints be removedfrom the drill string during lifting and placed back on the drill stringwhen lowered. Removing and adding joints requires additional time andlabor, and increases the risk of surging as circulation is stopped andstarted for each joint connection.

In some embodiments, cutting structures may be positioned at variouspoints along the drill string. Cutting structures may be positioned onthe drill string at selected locations, for example, where the diameterof the drill string or BHA changes. FIG. 28A and FIG. 28B depict cuttingstructures 452 located at or near diameter changes in drill string 418near to drill bit 424 and/or BHA 420. As depicted in FIG. 28C, cuttingstructures 452 may be positioned at selected locations along the lengthof BHA 420 and/or drill string 418 that has a substantially uniformdiameter. Cutting structures 452 may remove formation that extends intothe wellbore as the drilling string is rotated. Cuttings formed by thecutting structures 452 may be removed from the wellbore by the normalcirculation used during the formation of the wellbore.

FIG. 29 depicts an embodiment of drill bit 424 including cuttingstructures 452. Drill bit 424 includes downward facing cuttingstructures 452 b for forming the wellbore. Cutting structures 452 a areupwardly facing cutting structures for reaming out the wellbore toremove protrusions from the wellbore.

In some embodiments, some cutting structures may be upwardly facing,some cutting structures may be downwardly facing, and/or some cuttingstructures may be oriented substantially perpendicular to the drillstring. FIG. 30 depicts an embodiment of a portion of drilling string418 including upward facing cutting structures 452 a, downward facingcutting structures 452 b, and cutting structures 452 c that aresubstantially perpendicular to the drill string. Cutting structures 452a may remove protrusions extending into wellbore 428 that would inhibitupward movement of drill string 418. Cutting structures 452 a mayfacilitate reaming of wellbore 428 and/or removal of drill string 418from the wellbore for drill bit change, BHA maintenance and/or whentotal depth has been reached. Cutting structures 452 b may removeprotrusions extending into wellbore 428 that would inhibit downwardmovement of drill string 418. Cutting structures 452 c may ensure thatenlarged diameter portions of drill string 418 do not become stuck inwellbore 428.

Positioning downward facing cutting structures 452 b at variouslocations along a length of the drill string may allow for reaming ofthe wellbore while the drill bit forms additional borehole at the bottomof the wellbore. The ability to ream while drilling may avoid pressuresurges in the wellbore caused by lifting the drill string. Reaming whiledrilling allows the wellbore to be reamed without interrupting normaldrilling operation. Reaming while drilling allows the wellbore to beformed in less time because a separate reaming operation is avoided.Upward facing cutting structures 452 a allow for easy removal of thedrill string from the wellbore.

In some embodiments, the drill string includes a plurality of cuttingstructures positioned along the length of the drill string, but notnecessarily along the entire length of the drill string. The cuttingstructures may be positioned at regular or irregular intervals along thelength of the drill string. Positioning cutting structures along thelength of the drill string allows the entire wellbore to be reamedwithout the need to remove the entire drill string from the wellbore.

Cutting structures may be coupled or attached to the drill string usingtechniques known in the art (for example, by welding). In someembodiments, cutting structures are formed as part of a hinged ring ormulti-piece ring that may be bolted, welded, or otherwise attached tothe drill string. In some embodiments, the distance that the cuttingstructures extend beyond the drill string may be adjustable. Forexample, the cutting element of the cutting structure may includethreading and a locking ring that allows for positioning and setting ofthe cutting element.

In some wellbores, a wash over or over-coring operation may be needed tofree or recover an object in the wellbore that is stuck in the wellboredue to caving, closing, or squeezing of the formation around the object.The object may be a canister, tool, drill string, or other item. Awash-over pipe with downward facing cutting structures at the bottom ofthe pipe may be used. The wash over pipe may also include upward facingcutting structures and downward facing cutting structures at locationsnear the end of the wash-over pipe. The additional upward facing cuttingstructures and downward facing cutting structures may facilitate freeingand/or recovery of the object stuck in the wellbore. The formationholding the object may be cut away rather than broken by relying onhydraulics and force to break the portion of the formation holding thestuck object.

A problem in some formations is that the formed borehole begins to closesoon after the drill string is removed from the borehole. Boreholeswhich close up soon after being formed make it difficult to insertobjects such as tubulars, canisters, tools, or other equipment into thewellbore. In some embodiments, reaming while drilling applied to thecore drill string allows for emplacement of the objects in the center ofthe core drill pipe. The core drill pipe includes one or more upwardfacing cutting structures in addition to cutting structures located atthe end of the core drill pipe. The core drill pipe may be used to formthe wellbore for the object to be inserted in the formation. The objectmay be positioned in the core of the core drill pipe. Then, the coredrill pipe may be removed from the formation. Any parts of the formationthat may inhibit removal of the core drill pipe are cut by the upwardfacing cutting structures as the core drill pipe is removed from theformation.

Replacement canisters may be positioned in the formation using over coredrill pipe. First, the existing canister to be replaced is over cored.The existing canister is then pulled from within the core drill pipewithout removing the core drill pipe from the borehole. The replacementcanister is then run inside of the core drill pipe. Then, the core drillpipe is removed from the borehole. Upward facing cutting structurespositioned along the length of the core drill pipe cut portions of theformation that may inhibit removal of the core drill pipe.

FIG. 31 depicts a schematic drawing of a drilling system. Pilot bit 454may form an opening in the formation. Pilot bit 454 may be followed byfinal diameter bit 456. In some embodiments, pilot bit 454 may be about2.5 cm in diameter. Pilot bit 454 may be one or more meters below finaldiameter bit 456. Pilot bit 454 may rotate in a first direction andfinal diameter bit 456 may rotate in the opposite direction.Counter-rotating bits may allow for the formation of the wellbore alonga desired path. Standard mud may be used in both pilot bit 454 and finaldiameter bit 456. In some embodiments, air or mist may be used as thedrilling fluid in one or both bits.

During some in situ heat treatment processes, wellbores may need to beformed in heated formations. Wellbores drilled into hot formation may beadditional or replacement heater wells, additional or replacementproduction wells and/or monitor wells. Cooling while drilling mayenhance wellbore stability, safety, and longevity of drilling tools.When the drilling fluid is liquid, significant wellbore cooling canoccur due to the circulation of the drilling fluid.

In some in situ heat treatment processes, a barrier formed around all ora portion of the in situ heat treatment process is formed by freezewells that form a low temperature zone around the freeze wells. Aportion of the cooling capacity of the freeze well equipment may beutilized to cool the equipment needed to drill into the hot formation.Drilling bits may be advanced slowly in hot sections to ensure that theformed wellbore cools sufficiently to preclude drilling problems.

When using conventional circulation, drilling fluid flows down theinside of the drilling string and back up the outside of the drillingstring. Other circulation systems, such as reverse circulation, may alsobe used. In some embodiments, the drill pipe may be positioned in apipe-in-pipe configuration.

Drilling string used to form the wellbore may function as a counter-flowheat exchanger. The deeper the well, the more the drilling fluid heatsup on the way down to the drill bit as the drilling string passesthrough heated portions of the formation. Thus, the counter-flow heatexchanger effect reduces downhole cooling. When normal circulation doesnot deliver low enough temperature drilling fluid to the drill bit toprovide adequate cooling, two options have been employed to enhancecooling. Mud coolers on the surface can be used to reduce the inlettemperature of the drilling fluid being pumped downhole. If cooling isstill inadequate, insulated drilling string can be used to reduce thecounter-flow heat exchanger effect.

FIG. 32 depicts a schematic drawing of a system for drilling into a hotformation. Cold mud is introduced to drilling bit 456 through conduit458. As the drill bit penetrates into the formation, the mud cools thedrill bit and the surrounding formation. In an embodiment, a pilot holeis formed first and the wellbore is finished with a larger drill bitlater. In an embodiment, the finished wellbore is formed without a pilothole being formed. Well advancement is very slow to ensure sufficientcooling.

In some embodiments, all or a portion of conduit 458 may be insulated toreduce heat transfer to the cooled mud as the mud passes into theformation. Insulating all or a portion of conduit 458 may allow coldermud to be provided to the drill bit than if the conduit is notinsulated. Conduit 458 may be insulated for greater than ¼ of the lengthof the conduit, for greater than ½ the length of the conduit, forgreater than ¾ the length of the conduit, or for substantially all ofthe length of the conduit.

FIG. 33 depicts a schematic drawing of a system for drilling into a hotformation. Mud is introduced through conduit 458. Closed loop system 460is used to circulate cooling fluid within conduit 458. Closed loopsystem 460 may include a pump, a heat exchanger system, inlet leg 462,and exit leg 464. The pump may be used to draw cooling fluid throughexit leg 464 to the heat exchanger system. The pump and the heatexchanger system may be located at the surface. The heat exchangersystem may be used to remove heat from cooling fluid returning throughexit leg 464. Cooling fluid may exit the heat exchanger system intoinlet leg 462. Cooling fluid may flow down inlet leg 462 in conduit 458to a region near drill bit 456. The cooling fluid flows out of conduit458 through exit leg 464. The cooling fluid cools the drilling mud andthe formation as drilling bit 456 slowly penetrates into the formation.The cooled drilling mud may also cool the bottom hole assembly.

All or a portion of inlet leg 462 may be insulated to inhibit heattransfer to the cooling fluid entering closed loop system 460 fromcooling fluid leaving the closing loop system through exit leg 464and/or with the drilling mud. Insulating all or a portion of inlet leg462 may also maintain the cooling fluid at a low temperature so that thecooling fluid is able to absorb heat from the drilling mud in a regionnear drill bit 456 so that the drilling mud is able to cool the drillbit and/or the formation. In some embodiments, all or a portion of inletleg 462 is made of a material with low thermal conductivity to limitheat transfer to the cooling fluid in the inlet leg. For example, all ora portion of inlet leg 462 may be made of a polyethylene pipe.

In some embodiments, inlet leg 462 and the exit leg 464 for the coolingfluid are arranged in a conduit-in-conduit configuration. In oneembodiment, cooling fluid flows down the inner conduit (the inlet leg)and returns through the space between the inner conduit and the outerconduit (the exit leg). The inner conduit may be insulated or made of amaterial with low thermal conductivity to inhibit or reduce heattransfer between the cooling fluid going down the inner conduit and thecooling fluid returning through the space between the inner conduit andthe outer conduit. In some embodiments, the inner conduit may be made ofa polymer, such as high density polyethylene.

FIG. 34 depicts a schematic drawing of a system for drilling into a hotformation. Drilling mud is introduced through conduit 458. Pilot bit 454is followed by final diameter drill bit 456. Closed loop system 460 isused to circulate cooling fluid. Closed loop system may be the same typeof system as described with reference to FIG. 33, with the addition ofinlet leg 462′ and exit leg 464′ that supply and remove cooling fluidthat cools the drilling mud supplied to pilot bit 454. The cooling fluidcools the drilling mud supplied to drill bits 454, 456. The cooleddrilling mud cools drill bits 454, 456 and/or the formation near thedrill bits.

For various reasons including lost circulation, wells are frequentlydrilled with gas (for, example air, nitrogen, carbon dioxide, methane,ethane, and other light hydrocarbon gases) as the drilling fluidprimarily to maintain a low equivalent circulating density (low downholepressure gradient). Gas has low potential for cooling the wellborebecause mass flow rates of gas drilling are much lower than when liquiddrilling fluid is used. Also, gas has a low heat capacity compared toliquid. As a result of heat flow from the outside to the inside of thedrilling string, the gas arrives at the drill bit at close to formationtemperature. Controlling the inlet temperature of the gas (analogous tousing mud coolers when drilling with liquid) or using insulated drillingstring only marginally reduces the counter-flow heat exchanger effectwhen gas drilling. Some gases are more effective than others attransferring heat, but the use of gasses with better heat transferproperties does not significantly improve wellbore cooling while gasdrilling.

Gas drilling may deliver the drilling fluid to the drill bit at close tothe formation temperature. The gas may have little capacity to absorbheat. A defining feature of gas drilling is the low density column inthe annulus. Immaterial to the benefits of gas drilling is the phase ofthe drilling fluid flowing down the inside of the drilling pipe. Thus,the benefits of gas drilling can be accomplished if the drilling fluidis liquid while flowing down the drilling string and gas while flowingback up the annulus. The heat of vaporization is used to cool the drillbit and the formation rather than the sensible heat of the drillingfluid.

An advantage of this approach is that even though the liquid arrives atthe bit at close to formation temperature, it can absorb heat byvaporizing. In fact, the heat of vaporization is typically larger thanthe heat that can be absorbed by a temperature rise. As a comparison,consider drilling a 7⅞″ wellbore with 3½″ drilling string circulatinglow density mud at about 203 gpm and with about a 100 ft/min typicalannular velocity. Drilling through a 450° F. zone at 1000 feet willresult in a mud exit temperature about 8° F. hotter than the inlettemperature. This results in the removal of about 14,000 Btu/min. Theremoval of this much heat lowers the bit temperature from about 450° F.to about 285° F. If liquid water is injected down the drilling stringand allowed to boil at the bit and steam is produced up the annulus, themass flow required to remove ½″ cuttings is about 34 lbm/min assumingthe back pressure is about 100 psia. At 34 lbm/min the heat removed fromthe wellbore would be about 34 lbm/min×(1187-180) Btu/lbm or about34,000 Btu/min. This heat removal amount is about 2.4 times the liquidcooling case. Thus, at reasonable annular steam flow rates, asignificant amount of heat can be removed by vaporization.

The high velocities required for gas drilling are achieved by theexpansion that occurs during vaporization rather than by employingcompressors on the surface. Eliminating the need for compressors maysimplify the drilling process, eliminate the cost of the compressor, andeliminate a source of heat applied to the drilling fluid on the way tothe drill bit.

Critical to the process of delivering liquid to the drill bit ispreventing boiling within the drilling string. If the drilling fluidflowing downwards boils before reaching the drill bit, the heat ofvaporization is used to extract heat from the drilling fluid flowing upthe annulus. The heat transferred from the annulus (outside the drillingstring) to inside the drilling string boiling the fluid is heat that isnot rejected from the well when drilling fluid reaches the surface.Boiling that occurs inside of the drilling string before the drillingfluid reaches the bottom of the hole is not beneficial to drill bitand/or wellbore cooling.

If the pressure in the drilling string is maintained above the boilingpressure for a given temperature by use of a back pressure device, thenthe transfer of heat from outside the drilling string to inside can beminimized or essentially eliminated. The liquid supplied to the drillbit may be vaporized. Vaporization may result in the drilling fluidadsorbing the heat of vaporization from the drill bit and formation. Forexample, if the back pressure device is set to allow flow only when theback pressure is above 250 psi, the fluid within the drilling stringwill not boil unless the temperature is above 400° F. If the temperatureof the formation is above this (for example, 500° F.) steps may be takento inhibit boiling of the fluid on the way down to the drill bit. In anembodiment, the back pressure device is set to maintain a back pressurethat inhibits boiling of the drilling fluid at the temperature of theformation (for example, 580 psi to inhibit boiling up to a temperatureof 500° F.). In another embodiment, the drilling pipe is insulatedand/or the drilling fluid is cooled so that the back pressure device isable to maintain the drilling fluid that reaches the drill bit as aliquid.

Two back pressure devices that may be used to maiainin elevated pressurewithin the drilling string are a choke and a pressure activated valve.Other types of back pressure devices may also be used. Chokes have arestriction in flow area that creates back pressure by resisting flow.Resisting the flow results in increased upstream pressure to force thefluid through the restriction. Pressure activated valves do not openuntil a minimum upstream pressure is obtained. The pressure differenceacross a pressure activated valves may determine if the pressureactivated valve is open to allow flow or closed.

In some embodiments, both a choke and pressure activated valve may beused. A choke can be the bit nozzles allowing the liquid to be jettedtoward the drill bit and the bottom of the hole. The bit nozzles mayenhance drill bit cleaning and help prevent fouling of the drill bit andpressure activated valve. Fouling may occur if boiling in the drill bitor pressure activated valve caused solids to precipitate. The pressureactivated valve may prevent premature boiling at low flow rates belowflow rates at which the chokes are effective.

Additives may be added to the drilling fluid. The additives may modifythe properties of the fluids in the liquid phase and/or the gas phase.Additives may include, but are not limited to surfactants to foam thefluid, additives to chemically alter the interaction of the fluid withthe formations (for example, to stabilize the formation), additives tocontrol corrosion, and additives for other benefits.

In some embodiments, a non-condensable gas may be added to the drillingfluid pumped down the drilling string. The non-condensable gas may be,but is not limited to nitrogen, carbon dioxide, air, and mixturesthereof. Adding the non-condensable gas results in pumping a two phasemixture down the drilling string. One reason for adding thenon-condensable gas is to enhance the flow of the fluid out of theformation. The presence of the non-condensable gas may inhibitcondensation of the vaporized drilling fluid and help to carry cuttingsout of the formation. In some embodiments, one or more heaters may bepresent at one or more locations in the wellbore to provide heat thatinhibits condensation and reflux of drilling fluid leaving theformation.

Managed pressure drilling and/or managed volumetric drilling may be usedduring formation of wellbores. The back pressure on the wellbore may beheld to a prescribed value to control the down hole pressure. Similarly,the volume of fluid entering and exiting the well may be balanced sothat there is no net influx or out-flux of drilling fluid into theformation.

In some embodiments, one piece of equipment may be used to drillmultiple wellbores in a single day. The wellbores may be formed atpenetration rates that are many times faster than the penetration ratesusing conventional drilling with drilling bits. The high penetrationrate allows separate equipment to accomplish drilling and casingoperations in a more efficient manner than using a one-trip approach.The high penetration rate requires accurate, real time directionaldrilling in three dimensions.

In some embodiments, high penetration rates may be attained usingcomposite coiled tubing in combination with particle jet drilling.Particle jet drilling forms an opening in a formation by impacting theformation with high pressure fluid containing particles to removematerial from the formation. The particles may function as abrasives. Inaddition to composite coiled tubing and particle jet drilling, adownhole electric orienter, bubble entrained mud, downhole inertialnavigation, and a computer control system may be needed. Other types ofdrilling fluid and drilling fluid systems may be used instead of usingbubble entrained mud. Such drilling fluid systems may include, but arenot limited to, straight liquid circulation systems, multiphasecirculation systems using liquid and gas, and/or foam circulationsystems.

Composite coiled tubing has a fatigue life that is significantly greaterthan the fatigue life of coiled steel tubing. Composite coiled tubing isavailable from Airborne Composites BV (The Hague, The Netherlands).Composite coiled tubing can be used to form many boreholes in aformation. The composite coiled tubing may include integral power linesfor providing electricity to downhole tools. The composite coiled tubingmay include integral data lines for providing real time informationregarding downhole conditions to the computer control system and forsending real time control information from the computer control systemto the downhole equipment.

The coiled tubing may include an abrasion resistant outer sheath. Theouter sheath may inhibit damage to the coiled tubing due to slidingexperienced by the coiled tubing during deployment and retrieval. Insome embodiments, the coiled tubing may be rotated during use in lieu ofor in addition to having an abrasion resistant outer sheath to minimizeuneven wear of the composite coiled tubing.

Particle jet drilling may advantageously allow for stepped changes inthe drilling rate. Drill bits are no longer needed and downhole motorsare eliminated. Particle jet drilling may decouple cutting formation toform the borehole from the bottom hole assembly. Decoupling cuttingformation to form the borehole from the bottom hole assembly reduces theimpact that variable formation properties (for example, formation dip,vugs, fractures and transition zones) have on wellbore trajectory. Bydecoupling cutting formation to form the borehole from the bottom holeassembly, directional drilling may be reduced to orienting one or moreparticle jet nozzles in appropriate directions. Additionally, particlejet drilling may be used to under ream one or more portions of awellbore to form a larger diameter opening.

Particles may be introduced into a high pressure injection stream duringparticle jet drilling. The ability to achieve and circulate highparticle laden fluid under high pressure may facilitate the successfuluse of particle jet drilling. One type of pump that may be used forparticle jet drilling is a heavy duty piston membrane pump. Heavy dutypiston membrane pumps may be available from ABEL GmbH & Co. KG (Buchen,Germany). Piston membrane pumps have been used for long term, continuouspumping of slurries containing high total solids in the mining and powerindustries. Piston membrane pumps are similar to triplex pumps used fordrilling operations in the oil and gas industry except heavy dutypreformed membranes separate the slurry from the hydraulic side of thepump. In this fashion, the solids laden fluid is brought up to pressurein the injection line in one step and circulated downhole withoutdamaging the internal mechanisms of the pump.

Another type of pump that may be used for particle jet drilling is anannular pressure exchange pump. Annular pressure exchange pumps may beavailable from Macmahon Mining Services Pty Ltd (Lonsdale, Australia).Annular pressure exchange pumps have been used for long term, continuouspumping of slurries containing high total solids in the mining industry.Annular pressure exchange pumps use hydraulic oil to compress a hoseinside a high-strength pressure chamber in a peristaltic like way todisplace the contents of the hose. Annular pressure exchange pumps mayobtain continuous flow by having twin chambers. One chamber fills whilethe other chamber is purged.

The bottom hole assembly may include a downhole electric orienter. Thedownhole electric orienter may allow for directional drilling bydirecting one or more particle jet drilling nozzles in desireddirections. The downhole electric orienter may be coupled to a computercontrol system through one or more integral data lines of the compositecoiled tubing. Power for the downhole electric orienter may be suppliedthrough an integral power line of the composite coiled tubing or througha battery system in the bottom hole assembly.

Bubble entrained mud may be used as the drilling fluid. Bubble entrainedmud may allow for particle jet drilling without raising the equivalentcirculating density to unacceptable levels. A form of managed pressuredrilling may be affected by varying the density of bubble entrainment.In some embodiments, particles in the drilling fluid may be separatedfrom the drilling fluid using magnetic recovery when the particlesinclude iron or alloys that may be influenced by magnetic fields. Bubbleentrained mud may be used because using air or other gas as the drillingfluid may result in excessive wear of components from high velocityparticles in the return stream. The density of the bubble entrained mudgoing downhole as a function of real time gains and losses of fluid maybe automated using the computer control system.

In some embodiments, multiphase systems are used. For example, if gasinjection rates are low enough that wear rates are acceptable, agas-liquid circulating system may be used. Bottom hole circulatingpressures may be adjusted by the computer control system. The computercontrol system may adjust the gas and/or liquid injection rates.

In some embodiments, pipe-in-pipe drilling is used. Pipe-in-pipedrilling may include circulating fluid through the space between theouter pipe and the inner pipe instead of between the wellbore and thedrill string. Pipe-in-pipe drilling may be used if contact of thedrilling fluid with one or more fresh water aquifers is not acceptable.Pipe-in-pipe drilling may be used if the density of the drilling fluidcannot be adjusted low enough to effectively reduce potential lostcirculation issues.

Downhole inertial navigation may be part of the bottom hole assembly.The use of downhole inertial navigation allows for determination of theposition (including depth, azimuth and inclination) without magneticsensors. Magnetic interference from casings and/or emissions from thehigh density of wells in the formation may interfere with a system thatdetermines the position of the bottom hole assembly based on magnetsensors.

The computer control system may receive information from the bottom holeassembly. The computer control system may process the information todetermine the position of the bottom hole assembly. The computer controlsystem may control drilling fluid rate, drilling fluid density, drillingfluid pressure, particle density, other variables, and/or the downholeelectric orienter to control the rate of penetration and/or thedirection of borehole formation.

In some embodiments, robots are used to perform a task in a wellboreformed or being formed using composite coiled tubing. The task may be,but is not limited to, providing traction to move the coiled tubing,surveying, removing cuttings, logging, and/or freeing pipe. For example,a robot may be used when drilling a horizontal opening if enough weightcannot be applied to the bottom hole assembly to advance the coiledtubing and bottom hole assembly in the formed borehole. The robot may besent down the borehole. The robot may clamp to the composite coiledtubing. Portions of the robot may extend to engage the formation.Traction between the robot and the formation may be used to advance therobot forward so that the composite coiled tubing and the bottom holeassembly advance forward.

The robots may be battery powered. To use the robot, drilling could bestopped, and the robot could be connected to the outside of thecomposite coiled tubing. The robot would run along the outside of thecomposite coiled tubing to the bottom of the hole. If needed, the robotcould electrically couple to the bottom hole assembly. The robot couldcouple to a contact plate on the bottom hole assembly. The bottom holeassembly may include a step-down transformer that brings the highvoltage, low current electricity supplied to the bottom hole assembly toa lower voltage and higher current (for example, one third the voltageand three times the amperage supplied to the bottom hole assembly). Thelower voltage, higher current electricity supplied from the step-downtransformer may be used to recharge the batteries of the robot. In someembodiments, the robot may function while coupled to the bottom holeassembly. The batteries may supply sufficient energy for the robot totravel to the drill bit and back to the surface.

Some wellbores formed in the formation may be used to facilitateformation of a perimeter barrier around a treatment area. Heat sourcesin the treatment area may heat hydrocarbons in the formation within thetreatment area. The perimeter barrier may be, but is not limited to, alow temperature or frozen barrier formed by freeze wells, a wax barrierformed in the formation, dewatering wells, a grout wall formed in theformation, a sulfur cement barrier, a barrier formed by a gel producedin the formation, a barrier formed by precipitation of salts in theformation, a barrier formed by a polymerization reaction in theformation, and/or sheets driven into the formation. Heat sources,production wells, injection wells, dewatering wells, and/or monitoringwells may be installed in the treatment area defined by the barrierprior to, simultaneously with, or after installation of the barrier.

A low temperature zone around at least a portion of a treatment area maybe formed by freeze wells. In an embodiment, refrigerant is circulatedthrough freeze wells to form low temperature zones around each freezewell. The freeze wells are placed in the formation so that the lowtemperature zones overlap and form a low temperature zone around thetreatment area. The low temperature zone established by freeze wells ismaintained below the freezing temperature of aqueous fluid in theformation. Aqueous fluid entering the low temperature zone freezes andforms the frozen barrier. In other embodiments, the freeze barrier isformed by batch operated freeze wells. A cold fluid, such as liquidnitrogen, is introduced into the freeze wells to form low temperaturezones around the freeze wells. The fluid is replenished as needed.

In some embodiments, two or more rows of freeze wells are located aboutall or a portion of the perimeter of the treatment area to form a thickinterconnected low temperature zone. Thick low temperature zones may beformed adjacent to areas in the formation where there is a high flowrate of aqueous fluid in the formation. The thick barrier may ensurethat breakthrough of the frozen barrier established by the freeze wellsdoes not occur.

In some embodiments, a double barrier system is used to isolate atreatment area. The double barrier system may be formed with a firstbarrier and a second barrier. The first barrier may be formed around atleast a portion of the treatment area to inhibit fluid from entering orexiting the treatment area. The second barrier may be formed around atleast a portion of the first barrier to isolate an inter-barrier zonebetween the first barrier and the second barrier. The inter-barrier zonemay have a thickness from about 1 m to about 300 m. In some embodiments,the thickness of the inter-barrier zone is from about 10 m to about 100m, or from about 20 m to about 50 m.

The double barrier system may allow greater project depths than a singlebarrier system. Greater depths are possible with the double barriersystem because the stepped differential pressures across the firstbarrier and the second barrier is less than the differential pressureacross a single barrier. The smaller differential pressures across thefirst barrier and the second barrier make a breach of the double barriersystem less likely to occur at depth for the double barrier system ascompared to the single barrier system.

The first barrier and the second barrier may be the same type of barrieror different types of barriers. In some embodiments, the first barrierand the second barrier are formed by freeze wells. In some embodiments,the first barrier is formed by freeze wells, and the second barrier is agrout wall. The grout wall may be formed of cement, sulfur, sulfurcement, or combinations thereof. In some embodiments, a portion of thefirst barrier and/or a portion of the second barrier is a naturalbarrier, such as an impermeable rock formation.

Vertically positioned freeze wells and/or horizontally positioned freezewells may be positioned around sides of the treatment area. If the upperlayer (the overburden) or the lower layer (the underburden) of theformation is likely to allow fluid flow into the treatment area or outof the treatment area, horizontally positioned freeze wells may be usedto form an upper and/or a lower barrier for the treatment area. In someembodiments, an upper barrier and/or a lower barrier may not benecessary if the upper layer and/or the lower layer are at leastsubstantially impermeable. If the upper freeze barrier is formed,portions of heat sources, production wells, injection wells, and/ordewatering wells that pass through the low temperature zone created bythe freeze wells forming the upper freeze barrier wells may be insulatedand/or heat traced so that the low temperature zone does not adverselyaffect the functioning of the heat sources, production wells, injectionwells and/or dewatering wells passing through the low temperature zone.

FIG. 35 depicts an embodiment of freeze well 466. Freeze well 466 mayinclude canister 468, inlet conduit 470, spacers 472, and wellcap 474.Spacers 472 may position inlet conduit 470 in canister 468 so that anannular space is formed between the canister and the conduit. Spacers472 may promote turbulent flow of refrigerant in the annular spacebetween inlet conduit 470 and canister 468, but the spacers may alsocause a significant fluid pressure drop. Turbulent fluid flow in theannular space may be promoted by roughening the inner surface ofcanister 468, by roughening the outer surface of inlet conduit 470,and/or by having a small cross-sectional area annular space that allowsfor high refrigerant velocity in the annular space. In some embodiments,spacers are not used. Wellhead 476 may suspend canister 468 in wellbore428.

Formation refrigerant may flow through cold side conduit 478 from arefrigeration unit to inlet conduit 470 of freeze well 466. Theformation refrigerant may flow through an annular space between inletconduit 470 and canister 468 to warm side conduit 480. Heat may transferfrom the formation to canister 468 and from the canister to theformation refrigerant in the annular space. Inlet conduit 470 may beinsulated to inhibit heat transfer to the formation refrigerant duringpassage of the formation refrigerant into freeze well 466. In anembodiment, inlet conduit 470 is a high density polyethylene tube. Atcold temperatures, some polymers may exhibit a large amount of thermalcontraction. For example, a 260 m initial length of polyethylene conduitsubjected to a temperature of about −25° C. may contract by 6 m or more.If a high density polyethylene conduit, or other polymer conduit, isused, the large thermal contraction of the material must be taken intoaccount in determining the final depth of the freeze well. For example,the freeze well may be drilled deeper than needed, and the conduit maybe allowed to shrink back during use. In some embodiments, inlet conduit470 is an insulated metal tube. In some embodiments, the insulation maybe a polymer coating, such as, but not limited to, polyvinylchloride,high density polyethylene, and/or polystyrene.

Freeze well 466 may be introduced into the formation using a coiledtubing rig. In an embodiment, canister 468 and inlet conduit 470 arewound on a single reel. The coiled tubing rig introduces the canisterand inlet conduit 470 into the formation. In an embodiment, canister 468is wound on a first reel and inlet conduit 470 is wound on a secondreel. The coiled tubing rig introduces canister 468 into the formation.Then, the coiled tubing rig is used to introduce inlet conduit 470 intothe canister. In other embodiments, freeze well is assembled in sectionsat the wellbore site and introduced into the formation.

An insulated section of freeze well 466 may be placed adjacent tooverburden 482. An uninsulated section of freeze well 466 may be placedadjacent to layer or layers 484 where a low temperature zone is to beformed. In some embodiments, uninsulated sections of the freeze wellsmay be positioned adjacent only to aquifers or other permeable portionsof the formation that would allow fluid to flow into or out of thetreatment area. Portions of the formation where uninsulated sections ofthe freeze wells are to be placed may be determined using analysis ofcores and/or logging techniques.

FIG. 36 depicts an embodiment of the lower portion of freeze well 466.Freeze well may include canister 468, and inlet conduit 470. Latch pin486 may be welded to canister 468. Latch pin 486 may include taperedupper end 488 and groove 490. Tapered upper end 488 may facilitateplacement of a latch of inlet conduit 470 on latch pin 486. A springring of the latch may be positioned in groove 490 to couple inletconduit 470 to canister 468.

Inlet conduit 470 may include plastic portion 492, transition piece 494,outer sleeve 496, and inner sleeve 498. Plastic portion 492 may be aplastic conduit that carries refrigerant into freeze well 466. In someembodiments, plastic portion 492 is high density polyethylene pipe.

Transition piece 494 may be a transition between plastic portion 492 andouter sleeve 496. A plastic end of transition piece 494 may be fusionwelded to the end of plastic portion 492. A metal portion of transitionpiece may be butt welded to outer sleeve 496. In some embodiments, themetal portion and outer sleeve 496 are formed of 304 stainless steel.Other material may be used in other embodiments. Transition pieces 494may be available from Central Plastics Company (Shawnee, Okla.).

In some embodiments, outer sleeve 496 may include stop 500. Stop 500 mayengage a stop of inner sleeve 498 to limit a bottom position of theouter sleeve relative to the inner sleeve. In some embodiments, outersleeve 496 may include opening 502. Opening 502 may align with acorresponding opening in inner sleeve 498. A shear pin may be positionedin the openings during insertion of inlet conduit 470 in canister 468 toinhibit movement of outer sleeve 496 relative to inner sleeve 498. Shearpin is strong enough to support the weight of inner sleeve 498, but weakenough to shear due to force applied to the shear pin when outer sleeve496 moves upwards in the wellbore due to thermal contraction or duringinstallation of the inlet conduit after inlet conduit is coupled tocanister 468.

Inner sleeve 498 may be positioned in outer sleeve 496. Inner sleeve hasa length sufficient to inhibit separation of the inner sleeve from outersleeve 496 when inlet conduit has fully contracted due to exposure ofthe inlet conduit to low temperature refrigerant. Inner sleeve 498 mayinclude a plurality of slip rings 504 held in place by positioners 506,a plurality of openings 508, stop 510, and latch 512. Slip rings 504 mayposition inner sleeve 498 relative to outer sleeve 496 and allow theouter sleeve to move relative to the inner sleeve. In some embodiments,slip rings 504 are TEFLON® rings, such as polytetrafluoroethylene rings.Slip rings 504 may be made of different material in other embodiments.Positioners 506 may be steel rings welded to inner sleeve. Positioners506 may be thinner than slip rings 504. Positioners 506 may inhibitmovement of slip rings 504 relative to inner sleeve 498.

Openings 508 may be formed in a portion of inner sleeve 498 near thebottom of the inner sleeve. Openings 508 may allow refrigerant to passfrom inlet conduit 470 to canister 468. A majority of refrigerantflowing through inlet conduit 470 may pass through openings 508 tocanister 468. Some refrigerant flowing through inlet conduit 470 maypass to canister 468 through the space between inner sleeve 498 andouter sleeve 496.

Stop 510 may be located above openings 508. Stop 510 interacts with stop500 of outer sleeve 496 to limit the downward movement of the outersleeve relative to inner sleeve 498.

Latch 512 may be welded to the bottom of inner sleeve 498. Latch 512 mayinclude flared opening 514 that engages tapered end 488 of latch pin486. Latch 512 may include spring ring 516 that snaps into groove oflatch pin 490 to couple inlet conduit 470 to canister 468.

To install freeze well 466, a wellbore is formed in the formation andcanister 468 is placed in the wellbore. The bottom of canister 468 haslatch pin 486. Transition piece is fusion welded to an end of coiledplastic portion 492 of inlet conduit 470. Latch 512 is placed incanister 468 and inlet conduit is spooled into the canister. Spacers maybe coupled to plastic portion 492 at selected positions. Latch may belowered until flared opening 514 engages tapered end 488 of latch pin486 and spring ring 504 snaps into the groove of the latch pin. Afterspring ring 504 engages latch pin 486, inlet conduit 470 may be movedupwards to shear the pin joining outer sleeve 496 to inner sleeve 498.Inlet conduit 470 may be coupled to the refrigerant supply piping andcanister may be coupled to the refrigerant return piping.

If needed, inlet conduit 470 may be removed from canister 468. Inletconduit may be pulled upwards to separate outer sleeve 496 from innersleeve 498. Plastic portion 492, transition piece 494, and outer sleeve496 may be pulled out of canister 468. A removal instrument may belowered into canister 468. The removal instrument may secure to innersleeve 498. The removal instrument may be pulled upwards to pull springring 516 of latch 512 out of groove 490 of latch pin 486. The removaltool may be withdrawn out of canister 468 to remove inner sleeve 498from the canister.

Grout, wax, polymer or other material may be used in combination withfreeze wells to provide a barrier for the in situ heat treatmentprocess. The material may fill cavities (vugs) in the formation andreduces the permeability of the formation. The material may have higherthermal conductivity than gas and/or formation fluid that fills cavitiesin the formation. Placing material in the cavities may allow for fasterlow temperature zone formation. The material may form a perpetualbarrier in the formation that may strengthen the formation. The use ofmaterial to form the barrier in unconsolidated or substantiallyunconsolidated formation material may allow for larger well spacing thanis possible without the use of the material. The combination of thematerial and the low temperature zone formed by freeze wells mayconstitute a double barrier for environmental regulation purposes. Insome embodiments, the material is introduced into the formation as aliquid, and the liquid sets in the formation to form a solid. Thematerial may be, but is not limited to, fine cement, micro fine cement,sulfur, sulfur cement, viscous thermoplastics, and/or waxes. Thematerial may include surfactants, stabilizers or other chemicals thatmodify the properties of the material. For example, the presence ofsurfactant in the material may promote entry of the material into smallopenings in the formation.

Material may be introduced into the formation through freeze wellwellbores. The material may be allowed to set. The integrity of the wallformed by the material may be checked. The integrity of the materialwall may be checked by logging techniques and/or by hydrostatic testing.If the permeability of a section formed by the material is too high,additional material may be introduced into the formation through freezewell wellbores. After the permeability of the section is sufficientlyreduced, freeze wells may be installed in the freeze well wellbores.

Material may be injected into the formation at a pressure that is high,but below the fracture pressure of the formation. In some embodiments,injection of material is performed in 16 m increments in the freezewellbore. Larger or smaller increments may be used if desired. In someembodiments, material is only applied to certain portions of theformation. For example, material may be applied to the formation throughthe freeze wellbore only adjacent to aquifer zones and/or to relativelyhigh permeability zones (for example, zones with a permeability greaterthan about 0.1 darcy). Applying material to aquifers may inhibitmigration of water from one aquifer to a different aquifer. For materialplaced in the formation through freeze well wellbores, the material mayinhibit water migration between aquifers during formation of the lowtemperature zone. The material may also inhibit water migration betweenaquifers when an established low temperature zone is allowed to thaw.

In some embodiments, the material used to form a barrier may be finecement and micro fine cement. Cement may provide structural support inthe formation. Fine cement may be ASTM type 3 Portland cement. Finecement may be less expensive than micro fine cement. In an embodiment, afreeze wellbore is formed in the formation. Selected portions of thefreeze wellbore are grouted using fine cement. Then, micro fine cementis injected into the formation through the freeze wellbore. The finecement may reduce the permeability down to about 10 millidarcy. Themicro fine cement may further reduce the permeability to about 0.1millidarcy. After the grout is introduced into the formation, a freezewellbore canister may be inserted into the formation. The process may berepeated for each freeze well that will be used to form the barrier.

In some embodiments, fine cement is introduced into every other freezewellbore. Micro fine cement is introduced into the remaining wellbores.For example, grout may be used in a formation with freeze wellbores setat about 5 m spacing. A first wellbore is drilled and fine cement isintroduced into the formation through the wellbore. A freeze wellcanister is positioned in the first wellbore. A second wellbore isdrilled 10 m away from the first wellbore. Fine cement is introducedinto the formation through the second wellbore. A freeze well canisteris positioned in the second wellbore. A third wellbore is drilledbetween the first wellbore and the second wellbore. In some embodiments,grout from the first and/or second wellbores may be detected in thecuttings of the third wellbore. Micro fine cement is introduced into theformation through the third wellbore. A freeze wellbore canister ispositioned in the third wellbore. The same procedure is used to form theremaining freeze wells that will form the barrier around the treatmentarea.

In some embodiments, material including wax is used to form a barrier ina formation. Wax barriers may be formed in wet, dry, or oil wettedformations. Wax barriers may be formed above, at the bottom of, and/orbelow the water table. Material including liquid wax introduced into theformation may permeate into adjacent rock and fractures in theformation. The material may permeate into rock to fill microscopic aswell as macroscopic pores and vugs in the rock. The wax solidifies toform a barrier that inhibits fluid flow into or out of a treatment area.A wax barrier may provide a minimal amount of structural support in theformation. Molten wax may reduce the strength of poorly consolidatedsoil by reducing inter-grain friction so that the poorly consolidatedsoil sloughs or liquefies. Poorly consolidated layers may beconsolidated by use of cement or other binding agents beforeintroduction of molten wax.

In some embodiments, the formation where a wax barrier is to beestablished is dewatered before and/or during formation of the waxbarrier. In some embodiments, the portion of the formation where the waxbarrier is to form is dewatered or diluted to remove or reduce salinewater that could adversely affect the properties of the materialintroduced into the formation to form the wax barrier.

In some embodiments, water is introduced into the formation duringformation of the wax barrier. Water may be introduced into the formationwhen the barrier is to be formed below the water table or in a dryportion of the formation. The water may be used to heat the formation toa desired temperature before introducing the material that forms the waxbarrier. The water may be introduced at an elevated temperature and/orthe water may be heated in the formation from one or more heaters.

The wax of the barrier may be a branched paraffin to inhibit biologicaldegradation of the wax. The wax may include stabilizers, surfactants orother chemicals that modify the physical and/or chemical properties ofthe wax. The physical properties may be tailored to meet specific needs.The wax may melt at a relative low temperature (for example, the wax mayhave a typical melting point of about 52° C.). The temperature at whichthe wax congeals may be at least 5° C., 10° C., 20° C., or 30° C. abovethe ambient temperature of the formation prior to any heating of theformation. When molten, the wax may have a relatively low viscosity (forexample, 4 to 10 cp at about 99° C.). The flash point of the wax may berelatively high (for example, the flash point may be over 204° C.). Thewax may have a density less than the density of water and may have aheat capacity that is less than half the heat capacity of water. Thesolid wax may have a low thermal conductivity (for example, about 0.18W/m ° C.) so that the solid wax is a thermal insulator. Waxes suitablefor forming a barrier are available as WAXFIX™ from Carter TechnologiesCompany (Sugar Land, Tex., U.S.A.). WAXFIX™ is very resistant tomicrobial attack. WAXFIX™ may have a half life of greater than 5000years.

In some embodiments, a wax barrier or wax barriers may be used as thebarriers for the in situ heat treatment process. In some embodiments, awax barrier may be used in conjunction with freeze wells that form a lowtemperature barrier around the treatment area. In some embodiments, thewax barrier is formed and freeze wells are installed in the wellboresused for introducing wax into the formation. In some embodiments, thewax barrier is formed in wellbores offset from the freeze wellwellbores. The wax barrier may be on the outside or the inside of thefreeze wells. In some embodiments, a wax barrier may be formed on boththe inside and outside of the freeze wells. The wax barrier may inhibitwater flow in the formation that would inhibit the formation of the lowtemperature zone by the freeze wells. In some embodiments, a wax barrieris formed in the inter-barrier zone between two freeze barriers of adouble barrier system.

Material used to form the wax barrier may be introduced into theformation through wellbores. The wellbores may include verticalwellbores, slanted wellbores, and/or horizontal wellbores (for example,wellbores with sections that are horizontally or near horizontallyoriented). The use of vertical wellbores, slanted wellbores, and/orhorizontal wellbores for forming the wax barrier allows the formation ofa barrier that seals both horizontal and vertical fractures.

Wellbores may be formed in the formation around the treatment area at aclose spacing. In some embodiments, the spacing is from about 1.5 m toabout 4 m. Larger or smaller spacings may be used. Low temperatureheaters may be inserted in the wellbores. The heaters may operate attemperatures from about 260° C. to about 320° C. so that the temperatureat the formation face is below the pyrolysis temperature of hydrocarbonsin the formation. The heaters may be activated to heat the formationuntil the overlap between two adjacent heaters raises the temperature ofthe zone between the two heaters above the melting temperature of thewax. Heating the formation to obtain superposition of heat with atemperature above the melting temperature of the wax may take one month,two months, or longer. After heating, the heaters may be turned off. Insome embodiments, the heaters are downhole antennas that operate atabout 10 MHz to heat the formation.

After heating, the material used to form the wax barrier may beintroduced into the wellbores to form the barrier. The material may flowinto the formation and fill any fractures and porosity that has beenheated. The wax in the material congeals when the wax flows to coldregions beyond the heated circumference. This wax barrier formationmethod may form a more complete barrier than some other methods of waxbarrier formation, but the time for heating may be longer than for someof the other methods. Also, if a low temperature barrier is to be formedwith the freeze wells placed in the wellbores used for injection of thematerial used to form the barrier, the freeze wells will have to removethe heat supplied to the formation to allow for introduction of thematerial used to form the barrier. The low temperature barrier may takelonger to form.

In some embodiments, the wax barrier may be formed using a conduitplaced in the wellbore. FIG. 37 depicts an embodiment of a system forforming a wax barrier in a formation. Wellbore 428 may extend into oneor more layers 484 below overburden 482. Wellbore 428 may be an openwellbore below overburden 482. One or more of the layers 484 may includefracture systems 518. One or more of the layers may be vuggy so that thelayer or a portion of the layer has a high porosity. Conduit 520 may bepositioned in wellbore 428. In some embodiments, low temperature heater522 may be strapped or attached to conduit 520. In some embodiments,conduit 520 may be a heater element. Heater 522 may be operated so thatthe heater does not cause pyrolysis of hydrocarbons adjacent to theheater. At least a portion of wellbore 428 may be filled with fluid. Thefluid may be formation fluid or water. Heater 522 may be activated toheat the fluid. A portion of the heated fluid may move outwards fromheater 522 into the formation. The heated fluid may be injected into thefractures and permeable vuggy zones. The heated fluid may be injectedinto the fractures and permeable vuggy zones by introducing heatedbarrier material into wellbore 428 in the annular space between conduit520 and the wellbore. The introduced material flows to the areas heatedby the fluid and congeals when the fluid reaches cold regions not heatedby the fluid. The material fills fracture systems 518 and permeablevuggy pathways heated by the fluid, but the material may not permeatethrough a significant portion of the rock matrix as when the hotmaterial is introduced into a heated formation as described above. Thematerial flows into fracture systems 518 a sufficient distance to joinwith material injected from an adjacent well so that a barrier to fluidflow through the fracture systems forms when the wax congeals. A portionof material may congeal along the wall of a fracture or a vug withoutcompletely blocking the fracture or filling the vug. The congealedmaterial may act as an insulator and allow additional liquid wax to flowbeyond the congealed portion to penetrate deeply into the formation andform blockages to fluid flow when the material cools below the meltingtemperature of the wax in the material.

Material in the annular space of wellbore 428 between conduit 520 andthe formation may be removed through conduit by displacing the materialwith water or other fluid. Conduit 520 may be removed and a freeze wellmay be installed in the wellbore. This method may use less material thanthe method described above. The heating of the fluid may be accomplishedin less than a week or within a day. The small amount of heat input mayallow for quicker formation of a low temperature barrier if freeze wellsare to be positioned in the wellbores used to introduce material intothe formation.

In some embodiments, a heater may be suspended in the well without aconduit that allows for removal of excess material from the wellbore.The material may be introduced into the well. After materialintroduction, the heater may be removed from the well. In someembodiments, a conduit may be positioned in the wellbore, but a heatermay not be coupled to the conduit. Hot material may be circulatedthrough the conduit so that the wax enters fractures systems and/or vugsadjacent to the wellbore.

In some embodiments, material may be used during the formation of awellbore to improve inter-zonal isolation and protect a low-pressurezone from inflow from a high-pressure zone. During wellbore formationwhere a high pressure zone and a low pressure zone are penetrated by acommon wellbore, it is possible for fluid from the high pressure zone toflow into the low pressure zone and cause an underground blowout. Toavoid this, the wellbore may be formed through the first zone. Then, anintermediate casing may be set and cemented through the first zone.Setting casing may be time consuming and expensive. Instead of setting acasing, material may be introduced to form a wax barrier that seals thefirst zone. The material may also inhibit or prevent mixing of highsalinity brines from lower, high pressure zones with fresher brines inupper, lower pressure zones.

FIG. 38A depicts wellbore 428 drilled to a first depth in formation 524.After the surface casing for wellbore 428 is set and cemented in place,the wellbore is drilled to the first depth which passes through apermeable zone, such as an aquifer. The permeable zone may be fracturesystem 518′. In some embodiments, a heater is placed in wellbore 428 toheat the vertical interval of fracture system 518′. In some embodiments,hot fluid is circulated in wellbore 428 to heat the vertical interval offracture system 518′. After heating, molten material is pumped downwellbore 428. The molten material flows a selected distance intofracture system 518′ before the material cools sufficiently to solidifyand form a seal. The molten material is introduced into formation 524 ata pressure below the fracture pressure of the formation. In someembodiments, pressure is maintained on the wellhead until the materialhas solidified. In some embodiments, the material is allowed to cooluntil the material in wellbore 428 is almost to the congealingtemperature of the material. The material in wellbore 428 may then bedisplaced out of the wellbore. Wax in the material makes the portion offormation 524 near wellbore 428 into a substantially impermeable zone.Wellbore 428 may be drilled to depth through one or more permeable zonesthat are at higher pressures than the pressure in the first permeablezone, such as fracture system 518″. Congealed wax in fracture system518′ may inhibit blowout into the lower pressure zone. FIG. 38B depictswellbore 428 drilled to depth with congealed wax 526 in formation 524.

In some embodiments, a material including wax may be used to contain andinhibit migration in a subsurface formation that has liquid hydrocarboncontaminants (for example, compounds such as benzene, toluene,ethylbenzene and xylene) condensed in fractures in the formation. Thelocation of the contaminants may be surrounded with heated injectionwells. The material may be introduced into the wells to form an outerwax barrier. The material injected into the fractures from the injectionwells may mix with the contaminants. The contaminants may be solubilizedinto the material. When the material congeals, the contaminants may bepermanently contained in the solid wax phase of the material.

In some embodiments, a portion or all of the wax barrier may be removedafter completion of the in situ heat treatment process. Removing all ora portion of the wax barrier may allow fluid to flow into and out of thetreatment area of the in situ heat treatment process. Removing all or aportion of the wax barrier may return flow conditions in the formationto substantially the same conditions as existed before the in situ heattreatment process. To remove a portion or all of the wax barrier,heaters may be used to heat the formation adjacent to the wax barrier.In some embodiments, the heaters raise the temperature above thedecomposition temperature of the material forming the wax barrier. Insome embodiments, the heaters raise the temperature above the meltingtemperature of the material forming the wax barrier. Fluid (for examplewater) may be introduced into the formation to drive the molten materialto one or more production wells positioned in the formation. Theproduction wells may remove the material from the formation.

In some embodiments, a composition that includes a cross-linkablepolymer may be used with or in addition to a material that includes waxto form the barrier. Such composition may be provided to the formationas is described above for the material that includes wax. Thecomposition may be configured to react and solidify after a selectedtime in the formation, thereby allowing the composition to be providedas a liquid to the formation. The cross-linkable polymer may include,for example, acrylates, methacrylates, urethanes, and/or epoxies. Across-linking initiator may be included in the composition. Thecomposition may also include a cross-linking inhibitor. Thecross-linking inhibitor may be configured to degrade while in theformation, thereby allowing the composition to solidify.

In situ heat treatment processes and solution mining processes may heatthe treatment area, remove mass from the treatment area, and greatlyincrease the permeability of the treatment area. In certain embodiments,the treatment area after being treated may have a permeability of atleast 0.1 darcy. In some embodiments, the treatment area after beingtreated has a permeability of at least 1 darcy, of at least 10 darcy, orof at least 100 darcy. The increased permeability allows the fluid tospread in the formation into fractures, microfractures, and/or porespaces in the formation. Outside of the treatment area, the permeabilitymay remain at the initial permeability of the formation. The increasedpermeability allows fluid introduced to flow easily within theformation.

In certain embodiments, a barrier may be formed in the formation after asolution mining process and/or an in situ heat treatment process byintroducing a fluid into the formation. The barrier may inhibitformation fluid from entering the treatment area after the solutionmining and/or in situ heat treatment processes have ended. The barrierformed by introducing fluid into the formation may allow for isolationof the treatment area.

The fluid introduced into the formation to form a barrier may includewax, bitumen, heavy oil, sulfur, polymer, gel, saturated salinesolution, and/or one or more reactants that react to form a precipitate,solid or high viscosity fluid in the formation. In some embodiments,bitumen, heavy oil, reactants and/or sulfur used to form the barrier areobtained from treatment facilities associated with the in situ heattreatment process. For example, sulfur may be obtained from a Clausprocess used to treat produced gases to remove hydrogen sulfide andother sulfur compounds.

The fluid may be introduced into the formation as a liquid, vapor, ormixed phase fluid. The fluid may be introduced into a portion of theformation that is at an elevated temperature. In some embodiments, thefluid is introduced into the formation through wells located near aperimeter of the treatment area. The fluid may be directed away from thetreatment area. The elevated temperature of the formation maintains orallows the fluid to have a low viscosity so that the fluid moves awayfrom the wells. A portion of the fluid may spread outwards in theformation towards a cooler portion of the formation. The relatively highpermeability of the formation allows fluid introduced from one wellboreto spread and mix with fluid introduced from other wellbores. In thecooler portion of the formation, the viscosity of the fluid increases, aportion of the fluid precipitates, and/or the fluid solidifies orthickens so that the fluid forms the barrier to flow of formation fluidinto or out of the treatment area.

In some embodiments, a low temperature barrier formed by freeze wellssurrounds all or a portion of the treatment area. As the fluidintroduced into the formation approaches the low temperature barrier,the temperature of the formation becomes colder. The colder temperatureincreases the viscosity of the fluid, enhances precipitation, and/orsolidifies the fluid to form the barrier to the flow of formation fluidinto or out of the formation. The fluid may remain in the formation as ahighly viscous fluid or a solid after the low temperature barrier hasdissipated.

In certain embodiments, saturated saline solution is introduced into theformation. Components in the saturated saline solution may precipitateout of solution when the solution reaches a colder temperature. Thesolidified particles may form the barrier to the flow of formation fluidinto or out of the formation. The solidified components may besubstantially insoluble in formation fluid.

In certain embodiments, brine is introduced into the formation as areactant. A second reactant, such as carbon dioxide, may be introducedinto the formation to react with the brine. The reaction may generate amineral complex that grows in the formation. The mineral complex may besubstantially insoluble to formation fluid. In an embodiment, the brinesolution includes a sodium and aluminum solution. The second reactantintroduced in the formation is carbon dioxide. The carbon dioxide reactswith the brine solution to produce dawsonite. The minerals may solidifyand form the barrier to the flow of formation fluid into or out of theformation.

In some embodiments, the barrier may be formed around a treatment areausing sulfur. Advantageously, elemental sulfur is insoluble in water.Liquid and/or solid sulfur in the formation may form a barrier toformation fluid flow into or out of the treatment area.

A sulfur barrier may be established in the formation during or beforeinitiation of heating to heat the treatment area of the in situ heattreatment process. In some embodiments, sulfur may be introduced intowellbores in the formation that are located between the treatment areaand a first barrier (for example, a low temperature barrier establishedby freeze wells). The formation adjacent to the wellbores that thesulfur is introduced into may be dewatered. In some embodiments, theformation adjacent to the wellbores that the sulfur is introduced intois heated to facilitate removal of water and to prepare the wellboresand adjacent formation for the introduction of sulfur. The formationadjacent to the wellbores may be heated to a temperature below thepyrolysis temperature of hydrocarbons in the formation. The formationmay be heated so that the temperature of a portion of the formationbetween two adjacent heaters is influenced by both heaters. In someembodiments, the heat may increase the permeability of the formation sothat a first wellbore is in fluid communication with an adjacentwellbore.

After the formation adjacent to the wellbores is heated, molten sulfurat a temperature below the pyrolysis temperature of hydrocarbons in theformation is introduced into the formation. Over a certain temperaturerange, the viscosity of molten sulfur increases with increasingtemperature. The molten sulfur introduced into the formation may be nearthe melting temperature of sulfur (about 115° C.) so that the sulfur hasa relatively low viscosity (about 4-10 cp). Heaters in the wellbores maybe temperature limited heaters with Curie temperatures near the meltingtemperature of sulfur so that the temperature of the molten sulfur staysrelatively constant and below temperatures resulting in the formation ofviscous molten sulfur. In some embodiments, the region adjacent to thewellbores may be heated to a temperature above the melting point ofsulfur, but below the pyrolysis temperature of hydrocarbons in theformation. The heaters may be turned off and the temperature in thewellbores may be monitored (for example, using a fiber optic temperaturemonitoring system). When the temperature in the wellbore cools to atemperature near the melting temperature of sulfur, molten sulfur may beintroduced into the formation.

The sulfur introduced into the formation is allowed to flow and diffuseinto the formation from the wellbores. As the sulfur enters portions ofthe formation below the melting temperature, the sulfur solidifies andforms a barrier to fluid flow in the formation. Sulfur may be introduceduntil the formation is not able to accept additional sulfur. Heating maybe stopped, and the formation may be allowed to naturally cool so thatthe sulfur in the formation solidifies. After introduction of thesulfur, the integrity of the formed barrier may be tested using pulsetests and/or tracer tests.

A barrier may be formed around the treatment area after the in situ heattreatment process. The sulfur may form a substantially permanent barrierin the formation. In some embodiments, a low temperature barrier formedby freeze wells surrounds the treatment area. Sulfur may be introducedon one or both sides of the low temperature barrier to form a barrier inthe formation. The sulfur may be introduced into the formation as vaporor a liquid. As the sulfur approaches the low temperature barrier, thesulfur may condense and/or solidify in the formation to form thebarrier.

In some embodiments, the sulfur may be introduced in the heated portionof the portion. The sulfur may be introduced into the formation throughwells located near the perimeter of the treatment area. The temperatureof the formation may be hotter than the vaporization temperature ofsulfur (about 445° C.). The sulfur may be introduced as a liquid, vaporor mixed phase fluid. If a part of the introduced sulfur is in theliquid phase, the heat of the formation may vaporize the sulfur. Thesulfur may flow outwards from the introduction wells towards coolerportions of the formation. The sulfur may condense and/or solidify inthe formation to form the barrier.

In some embodiments, the Claus reaction may be used to form sulfur inthe formation after the in situ heat treatment process. The Clausreaction is a gas phase equilibrium reaction. The Claus reaction is:

4H₂S+2SO₂

3S₂+4H₂O  (EQN. 1)

Hydrogen sulfide may be obtained by separating the hydrogen sulfide fromthe produced fluid of an ongoing in situ heat treatment process. Aportion of the hydrogen sulfide may be burned to form the needed sulfurdioxide. Hydrogen sulfide may be introduced into the formation through anumber of wells in the formation. Sulfur dioxide may be introduced intothe formation through other wells. The wells used for injecting sulfurdioxide or hydrogen sulfide may have been production wells, heaterwells, monitor wells or other type of well during the in situ heattreatment process. The wells used for injecting sulfur dioxide orhydrogen sulfide may be near the perimeter of the treatment area. Thenumber of wells may be enough so that the formation in the vicinity ofthe injection wells does not cool to a point where the sulfur dioxideand the hydrogen sulfide can form sulfur and condense, rather thanremain in the vapor phase. The wells used to introduce the sulfurdioxide into the formation may also be near the perimeter of thetreatment area. In some embodiments, the hydrogen sulfide and sulfurdioxide may be introduced into the formation through the same wells (forexample, through two conduits positioned in the same wellbore). Thehydrogen sulfide and the sulfur dioxide may react in the formation toform sulfur and water. The sulfur may flow outwards in the formation andcondense and/or solidify to form the barrier in the formation.

The sulfur barrier may form in the formation beyond the area wherehydrocarbons in formation fluid generated by the heat treatment processcondense in the formation. Regions near the perimeter of the treatedarea may be at lower temperatures than the treated area. Sulfur maycondense and/or solidify from the vapor phase in these lower temperatureregions. Additional hydrogen sulfide, and/or sulfur dioxide may diffuseto these lower temperature regions. Additional sulfur may form by theClaus reaction to maintain an equilibrium concentration of sulfur in thevapor phase. Eventually, a sulfur barrier may form around the treatedzone. The vapor phase in the treated region may remain as an equilibriummixture of sulfur, hydrogen sulfide, sulfur dioxide, water vapor andother vapor products present or evolving from the formation.

The conversion to sulfur is favored at lower temperatures, so theconversion of hydrogen sulfide and sulfur dioxide to sulfur may takeplace a distance away from the wells that introduce the reactants intothe formation. The Claus reaction may result in the formation of sulfurwhere the temperature of the formation is cooler (for example where thetemperature of the formation is at temperatures from about 180° C. toabout 240° C.).

A temperature monitoring system may be installed in wellbores of freezewells and/or in monitor wells adjacent to the freeze wells to monitorthe temperature profile of the freeze wells and/or the low temperaturezone established by the freeze wells. The monitoring system may be usedto monitor progress of low temperature zone formation. The monitoringsystem may be used to determine the location of high temperature areas,potential breakthrough locations, or breakthrough locations after thelow temperature zone has formed. Periodic monitoring of the temperatureprofile of the freeze wells and/or low temperature zone established bythe freeze wells may allow additional cooling to be provided topotential trouble areas before breakthrough occurs. Additional coolingmay be provided at or adjacent to breakthroughs and high temperatureareas to ensure the integrity of the low temperature zone around thetreatment area. Additional cooling may be provided by increasingrefrigerant flow through selected freeze wells, installing an additionalfreeze well or freeze wells, and/or by providing a cryogenic fluid, suchas liquid nitrogen, to the high temperature areas. Providing additionalcooling to potential problem areas before breakthrough occurs may bemore time efficient and cost efficient than sealing a breach, reheatinga portion of the treatment area that has been cooled by influx of fluid,and/or remediating an area outside of the breached frozen barrier.

In some embodiments, a traveling thermocouple may be used to monitor thetemperature profile of selected freeze wells or monitor wells. In someembodiments, the temperature monitoring system includes thermocouplesplaced at discrete locations in the wellbores of the freeze wells, inthe freeze wells, and/or in the monitoring wells. In some embodiments,the temperature monitoring system comprises a fiber optic temperaturemonitoring system.

Fiber optic temperature monitoring systems are available from Sensornet(London, United Kingdom), Sensa (Houston, Tex., U.S.A.), Luna Energy(Blacksburg, Va., U.S.A.), Lios Technology GMBH (Cologne, Germany),Oxford Electronics Ltd. (Hampshire, United Kingdom), and Sabeus SensorSystems (Calabasas, Calif., U.S.A.). The fiber optic temperaturemonitoring system includes a data system and one or more fiber opticcables. The data system includes one or more lasers for sending light tothe fiber optic cable; and one or more computers, software andperipherals for receiving, analyzing, and outputting data. The datasystem may be coupled to one or more fiber optic cables.

A single fiber optic cable may be several kilometers long. The fiberoptic cable may be installed in many freeze wells and/or monitor wells.In some embodiments, two fiber optic cables may be installed in eachfreeze well and/or monitor well. The two fiber optic cables may becoupled. Using two fiber optic cables per well allows for compensationdue to optical losses that occur in the wells and allows for betteraccuracy of measured temperature profiles.

The fiber optic temperature monitoring system may be used to detect thelocation of a breach or a potential breach in a frozen barrier. Thesearch for potential breaches may be performed at scheduled intervals,for example, every two or three months. To determine the location of thebreach or potential breach, flow of formation refrigerant to the freezewells of interest is stopped. In some embodiments, the flow of formationrefrigerant to all of the freeze wells is stopped. The rise in thetemperature profiles, as well as the rate of change of the temperatureprofiles, provided by the fiber optic temperature monitoring system foreach freeze well can be used to determine the location of any breachesor hot spots in the low temperature zone maintained by the freeze wells.The temperature profile monitored by the fiber optic temperaturemonitoring system for the two freeze wells closest to the hot spot orfluid flow will show the quickest and greatest rise in temperature. Atemperature change of a few degrees Centigrade in the temperatureprofiles of the freeze wells closest to a troubled area may besufficient to isolate the location of the trouble area. The shut downtime of flow of circulation fluid in the freeze wells of interest neededto detect breaches, potential breaches, and hot spots may be on theorder of a few hours or days, depending on the well spacing and theamount of fluid flow affecting the low temperature zone.

Fiber optic temperature monitoring systems may also be used to monitortemperatures in heated portions of the formation during in situ heattreatment processes. The fiber of a fiber optic cable used in the heatedportion of the formation may be clad with a reflective material tofacilitate retention of a signal or signals transmitted down the fiber.In some embodiments, the fiber is clad with gold, copper, nickel,aluminum and/or alloys thereof. The cladding may be formed of a materialthat is able to withstand chemical and temperature conditions in theheated portion of the formation. For example, gold cladding may allow anoptical sensor to be used up to temperatures of 700° C. In someembodiments, the fiber is clad with aluminum. The fiber may be dipped inor run through a bath of liquid aluminum. The clad fiber may then beallowed to cool to secure the aluminum to the fiber. The gold oraluminum cladding may reduce hydrogen darkening of the optical fiber.

A potential source of heat loss from the heated formation is due toreflux in wells. Refluxing occurs when vapors condense in a well andflow into a portion of the well adjacent to the heated portion of theformation. Vapors may condense in the well adjacent to the overburden ofthe formation to form condensed fluid. Condensed fluid flowing into thewell adjacent to the heated formation absorbs heat from the formation.Heat absorbed by condensed fluids cools the formation and necessitatesadditional energy input into the formation to maintain the formation ata desired temperature. Some fluids that condense in the overburden andflow into the portion of the well adjacent to the heated formation mayreact to produce undesired compounds and/or coke. Inhibiting fluids fromrefluxing may significantly improve the thermal efficiency of the insitu heat treatment system and/or the quality of the product producedfrom the in situ heat treatment system.

For some well embodiments, the portion of the well adjacent to theoverburden section of the formation is cemented to the formation. Insome well embodiments, the well includes packing material placed nearthe transition from the heated section of the formation to theoverburden. The packing material inhibits formation fluid from passingfrom the heated section of the formation into the section of thewellbore adjacent to the overburden. Cables, conduits, devices, and/orinstruments may pass through the packing material, but the packingmaterial inhibits formation fluid from passing up the wellbore adjacentto the overburden section of the formation.

In some embodiments, one or more baffle systems may be placed in thewellbores to inhibit reflux. The baffle systems may be obstructions tofluid flow into the heated portion of the formation. In someembodiments, refluxing fluid may revaporize on the baffle system beforecoming into contact with the heated portion of the formation.

In some embodiments, a gas may be introduced into the formation throughwellbores to inhibit reflux in the wellbores. In some embodiments, gasmay be introduced into wellbores that include baffle systems to inhibitreflux of fluid in the wellbores. The gas may be carbon dioxide,methane, nitrogen or other desired gas. In some embodiments, theintroduction of gas may be used in conjunction with one or more bafflesystems in the wellbores. The introduced gas may enhance heat exchangeat the baffle systems to help maintain top portions of the bafflesystems colder than the lower portions of the baffle systems.

The flow of production fluid up the well to the surface is desired forsome types of wells, especially for production wells. Flow of productionfluid up the well is also desirable for some heater wells that are usedto control pressure in the formation. The overburden, or a conduit inthe well used to transport formation fluid from the heated portion ofthe formation to the surface, may be heated to inhibit condensation onor in the conduit. Providing heat in the overburden, however, may becostly and/or may lead to increased cracking or coking of formationfluid as the formation fluid is being produced from the formation.

To avoid the need to heat the overburden or to heat the conduit passingthrough the overburden, one or more diverters may be placed in thewellbore to inhibit fluid from refluxing into the wellbore adjacent tothe heated portion of the formation. In some embodiments, the diverterretains fluid above the heated portion of the formation. Fluids retainedin the diverter may be removed from the diverter using a pump, gaslifting, and/or other fluid removal technique. In certain embodiments,two or more diverters that retain fluid above the heated portion of theformation may be located in the production well. Two or more divertersprovide a simple way of separating initial fractions of condensed fluidproduced from the in situ heat treatment system. A pump may be placed ineach of the diverters to remove condensed fluid from the diverters.

In some embodiments, the diverter directs fluid to a sump below theheated portion of the formation. An inlet for a lift system may belocated in the sump. In some embodiments, the intake of the lift systemis located in casing in the sump. In some embodiments, the intake of thelift system is located in an open wellbore. The sump is below the heatedportion of the formation. The intake of the pump may be located 1 m, 5m, 10 m, 20 m or more below the deepest heater used to heat the heatedportion of the formation. The sump may be at a cooler temperature thanthe heated portion of the formation. The sump may be more than 10° C.,more than 50° C., more than 75° C., or more than 100° C. below thetemperature of the heated portion of the formation. A portion of thefluid entering the sump may be liquid. A portion of the fluid enteringthe sump may condense within the sump. The lift system moves the fluidin the sump to the surface.

Production well lift systems may be used to efficiently transportformation fluid from the bottom of the production wells to the surface.Production well lift systems may provide and maintain the maximumrequired well drawdown (minimum reservoir producing pressure) andproducing rates. The production well lift systems may operateefficiently over a wide range of high temperature/multiphase fluids(gas/vapor/steam/water/hydrocarbon liquids) and production ratesexpected during the life of a typical project. Production well liftsystems may include dual concentric rod pump lift systems, chamber liftsystems and other types of lift systems.

Temperature limited heaters may be in configurations and/or may includematerials that provide automatic temperature limiting properties for theheater at certain temperatures. In certain embodiments, ferromagneticmaterials are used in temperature limited heaters. Ferromagneticmaterial may self-limit temperature at or near the Curie temperature ofthe material and/or the phase transformation temperature range toprovide a reduced amount of heat when a time-varying current is appliedto the material. In certain embodiments, the ferromagnetic materialself-limits temperature of the temperature limited heater at a selectedtemperature that is approximately the Curie temperature and/or in thephase transformation temperature range. In certain embodiments, theselected temperature is within about 35° C., within about 25° C., withinabout 20° C., or within about 10° C. of the Curie temperature and/or thephase transformation temperature range. In certain embodiments,ferromagnetic materials are coupled with other materials (for example,highly conductive materials, high strength materials, corrosionresistant materials, or combinations thereof) to provide variouselectrical and/or mechanical properties. Some parts of the temperaturelimited heater may have a lower resistance (caused by differentgeometries and/or by using different ferromagnetic and/ornon-ferromagnetic materials) than other parts of the temperature limitedheater. Having parts of the temperature limited heater with variousmaterials and/or dimensions allows for tailoring the desired heat outputfrom each part of the heater.

Temperature limited heaters may be more reliable than other heaters.Temperature limited heaters may be less apt to break down or fail due tohot spots in the formation. In some embodiments, temperature limitedheaters allow for substantially uniform heating of the formation. Insome embodiments, temperature limited heaters are able to heat theformation more efficiently by operating at a higher average heat outputalong the entire length of the heater. The temperature limited heateroperates at the higher average heat output along the entire length ofthe heater because power to the heater does not have to be reduced tothe entire heater, as is the case with typical constant wattage heaters,if a temperature along any point of the heater exceeds, or is about toexceed, a maximum operating temperature of the heater. Heat output fromportions of a temperature limited heater approaching a Curie temperatureand/or the phase transformation temperature range of the heaterautomatically reduces without controlled adjustment of the time-varyingcurrent applied to the heater. The heat output automatically reduces dueto changes in electrical properties (for example, electrical resistance)of portions of the temperature limited heater. Thus, more power issupplied by the temperature limited heater during a greater portion of aheating process.

In certain embodiments, the system including temperature limited heatersinitially provides a first heat output and then provides a reduced(second heat output) heat output, near, at, or above the Curietemperature and/or the phase transformation temperature range of anelectrically resistive portion of the heater when the temperaturelimited heater is energized by a time-varying current. The first heatoutput is the heat output at temperatures below which the temperaturelimited heater begins to self-limit. In some embodiments, the first heatoutput is the heat output at a temperature about 50° C., about 75° C.,about 100° C., or about 125° C. below the Curie temperature and/or thephase transformation temperature range of the ferromagnetic material inthe temperature limited heater.

The temperature limited heater may be energized by time-varying current(alternating current or modulated direct current) supplied at thewellhead. The wellhead may include a power source and other components(for example, modulation components, transformers, and/or capacitors)used in supplying power to the temperature limited heater. Thetemperature limited heater may be one of many heaters used to heat aportion of the formation.

In certain embodiments, the temperature limited heater includes aconductor that operates as a skin effect or proximity effect heater whentime-varying current is applied to the conductor. The skin effect limitsthe depth of current penetration into the interior of the conductor. Forferromagnetic materials, the skin effect is dominated by the magneticpermeability of the conductor. The relative magnetic permeability offerromagnetic materials is typically between 10 and 1000 (for example,the relative magnetic permeability of ferromagnetic materials istypically at least 10 and may be at least 50, 100, 500, 1000 orgreater). As the temperature of the ferromagnetic material is raisedabove the Curie temperature, or the phase transformation temperaturerange, and/or as the applied electrical current is increased, themagnetic permeability of the ferromagnetic material decreasessubstantially and the skin depth expands rapidly (for example, the skindepth expands as the inverse square root of the magnetic permeability).The reduction in magnetic permeability results in a decrease in the ACor modulated DC resistance of the conductor near, at, or above the Curietemperature, the phase transformation temperature range, and/or as theapplied electrical current is increased. When the temperature limitedheater is powered by a substantially constant current source, portionsof the heater that approach, reach, or are above the Curie temperatureand/or the phase transformation temperature range may have reduced heatdissipation. Sections of the temperature limited heater that are not ator near the Curie temperature and/or the phase transformationtemperature range may be dominated by skin effect heating that allowsthe heater to have high heat dissipation due to a higher resistive load.

Curie temperature heaters have been used in soldering equipment, heatersfor medical applications, and heating elements for ovens (for example,pizza ovens). Some of these uses are disclosed in U.S. Pat. No.5,579,575 to Lamome et al.; U.S. Pat. No. 5,065,501 to Henschen et al.;and U.S. Pat. No. 5,512,732 to Yagnik et al., all of which areincorporated by reference as if fully set forth herein. U.S. Pat. No.4,849,611 to Whitney et al., which is incorporated by reference as iffully set forth herein, describes a plurality of discrete, spaced-apartheating units including a reactive component, a resistive heatingcomponent, and a temperature responsive component.

An advantage of using the temperature limited heater to heathydrocarbons in the formation is that the conductor is chosen to have aCurie temperature and/or a phase transformation temperature range in adesired range of temperature operation. Operation within the desiredoperating temperature range allows substantial heat injection into theformation while maintaining the temperature of the temperature limitedheater, and other equipment, below design limit temperatures. Designlimit temperatures are temperatures at which properties such ascorrosion, creep, and/or deformation are adversely affected. Thetemperature limiting properties of the temperature limited heaterinhibit overheating or burnout of the heater adjacent to low thermalconductivity “hot spots” in the formation. In some embodiments, thetemperature limited heater is able to lower or control heat outputand/or withstand heat at temperatures above 25° C., 37° C., 100° C.,250° C., 500° C., 700° C., 800° C., 900° C., or higher up to 1131° C.,depending on the materials used in the heater.

The temperature limited heater allows for more heat injection into theformation than constant wattage heaters because the energy input intothe temperature limited heater does not have to be limited toaccommodate low thermal conductivity regions adjacent to the heater. Forexample, in Green River oil shale there is a difference of at least afactor of 3 in the thermal conductivity of the lowest richness oil shalelayers and the highest richness oil shale layers. When heating such aformation, substantially more heat is transferred to the formation withthe temperature limited heater than with the conventional heater that islimited by the temperature at low thermal conductivity layers. The heatoutput along the entire length of the conventional heater needs toaccommodate the low thermal conductivity layers so that the heater doesnot overheat at the low thermal conductivity layers and burn out. Theheat output adjacent to the low thermal conductivity layers that are athigh temperature will reduce for the temperature limited heater, but theremaining portions of the temperature limited heater that are not athigh temperature will still provide high heat output. Because heatersfor heating hydrocarbon formations typically have long lengths (forexample, at least 10 m, 100 m, 300 m, 500 m, 1 km or more up to about 10km), the majority of the length of the temperature limited heater may beoperating below the Curie temperature and/or the phase transformationtemperature range while only a few portions are at or near the Curietemperature and/or the phase transformation temperature range of thetemperature limited heater.

The use of temperature limited heaters allows for efficient transfer ofheat to the formation. Efficient transfer of heat allows for reductionin time needed to heat the formation to a desired temperature. Forexample, in Green River oil shale, pyrolysis typically requires 9.5years to 10 years of heating when using a 12 m heater well spacing withconventional constant wattage heaters. For the same heater spacing,temperature limited heaters may allow a larger average heat output whilemaintaining heater equipment temperatures below equipment design limittemperatures. Pyrolysis in the formation may occur at an earlier timewith the larger average heat output provided by temperature limitedheaters than the lower average heat output provided by constant wattageheaters. For example, in Green River oil shale, pyrolysis may occur in 5years using temperature limited heaters with a 12 m heater well spacing.Temperature limited heaters counteract hot spots due to inaccurate wellspacing or drilling where heater wells come too close together. Incertain embodiments, temperature limited heaters allow for increasedpower output over time for heater wells that have been spaced too farapart, or limit power output for heater wells that are spaced too closetogether. Temperature limited heaters also supply more power in regionsadjacent the overburden and underburden to compensate for temperaturelosses in these regions.

Temperature limited heaters may be advantageously used in many types offormations. For example, in tar sands formations or relatively permeableformations containing heavy hydrocarbons, temperature limited heatersmay be used to provide a controllable low temperature output forreducing the viscosity of fluids, mobilizing fluids, and/or enhancingthe radial flow of fluids at or near the wellbore or in the formation.Temperature limited heaters may be used to inhibit excess coke formationdue to overheating of the near wellbore region of the formation.

The use of temperature limited heaters, in some embodiments, eliminatesor reduces the need for expensive temperature control circuitry. Forexample, the use of temperature limited heaters eliminates or reducesthe need to perform temperature logging and/or the need to use fixedthermocouples on the heaters to monitor potential overheating at hotspots.

In certain embodiments, phase transformation (for example, crystallinephase transformation or a change in the crystal structure) of materialsused in a temperature limited heater change the selected temperature atwhich the heater self-limits. Ferromagnetic material used in thetemperature limited heater may have a phase transformation (for example,a transformation from ferrite to austenite) that decreases the magneticpermeability of the ferromagnetic material. This reduction in magneticpermeability is similar to reduction in magnetic permeability due to themagnetic transition of the ferromagnetic material at the Curietemperature. The Curie temperature is the magnetic transitiontemperature of the ferrite phase of the ferromagnetic material. Thereduction in magnetic permeability results in a decrease in the AC ormodulated DC resistance of the temperature limited heater near, at, orabove the temperature of the phase transformation and/or the Curietemperature of the ferromagnetic material.

The phase transformation of the ferromagnetic material may occur over atemperature range. The temperature range of the phase transformationdepends on the ferromagnetic material and may vary, for example, over arange of about 5° C. to a range of about 200° C. Because the phasetransformation takes place over a temperature range, the reduction inthe magnetic permeability due to the phase transformation takes placeover the temperature range. The reduction in magnetic permeability mayalso occur hysteretically over the temperature range of the phasetransformation. In some embodiments, the phase transformation back tothe lower temperature phase of the ferromagnetic material is slower thanthe phase transformation to the higher temperature phase (for example,the transition from austenite back to ferrite is slower than thetransition from ferrite to austenite). The slower phase transformationback to the lower temperature phase may cause hysteretic operation ofthe heater at or near the phase transformation temperature range thatallows the heater to slowly increase to higher resistance after theresistance of the heater reduces due to high temperature.

In some embodiments, the phase transformation temperature range overlapswith the reduction in the magnetic permeability when the temperatureapproaches the Curie temperature of the ferromagnetic material. Theoverlap may produce a faster drop in electrical resistance versustemperature than if the reduction in magnetic permeability is solely dueto the temperature approaching the Curie temperature. The overlap mayalso produce hysteretic behavior of the temperature limited heater nearthe Curie temperature and/or in the phase transformation temperaturerange.

In certain embodiments, the hysteretic operation due to the phasetransformation is a smoother transition than the reduction in magneticpermeability due to magnetic transition at the Curie temperature. Thesmoother transition may be easier to control (for example, electricalcontrol using a process control device that interacts with the powersupply) than the sharper transition at the Curie temperature. In someembodiments, the Curie temperature is located inside the phasetransformation range for selected metallurgies used in temperaturelimited heaters. This phenomenon provides temperature limited heaterswith the smooth transition properties of the phase transformation inaddition to a sharp and definite transition due to the reduction inmagnetic properties at the Curie temperature. Such temperature limitedheaters may be easy to control (due to the phase transformation) whileproviding finite temperature limits (due to the sharp Curie temperaturetransition). Using the phase transformation temperature range instead ofand/or in addition to the Curie temperature in temperature limitedheaters increases the number and range of metallurgies that may be usedfor temperature limited heaters.

In certain embodiments, alloy additions are made to the ferromagneticmaterial to adjust the temperature range of the phase transformation.For example, adding carbon to the ferromagnetic material may increasethe phase transformation temperature range and lower the onsettemperature of the phase transformation. Adding titanium to theferromagnetic material may increase the onset temperature of the phasetransformation and decrease the phase transformation temperature range.Alloy compositions may be adjusted to provide desired Curie temperatureand phase transformation properties for the ferromagnetic material. Thealloy composition of the ferromagnetic material may be chosen based ondesired properties for the ferromagnetic material (such as, but notlimited to, magnetic permeability transition temperature or temperaturerange, resistance versus temperature profile, or power output). Additionof titanium may allow higher Curie temperatures to be obtained whenadding cobalt to 410 stainless steel by raising the ferrite to austenitephase transformation temperature range to a temperature range that isabove, or well above, the Curie temperature of the ferromagneticmaterial.

In some embodiments, temperature limited heaters are more economical tomanufacture or make than standard heaters. Typical ferromagneticmaterials include iron, carbon steel, or ferritic stainless steel. Suchmaterials are inexpensive as compared to nickel-based heating alloys(such as nichrome, Kanthal™ (Bulten-Kanthal AB, Sweden), and/or LOHM™(Driver-Harris Company, Harrison, N.J., U.S.A.)) typically used ininsulated conductor (mineral insulated cable) heaters. In one embodimentof the temperature limited heater, the temperature limited heater ismanufactured in continuous lengths as an insulated conductor heater tolower costs and improve reliability.

In some embodiments, the temperature limited heater is placed in theheater well using a coiled tubing rig. A heater that can be coiled on aspool may be manufactured by using metal such as ferritic stainlesssteel (for example, 409 stainless steel) that is welded using electricalresistance welding (ERW). U.S. Pat. No. 7,032,809 to Hopkins, which isincorporated by reference as if fully set forth herein, describesforming seam-welded pipe. To form a heater section, a metal strip from aroll is passed through a former where it is shaped into a tubular andthen longitudinally welded using ERW.

In some embodiments, a composite tubular may be formed from theseam-welded tubular. The seam-welded tubular is passed through a secondformer where a conductive strip (for example, a copper strip) isapplied, drawn down tightly on the tubular through a die, andlongitudinally welded using ERW. A sheath may be formed bylongitudinally welding a support material (for example, steel such as347H or 347HH) over the conductive strip material. The support materialmay be a strip rolled over the conductive strip material. An overburdensection of the heater may be formed in a similar manner.

In certain embodiments, the overburden section uses a non-ferromagneticmaterial such as 304 stainless steel or 316 stainless steel instead of aferromagnetic material. The heater section and overburden section may becoupled using standard techniques such as butt welding using an orbitalwelder. In some embodiments, the overburden section material (thenon-ferromagnetic material) may be pre-welded to the ferromagneticmaterial before rolling. The pre-welding may eliminate the need for aseparate coupling step (for example, butt welding). In an embodiment, aflexible cable (for example, a furnace cable such as a MGT 1000 furnacecable) may be pulled through the center after forming the tubularheater. An end bushing on the flexible cable may be welded to thetubular heater to provide an electrical current return path. The tubularheater, including the flexible cable, may be coiled onto a spool beforeinstallation into a heater well. In an embodiment, the temperaturelimited heater is installed using the coiled tubing rig. The coiledtubing rig may place the temperature limited heater in a deformationresistant container in the formation. The deformation resistantcontainer may be placed in the heater well using conventional methods.

Temperature limited heaters may be used for heating hydrocarbonformations including, but not limited to, oil shale formations, coalformations, tar sands formations, and formations with heavy viscousoils. Temperature limited heaters may also be used in the field ofenvironmental remediation to vaporize or destroy soil contaminants.Embodiments of temperature limited heaters may be used to heat fluids ina wellbore or sub-sea pipeline to inhibit deposition of paraffin orvarious hydrates. In some embodiments, a temperature limited heater isused for solution mining a subsurface formation (for example, an oilshale or a coal formation). In certain embodiments, a fluid (forexample, molten salt) is placed in a wellbore and heated with atemperature limited heater to inhibit deformation and/or collapse of thewellbore. In some embodiments, the temperature limited heater isattached to a sucker rod in the wellbore or is part of the sucker roditself. In some embodiments, temperature limited heaters are used toheat a near wellbore region to reduce near wellbore oil viscosity duringproduction of high viscosity crude oils and during transport of highviscosity oils to the surface. In some embodiments, a temperaturelimited heater enables gas lifting of a viscous oil by lowering theviscosity of the oil without coking the oil. Temperature limited heatersmay be used in sulfur transfer lines to maintain temperatures betweenabout 110° C. and about 130° C.

The ferromagnetic alloy or ferromagnetic alloys used in the temperaturelimited heater determine the Curie temperature of the heater. Curietemperature data for various metals is listed in “American Institute ofPhysics Handbook,” Second Edition, McGraw-Hill, pages 5-170 through5-176. Ferromagnetic conductors may include one or more of theferromagnetic elements (iron, cobalt, and nickel) and/or alloys of theseelements. In some embodiments, ferromagnetic conductors includeiron-chromium (Fe—Cr) alloys that contain tungsten (W) (for example,HCM12A and SAVE12 (Sumitomo Metals Co., Japan) and/or iron alloys thatcontain chromium (for example, Fe—Cr alloys, Fe—Cr—W alloys, Fe—Cr—V(vanadium) alloys, and Fe—Cr—Nb (Niobium) alloys). Of the three mainferromagnetic elements, iron has a Curie temperature of approximately770° C.; cobalt (Co) has a Curie temperature of approximately 1131° C.;and nickel has a Curie temperature of approximately 358° C. Aniron-cobalt alloy has a Curie temperature higher than the Curietemperature of iron. For example, iron-cobalt alloy with 2% by weightcobalt has a Curie temperature of approximately 800° C.; iron-cobaltalloy with 12% by weight cobalt has a Curie temperature of approximately900° C.; and iron-cobalt alloy with 20% by weight cobalt has a Curietemperature of approximately 950° C. Iron-nickel alloy has a Curietemperature lower than the Curie temperature of iron. For example,iron-nickel alloy with 20% by weight nickel has a Curie temperature ofapproximately 720° C., and iron-nickel alloy with 60% by weight nickelhas a Curie temperature of approximately 560° C.

Some non-ferromagnetic elements used as alloys raise the Curietemperature of iron. For example, an iron-vanadium alloy with 5.9% byweight vanadium has a Curie temperature of approximately 815° C. Othernon-ferromagnetic elements (for example, carbon, aluminum, copper,silicon, and/or chromium) may be alloyed with iron or otherferromagnetic materials to lower the Curie temperature.Non-ferromagnetic materials that raise the Curie temperature may becombined with non-ferromagnetic materials that lower the Curietemperature and alloyed with iron or other ferromagnetic materials toproduce a material with a desired Curie temperature and other desiredphysical and/or chemical properties. In some embodiments, the Curietemperature material is a ferrite such as NiFe₂O₄. In other embodiments,the Curie temperature material is a binary compound such as FeNi₃ orFe₃Al.

In some embodiments, the improved alloy includes carbon, cobalt, iron,manganese, silicon, or mixtures thereof. In certain embodiments, theimproved alloy includes, by weight: about 0.1% to about 10% cobalt;about 0.1% carbon, about 0.5% manganese, about 0.5% silicon, with thebalance being iron. In certain embodiments, the improved alloy includes,by weight: about 0.1% to about 10% cobalt; about 0.1% carbon, about 0.5%manganese, about 0.5% silicon, with the balance being iron.

In some embodiments, the improved alloy includes chromium, carbon,cobalt, iron, manganese, silicon, titanium, vanadium, or mixturesthereof. In certain embodiments, the improved alloy includes, by weight:about 5% to about 20% cobalt, about 0.1% carbon, about 0.5% manganese,about 0.5% silicon, about 0.1% to about 2% vanadium with the balancebeing iron. In some embodiments, the improved alloy includes, by weight:about 12% chromium, about 0.1% carbon, about 0.5% silicon, about 0.1% toabout 0.5% manganese, above 0% to about 15% cobalt, above 0% to about 2%vanadium, above 0% to about 1% titanium, with the balance being iron. Insome embodiments, the improved alloy includes, by weight: about 12%chromium, about 0.1% carbon, about 0.5% silicon, about 0.1% to about0.5% manganese, above 0% to about 2% vanadium, above 0% to about 1%titanium, with the balance being iron. In some embodiments, the improvedalloy includes, by weight: about 12% chromium, about 0.1% carbon, about0.5% silicon, about 0.1% to about 0.5% manganese, above 0% to about 2%vanadium, with the balance being iron. In certain embodiments, theimproved alloy includes, by weight: about 12% chromium, about 0.1%carbon, about 0.5% silicon, about 0.1% to about 0.5% manganese, above 0%to about 15% cobalt, above 0% to about 1% titanium, with the balancebeing iron. In certain embodiments, the improved alloy includes, byweight: about 12% chromium, about 0.1% carbon, about 0.5% silicon, about0.1% to about 0.5% manganese, above 0% to about 15% cobalt, with thebalance being iron. The addition of vanadium may allow for use of higheramounts of cobalt in the improved alloy.

Certain embodiments of temperature limited heaters may include more thanone ferromagnetic material. Such embodiments are within the scope ofembodiments described herein if any conditions described herein apply toat least one of the ferromagnetic materials in the temperature limitedheater.

Ferromagnetic properties generally decay as the Curie temperature and/orthe phase transformation temperature range is approached. The “Handbookof Electrical Heating for Industry” by C. James Erickson (IEEE Press,1995) shows a typical curve for 1% carbon steel (steel with 1% carbon byweight). The loss of magnetic permeability starts at temperatures above650° C. and tends to be complete when temperatures exceed 730° C. Thus,the self-limiting temperature may be somewhat below the actual Curietemperature and/or the phase transformation temperature range of theferromagnetic conductor. The skin depth for current flow in 1% carbonsteel is 0.132 cm at room temperature and increases to 0.445 cm at 720°C. From 720° C. to 730° C., the skin depth sharply increases to over 2.5cm. Thus, a temperature limited heater embodiment using 1% carbon steelbegins to self-limit between 650° C. and 730° C.

Skin depth generally defines an effective penetration depth oftime-varying current into the conductive material. In general, currentdensity decreases exponentially with distance from an outer surface tothe center along the radius of the conductor. The depth at which thecurrent density is approximately 1/e of the surface current density iscalled the skin depth. For a solid cylindrical rod with a diameter muchgreater than the penetration depth, or for hollow cylinders with a wallthickness exceeding the penetration depth, the skin depth, δ, is:

δ=1981.5*(ρ/(μ*f))^(1/2);  (EQN. 2)

in which:

-   -   δ=skin depth in inches;    -   ρ=resistivity at operating temperature (ohm-cm);    -   μ=relative magnetic permeability; and    -   f=frequency (Hz).        EQN. 2 is obtained from “Handbook of Electrical Heating for        Industry” by C. James Erickson (IEEE Press, 1995). For most        metals, resistivity (ρ) increases with temperature. The relative        magnetic permeability generally varies with temperature and with        current. Additional equations may be used to assess the variance        of magnetic permeability and/or skin depth on both temperature        and/or current. The dependence of μ on current arises from the        dependence of μ on the electromagnetic field.

Materials used in the temperature limited heater may be selected toprovide a desired turndown ratio. Turndown ratios of at least 1.1:1,2:1, 3:1, 4:1, 5:1, 10:1, 30:1, or 50:1 may be selected for temperaturelimited heaters. Larger turndown ratios may also be used. A selectedturndown ratio may depend on a number of factors including, but notlimited to, the type of formation in which the temperature limitedheater is located (for example, a higher turndown ratio may be used foran oil shale formation with large variations in thermal conductivitybetween rich and lean oil shale layers) and/or a temperature limit ofmaterials used in the wellbore (for example, temperature limits ofheater materials). In some embodiments, the turndown ratio is increasedby coupling additional copper or another good electrical conductor tothe ferromagnetic material (for example, adding copper to lower theresistance above the Curie temperature and/or the phase transformationtemperature range).

The temperature limited heater may provide a maximum heat output (poweroutput) below the Curie temperature and/or the phase transformationtemperature range of the heater. In certain embodiments, the maximumheat output is at least 400 W/m (Watts per meter), 600 W/m, 700 W/m, 800W/m, or higher up to 2000 W/m. The temperature limited heater reducesthe amount of heat output by a section of the heater when thetemperature of the section of the heater approaches or is above theCurie temperature and/or the phase transformation temperature range. Thereduced amount of heat may be substantially less than the heat outputbelow the Curie temperature and/or the phase transformation temperaturerange. In some embodiments, the reduced amount of heat is at most 400W/m, 200 W/m, 100 W/m or may approach 0 W/m.

In certain embodiments, the temperature limited heater operatessubstantially independently of the thermal load on the heater in acertain operating temperature range. “Thermal load” is the rate thatheat is transferred from a heating system to its surroundings. It is tobe understood that the thermal load may vary with temperature of thesurroundings and/or the thermal conductivity of the surroundings. In anembodiment, the temperature limited heater operates at or above theCurie temperature and/or the phase transformation temperature range ofthe temperature limited heater such that the operating temperature ofthe heater increases at most by 3° C., 2° C., 1.5° C., 1° C., or 0.5° C.for a decrease in thermal load of 1 W/m proximate to a portion of theheater. In certain embodiments, the temperature limited heater operatesin such a manner at a relatively constant current.

The AC or modulated DC resistance and/or the heat output of thetemperature limited heater may decrease as the temperature approachesthe Curie temperature and/or the phase transformation temperature rangeand decrease sharply near or above the Curie temperature due to theCurie effect and/or phase transformation effect. In certain embodiments,the value of the electrical resistance or heat output above or near theCurie temperature and/or the phase transformation temperature range isat most one-half of the value of electrical resistance or heat output ata certain point below the Curie temperature and/or the phasetransformation temperature range. In some embodiments, the heat outputabove or near the Curie temperature and/or the phase transformationtemperature range is at most 90%, 70%, 50%, 30%, 20%, 10%, or less (downto 1%) of the heat output at a certain point below the Curie temperatureand/or the phase transformation temperature range (for example, 30° C.below the Curie temperature, 40° C. below the Curie temperature, 50° C.below the Curie temperature, or 100° C. below the Curie temperature). Incertain embodiments, the electrical resistance above or near the Curietemperature and/or the phase transformation temperature range decreasesto 80%, 70%, 60%, 50%, or less (down to 1%) of the electrical resistanceat a certain point below the Curie temperature and/or the phasetransformation temperature range (for example, 30° C. below the Curietemperature, 40° C. below the Curie temperature, 50° C. below the Curietemperature, or 100° C. below the Curie temperature).

In some embodiments, AC frequency is adjusted to change the skin depthof the ferromagnetic material. For example, the skin depth of 1% carbonsteel at room temperature is 0.132 cm at 60 Hz, 0.0762 cm at 180 Hz, and0.046 cm at 440 Hz. Since heater diameter is typically larger than twicethe skin depth, using a higher frequency (and thus a heater with asmaller diameter) reduces heater costs. For a fixed geometry, the higherfrequency results in a higher turndown ratio. The turndown ratio at ahigher frequency is calculated by multiplying the turndown ratio at alower frequency by the square root of the higher frequency divided bythe lower frequency. In some embodiments, a frequency between 100 Hz and1000 Hz, between 140 Hz and 200 Hz, or between 400 Hz and 600 Hz is used(for example, 180 Hz, 540 Hz, or 720 Hz). In some embodiments, highfrequencies may be used. The frequencies may be greater than 1000 Hz.

To maintain a substantially constant skin depth until the Curietemperature and/or the phase transformation temperature range of thetemperature limited heater is reached, the heater may be operated at alower frequency when the heater is cold and operated at a higherfrequency when the heater is hot. Line frequency heating is generallyfavorable, however, because there is less need for expensive componentssuch as power supplies, transformers, or current modulators that alterfrequency. Line frequency is the frequency of a general supply ofcurrent. Line frequency is typically 60 Hz, but may be 50 Hz or anotherfrequency depending on the source for the supply of the current. Higherfrequencies may be produced using commercially available equipment suchas solid state variable frequency power supplies. Transformers thatconvert three-phase power to single-phase power with three times thefrequency are commercially available. For example, high voltagethree-phase power at 60 Hz may be transformed to single-phase power at180 Hz and at a lower voltage. Such transformers are less expensive andmore energy efficient than solid state variable frequency powersupplies. In certain embodiments, transformers that convert three-phasepower to single-phase power are used to increase the frequency of powersupplied to the temperature limited heater.

In certain embodiments, modulated DC (for example, chopped DC, waveformmodulated DC, or cycled DC) may be used for providing electrical powerto the temperature limited heater. A DC modulator or DC chopper may becoupled to a DC power supply to provide an output of modulated directcurrent. In some embodiments, the DC power supply may include means formodulating DC. One example of a DC modulator is a DC-to-DC convertersystem. DC-to-DC converter systems are generally known in the art. DC istypically modulated or chopped into a desired waveform. Waveforms for DCmodulation include, but are not limited to, square-wave, sinusoidal,deformed sinusoidal, deformed square-wave, triangular, and other regularor irregular waveforms.

The modulated DC waveform generally defines the frequency of themodulated DC. Thus, the modulated DC waveform may be selected to providea desired modulated DC frequency. The shape and/or the rate ofmodulation (such as the rate of chopping) of the modulated DC waveformmay be varied to vary the modulated DC frequency. DC may be modulated atfrequencies that are higher than generally available AC frequencies. Forexample, modulated DC may be provided at frequencies of at least 1000Hz. Increasing the frequency of supplied current to higher valuesadvantageously increases the turndown ratio of the temperature limitedheater.

In certain embodiments, the modulated DC waveform is adjusted or alteredto vary the modulated DC frequency. The DC modulator may be able toadjust or alter the modulated DC waveform at any time during use of thetemperature limited heater and at high currents or voltages. Thus,modulated DC provided to the temperature limited heater is not limitedto a single frequency or even a small set of frequency values. Waveformselection using the DC modulator typically allows for a wide range ofmodulated DC frequencies and for discrete control of the modulated DCfrequency. Thus, the modulated DC frequency is more easily set at adistinct value whereas AC frequency is generally limited to multiples ofthe line frequency. Discrete control of the modulated DC frequencyallows for more selective control over the turndown ratio of thetemperature limited heater. Being able to selectively control theturndown ratio of the temperature limited heater allows for a broaderrange of materials to be used in designing and constructing thetemperature limited heater.

In some embodiments, the modulated DC frequency or the AC frequency isadjusted to compensate for changes in properties (for example,subsurface conditions such as temperature or pressure) of thetemperature limited heater during use. The modulated DC frequency or theAC frequency provided to the temperature limited heater is varied basedon assessed downhole conditions. For example, as the temperature of thetemperature limited heater in the wellbore increases, it may beadvantageous to increase the frequency of the current provided to theheater, thus increasing the turndown ratio of the heater. In anembodiment, the downhole temperature of the temperature limited heaterin the wellbore is assessed.

In certain embodiments, the modulated DC frequency, or the AC frequency,is varied to adjust the turndown ratio of the temperature limitedheater. The turndown ratio may be adjusted to compensate for hot spotsoccurring along a length of the temperature limited heater. For example,the turndown ratio is increased because the temperature limited heateris getting too hot in certain locations. In some embodiments, themodulated DC frequency, or the AC frequency, are varied to adjust aturndown ratio without assessing a subsurface condition.

At or near the Curie temperature and/or the phase transformationtemperature range of the ferromagnetic material, a relatively smallchange in voltage may cause a relatively large change in current to theload. The relatively small change in voltage may produce problems in thepower supplied to the temperature limited heater, especially at or nearthe Curie temperature and/or the phase transformation temperature range.The problems include, but are not limited to, reducing the power factor,tripping a circuit breaker, and/or blowing a fuse. In some cases,voltage changes may be caused by a change in the load of the temperaturelimited heater. In certain embodiments, an electrical current supply(for example, a supply of modulated DC or AC) provides a relativelyconstant amount of current that does not substantially vary with changesin load of the temperature limited heater. In an embodiment, theelectrical current supply provides an amount of electrical current thatremains within 15%, within 10%, within 5%, or within 2% of a selectedconstant current value when a load of the temperature limited heaterchanges.

Temperature limited heaters may generate an inductive load. Theinductive load is due to some applied electrical current being used bythe ferromagnetic material to generate a magnetic field in addition togenerating a resistive heat output. As downhole temperature changes inthe temperature limited heater, the inductive load of the heater changesdue to changes in the ferromagnetic properties of ferromagneticmaterials in the heater with temperature. The inductive load of thetemperature limited heater may cause a phase shift between the currentand the voltage applied to the heater.

A reduction in actual power applied to the temperature limited heatermay be caused by a time lag in the current waveform (for example, thecurrent has a phase shift relative to the voltage due to an inductiveload) and/or by distortions in the current waveform (for example,distortions in the current waveform caused by introduced harmonics dueto a non-linear load). Thus, it may take more current to apply aselected amount of power due to phase shifting or waveform distortion.The ratio of actual power applied and the apparent power that would havebeen transmitted if the same current were in phase and undistorted isthe power factor. The power factor is always less than or equal to 1.The power factor is 1 when there is no phase shift or distortion in thewaveform.

Actual power applied to a heater due to a phase shift may be describedby EQN. 3:

P=I×V×cos(θ);  (EQN. 3)

in which P is the actual power applied to a heater; I is the appliedcurrent; V is the applied voltage; and θ is the phase angle differencebetween voltage and current. Other phenomena such as waveform distortionmay contribute to further lowering of the power factor. If there is nodistortion in the waveform, then cos(θ) is equal to the power factor.

In certain embodiments, the temperature limited heater includes an innerconductor inside an outer conductor. The inner conductor and the outerconductor are radially disposed about a central axis. The inner andouter conductors may be separated by an insulation layer. In certainembodiments, the inner and outer conductors are coupled at the bottom ofthe temperature limited heater. Electrical current may flow into thetemperature limited heater through the inner conductor and returnthrough the outer conductor. One or both conductors may includeferromagnetic material.

The insulation layer may comprise an electrically insulating ceramicwith high thermal conductivity, such as magnesium oxide, aluminum oxide,silicon dioxide, beryllium oxide, boron nitride, silicon nitride, orcombinations thereof. The insulating layer may be a compacted powder(for example, compacted ceramic powder). Compaction may improve thermalconductivity and provide better insulation resistance. For lowertemperature applications, polymer insulation made from, for example,fluoropolymers, polyimides, polyamides, and/or polyethylenes, may beused. In some embodiments, the polymer insulation is made ofperfluoroalkoxy (PFA) or polyetheretherketone (PEEK™ (Victrex Ltd,England)). The insulating layer may be chosen to be substantiallyinfrared transparent to aid heat transfer from the inner conductor tothe outer conductor. In an embodiment, the insulating layer istransparent quartz sand. The insulation layer may be air or anon-reactive gas such as helium, nitrogen, or sulfur hexafluoride. Ifthe insulation layer is air or a non-reactive gas, there may beinsulating spacers designed to inhibit electrical contact between theinner conductor and the outer conductor. The insulating spacers may bemade of, for example, high purity aluminum oxide or another thermallyconducting, electrically insulating material such as silicon nitride.The insulating spacers may be a fibrous ceramic material such as Nextel™312 (3M Corporation, St. Paul, Minn., U.S.A.), mica tape, or glassfiber. Ceramic material may be made of alumina, alumina-silicate,alumina-borosilicate, silicon nitride, boron nitride, or othermaterials.

The insulation layer may be flexible and/or substantially deformationtolerant. For example, if the insulation layer is a solid or compactedmaterial that substantially fills the space between the inner and outerconductors, the temperature limited heater may be flexible and/orsubstantially deformation tolerant. Forces on the outer conductor can betransmitted through the insulation layer to the solid inner conductor,which may resist crushing. Such a temperature limited heater may bebent, dog-legged, and spiraled without causing the outer conductor andthe inner conductor to electrically short to each other. Deformationtolerance may be important if the wellbore is likely to undergosubstantial deformation during heating of the formation.

In certain embodiments, an outermost layer of the temperature limitedheater (for example, the outer conductor) is chosen for corrosionresistance, yield strength, and/or creep resistance. In one embodiment,austenitic (non-ferromagnetic) stainless steels such as 201, 304H, 347H,347HH, 316H, 310H, 347HP, NF709 (Nippon Steel Corp., Japan) stainlesssteels, or combinations thereof may be used in the outer conductor. Theoutermost layer may also include a clad conductor. For example, acorrosion resistant alloy such as 800H or 347H stainless steel may beclad for corrosion protection over a ferromagnetic carbon steel tubular.If high temperature strength is not required, the outermost layer may beconstructed from ferromagnetic metal with good corrosion resistance suchas one of the ferritic stainless steels. In one embodiment, a ferriticalloy of 82.3% by weight iron with 17.7% by weight chromium (Curietemperature of 678° C.) provides desired corrosion resistance.

The Metals Handbook, vol. 8, page 291 (American Society of Materials(ASM)) includes a graph of Curie temperature of iron-chromium alloysversus the amount of chromium in the alloys. In some temperature limitedheater embodiments, a separate support rod or tubular (made from 347Hstainless steel) is coupled to the temperature limited heater made froman iron-chromium alloy to provide yield strength and/or creepresistance. In certain embodiments, the support material and/or theferromagnetic material is selected to provide a 100,000 hourcreep-rupture strength of at least 20.7 MPa at 650° C. In someembodiments, the 100,000 hour creep-rupture strength is at least 13.8MPa at 650° C. or at least 6.9 MPa at 650° C. For example, 347H steelhas a favorable creep-rupture strength at or above 650° C. In someembodiments, the 100,000 hour creep-rupture strength ranges from 6.9 MPato 41.3 MPa or more for longer heaters and/or higher earth or fluidstresses.

In temperature limited heater embodiments with both an innerferromagnetic conductor and an outer ferromagnetic conductor, the skineffect current path occurs on the outside of the inner conductor and onthe inside of the outer conductor. Thus, the outside of the outerconductor may be clad with the corrosion resistant alloy, such asstainless steel, without affecting the skin effect current path on theinside of the outer conductor.

A ferromagnetic conductor with a thickness of at least the skin depth atthe Curie temperature and/or the phase transformation temperature rangeallows a substantial decrease in resistance of the ferromagneticmaterial as the skin depth increases sharply near the Curie temperatureand/or the phase transformation temperature range. In certainembodiments when the ferromagnetic conductor is not clad with a highlyconducting material such as copper, the thickness of the conductor maybe 1.5 times the skin depth near the Curie temperature and/or the phasetransformation temperature range, 3 times the skin depth near the Curietemperature and/or the phase transformation temperature range, or even10 or more times the skin depth near the Curie temperature and/or thephase transformation temperature range. If the ferromagnetic conductoris clad with copper, thickness of the ferromagnetic conductor may besubstantially the same as the skin depth near the Curie temperatureand/or the phase transformation temperature range. In some embodiments,the ferromagnetic conductor clad with copper has a thickness of at leastthree-fourths of the skin depth near the Curie temperature and/or thephase transformation temperature range.

In certain embodiments, the temperature limited heater includes acomposite conductor with a ferromagnetic tubular and anon-ferromagnetic, high electrical conductivity core. Thenon-ferromagnetic, high electrical conductivity core reduces a requireddiameter of the conductor. For example, the conductor may be composite1.19 cm diameter conductor with a core of 0.575 cm diameter copper cladwith a 0.298 cm thickness of ferritic stainless steel or carbon steelsurrounding the core. The core or non-ferromagnetic conductor may becopper or copper alloy. The core or non-ferromagnetic conductor may alsobe made of other metals that exhibit low electrical resistivity andrelative magnetic permeabilities near 1 (for example, substantiallynon-ferromagnetic materials such as aluminum and aluminum alloys,phosphor bronze, beryllium copper, and/or brass). A composite conductorallows the electrical resistance of the temperature limited heater todecrease more steeply near the Curie temperature and/or the phasetransformation temperature range. As the skin depth increases near theCurie temperature and/or the phase transformation temperature range toinclude the copper core, the electrical resistance decreases verysharply.

The composite conductor may increase the conductivity of the temperaturelimited heater and/or allow the heater to operate at lower voltages. Inan embodiment, the composite conductor exhibits a relatively flatresistance versus temperature profile at temperatures below a regionnear the Curie temperature and/or the phase transformation temperaturerange of the ferromagnetic conductor of the composite conductor. In someembodiments, the temperature limited heater exhibits a relatively flatresistance versus temperature profile between 100° C. and 750° C. orbetween 300° C. and 600° C. The relatively flat resistance versustemperature profile may also be exhibited in other temperature ranges byadjusting, for example, materials and/or the configuration of materialsin the temperature limited heater. In certain embodiments, the relativethickness of each material in the composite conductor is selected toproduce a desired resistivity versus temperature profile for thetemperature limited heater.

In certain embodiments, the relative thickness of each material in acomposite conductor is selected to produce a desired resistivity versustemperature profile for a temperature limited heater. In an embodiment,the composite conductor is an inner conductor surrounded by 0.127 cmthick magnesium oxide powder as an insulator. The outer conductor may be304H stainless steel with a wall thickness of 0.127 cm. The outsidediameter of the heater may be about 1.65 cm.

A composite conductor (for example, a composite inner conductor or acomposite outer conductor) may be manufactured by methods including, butnot limited to, coextrusion, roll forming, tight fit tubing (forexample, cooling the inner member and heating the outer member, theninserting the inner member in the outer member, followed by a drawingoperation and/or allowing the system to cool), explosive orelectromagnetic cladding, arc overlay welding, longitudinal stripwelding, plasma powder welding, billet coextrusion, electroplating,drawing, sputtering, plasma deposition, coextrusion casting, magneticforming, molten cylinder casting (of inner core material inside theouter or vice versa), insertion followed by welding or high temperaturebraising, shielded active gas welding (SAG), and/or insertion of aninner pipe in an outer pipe followed by mechanical expansion of theinner pipe by hydroforming or use of a pig to expand and swage the innerpipe against the outer pipe. In some embodiments, a ferromagneticconductor is braided over a non-ferromagnetic conductor. In certainembodiments, composite conductors are formed using methods similar tothose used for cladding (for example, cladding copper to steel). Ametallurgical bond between copper cladding and base ferromagneticmaterial may be advantageous. Composite conductors produced by acoextrusion process that forms a good metallurgical bond (for example, agood bond between copper and 446 stainless steel) may be provided byAnomet Products, Inc. (Shrewsbury, Mass., U.S.A.).

FIGS. 39-60 depict various embodiments of temperature limited heaters.One or more features of an embodiment of the temperature limited heaterdepicted in any of these figures may be combined with one or morefeatures of other embodiments of temperature limited heaters depicted inthese figures. In certain embodiments described herein, temperaturelimited heaters are dimensioned to operate at a frequency of 60 Hz AC.It is to be understood that dimensions of the temperature limited heatermay be adjusted from those described herein to operate in a similarmanner at other AC frequencies or with modulated DC current.

The temperature limited heaters may be used in conductor-in-conduitheaters. In some embodiments of conductor-in-conduit heaters, themajority of the resistive heat is generated in the conductor, and theheat radiatively, conductively and/or convectively transfers to theconduit. In some embodiments of conductor-in-conduit heaters, themajority of the resistive heat is generated in the conduit.

FIG. 39 depicts a cross-sectional representation of an embodiment of thetemperature limited heater with an outer conductor having aferromagnetic section and a non-ferromagnetic section. FIGS. 40 and 41depict transverse cross-sectional views of the embodiment shown in FIG.39. In one embodiment, ferromagnetic section 528 is used to provide heatto hydrocarbon layers in the formation. Non-ferromagnetic section 530 isused in the overburden of the formation. Non-ferromagnetic section 530provides little or no heat to the overburden, thus inhibiting heatlosses in the overburden and improving heater efficiency. Ferromagneticsection 528 includes a ferromagnetic material such as 409 stainlesssteel or 410 stainless steel. Ferromagnetic section 528 has a thicknessof 0.3 cm. Non-ferromagnetic section 530 is copper with a thickness of0.3 cm. Inner conductor 532 is copper. Inner conductor 532 has adiameter of 0.9 cm. Electrical insulator 534 is silicon nitride, boronnitride, magnesium oxide powder, or another suitable insulator material.Electrical insulator 534 has a thickness of 0.1 cm to 0.3 cm.

FIG. 42 depicts a cross-sectional representation of an embodiment of atemperature limited heater with an outer conductor having aferromagnetic section and a non-ferromagnetic section placed inside asheath. FIGS. 43, 44, and 45 depict transverse cross-sectional views ofthe embodiment shown in FIG. 42. Ferromagnetic section 528 is 410stainless steel with a thickness of 0.6 cm. Non-ferromagnetic section530 is copper with a thickness of 0.6 cm. Inner conductor 532 is copperwith a diameter of 0.9 cm. Outer conductor 536 includes ferromagneticmaterial. Outer conductor 536 provides some heat in the overburdensection of the heater. Providing some heat in the overburden inhibitscondensation or refluxing of fluids in the overburden. Outer conductor536 is 409, 410, or 446 stainless steel with an outer diameter of 3.0 cmand a thickness of 0.6 cm. Electrical insulator 534 includes compactedmagnesium oxide powder with a thickness of 0.3 cm. In some embodiments,electrical insulator 534 includes silicon nitride, boron nitride, orhexagonal type boron nitride. Conductive section 538 may couple innerconductor 532 with ferromagnetic section 528 and/or outer conductor 536.

FIG. 46A and FIG. 46B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic innerconductor. Inner conductor 532 is a 1″ Schedule XXS 446 stainless steelpipe. In some embodiments, inner conductor 532 includes 409 stainlesssteel, 410 stainless steel, Invar 36, alloy 42-6, alloy 52, or otherferromagnetic materials. Inner conductor 532 has a diameter of 2.5 cm.Electrical insulator 534 includes compacted silicon nitride, boronnitride, or magnesium oxide powders; or polymers, Nextel ceramic fiber,mica, or glass fibers. Outer conductor 536 is copper or any othernon-ferromagnetic material, such as but not limited to copper alloys,aluminum and/or aluminum alloys. Outer conductor 536 is coupled tojacket 540. Jacket 540 is 304H, 316H, or 347H stainless steel. In thisembodiment, a majority of the heat is produced in inner conductor 532.

FIG. 47A and FIG. 47B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic innerconductor and a non-ferromagnetic core. Inner conductor 532 may be madeof 446 stainless steel, 409 stainless steel, 410 stainless steel, carbonsteel, Armco ingot iron, iron-cobalt alloys, or other ferromagneticmaterials. Core 542 may be tightly bonded inside inner conductor 532.Core 542 is copper or other non-ferromagnetic material. In certainembodiments, core 542 is inserted as a tight fit inside inner conductor532 before a drawing operation. In some embodiments, core 542 and innerconductor 532 are coextrusion bonded. Outer conductor 536 is 347Hstainless steel. A drawing or rolling operation to compact electricalinsulator 534 (for example, compacted silicon nitride, boron nitride, ormagnesium oxide powder) may ensure good electrical contact between innerconductor 532 and core 542. In this embodiment, heat is producedprimarily in inner conductor 532 until the Curie temperature and/or thephase transformation temperature range is approached. Resistance thendecreases sharply as current penetrates core 542.

FIG. 48A and FIG. 48B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic outerconductor. Inner conductor 532 is nickel-clad copper. Electricalinsulator 534 is silicon nitride, boron nitride, or magnesium oxide.Outer conductor 536 is a 1″ Schedule XXS carbon steel pipe. In thisembodiment, heat is produced primarily in outer conductor 536, resultingin a small temperature differential across electrical insulator 534.

FIG. 49A and FIG. 49B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic outerconductor that is clad with a corrosion resistant alloy. Inner conductor532 is copper. Outer conductor 536 is a 1″ Schedule XXS carbon steelpipe. Outer conductor 536 is coupled to jacket 540. Jacket 540 is madeof corrosion resistant material (for example, 347H stainless steel).Jacket 540 provides protection from corrosive fluids in the wellbore(for example, sulfidizing and carburizing gases). Heat is producedprimarily in outer conductor 536, resulting in a small temperaturedifferential across electrical insulator 534.

FIG. 50A and FIG. 50B depict cross-sectional representations of anembodiment of a temperature limited heater with a ferromagnetic outerconductor. The outer conductor is clad with a conductive layer and acorrosion resistant alloy. Inner conductor 532 is copper. Electricalinsulator 534 is silicon nitride, boron nitride, or magnesium oxide.Outer conductor 536 is a 1″ Schedule 80 446 stainless steel pipe. Outerconductor 536 is coupled to jacket 540. Jacket 540 is made fromcorrosion resistant material such as 347H stainless steel. In anembodiment, conductive layer 544 is placed between outer conductor 536and jacket 540. Conductive layer 544 is a copper layer. Heat is producedprimarily in outer conductor 536, resulting in a small temperaturedifferential across electrical insulator 534. Conductive layer 544allows a sharp decrease in the resistance of outer conductor 536 as theouter conductor approaches the Curie temperature and/or the phasetransformation temperature range. Jacket 540 provides protection fromcorrosive fluids in the wellbore.

In some embodiments, the conductor (for example, an inner conductor, anouter conductor, or a ferromagnetic conductor) is the compositeconductor that includes two or more different materials. In certainembodiments, the composite conductor includes two or more ferromagneticmaterials. In some embodiments, the composite ferromagnetic conductorincludes two or more radially disposed materials. In certainembodiments, the composite conductor includes a ferromagnetic conductorand a non-ferromagnetic conductor. In some embodiments, the compositeconductor includes the ferromagnetic conductor placed over anon-ferromagnetic core. Two or more materials may be used to obtain arelatively flat electrical resistivity versus temperature profile in atemperature region below the Curie temperature, and/or the phasetransformation temperature range, and/or a sharp decrease (a highturndown ratio) in the electrical resistivity at or near the Curietemperature and/or the phase transformation temperature range. In somecases, two or more materials are used to provide more than one Curietemperature and/or phase transformation temperature range for thetemperature limited heater.

The composite electrical conductor may be used as the conductor in anyelectrical heater embodiment described herein. For example, thecomposite conductor may be used as the conductor in aconductor-in-conduit heater or an insulated conductor heater. In certainembodiments, the composite conductor may be coupled to a support membersuch as a support conductor. The support member may be used to providesupport to the composite conductor so that the composite conductor isnot relied upon for strength at or near the Curie temperature and/or thephase transformation temperature range. The support member may be usefulfor heaters of lengths of at least 100 m. The support member may be anon-ferromagnetic member that has good high temperature creep strength.Examples of materials that are used for a support member include, butare not limited to, Haynes® 625 alloy and Haynes® HR120® alloy (HaynesInternational, Kokomo, Ind., U.S.A.), NF709, Incoloy® 800H alloy and347HP alloy (Allegheny Ludlum Corp., Pittsburgh, Pa., U.S.A.). In someembodiments, materials in a composite conductor are directly coupled(for example, brazed, metallurgically bonded, or swaged) to each otherand/or the support member. Using a support member may reduce the needfor the ferromagnetic member to provide support for the temperaturelimited heater, especially at or near the Curie temperature and/or thephase transformation temperature range. Thus, the temperature limitedheater may be designed with more flexibility in the selection offerromagnetic materials.

FIG. 51 depicts a cross-sectional representation of an embodiment of thecomposite conductor with the support member. Core 542 is surrounded byferromagnetic conductor 546 and support member 548. In some embodiments,core 542, ferromagnetic conductor 546, and support member 548 aredirectly coupled (for example, brazed together or metallurgically bondedtogether). In one embodiment, core 542 is copper, ferromagneticconductor 546 is 446 stainless steel, and support member 548 is 347Halloy. In certain embodiments, support member 548 is a Schedule 80 pipe.Support member 548 surrounds the composite conductor havingferromagnetic conductor 546 and core 542. Ferromagnetic conductor 546and core 542 may be joined to form the composite conductor by, forexample, a coextrusion process. For example, the composite conductor isa 1.9 cm outside diameter 446 stainless steel ferromagnetic conductorsurrounding a 0.95 cm diameter copper core.

In certain embodiments, the diameter of core 542 is adjusted relative toa constant outside diameter of ferromagnetic conductor 546 to adjust theturndown ratio of the temperature limited heater. For example, thediameter of core 542 may be increased to 1.14 cm while maintaining theoutside diameter of ferromagnetic conductor 546 at 1.9 cm to increasethe turndown ratio of the heater.

In some embodiments, conductors (for example, core 542 and ferromagneticconductor 546) in the composite conductor are separated by supportmember 548. FIG. 52 depicts a cross-sectional representation of anembodiment of the composite conductor with support member 548 separatingthe conductors. In one embodiment, core 542 is copper with a diameter of0.95 cm, support member 548 is 347H alloy with an outside diameter of1.9 cm, and ferromagnetic conductor 546 is 446 stainless steel with anoutside diameter of 2.7 cm. The support member depicted in FIG. 52 has alower creep strength relative to the support members depicted in FIG.51.

In certain embodiments, support member 548 is located inside thecomposite conductor. FIG. 53 depicts a cross-sectional representation ofan embodiment of the composite conductor surrounding support member 548.Support member 548 is made of 347H alloy. Inner conductor 532 is copper.Ferromagnetic conductor 546 is 446 stainless steel. In one embodiment,support member 548 is 1.25 cm diameter 347H alloy, inner conductor 532is 1.9 cm outside diameter copper, and ferromagnetic conductor 546 is2.7 cm outside diameter 446 stainless steel. The turndown ratio ishigher than the turndown ratio for the embodiments depicted in FIGS. 51,52, and 54 for the same outside diameter, but the creep strength islower.

In some embodiments, the thickness of inner conductor 532, which iscopper, is reduced and the thickness of support member 548 is increasedto increase the creep strength at the expense of reduced turndown ratio.For example, the diameter of support member 548 is increased to 1.6 cmwhile maintaining the outside diameter of inner conductor 532 at 1.9 cmto reduce the thickness of the conduit. This reduction in thickness ofinner conductor 532 results in a decreased turndown ratio relative tothe thicker inner conductor embodiment but an increased creep strength.

In one embodiment, support member 548 is a conduit (or pipe) insideinner conductor 532 and ferromagnetic conductor 546. FIG. 54 depicts across-sectional representation of an embodiment of the compositeconductor surrounding support member 548. In one embodiment, supportmember 548 is 347H alloy with a 0.63 cm diameter center hole. In someembodiments, support member 548 is a preformed conduit. In certainembodiments, support member 548 is formed by having a dissolvablematerial (for example, copper dissolvable by nitric acid) located insidethe support member during formation of the composite conductor. Thedissolvable material is dissolved to form the hole after the conductoris assembled. In an embodiment, support member 548 is 347H alloy with aninside diameter of 0.63 cm and an outside diameter of 1.6 cm, innerconductor 532 is copper with an outside diameter of 1.8 cm, andferromagnetic conductor 546 is 446 stainless steel with an outsidediameter of 2.7 cm.

In certain embodiments, the composite electrical conductor is used asthe conductor in the conductor-in-conduit heater. For example, thecomposite electrical conductor may be used as conductor 550 in FIG. 55.

FIG. 55 depicts a cross-sectional representation of an embodiment of theconductor-in-conduit heater. Conductor 550 is disposed in conduit 552.Conductor 550 is a rod or conduit of electrically conductive material.Low resistance sections 554 are present at both ends of conductor 550 togenerate less heating in these sections. Low resistance section 554 isformed by having a greater cross-sectional area of conductor 550 in thatsection, or the sections are made of material having less resistance. Incertain embodiments, low resistance section 554 includes a lowresistance conductor coupled to conductor 550.

Conduit 552 is made of an electrically conductive material. Conduit 552is disposed in opening 556 in hydrocarbon layer 484. Opening 556 has adiameter that accommodates conduit 552.

Conductor 550 may be centered in conduit 552 by centralizers 558.Centralizers 558 electrically isolate conductor 550 from conduit 552.Centralizers 558 inhibit movement and properly locate conductor 550 inconduit 552. Centralizers 558 are made of ceramic material or acombination of ceramic and metallic materials. Centralizers 558 inhibitdeformation of conductor 550 in conduit 552. Centralizers 558 aretouching or spaced at intervals between approximately 0.1 m (meters) andapproximately 3 m or more along conductor 550.

A second low resistance section 554 of conductor 550 may coupleconductor 550 to wellhead 476. Electrical current may be applied toconductor 550 from power cable 560 through low resistance section 554 ofconductor 550. Electrical current passes from conductor 550 throughsliding connector 562 to conduit 552. Conduit 552 may be electricallyinsulated from overburden casing 564 and from wellhead 476 to returnelectrical current to power cable 560. Heat may be generated inconductor 550 and conduit 552. The generated heat may radiate in conduit552 and opening 556 to heat at least a portion of hydrocarbon layer 484.

Overburden casing 564 may be disposed in overburden 482. Overburdencasing 564 is, in some embodiments, surrounded by materials (forexample, reinforcing material and/or cement) that inhibit heating ofoverburden 482. Low resistance section 554 of conductor 550 may beplaced in overburden casing 564. Low resistance section 554 of conductor550 is made of, for example, carbon steel. Low resistance section 554 ofconductor 550 may be centralized in overburden casing 564 usingcentralizers 558. Centralizers 558 are spaced at intervals ofapproximately 6 m to approximately 12 m or, for example, approximately 9m along low resistance section 554 of conductor 550. In a heaterembodiment, low resistance section 554 of conductor 550 is coupled toconductor 550 by one or more welds. In other heater embodiments, lowresistance sections are threaded, threaded and welded, or otherwisecoupled to the conductor. Low resistance section 554 generates little orno heat in overburden casing 564. Packing 566 may be placed betweenoverburden casing 564 and opening 556. Packing 566 may be used as a capat the junction of overburden 482 and hydrocarbon layer 484 to allowfilling of materials in the annulus between overburden casing 564 andopening 556. In some embodiments, packing 566 inhibits fluid fromflowing from opening 556 to surface 568.

FIG. 56 depicts a cross-sectional representation of an embodiment of aremovable conductor-in-conduit heat source. Conduit 552 may be placed inopening 556 through overburden 482 such that a gap remains between theconduit and overburden casing 564. Fluids may be removed from opening556 through the gap between conduit 552 and overburden casing 564.Fluids may be removed from the gap through conduit 570. Conduit 552 andcomponents of the heat source included in the conduit that are coupledto wellhead 476 may be removed from opening 556 as a single unit. Theheat source may be removed as a single unit to be repaired, replaced,and/or used in another portion of the formation.

For a temperature limited heater in which the ferromagnetic conductorprovides a majority of the resistive heat output below the Curietemperature and/or the phase transformation temperature range, amajority of the current flows through material with highly non-linearfunctions of magnetic field (H) versus magnetic induction (B). Thesenon-linear functions may cause strong inductive effects and distortionthat lead to decreased power factor in the temperature limited heater attemperatures below the Curie temperature and/or the phase transformationtemperature range. These effects may render the electrical power supplyto the temperature limited heater difficult to control and may result inadditional current flow through surface and/or overburden power supplyconductors. Expensive and/or difficult to implement control systems suchas variable capacitors or modulated power supplies may be used tocompensate for these effects and to control temperature limited heaterswhere the majority of the resistive heat output is provided by currentflow through the ferromagnetic material.

In certain temperature limited heater embodiments, the ferromagneticconductor confines a majority of the flow of electrical current to anelectrical conductor coupled to the ferromagnetic conductor when thetemperature limited heater is below or near the Curie temperature and/orthe phase transformation temperature range of the ferromagneticconductor. The electrical conductor may be a sheath, jacket, supportmember, corrosion resistant member, or other electrically resistivemember. In some embodiments, the ferromagnetic conductor confines amajority of the flow of electrical current to the electrical conductorpositioned between an outermost layer and the ferromagnetic conductor.The ferromagnetic conductor is located in the cross section of thetemperature limited heater such that the magnetic properties of theferromagnetic conductor at or below the Curie temperature and/or thephase transformation temperature range of the ferromagnetic conductorconfine the majority of the flow of electrical current to the electricalconductor. The majority of the flow of electrical current is confined tothe electrical conductor due to the skin effect of the ferromagneticconductor. Thus, the majority of the current is flowing through materialwith substantially linear resistive properties throughout most of theoperating range of the heater.

In certain embodiments, the ferromagnetic conductor and the electricalconductor are located in the cross section of the temperature limitedheater so that the skin effect of the ferromagnetic material limits thepenetration depth of electrical current in the electrical conductor andthe ferromagnetic conductor at temperatures below the Curie temperatureand/or the phase transformation temperature range of the ferromagneticconductor. Thus, the electrical conductor provides a majority of theelectrically resistive heat output of the temperature limited heater attemperatures up to a temperature at or near the Curie temperature and/orthe phase transformation temperature range of the ferromagneticconductor. In certain embodiments, the dimensions of the electricalconductor may be chosen to provide desired heat output characteristics.

Because the majority of the current flows through the electricalconductor below the Curie temperature and/or the phase transformationtemperature range, the temperature limited heater has a resistanceversus temperature profile that at least partially reflects theresistance versus temperature profile of the material in the electricalconductor. Thus, the resistance versus temperature profile of thetemperature limited heater is substantially linear below the Curietemperature and/or the phase transformation temperature range of theferromagnetic conductor if the material in the electrical conductor hasa substantially linear resistance versus temperature profile. Forexample, the temperature limited heater in which the majority of thecurrent flows in the electrical conductor below the Curie temperatureand/or the phase transformation temperature range may have a resistanceversus temperature profile similar to the profile shown in FIG. 260. Theresistance of the temperature limited heater has little or no dependenceon the current flowing through the heater until the temperature nearsthe Curie temperature and/or the phase transformation temperature range.The majority of the current flows in the electrical conductor ratherthan the ferromagnetic conductor below the Curie temperature and/or thephase transformation temperature range.

Resistance versus temperature profiles for temperature limited heatersin which the majority of the current flows in the electrical conductoralso tend to exhibit sharper reductions in resistance near or at theCurie temperature and/or the phase transformation temperature range ofthe ferromagnetic conductor. For example, the reduction in resistanceshown in FIG. 260 is sharper than the reduction in resistance shown inFIG. 246. The sharper reductions in resistance near or at the Curietemperature and/or the phase transformation temperature range are easierto control than more gradual resistance reductions near the Curietemperature and/or the phase transformation temperature range becauselittle current is flowing through the ferromagnetic material.

In certain embodiments, the material and/or the dimensions of thematerial in the electrical conductor are selected so that thetemperature limited heater has a desired resistance versus temperatureprofile below the Curie temperature and/or the phase transformationtemperature range of the ferromagnetic conductor.

Temperature limited heaters in which the majority of the current flowsin the electrical conductor rather than the ferromagnetic conductorbelow the Curie temperature and/or the phase transformation temperaturerange are easier to predict and/or control. Behavior of temperaturelimited heaters in which the majority of the current flows in theelectrical conductor rather than the ferromagnetic conductor below theCurie temperature and/or the phase transformation temperature range maybe predicted by, for example, the resistance versus temperature profileand/or the power factor versus temperature profile. Resistance versustemperature profiles and/or power factor versus temperature profiles maybe assessed or predicted by, for example, experimental measurements thatassess the behavior of the temperature limited heater, analyticalequations that assess or predict the behavior of the temperature limitedheater, and/or simulations that assess or predict the behavior of thetemperature limited heater.

In certain embodiments, assessed or predicted behavior of thetemperature limited heater is used to control the temperature limitedheater. The temperature limited heater may be controlled based onmeasurements (assessments) of the resistance and/or the power factorduring operation of the heater. In some embodiments, the power, orcurrent, supplied to the temperature limited heater is controlled basedon assessment of the resistance and/or the power factor of the heaterduring operation of the heater and the comparison of this assessmentversus the predicted behavior of the heater. In certain embodiments, thetemperature limited heater is controlled without measurement of thetemperature of the heater or a temperature near the heater. Controllingthe temperature limited heater without temperature measurementeliminates operating costs associated with downhole temperaturemeasurement. Controlling the temperature limited heater based onassessment of the resistance and/or the power factor of the heater alsoreduces the time for making adjustments in the power or current suppliedto the heater compared to controlling the heater based on measuredtemperature.

As the temperature of the temperature limited heater approaches orexceeds the Curie temperature and/or the phase transformationtemperature range of the ferromagnetic conductor, reduction in theferromagnetic properties of the ferromagnetic conductor allowselectrical current to flow through a greater portion of the electricallyconducting cross section of the temperature limited heater. Thus, theelectrical resistance of the temperature limited heater is reduced andthe temperature limited heater automatically provides reduced heatoutput at or near the Curie temperature and/or the phase transformationtemperature range of the ferromagnetic conductor. In certainembodiments, a highly electrically conductive member is coupled to theferromagnetic conductor and the electrical conductor to reduce theelectrical resistance of the temperature limited heater at or above theCurie temperature and/or the phase transformation temperature range ofthe ferromagnetic conductor. The highly electrically conductive membermay be an inner conductor, a core, or another conductive member ofcopper, aluminum, nickel, or alloys thereof.

The ferromagnetic conductor that confines the majority of the flow ofelectrical current to the electrical conductor at temperatures below theCurie temperature and/or the phase transformation temperature range mayhave a relatively small cross section compared to the ferromagneticconductor in temperature limited heaters that use the ferromagneticconductor to provide the majority of resistive heat output up to or nearthe Curie temperature and/or the phase transformation temperature range.A temperature limited heater that uses the electrical conductor toprovide a majority of the resistive heat output below the Curietemperature and/or the phase transformation temperature range has lowmagnetic inductance at temperatures below the Curie temperature and/orthe phase transformation temperature range because less current isflowing through the ferromagnetic conductor as compared to thetemperature limited heater where the majority of the resistive heatoutput below the Curie temperature and/or the phase transformationtemperature range is provided by the ferromagnetic material. Magneticfield (H) at radius (r) of the ferromagnetic conductor is proportionalto the current (I) flowing through the ferromagnetic conductor and thecore divided by the radius, or:

H∝I/r.  (EQN. 4)

Since only a portion of the current flows through the ferromagneticconductor for a temperature limited heater that uses the outer conductorto provide a majority of the resistive heat output below the Curietemperature and/or the phase transformation temperature range, themagnetic field of the temperature limited heater may be significantlysmaller than the magnetic field of the temperature limited heater wherethe majority of the current flows through the ferromagnetic material.The relative magnetic permeability (μ) may be large for small magneticfields.

The skin depth (δ) of the ferromagnetic conductor is inverselyproportional to the square root of the relative magnetic permeability(μ):

δ∝(1/μ)^(1/2).  (EQN. 5)

Increasing the relative magnetic permeability decreases the skin depthof the ferromagnetic conductor. However, because only a portion of thecurrent flows through the ferromagnetic conductor for temperatures belowthe Curie temperature and/or the phase transformation temperature range,the radius (or thickness) of the ferromagnetic conductor may bedecreased for ferromagnetic materials with large relative magneticpermeabilities to compensate for the decreased skin depth while stillallowing the skin effect to limit the penetration depth of theelectrical current to the electrical conductor at temperatures below theCurie temperature and/or the phase transformation temperature range ofthe ferromagnetic conductor. The radius (thickness) of the ferromagneticconductor may be between 0.3 mm and 8 mm, between 0.3 mm and 2 mm, orbetween 2 mm and 4 mm depending on the relative magnetic permeability ofthe ferromagnetic conductor. Decreasing the thickness of theferromagnetic conductor decreases costs of manufacturing the temperaturelimited heater, as the cost of ferromagnetic material tends to be asignificant portion of the cost of the temperature limited heater.Increasing the relative magnetic permeability of the ferromagneticconductor provides a higher turndown ratio and a sharper decrease inelectrical resistance for the temperature limited heater at or near theCurie temperature and/or the phase transformation temperature range ofthe ferromagnetic conductor.

Ferromagnetic materials (such as purified iron or iron-cobalt alloys)with high relative magnetic permeabilities (for example, at least 200,at least 1000, at least 1×10⁴, or at least 1×10⁵) and/or high Curietemperatures (for example, at least 600° C., at least 700° C., or atleast 800° C.) tend to have less corrosion resistance and/or lessmechanical strength at high temperatures. The electrical conductor mayprovide corrosion resistance and/or high mechanical strength at hightemperatures for the temperature limited heater. Thus, the ferromagneticconductor may be chosen primarily for its ferromagnetic properties.

Confining the majority of the flow of electrical current to theelectrical conductor below the Curie temperature and/or the phasetransformation temperature range of the ferromagnetic conductor reducesvariations in the power factor. Because only a portion of the electricalcurrent flows through the ferromagnetic conductor below the Curietemperature and/or the phase transformation temperature range, thenon-linear ferromagnetic properties of the ferromagnetic conductor havelittle or no effect on the power factor of the temperature limitedheater, except at or near the Curie temperature and/or the phasetransformation temperature range. Even at or near the Curie temperatureand/or the phase transformation temperature range, the effect on thepower factor is reduced compared to temperature limited heaters in whichthe ferromagnetic conductor provides a majority of the resistive heatoutput below the Curie temperature and/or the phase transformationtemperature range. Thus, there is less or no need for externalcompensation (for example, variable capacitors or waveform modification)to adjust for changes in the inductive load of the temperature limitedheater to maintain a relatively high power factor.

In certain embodiments, the temperature limited heater, which confinesthe majority of the flow of electrical current to the electricalconductor below the Curie temperature and/or the phase transformationtemperature range of the ferromagnetic conductor, maintains the powerfactor above 0.85, above 0.9, or above 0.95 during use of the heater.Any reduction in the power factor occurs only in sections of thetemperature limited heater at temperatures near the Curie temperatureand/or the phase transformation temperature range. Most sections of thetemperature limited heater are typically not at or near the Curietemperature and/or the phase transformation temperature range duringuse. These sections have a high power factor that approaches 1.0. Thepower factor for the entire temperature limited heater is maintainedabove 0.85, above 0.9, or above 0.95 during use of the heater even ifsome sections of the heater have power factors below 0.85.

Maintaining high power factors allows for less expensive power suppliesand/or control devices such as solid state power supplies or SCRs(silicon controlled rectifiers). These devices may fail to operateproperly if the power factor varies by too large an amount because ofinductive loads. With the power factors maintained at high values;however, these devices may be used to provide power to the temperaturelimited heater. Solid state power supplies have the advantage ofallowing fine tuning and controlled adjustment of the power supplied tothe temperature limited heater.

In some embodiments, transformers are used to provide power to thetemperature limited heater. Multiple voltage taps may be made into thetransformer to provide power to the temperature limited heater. Multiplevoltage taps allow the current supplied to switch back and forth betweenthe multiple voltages. This maintains the current within a range boundby the multiple voltage taps.

The highly electrically conductive member, or inner conductor, increasesthe turndown ratio of the temperature limited heater. In certainembodiments, thickness of the highly electrically conductive member isincreased to increase the turndown ratio of the temperature limitedheater. In some embodiments, the thickness of the electrical conductoris reduced to increase the turndown ratio of the temperature limitedheater. In certain embodiments, the turndown ratio of the temperaturelimited heater is between 1.1 and 10, between 2 and 8, or between 3 and6 (for example, the turndown ratio is at least 1.1, at least 2, or atleast 3).

FIG. 57 depicts an embodiment of a temperature limited heater in whichthe support member provides a majority of the heat output below theCurie temperature and/or the phase transformation temperature range ofthe ferromagnetic conductor. Core 542 is an inner conductor of thetemperature limited heater. In certain embodiments, core 542 is a highlyelectrically conductive material such as copper or aluminum. In someembodiments, core 542 is a copper alloy that provides mechanicalstrength and good electrically conductivity such as a dispersionstrengthened copper. In one embodiment, core 542 is Glidcop® (SCM MetalProducts, Inc., Research Triangle Park, North Carolina, U.S.A.).Ferromagnetic conductor 546 is a thin layer of ferromagnetic materialbetween electrical conductor 572 and core 542. In certain embodiments,electrical conductor 572 is also support member 548. In certainembodiments, ferromagnetic conductor 546 is iron or an iron alloy. Insome embodiments, ferromagnetic conductor 546 includes ferromagneticmaterial with a high relative magnetic permeability. For example,ferromagnetic conductor 546 may be purified iron such as Armco ingotiron (AK Steel Ltd., United Kingdom). Iron with some impuritiestypically has a relative magnetic permeability on the order of 400.Purifying the iron by annealing the iron in hydrogen gas (H₂) at 1450°C. increases the relative magnetic permeability of the iron. Increasingthe relative magnetic permeability of ferromagnetic conductor 546 allowsthe thickness of the ferromagnetic conductor to be reduced. For example,the thickness of unpurified iron may be approximately 4.5 mm while thethickness of the purified iron is approximately 0.76 mm.

In certain embodiments, electrical conductor 572 provides support forferromagnetic conductor 546 and the temperature limited heater.Electrical conductor 572 may be made of a material that provides goodmechanical strength at temperatures near or above the Curie temperatureand/or the phase transformation temperature range of ferromagneticconductor 546. In certain embodiments, electrical conductor 572 is acorrosion resistant member. Electrical conductor 572 (support member548) may provide support for ferromagnetic conductor 546 and corrosionresistance. Electrical conductor 572 is made from a material thatprovides desired electrically resistive heat output at temperatures upto and/or above the Curie temperature and/or the phase transformationtemperature range of ferromagnetic conductor 546.

In an embodiment, electrical conductor 572 is 347H stainless steel. Insome embodiments, electrical conductor 572 is another electricallyconductive, good mechanical strength, corrosion resistant material. Forexample, electrical conductor 572 may be 304H, 316H, 347HH, NF709,Incoloy® 800H alloy (Inco Alloys International, Huntington, W. Va.,U.S.A.), Haynes® HR120® alloy, or Inconel® 617 alloy.

In some embodiments, electrical conductor 572 (support member 548)includes different alloys in different portions of the temperaturelimited heater. For example, a lower portion of electrical conductor 572(support member 548) is 347H stainless steel and an upper portion of theelectrical conductor (support member) is NF709. In certain embodiments,different alloys are used in different portions of the electricalconductor (support member) to increase the mechanical strength of theelectrical conductor (support member) while maintaining desired heatingproperties for the temperature limited heater.

In some embodiments, ferromagnetic conductor 546 includes differentferromagnetic conductors in different portions of the temperaturelimited heater. Different ferromagnetic conductors may be used indifferent portions of the temperature limited heater to vary the Curietemperature and/or the phase transformation temperature range and, thus,the maximum operating temperature in the different portions. In someembodiments, the Curie temperature and/or the phase transformationtemperature range in an upper portion of the temperature limited heateris lower than the Curie temperature and/or the phase transformationtemperature range in a lower portion of the heater. The lower Curietemperature and/or the phase transformation temperature range in theupper portion increases the creep-rupture strength lifetime in the upperportion of the heater.

In the embodiment depicted in FIG. 57, ferromagnetic conductor 546,electrical conductor 572, and core 542 are dimensioned so that the skindepth of the ferromagnetic conductor limits the penetration depth of themajority of the flow of electrical current to the support member whenthe temperature is below the Curie temperature and/or the phasetransformation temperature range of the ferromagnetic conductor. Thus,electrical conductor 572 provides a majority of the electricallyresistive heat output of the temperature limited heater at temperaturesup to a temperature at or near the Curie temperature and/or the phasetransformation temperature range of ferromagnetic conductor 546. Incertain embodiments, the temperature limited heater depicted in FIG. 57is smaller (for example, an outside diameter of 3 cm, 2.9 cm, 2.5 cm, orless) than other temperature limited heaters that do not use electricalconductor 572 to provide the majority of electrically resistive heatoutput. The temperature limited heater depicted in FIG. 57 may besmaller because ferromagnetic conductor 546 is thin as compared to thesize of the ferromagnetic conductor needed for a temperature limitedheater in which the majority of the resistive heat output is provided bythe ferromagnetic conductor.

In some embodiments, the support member and the corrosion resistantmember are different members in the temperature limited heater. FIGS. 58and 59 depict embodiments of temperature limited heaters in which thejacket provides a majority of the heat output below the Curietemperature and/or the phase transformation temperature range of theferromagnetic conductor. In these embodiments, electrical conductor 572is jacket 540. Electrical conductor 572, ferromagnetic conductor 546,support member 548, and core 542 (in FIG. 58) or inner conductor 532 (inFIG. 59) are dimensioned so that the skin depth of the ferromagneticconductor limits the penetration depth of the majority of the flow ofelectrical current to the thickness of the jacket. In certainembodiments, electrical conductor 572 is a material that is corrosionresistant and provides electrically resistive heat output below theCurie temperature and/or the phase transformation temperature range offerromagnetic conductor 546. For example, electrical conductor 572 is825 stainless steel or 347H stainless steel. In some embodiments,electrical conductor 572 has a small thickness (for example, on theorder of 0.5 mm).

In FIG. 58, core 542 is highly electrically conductive material such ascopper or aluminum. Support member 548 is 347H stainless steel oranother material with good mechanical strength at or near the Curietemperature and/or the phase transformation temperature range offerromagnetic conductor 546.

In FIG. 59, support member 548 is the core of the temperature limitedheater and is 347H stainless steel or another material with goodmechanical strength at or near the Curie temperature and/or the phasetransformation temperature range of ferromagnetic conductor 546. Innerconductor 532 is highly electrically conductive material such as copperor aluminum.

In some embodiments, a relatively thin conductive layer is used toprovide the majority of the electrically resistive heat output of thetemperature limited heater at temperatures up to a temperature at ornear the Curie temperature and/or the phase transformation temperaturerange of the ferromagnetic conductor. Such a temperature limited heatermay be used as the heating member in an insulated conductor heater. Theheating member of the insulated conductor heater may be located inside asheath with an insulation layer between the sheath and the heatingmember.

FIGS. 60A and 60B depict cross-sectional representations of anembodiment of the insulated conductor heater with the temperaturelimited heater as the heating member. Insulated conductor 574 includescore 542, ferromagnetic conductor 546, inner conductor 532, electricalinsulator 534, and jacket 540. Core 542 is a copper core. Ferromagneticconductor 546 is, for example, iron or an iron alloy.

Inner conductor 532 is a relatively thin conductive layer ofnon-ferromagnetic material with a higher electrical conductivity thanferromagnetic conductor 546. In certain embodiments, inner conductor 532is copper. Inner conductor 532 may be a copper alloy. Copper alloystypically have a flatter resistance versus temperature profile than purecopper. A flatter resistance versus temperature profile may provide lessvariation in the heat output as a function of temperature up to theCurie temperature and/or the phase transformation temperature range. Insome embodiments, inner conductor 532 is copper with 6% by weight nickel(for example, CuNi6 or LOHM™). In some embodiments, inner conductor 532is CuNi10Fe1Mn alloy. Below the Curie temperature and/or the phasetransformation temperature range of ferromagnetic conductor 546, themagnetic properties of the ferromagnetic conductor confine the majorityof the flow of electrical current to inner conductor 532. Thus, innerconductor 532 provides the majority of the resistive heat output ofinsulated conductor 574 below the Curie temperature and/or the phasetransformation temperature range.

In certain embodiments, inner conductor 532 is dimensioned, along withcore 542 and ferromagnetic conductor 546, so that the inner conductorprovides a desired amount of heat output and a desired turndown ratio.For example, inner conductor 532 may have a cross-sectional area that isaround 2 or 3 times less than the cross-sectional area of core 542.Typically, inner conductor 532 has to have a relatively smallcross-sectional area to provide a desired heat output if the innerconductor is copper or copper alloy. In an embodiment with copper innerconductor 532, core 542 has a diameter of 0.66 cm, ferromagneticconductor 546 has an outside diameter of 0.91 cm, inner conductor 532has an outside diameter of 1.03 cm, electrical insulator 534 has anoutside diameter of 1.53 cm, and jacket 540 has an outside diameter of1.79 cm. In an embodiment with a CuNi6 inner conductor 532, core 542 hasa diameter of 0.66 cm, ferromagnetic conductor 546 has an outsidediameter of 0.91 cm, inner conductor 532 has an outside diameter of 1.12cm, electrical insulator 534 has an outside diameter of 1.63 cm, andjacket 540 has an outside diameter of 1.88 cm. Such insulated conductorsare typically smaller and cheaper to manufacture than insulatedconductors that do not use the thin inner conductor to provide themajority of heat output below the Curie temperature and/or the phasetransformation temperature range.

Electrical insulator 534 may be magnesium oxide, aluminum oxide, silicondioxide, beryllium oxide, boron nitride, silicon nitride, orcombinations thereof. In certain embodiments, electrical insulator 534is a compacted powder of magnesium oxide. In some embodiments,electrical insulator 534 includes beads of silicon nitride.

In certain embodiments, a small layer of material is placed betweenelectrical insulator 534 and inner conductor 532 to inhibit copper frommigrating into the electrical insulator at higher temperatures. Forexample, a small layer of nickel (for example, about 0.5 mm of nickel)may be placed between electrical insulator 534 and inner conductor 532.

Jacket 540 is made of a corrosion resistant material such as, but notlimited to, 347 stainless steel, 347H stainless steel, 446 stainlesssteel, or 825 stainless steel. In some embodiments, jacket 540 providessome mechanical strength for insulated conductor 574 at or above theCurie temperature and/or the phase transformation temperature range offerromagnetic conductor 546. In certain embodiments, jacket 540 is notused to conduct electrical current.

For long vertical temperature limited heaters (for example, heaters atleast 300 m, at least 500 m, or at least 1 km in length), the hangingstress becomes important in the selection of materials for thetemperature limited heater. Without the proper selection of material,the support member may not have sufficient mechanical strength (forexample, creep-rupture strength) to support the weight of thetemperature limited heater at the operating temperatures of the heater.

In certain embodiments, materials for the support member are varied toincrease the maximum allowable hanging stress at operating temperaturesof the temperature limited heater and, thus, increase the maximumoperating temperature of the temperature limited heater. Altering thematerials of the support member affects the heat output of thetemperature limited heater below the Curie temperature and/or the phasetransformation temperature range because changing the materials changesthe resistance versus temperature profile of the support member. Incertain embodiments, the support member is made of more than onematerial along the length of the heater so that the temperature limitedheater maintains desired operating properties (for example, resistanceversus temperature profile below the Curie temperature and/or the phasetransformation temperature range) as much as possible while providingsufficient mechanical properties to support the heater. In someembodiments, transition sections are used between sections of the heaterto provide strength that compensates for the difference in temperaturebetween sections of the heater. In certain embodiments, one or moreportions of the temperature limited heater have varying outsidediameters and/or materials to provide desired properties for the heater.

In certain embodiments of temperature limited heaters, three temperaturelimited heaters are coupled together in a three-phase wye configuration.Coupling three temperature limited heaters together in the three-phasewye configuration lowers the current in each of the individualtemperature limited heaters because the current is split between thethree individual heaters. Lowering the current in each individualtemperature limited heater allows each heater to have a small diameter.The lower currents allow for higher relative magnetic permeabilities ineach of the individual temperature limited heaters and, thus, higherturndown ratios. In addition, there may be no return current needed foreach of the individual temperature limited heaters. Thus, the turndownratio remains higher for each of the individual temperature limitedheaters than if each temperature limited heater had its own returncurrent path.

In the three-phase wye configuration, individual temperature limitedheaters may be coupled together by shorting the sheaths, jackets, orcanisters of each of the individual temperature limited heaters to theelectrically conductive sections (the conductors providing heat) attheir terminating ends (for example, the ends of the heaters at thebottom of a heater wellbore). In some embodiments, the sheaths, jackets,canisters, and/or electrically conductive sections are coupled to asupport member that supports the temperature limited heaters in thewellbore.

In certain embodiments, coupling multiple heaters (for example,insulated conductor, or mineral insulated conductor, heaters) to asingle power source, such as a transformer, is advantageous. Couplingmultiple heaters to a single transformer may result in using fewertransformers to power heaters used for a treatment area as compared tousing individual transformers for each heater. Using fewer transformersreduces surface congestion and allows easier access to the heaters andsurface components. Using fewer transformers reduces capital costsassociated with providing power to the treatment area. In someembodiments, at least 4, at least 5, at least 10, at least 25 heaters,at least 35 heaters, or at least 45 heaters are powered by a singletransformer. Additionally, powering multiple heaters (in differentheater wells) from the single transformer may reduce overburden lossesbecause of reduced voltage and/or phase differences between each of theheater wells powered by the single transformer. Powering multipleheaters from the single transformer may inhibit current imbalancesbetween the heaters because the heaters are coupled to the singletransformer.

To provide power to multiple heaters using the single transformer, thetransformer may have to provide power at higher voltages to carry thecurrent to each of the heaters effectively. In certain embodiments, theheaters are floating (ungrounded) heaters in the formation. Floating theheaters allows the heaters to operate at higher voltages. In someembodiments, the transformer provides power output of at least about 3kV, at least about 4 kV, at least about 5 kV, or at least about 6 kV.

FIG. 61 depicts a top view representation of heater 438 with threeinsulated conductors 574 in conduit 570. Heater 438 includes threeinsulated conductors 574 in conduit 570. Heater 438 may be located in aheater well in the subsurface formation. Conduit 570 may be a sheath,jacket, or other enclosure around insulated conductors 574. Eachinsulated conductor 574 includes core 542, electrical insulator 534, andjacket 540. Insulated conductors 574 may be mineral insulated conductorswith core 542 being a copper alloy (for example, a copper-nickel alloysuch as Alloy 180), electrical insulator 534 being magnesium oxide, andjacket 540 being Incoloy® 825, copper, or stainless steel (for example347H stainless steel). In some embodiments, jacket 540 includes non-workhardenable metals so that the jacket is annealable.

In some embodiments, core 542 and/or jacket 540 include ferromagneticmaterials. In some embodiments, one or more insulated conductors 574 aretemperature limited heaters. In certain embodiments, the overburdenportion of insulated conductors 574 include high electrical conductivitymaterials in core 542 (for example, pure copper or copper alloys such ascopper with 3% silicon at a weldjoint) so that the overburden portionsof the insulated conductors provide little or no heat output. In certainembodiments, conduit 570 includes non-corrosive materials and/or highstrength materials such as stainless steel. In one embodiment, conduit570 is 347H stainless steel.

Insulated conductors 574 may be coupled to the single transformer in athree-phase configuration (for example, a three-phase wyeconfiguration). Each insulated conductor 574 may be coupled to one phaseof the single transformer. In certain embodiments, the singletransformer is also coupled to a plurality of identical heaters 438 inother heater wells in the formation (for example, the single transformermay couple to 40 or more heaters in the formation). In some embodiments,the single transformer couples to at least 4, at least 5, at least 10,at least 15, or at least 25 additional heaters in the formation.

Electrical insulator 534′ may be located inside conduit 570 toelectrically insulate insulated conductors 574 from the conduit. Incertain embodiments, electrical insulator 534′ is magnesium oxide (forexample, compacted magnesium oxide). In some embodiments, electricalinsulator 534′ is silicon nitride (for example, silicon nitride blocks).Electrical insulator 534′ electrically insulates insulated conductors574 from conduit 570 so that at high operating voltages (for example, 3kV or higher), there is no arcing between the conductors and theconduit. In some embodiments, electrical insulator 534′ inside conduit570 has at least the thickness of electrical insulators 534 in insulatedconductors 574. The increased thickness of insulation in heater 438(from electrical insulators 534 and/or electrical insulator 534′)inhibits and may prevent current leakage into the formation from theheater. In some embodiments, electrical insulator 534′ spatially locatesinsulated conductors 574 inside conduit 570.

FIG. 62 depicts an embodiment of three-phase wye transformer 580 coupledto a plurality of heaters 438. For simplicity in the drawing, only fourheaters 438 are shown in FIG. 62. It is to be understood that severalmore heaters may be coupled to the transformer 580. As shown in FIG. 62,each leg (each insulated conductor) of each heater is coupled to onephase of transformer 580 and current is returned to the neutral orground of the transformer (for example, returned through conductor 582depicted in FIGS. 61 and 63).

Return conductor 582 may be electrically coupled to the ends ofinsulated conductors 574 (as shown in FIG. 63) current returns from theends of the insulated conductors to the transformer on the surface ofthe formation. Return conductor 582 may include high electricalconductivity materials such as pure copper, nickel, copper alloys, orcombinations thereof so that the return conductor provides little or noheat output. In some embodiments, return conductor 582 is a tubular (forexample, a stainless steel tubular) that allows an optical fiber to beplaced inside the tubular to be used for temperature and/or othermeasurement. In some embodiments, return conductor 582 is a smallinsulated conductor (for example, small mineral insulated conductor).Return conductor 582 may be coupled to the neutral or ground leg of thetransformer in a three-phase wye configuration. Thus, insulatedconductors 574 are electrically isolated from conduit 570 and theformation. Using return conductor 582 to return current to the surfacemay make coupling the heater to a wellhead easier. In some embodiments,current is returned using one or more of jackets 540, depicted in FIG.61. One or more jackets 540 may be coupled to cores 542 at the end ofthe heaters and return current to the neutral of the three-phase wyetransformer.

FIG. 63 depicts a side view representation of the end section of threeinsulated conductors 574 in conduit 570. The end section is the sectionof the heaters the furthest away from (distal from) the surface of theformation. The end section includes contactor section 576 coupled toconduit 570. In some embodiments, contactor section 576 is welded orbrazed to conduit 570. Termination 578 is located in contactor section576. Termination 578 is electrically coupled to insulated conductors 574and return conductor 582. Termination 578 electrically couples the coresof insulated conductors 574 to the return conductor 582 at the ends ofthe heaters.

In certain embodiments, heater 438, depicted in FIGS. 61 and 63,includes an overburden section using copper as the core of the insulatedconductors. The copper in the overburden section may be the samediameter as the cores used in the heating section of the heater. Thecopper in the overburden section may have a larger diameter than thecores in the heating section of the heater. Increasing the size of thecopper in the overburden section may decrease losses in the overburdensection of the heater.

Heaters that include three insulated conductors 574 in conduit 570, asdepicted in FIGS. 61 and 63, may be made in a multiple step process. Insome embodiments, the multiple step process is performed at the site ofthe formation or treatment area. In some embodiments, the multiple stepprocess is performed at a remote manufacturing site away from theformation. The finished heater is then transported to the treatmentarea.

Insulated conductors 574 may be pre-assembled prior to the bundlingeither on site or at a remote location. Insulated conductors 574 andreturn conductor 582 may be positioned on spools. A machine may drawinsulated conductors 574 and return conductor 582 from the spools at aselected rate. Preformed blocks of insulation material may be positionedaround return conductor 582 and insulated conductors 574. In anembodiment, two blocks are positioned around return conductor 582 andthree blocks are positioned around insulated conductors 574 to formelectrical insulator 534′. The insulated conductors and return conductormay be drawn or pushed into a plate of conduit material that has beenrolled into a tubular shape. The edges of the plate may be pressedtogether and welded (for example, by laser welding). After formingconduit 570 around electrical insulator 534′, the bundle of insulatedconductors 574, and return conductor 582, the conduit may be compactedagainst the electrical insulator 582 so that all of the components ofthe heater are pressed together into a compact and tightly fitting form.During the compaction, the electrical insulator may flow and fill anygaps inside the heater.

In some embodiments, heater 438 (which includes conduit 570 aroundelectrical insulator 534′ and the bundle of insulated conductors 574 andreturn conductor 582) is inserted into a coiled tubing tubular that isplaced in a wellbore in the formation. The coiled tubing tubular may beleft in place in the formation (left in during heating of the formation)or removed from the formation after installation of the heater. Thecoiled tubing tubular may allow for easier installation of heater 438into the wellbore.

In some embodiments, one or more components of heater 438 are varied(for example, removed, moved, or replaced) while the operation of theheater remains substantially identical. FIG. 64 depicts an embodiment ofheater 438 with three insulated cores 542 in conduit 570. In thisembodiment, electrical insulator 534′ surrounds cores 542 and returnconductor 582 in conduit 570. Cores 542 are located in conduit 570without an electrical insulator and jacket surrounding the cores. Cores542 are coupled to the single transformer in a three-phase wyeconfiguration with each core 542 coupled to one phase of thetransformer. Return conductor 582 is electrically coupled to the ends ofcores 542 and returns current from the ends of the cores to thetransformer on the surface of the formation.

FIG. 65 depicts an embodiment of heater 438 with three insulatedconductors 574 and insulated return conductor in conduit 570. In thisembodiment, return conductor 582 is an insulated conductor with core542, electrical insulator 534, and jacket 540. Return conductor 582 andinsulated conductors 574 are located in conduit 570 surrounded byelectrical insulator 534. Return conductor 582 and insulated conductors574 may be the same size or different sizes. Return conductor 582 andinsulated conductors 574 operate substantially the same as in theembodiment depicted in FIGS. 61 and 63.

FIGS. 66 and 67 depict embodiments of three insulated conductors 574banded together. Heater 438 includes three, or other multiples,insulated conductors 574 coupled together in a spiral configuration. Incertain embodiments, insulated conductors 574 are held together in thespiral configuration with band 584. In some embodiments, band 584includes a plurality of bands that hold together insulated conductors574. The bands may be periodically placed around insulated conductors574 to hold the conductors together.

Banding insulated conductors 574 together instead of placing theconductors in a casing allows open spaces between the conductors toradiate heat to the formation, thus, increasing the radiating surfacearea of heater 438. Banding insulated conductors 574 together mayimprove the insertion strength of heater 438.

In some embodiments, insulated conductors 574 are banded onto and aroundsupport member 586, as shown in FIG. 67. Support member 586 may providestructural support and/or increase the insertion strength of heater 438.In some embodiments, support member 586 includes a conduit used toprovide fluids and/or to remove fluids from heater 438. For example,oxidization inhibiting fluids may be provided to heater 438 throughsupport member 586. In some embodiments, other structures are used toprovide fluids and/or to remove fluids from heater 438.

Heater 438 may be provided power from single phase power sources, asdepicted in FIG. 66, or three-phase power sources, as depicted in FIG.67, depending on desired operation of the heater. Support member 586 mayprovide electrical isolation for insulated conductors 438 coupled to thethree-phase power source. The voltage differentials on the surfaces(jackets) of insulated conductors 574 in the three-phase embodiment maybe reduced because of the proximity effect.

In some embodiments, optical sensor 588 is located at or near a centerof insulated conductors 574. Optical sensor 588 may be used to assessproperties of heater 438 such as, but not limited to, stress,temperature, and/or pressure. In some embodiments, support member 586includes a notch, as shown in FIG. 67, for insertion of optical sensor588. The notch may allow continuous insertion of optical sensor opticalsensor 588 during installation of heater 438.

FIG. 68 depicts an embodiment of a heater in wellbore 742 in formation524. The heater includes insulated conductor 574 in conduit 552 withmaterial 590 between the insulated conductor and the conduit. In someembodiments, insulated conductor 574 is a mineral insulated conductor.Electricity supplied to insulated conductor 574 resistively heats theinsulated conductor. Insulated conductor conductively transfers heat tomaterial 590. Heat may transfer within material 590 by heat conductionand/or by heat convection. Radiant heat from insulated conductor 574and/or heat from material 590 transfers to conduit 552. Heat maytransfer to the formation from the heater by conductive or radiativeheat transfer from conduit 552. Material 590 may be molten metal, moltensalt, or other liquid. In some embodiments, a gas (for example,nitrogen, carbon dioxide, and/or helium) is in conduit 552 abovematerial 590. The gas may inhibit oxidation or other chemical changes ofmaterial 590. The gas may inhibit vaporization of material 590. U.S.Published Patent Application 2008-0078551 to DeVault et al., which isincorporated by reference as if fully set forth herein, describes asystem for placement in a wellbore, the system including a heater in aconduit with a liquid metal between the heater and the conduit forheating subterranean earth.

Insulated conductor 574 and conduit 552 may be placed in an opening in asubsurface formation. Insulated conductor 574 and conduit 552 may haveany orientation in a subsurface formation (for example, the insulatedconductor and conduit may be substantially vertical or substantiallyhorizontally oriented in the formation). Insulated conductor 574includes core 542, electrical insulator 534, and jacket 540. In someembodiments, core 542 is a copper core. In some embodiments, core 542includes other electrical conductors or alloys (for example, copperalloys). In some embodiments, core 542 includes a ferromagneticconductor so that insulated conductor 574 operates as a temperaturelimited heater. In some embodiments, core 542 does not include aferromagnetic conductor.

In some embodiments, core 542 of insulated conductor 574 is made of twoor more portions. The first portion may be placed adjacent to theoverburden. The first portion may be sized and/or made of a highlyconductive material so that the first portion does not resistively heatto a high temperature. One or more other portions of core 574 may besized and/or made of material that resistively heats to a hightemperature. These portions of core 574 may be positioned adjacent tosections of the formation that are to be heated by the heater. In someembodiments, the insulated conductor does not include a highlyconductive first portion. A lead in cable may be coupled to theinsulated conductor to supply electricity to the insulated conductor.

In some embodiments, core 542 of insulated conductor 574 is a highlyconductive material such as copper. Core 542 may be electrically coupledto jacket 540 at or near the end of the insulated conductor. In someembodiments, insulated conductor 574 is electrically coupled to conduit552. Electrical current supplied to insulated conductor 574 mayresistively heat core 542, jacket 540, material 590, and/or conduit 552.Resistive heating of core 542, jacket 540, material 590, and/or conduit552 generates heat that may transfer to the formation.

Electrical insulator 534 may be magnesium oxide, aluminum oxide, silicondioxide, beryllium oxide, boron nitride, silicon nitride, orcombinations thereof. In certain embodiments, electrical insulator 534is a compacted powder of magnesium oxide. In some embodiments,electrical insulator 534 includes beads of silicon nitride. In certainembodiments, a thin layer of material clad over core 542 to inhibit thecore from migrating into the electrical insulator at higher temperatures(i.e., to inhibit copper of the core from migrating into magnesium oxideof the insulation). For example, a small layer of nickel (for example,about 0.5 mm of nickel) may be clad on core 542.

In some embodiments, material 590 may be relatively corrosive. Jacket540 and/or at least the inside surface of conduit 552 may be made of acorrosion resistant material such as, but not limited to, nickel, AlloyN (Carpenter Metals), 347 stainless steel, 347H stainless steel, 446stainless steel, or 825 stainless steel. For example, conduit 552 may beplated or lined with nickel. In some embodiments, material 590 may berelatively non-corrosive. Jacket 540 and/or at least the inside surfaceof conduit 552 may be made of a material such as carbon steel.

In some embodiments, jacket 540 of insulated conductor 574 is not usedas the main return of electrical current for the insulated conductor. Inembodiments where material 590 is a good electrical conductor such as amolten metal, current returns through the molten metal in the conduitand/or through the conduit 552. In some embodiments, conduit 552 is madeof a ferromagnetic material, (for example 410 stainless steel). Conduit552 may function as a temperature limited heater until the temperatureof the conduit approaches, reaches or exceeds the Curie temperature orphase transition temperature of the conduit material.

In some embodiments, material 590 returns electrical current to thesurface from insulated conductor 574 (i.e., the material acts as thereturn or ground conductor for the insulated conductor). Material 590may provide a current path with low resistance so that a long insulatedconductor 574 is useable in conduit 552. The long heater may operate atlow voltages for the length of the heater due to the presence ofmaterial 590 that is conductive.

FIG. 69 depicts an embodiment of a portion of insulated conductor 574 inconduit 552 wherein material 590 is a good conductor (for example, aliquid metal) and current flow is indicated by the arrows. Current flowsdown core 542 and returns through jacket 540, material 590, and conduit552. Jacket 540 and conduit 552 may be at approximately constantpotential. Current flows radially from jacket 540 to conduit 552 throughmaterial 590. Material 590 may resistively heat. Heat from material 590may transfer through conduit 552 into the formation.

In embodiments where material 590 is partially electrically conductive(for example, the material is a molten salt), current returns mainlythrough jacket 540. All or a portion of the current that passes throughpartially conductive material 590 may pass to ground through conduit552.

In the embodiment depicted in FIG. 68, core 542 of insulated conductor574 has a diameter of about 1 cm, electrical insulator 534 has anoutside diameter of about 1.6 cm, and jacket 540 has an outside diameterof about 1.8 cm. In other embodiments, the insulated conductor issmaller. For example, core 542 has a diameter of about 0.5 cm,electrical insulator 534 has an outside diameter of about 0.8 cm, andjacket 540 has an outside diameter of about 0.9 cm. Other insulatedconductor geometries may be used. For the same size conduit 552, thesmaller geometry of insulated conductor 574 may result in a higheroperating temperature of the insulated conductor to achieve the sametemperature at the conduit. The smaller geometry insulated conductorsmay be significantly more economically favorable due to manufacturingcost, weight, and other factors.

Material 590 may be placed between the outside surface of insulatedconductor 574 and the inside surface of conduit 552. In certainembodiments, material 590 is placed in the conduit in a solid form asballs or pellets. Material 590 may melt below the operating temperaturesof insulated conductor 574. Material may melt above ambient subsurfaceformation temperatures. Material 590 may be placed in conduit 552 afterinsulated conductor 574 is placed in the conduit. In certainembodiments, material 590 is placed in conduit 574 as a liquid. Theliquid may be placed in conduit 552 before or after insulated conductor574 is placed in the conduit (for example, the molten liquid may bepoured into the conduit before or after the insulated conductor isplaced in the conduit). Additionally, material 590 may be placed inconduit 552 before or after insulated conductor 574 is energized (i.e.,supplied with electricity). Material 590 may be added to conduit 552 orremoved from the conduit after operation of the heater is initialized.Material 590 may be added to or removed from conduit 552 to maintain adesired head of fluid in the conduit. In some embodiments, the amount ofmaterial 590 in conduit 552 may be adjusted (i.e., added to or depleted)to adjust or balance the stresses on the conduit. Material 590 mayinhibit deformation of conduit 552. The head of material 590 in conduit552 may inhibit the formation from crushing or otherwise deforming theconduit should the formation expand against the conduit. The head offluid in conduit 552 allows the wall of the conduit to be relativelythin. Having thin conduits 552 may increase the economic viability ofusing multiple heaters of this type to heat portions of the formation.

Material 590 may support insulated conductor 574 in conduit 552. Thesupport provided by material 590 of insulated conductor 574 may allowfor the deployment of long insulated conductors as compared to insulatedconductors positioned only in a gas in a conduit without the use ofspecial metallurgy to accommodate the weight of the insulated conductor.In certain embodiments, insulated conductor 574 is buoyant in material590 in conduit 552. For example, insulated conductor may be buoyant inmolten metal. The buoyancy of insulated conductor 574 reduces creepassociated problems in long, substantially vertical heaters. A bottomweight or tie down may be coupled to the bottom of insulated conductor574 to inhibit the insulated conductor from floating in material 590.

Material 590 may remain a liquid at operating temperatures of insulatedconductor 574. In some embodiments, material 590 melts at temperaturesabove about 100° C., above about 200° C., or above about 300° C. Theinsulated conductor may operate at temperatures greater than 200° C.,greater than 400° C., greater than 600° C., or greater than 800° C. Incertain embodiments, material 590 provides enhanced heat transfer frominsulated conductor 574 to conduit 552 at or near the operatingtemperatures of the insulated conductor.

Material 590 may include metals such as tin, zinc, an alloy such as a60% by weight tin, 40% by weight zinc alloy; bismuth; indium; cadmium,aluminum; lead; and/or combinations thereof (for example, eutecticalloys of these metals such as binary or ternary alloys). In oneembodiment, material 590 is tin. Some liquid metals may be corrosive.The jacket of the insulated conductor and/or at least the inside surfaceof the canister may need to be made of a material that is resistant tothe corrosion of the liquid metal. The jacket of the insulated conductorand/or at least the inside surface of the conduit may be made ofmaterials that inhibit the molten metal from leaching materials from theinsulating conductor and/or the conduit to form eutectic compositions ormetal alloys. Molten metals may be highly thermal conductive, but mayblock radiant heat transfer from the insulated conductor and/or haverelatively small heat transfer by natural convection.

Material 590 may be or include molten salts such as solar salt, saltspresented in Table 1, or other salts. The molten salts may be infraredtransparent to aid in heat transfer from the insulated conductor to thecanister. In some embodiments, solar salt includes sodium nitrate andpotassium nitrate (for example, about 60% by weight sodium nitrate andabout 40% by weight potassium nitrate). Solar salt melts at about 220°C. and is chemically stable up to temperatures of about 593° C. Othersalts that may be used include, but are not limited to LiNO₃ (melttemperature (T_(m)) of 264° C. and a decomposition temperature of about600° C.) and eutectic mixtures such as 53% by weight KNO₃, 40% by weightNaNO₃ and 7% by weight NaNO₂ (T_(m) of about 142° C. and an upperworking temperature of over 500° C.); 45.5% by weight KNO₃ and 54.5% byweight NaNO₂ (T_(m) of about 142-145° C. and an upper workingtemperature of over 500° C.); or 50% by weight NaCl and 50% by weightSrCl₂ (T_(m) of about 19° C. and an upper working temperature of over1200° C.).

TABLE 1 Material T_(m) (° C.) T_(b) (° C.) Zn 420 907 CdBr₂ 568 863 CdI₂388 744 CuBr₂ 498 900 PbBr₂ 371 892 TlBr 460 819 TlF 326 826 ThI₄ 566837 SnF₂ 215 850 SnI₂ 320 714 ZnCl₂ 290 732

Some molten salts, such as solar salt, may be relatively non-corrosiveso that the conduit and/or the jacket may be made of relativelyinexpensive material (for example, carbon steel). Some molten salts mayhave good thermal conductivity, may have high heat density, and mayresult in large heat transfer by natural convection.

In fluid mechanics, the Rayleigh number is a dimensionless numberassociated with heat transfer in a fluid. When the Rayleigh number isbelow the critical value for the fluid, heat transfer is primarily inthe form of conduction; and when the Rayleigh number is above thecritical value, heat transfer is primarily in the form of convection.The Rayleigh number is the product of the Grashof number (whichdescribes the relationship between buoyancy and viscosity in a fluid)and the Prandtl number (which describes the relationship betweenmomentum diffusivity and thermal diffusivity). For the same sizeinsulated conductors in conduits, and where the temperature of theconduit is 500° C., the Rayleigh number for solar salt in the conduit isabout 10 times the Rayleigh number for tin in the conduit. The higherRayleigh number implies that the strength of natural convection in themolten solar salt is much stronger than the strength of the naturalconvection in molten tin. The stronger natural convection of molten saltmay distribute heat and inhibit the formation of hot spots at locationsalong the length of the conduit. Hot spots may be caused by coke buildup at isolated locations adjacent to or on the conduit, contact of theconduit by the formation at isolated locations, and/or other highthermal load situations.

Conduit 552 may be a carbon steel or stainless steel canister. In someembodiments, conduit 552 may include cladding on the outer surface toinhibit corrosion of the conduit by formation fluid. Conduit 552 mayinclude cladding on an inner surface of the conduit that is corrosionresistant to material 590 in the conduit. Cladding applied to conduit552 may be a coating and/or a liner. If the conduit contains a metalsalt, the inner surface of the conduit may include coating of nickel, orthe conduit may be or include a liner of a corrosion resistant metalsuch as Alloy N. If the conduit contains a molten metal, the conduit mayinclude a corrosion resistant metal liner or coating, and/or a ceramiccoating (for example, a porcelain coating or fired enamel coating). Inan embodiment, conduit 552 is a canister of 410 stainless steel with anoutside diameter of about 6 cm. Conduit 552 may not need a thick wallbecause material 590 may provide internal pressure that inhibitsdeformation or crushing of the conduit due to external stresses.

FIG. 70 depicts an embodiment of the heater positioned in wellbore 742of formation 524 with a portion of insulated conductor 574 and conduit552 oriented substantially horizontally in the formation. Material 590may provide a head in conduit 552 due to the pressure of the material.The pressure head may keep material 590 in conduit 552. The pressurehead may also provide internal pressure that inhibits deformation orcollapse of conduit 552 due to external stresses.

In some embodiments, two or more insulated conductors are placed in theconduit. In some embodiments, only one of the insulated conductors isenergized. Should the energized conductor fail, one of the otherconductors may be energized to maintain the material in a molten phase.The failed insulated conductor may be removed and/or replaced.

The conduit of the heater may be a ribbed conduit. The ribbed conduitmay improve the heat transfer characteristics of the conduit as comparedto a cylindrical conduit. FIG. 71 depicts a cross-sectionalrepresentation of ribbed conduit 592. FIG. 72 depicts a perspective viewof a portion of ribbed conduit 592. Ribbed conduit 592 may include rings594 and ribs 596. Rings 594 and ribs 596 may improve the heat transfercharacteristics of ribbed conduit 592. In an embodiment, the cylinder ofconduit has an inner diameter of about 5.1 cm and a wall thickness ofabout 0.57 cm. Rings 594 may be spaced about every 3.8 cm. Rings 594 mayhave a height of about 1.9 cm and a thickness of about 0.5 cm. Six ribs596 may be spaced evenly about conduit 552. Ribs 596 may have athickness of about 0.5 cm and a height of about 1.6 cm. Other dimensionsfor the cylinder, rings and ribs may be used. Ribbed conduit 592 may beformed from two or more rolled pieces that are welded together to formthe ribbed conduit. Other types of conduit with extra surface area toenhance heat transfer from the conduit to the formation may be used.

In some embodiments, the ribbed conduit may be used as the conduit of aconductor-in-conduit heater. For example, the conductor may be a 3.05 cm410 stainless steel rod and the conduit has dimensions as describedabove. In other embodiments, the conductor is an insulated conductor anda fluid is positioned between the conductor and the ribbed conduit. Thefluid may be a gas or liquid at operating temperatures of the insulatedconductor.

In some embodiments, the heat source for the heater is not an insulatedconductor. For example, the heat source may be hot fluid circulatedthrough an inner conduit positioned in an outer conduit. The materialmay be positioned between the inner conduit and the outer conduit.Convection currents in the material may help to more evenly distributeheat to the formation and may inhibit or limit formation of a hot spotwhere insulation that limits heat transfer to the overburden ends. Insome embodiments, the heat sources are downhole oxidizers. The materialis placed between an outer conduit and an oxidizer conduit. The oxidizerconduit may be an exhaust conduit for the oxidizers or the oxidantconduit if the oxidizers are positioned in a u-shaped wellbore withexhaust gases exiting the formation through one of the legs of theu-shaped conduit. The material may help inhibit the formation of hotspots adjacent to the oxidizers of the oxidizer assembly.

The material to be heated by the insulated conductor may be placed in anopen wellbore. FIG. 73 depicts material 590 in open wellbore 742 information 524 with insulated conductor 574 in the wellbore. In someembodiments, a gas (for example, nitrogen, carbon dioxide, and/orhelium) is placed in wellbore 742 above material 590. The gas mayinhibit oxidation or other chemical changes of material 590. The gas mayinhibit vaporization of material 590.

Material 590 may have a melting point that is above the pyrolysistemperature of hydrocarbons in the formation. The melting point ofmaterial 590 may be above 375° C., above 400° C., or above 425° C. Theinsulated conductor may be energized to heat the formation. Heat fromthe insulated conductor may pyrolyze hydrocarbons in the formation.Adjacent the wellbore, the heat from insulated conductor 574 may resultin coking that reduces the permeability and plugs the formation nearwellbore 742. The plugged formation inhibits material 590 from leakingfrom wellbore 742 into formation 524 when the material is a liquid. Insome embodiments, material 590 is a salt.

Return electrical current for insulated conductor 574 may return throughjacket 540 of the insulated conductor. Any current that passes throughmaterial 590 may pass to ground. Above the level of material 590, anyremaining return electrical current may be confined to jacket 540 ofinsulated conductor 574.

In some embodiments, other types of heat sources besides for insulatedconductors are used to heat the material placed in the open wellbore.The other types of heat sources may include gas burners, pipes throughwhich hot heat transfer fluid flows, or other types of heaters.

In some embodiments, heat pipes are placed in the formation. The heatpipes may reduce the number of active heat sources needed to heat atreatment area of a given size. The heat pipes may reduce the timeneeded to heat the treatment area of a given size to a desired averagetemperature. A heat pipe is a closed system that utilizes phase changeof fluid in the heat pipe to transport heat applied to a first region toa second region remote from the first region. The phase change of thefluid allows for large heat transfer rates. Heat may be applied to thefirst region of the heat pipes from any type of heat source, includingbut not limited to, electric heaters, oxidizers, heat provided fromgeothermal sources, and/or heat provided from nuclear reactors.

Heat pipes are passive heat transport systems that include no movingparts. Heat pipes may be positioned in near horizontal to verticalconfigurations. The fluid used in heat pipes for heating the formationmay have a low cost, a low melting temperature, a boiling temperaturethat is not too high (e.g., generally below about 900° C.), a lowviscosity at temperatures below above about 540° C., a high heat ofvaporization, and a low corrosion rate for the heat pipe material. Insome embodiments, the heat pipe includes a liner of material that isresistant to corrosion by the fluid. TABLE 1 shows melting and boilingtemperatures for several materials that may be used as the fluid in heatpipes. Other salts that may be used include, but are not limited toLiNO₃, and eutectic mixtures such as 53% by weight KNO₃; 40% by weightNaNO₃ and 7% by weight NaNO₂; 45.5% by weight KNO₃ and 54.5% by weightNaNO₂; or 50% by weight NaCl and 50% by weight SrCl₂.

FIG. 74 depicts schematic cross-sectional representation of a portion ofthe formation with heat pipes 598 positioned adjacent to a substantiallyhorizontal portion of heat source 202. Heat source 202 is placed in awellbore in the formation. Heat source 202 may be a gas burner assembly,an electrical heater, a leg of a circulation system that circulates hotfluid through the formation, or other type of heat source. Heat pipes598 may be placed in the formation so that distal ends of the heat pipesare near or contact heat source 202. In some embodiments, heat pipes 598mechanically attach to heat source 202. Heat pipes 598 may be spaced adesired distance apart. In an embodiment, heat pipes 598 are spacedapart by about 40 feet. In other embodiments, large or smaller spacingsare used. Heat pipes 598 may be placed in a regular pattern with eachheat pipe spaced a given distance from the next heat pipe. In someembodiments, heat pipes 598 are placed in an irregular pattern. Anirregular pattern may be used to provide a greater amount of heat to aselected portion or portions of the formation. Heat pipes 598 may bevertically positioned in the formation. In some embodiments, heat pipes598 are placed at an angle in the formation.

Heat pipes 598 may include sealed conduit 600, seal 602, liquid heattransfer fluid 604 and vaporized heat transfer fluid 606. In someembodiments, heat pipes 598 include metal mesh or wicking material thatincreases the surface area for condensation and/or promotes flow of theheat transfer fluid in the heat pipe. Conduit 600 may have first portion608 and second portion 610. Liquid heat transfer fluid 604 may be infirst portion 608. Heat source 202 external to heat pipe 598 suppliesheat that vaporizes liquid heat transfer fluid 604. Vaporized heattransfer fluid 606 diffuses into second portion 610. Vaporized heattransfer fluid 606 condenses in second portion and transfers heat toconduit 600, which in turn transfers heat to the formation. Thecondensed liquid heat transfer fluid 604 flows by gravity to firstportion 608.

Position of seal 602 is a factor in determining the effective length ofheat pipe 598. The effective length of heat pipe 598 may also depend onthe physical properties of the heat transfer fluid and thecross-sectional area of conduit 600. Enough heat transfer fluid may beplaced in conduit 600 so that some liquid heat transfer fluid 604 ispresent in first portion 608 at all times.

Seal 602 may provide a top seal for conduit 600. In some embodiments,conduit 600 is purged with nitrogen, helium or other fluid prior tobeing loaded with heat transfer fluid and sealed. In some embodiments, avacuum may be drawn on conduit 600 to evacuate the conduit before theconduit is sealed. Drawing a vacuum on conduit 600 before sealing theconduit may enhance vapor diffusion throughout the conduit. In someembodiments, an oxygen getter may be introduced in conduit 600 to reactwith any oxygen present in the conduit.

FIG. 75 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with heat pipe 598 located radially around oxidizerassembly 612. Oxidizers 614 of oxidizer assembly 612 are positionedadjacent to first portion 608 of heat pipe 598. Fuel may be supplied tooxidizers 614 through fuel conduit 616. Oxidant may be supplied tooxidizers 614 through oxidant conduit 618. Exhaust gas may flow throughthe space between outer conduit 620 and oxidant conduit 618. Oxidizers614 combust fuel to provide heat that vaporizes liquid heat transferfluid 604. Vaporized heat transfer fluid 606 rises in heat pipe 598 andcondenses on walls of the heat pipe to transfer heat to sealed conduit600. Exhaust gas from oxidizers 614 provides heat along the length ofsealed conduit 600. The heat provided by the exhaust gas along theeffective length of heat pipe 598 may increase convective heat transferand/or reduce the lag time before significant heat is provided to theformation from the heat pipe along the effective length of the heatpipe.

FIG. 76 depicts a cross-sectional representation of an angled heat pipeembodiment with oxidizer assembly 612 located near a lowermost portionof heat pipe 598. Fuel may be supplied to oxidizers 614 through fuelconduit 616. Oxidant may be supplied to oxidizers 614 through oxidantconduit 618. Exhaust gas may flow through the space between outerconduit 620 and oxidant conduit 618.

FIG. 77 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with oxidizer 614 located at the bottom of heatpipe 598. Fuel may be supplied to oxidizer 614 through fuel conduit 616.Oxidant may be supplied to oxidizer 614 through oxidant conduit 618.Exhaust gas may flow through the space between the outer wall of heatpipe 598 and outer conduit 620. Oxidizer 614 combusts fuel to provideheat that vaporizers liquid heat transfer fluid 604. Vaporized heattransfer fluid 606 rises in heat pipe 598 and condenses on walls of theheat pipe to transfer heat to sealed conduit 600. Exhaust gas fromoxidizers 614 provides heat along the length of sealed conduit 600 andto outer conduit 620. The heat provided by the exhaust gas along theeffective length of heat pipe 598 may increase convective heat transferand/or reduce the lag time before significant heat is provided to theformation from the heat pipe and oxidizer combination along theeffective length of the heat pipe. FIG. 78 depicts a similar embodimentwith heat pipe 598 positioned at an angle in the formation.

FIG. 79 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with oxidizer 614 that produces flame zone adjacentto liquid heat transfer fluid 604 in the bottom of heat pipe 598. Fuelmay be supplied to oxidizer 614 through fuel conduit 616. Oxidant may besupplied to oxidizer 614 through oxidant conduit 618. Oxidant and fuelare mixed and combusted to produce flame zone 622. Flame zone 622provides heat that vaporizes liquid heat transfer fluid 604. Exhaustgases from oxidizer 614 may flow through the space between oxidantconduit 618 and the inner surface of heat pipe 598, and through thespace between the outer surface of the heat pipe and outer conduit 620.The heat provided by the exhaust gas along the effective length of heatpipe 598 may increase convective heat transfer and/or reduce the lagtime before significant heat is provided to the formation from the heatpipe and oxidizer combination along the effective length of the heatpipe.

FIG. 80 depicts a perspective cut-out representation of a portion of aheat pipe embodiment with a tapered bottom that accommodates multipleoxidizers of an oxidizer assembly. In some embodiments, efficient heatpipe operation requires a high heat input. Multiple oxidizers ofoxidizer assembly 612 may provide high heat input to liquid heattransfer fluid 604 of heat pipe 598. A portion of oxidizer assembly withthe oxidizers may be helically wound around a tapered portion of heatpipe 598. The tapered portion may have a large surface area toaccommodate the oxidizers. Fuel may be supplied to the oxidizers ofoxidizer assembly 612 through fuel conduit 616. Oxidant may be suppliedto oxidizer 614 through oxidant conduit 618. Exhaust gas may flowthrough the space between the outer wall of heat pipe 598 and outerconduit 620. Exhaust gas from oxidizers 614 provides heat along thelength of sealed conduit 600 and to outer conduit 620. The heat providedby the exhaust gas along the effective length of heat pipe 598 mayincrease convective heat transfer and/or reduce the lag time beforesignificant heat is provided to the formation from the heat pipe andoxidizer combination along the effective length of the heat pipe.

FIG. 81 depicts a cross-sectional representation of a heat pipeembodiment that is angled within the formation. First wellbore 624 andsecond wellbore 626 are drilled in the formation using magnetic rangingor techniques so that the first wellbore intersects the second wellbore.Heat pipe 598 may be positioned in first wellbore 624. First wellbore624 may be sloped so that liquid heat transfer fluid 604 within heatpipe 598 is positioned near the intersection of the first wellbore andsecond wellbore 626. Oxidizer assembly 612 may be positioned in secondwellbore 626. Oxidizer assembly 612 provides heat to heat pipe thatvaporizes liquid heat transfer fluid in the heat pipe. Packer or seal628 may direct exhaust gas from oxidizer assembly 612 through firstwellbore 624 to provide additional heat to the formation from theexhaust gas.

In some embodiments, the temperature limited heater is used to achievelower temperature heating (for example, for heating fluids in aproduction well, heating a surface pipeline, or reducing the viscosityof fluids in a wellbore or near wellbore region). Varying theferromagnetic materials of the temperature limited heater allows forlower temperature heating. In some embodiments, the ferromagneticconductor is made of material with a lower Curie temperature than thatof 446 stainless steel. For example, the ferromagnetic conductor may bean alloy of iron and nickel. The alloy may have between 30% by weightand 42% by weight nickel with the rest being iron. In one embodiment,the alloy is Invar 36. Invar 36 is 36% by weight nickel in iron and hasa Curie temperature of 277° C. In some embodiments, an alloy is a threecomponent alloy with, for example, chromium, nickel, and iron. Forexample, an alloy may have 6% by weight chromium, 42% by weight nickel,and 52% by weight iron. A 2.5 cm diameter rod of Invar 36 has a turndownratio of approximately 2 to 1 at the Curie temperature. Placing theInvar 36 alloy over a copper core may allow for a smaller rod diameter.A copper core may result in a high turndown ratio. The insulator inlower temperature heater embodiments may be made of a high performancepolymer insulator (such as PFA or PEEK™) when used with alloys with aCurie temperature that is below the melting point or softening point ofthe polymer insulator.

In certain embodiments, a conductor-in-conduit temperature limitedheater is used in lower temperature applications by using lower Curietemperature and/or the phase transformation temperature rangeferromagnetic materials. For example, a lower Curie temperature and/orthe phase transformation temperature range ferromagnetic material may beused for heating inside sucker pump rods. Heating sucker pump rods maybe useful to lower the viscosity of fluids in the sucker pump or rodand/or to maintain a lower viscosity of fluids in the sucker pump rod.Lowering the viscosity of the oil may inhibit sticking of a pump used topump the fluids. Fluids in the sucker pump rod may be heated up totemperatures less than about 250° C. or less than about 300° C.Temperatures need to be maintained below these values to inhibit cokingof hydrocarbon fluids in the sucker pump system.

In certain embodiments, a temperature limited heater includes a flexiblecable (for example, a furnace cable) as the inner conductor. Forexample, the inner conductor may be a 27% nickel-clad or stainlesssteel-clad stranded copper wire with four layers of mica tape surroundedby a layer of ceramic and/or mineral fiber (for example, alumina fiber,aluminosilicate fiber, borosilicate fiber, or aluminoborosilicatefiber). A stainless steel-clad stranded copper wire furnace cable may beavailable from Anomet Products, Inc. The inner conductor may be ratedfor applications at temperatures of 1000° C. or higher. The innerconductor may be pulled inside a conduit. The conduit may be aferromagnetic conduit (for example, a ¾″ Schedule 80 446 stainless steelpipe). The conduit may be covered with a layer of copper, or otherelectrical conductor, with a thickness of about 0.3 cm or any othersuitable thickness. The assembly may be placed inside a support conduit(for example, a 1¼″ Schedule 80 347H or 347HH stainless steel tubular).The support conduit may provide additional creep-rupture strength andprotection for the copper and the inner conductor. For uses attemperatures greater than about 1000° C., the inner copper conductor maybe plated with a more corrosion resistant alloy (for example, Incoloy®825) to inhibit oxidation. In some embodiments, the top of thetemperature limited heater is sealed to inhibit air from contacting theinner conductor.

The temperature limited heater may be a single-phase heater or athree-phase heater. In a three-phase heater embodiment, the temperaturelimited heater has a delta or a wye configuration. Each of the threeferromagnetic conductors in the three-phase heater may be inside aseparate sheath. A connection between conductors may be made at thebottom of the heater inside a splice section. The three conductors mayremain insulated from the sheath inside the splice section.

FIG. 82 depicts an embodiment of a three-phase temperature limitedheater with ferromagnetic inner conductors. Each leg 632 has innerconductor 532, core 542, and jacket 540. Inner conductors 532 areferritic stainless steel or 1% carbon steel. Inner conductors 532 havecore 542. Core 542 may be copper. Each inner conductor 532 is coupled toits own jacket 540. Jacket 540 is a sheath made of a corrosion resistantmaterial (such as 304H stainless steel). Electrical insulator 534 isplaced between inner conductor 532 and jacket 540. Inner conductor 532is ferritic stainless steel or carbon steel with an outside diameter of1.14 cm and a thickness of 0.445 cm. Core 542 is a copper core with a0.25 cm diameter. Each leg 632 of the heater is coupled to terminalblock 634. Terminal block 634 is filled with insulation material 636 andhas an outer surface of stainless steel. Insulation material 636 is, insome embodiments, silicon nitride, boron nitride, magnesium oxide orother suitable electrically insulating material. Inner conductors 532 oflegs 632 are coupled (welded) in terminal block 634. Jackets 540 of legs632 are coupled (welded) to the outer surface of terminal block 634.Terminal block 634 may include two halves coupled around the coupledportions of legs 632.

In some embodiments, the three-phase heater includes three legs that arelocated in separate wellbores. The legs may be coupled in a commoncontacting section (for example, a central wellbore, a connectingwellbore, or a solution filled contacting section). FIG. 83 depicts anembodiment of temperature limited heaters coupled in a three-phaseconfiguration. Each leg 638, 640, 642 may be located in separateopenings 556 in hydrocarbon layer 484. Each leg 638, 640, 642 mayinclude heating element 644. Each leg 638, 640, 642 may be coupled tosingle contacting element 646 in one opening 556. Contacting element 646may electrically couple legs 638, 640, 642 together in a three-phaseconfiguration. Contacting element 646 may be located in, for example, acentral opening in the formation. Contacting element 646 may be locatedin a portion of opening 556 below hydrocarbon layer 484 (for example, inthe underburden). In certain embodiments, magnetic tracking of amagnetic element located in a central opening (for example, opening 556of leg 640) is used to guide the formation of the outer openings (forexample, openings 556 of legs 638 and 642) so that the outer openingsintersect the central opening. The central opening may be formed firstusing standard wellbore drilling methods. Contacting element 646 mayinclude funnels, guides, or catchers for allowing each leg to beinserted into the contacting element.

FIG. 84 depicts an embodiment of three heaters coupled in a three-phaseconfiguration. Conductor “legs” 638, 640, 642 are coupled to three-phasetransformer 648. Transformer 648 may be an isolated three-phasetransformer. In certain embodiments, transformer 648 providesthree-phase output in a wye configuration. Input to transformer 648 maybe made in any input configuration, such as the shown deltaconfiguration. Legs 638, 640, 642 each include lead-in conductors 650 inthe overburden of the formation coupled to heating elements 644 inhydrocarbon layer 484. Lead-in conductors 650 include copper with aninsulation layer. For example, lead-in conductors 650 may be a 4-0copper cables with TEFLON® insulation, a copper rod with polyurethaneinsulation, or other metal conductors such as bare copper or aluminum.In certain embodiments, lead-in conductors 650 are located in anoverburden portion of the formation. The overburden portion may includeoverburden casings 564. Heating elements 644 may be temperature limitedheater heating elements. In an embodiment, heating elements 644 are 410stainless steel rods (for example, 3.1 cm diameter 410 stainless steelrods). In some embodiments, heating elements 644 are compositetemperature limited heater heating elements (for example, 347 stainlesssteel, 410 stainless steel, copper composite heating elements; 347stainless steel, iron, copper composite heating elements; or 410stainless steel and copper composite heating elements). In certainembodiments, heating elements 644 have a length of at least about 10 mto about 2000 m, about 20 m to about 400 m, or about 30 m to about 300m.

In certain embodiments, heating elements 644 are exposed to hydrocarbonlayer 484 and fluids from the hydrocarbon layer. Thus, heating elements644 are “bare metal” or “exposed metal” heating elements. Heatingelements 644 may be made from a material that has an acceptablesulfidation rate at high temperatures used for pyrolyzing hydrocarbons.In certain embodiments, heating elements 644 are made from material thathas a sulfidation rate that decreases with increasing temperature overat least a certain temperature range (for example, 500° C. to 650° C.,530° C. to 650° C., or 550° C. to 650° C.). For example, 410 stainlesssteel may have a sulfidation rate that decreases with increasingtemperature between 530° C. and 650° C. Using such materials reducescorrosion problems due to sulfur-containing gases (such as H₂S) from theformation. In certain embodiments, heating elements 644 are made frommaterial that has a sulfidation rate below a selected value in atemperature range. In some embodiments, heating elements 644 are madefrom material that has a sulfidation rate at most about 25 mils per yearat a temperature between about 800° C. and about 880° C. In someembodiments, the sulfidation rate is at most about 35 mils per year at atemperature between about 800° C. and about 880° C., at most about 45mils per year at a temperature between about 800° C. and about 880° C.,or at most about 55 mils per year at a temperature between about 800° C.and about 880° C. Heating elements 644 may also be substantially inertto galvanic corrosion.

In some embodiments, heating elements 644 have a thin electricallyinsulating layer such as aluminum oxide or thermal spray coated aluminumoxide. In some embodiments, the thin electrically insulating layer is aceramic composition such as an enamel coating. Enamel coatings include,but are not limited to, high temperature porcelain enamels. Hightemperature porcelain enamels may include silicon dioxide, boron oxide,alumina, and alkaline earth oxides (CaO or MgO), and minor amounts ofalkali oxides (Na₂O, K₂O, LiO). The enamel coating may be applied as afinely ground slurry by dipping the heating element into the slurry orspray coating the heating element with the slurry. The coated heatingelement is then heated in a furnace until the glass transitiontemperature is reached so that the slurry spreads over the surface ofthe heating element and makes the porcelain enamel coating. Theporcelain enamel coating contracts when cooled below the glasstransition temperature so that the coating is in compression. Thus, whenthe coating is heated during operation of the heater, the coating isable to expand with the heater without cracking.

The thin electrically insulating layer has low thermal impedanceallowing heat transfer from the heating element to the formation whileinhibiting current leakage between heating elements in adjacent openingsand/or current leakage into the formation. In certain embodiments, thethin electrically insulating layer is stable at temperatures above atleast 350° C., above 500° C., or above 800° C. In certain embodiments,the thin electrically insulating layer has an emissivity of at least0.7, at least 0.8, or at least 0.9. Using the thin electricallyinsulating layer may allow for long heater lengths in the formation withlow current leakage.

Heating elements 644 may be coupled to contacting elements 646 at ornear the underburden of the formation. Contacting elements 646 arecopper or aluminum rods or other highly conductive materials. In certainembodiments, transition sections 652 are located between lead-inconductors 650 and heating elements 644, and/or between heating elements644 and contacting elements 646. Transition sections 652 may be made ofa conductive material that is corrosion resistant such as 347 stainlesssteel over a copper core. In certain embodiments, transition sections652 are made of materials that electrically couple lead-in conductors650 and heating elements 644 while providing little or no heat output.Thus, transition sections 652 help to inhibit overheating of conductorsand insulation used in lead-in conductors 650 by spacing the lead-inconductors from heating elements 644. Transition section 652 may have alength of between about 3 m and about 9 m (for example, about 6 m).

Contacting elements 646 are coupled to contactor 654 in contactingsection 656 to electrically couple legs 638, 640, 642 to each other. Insome embodiments, contact solution 658 (for example, conductive cement)is placed in contacting section 656 to electrically couple contactingelements 646 in the contacting section. In certain embodiments, legs638, 640, 642 are substantially parallel in hydrocarbon layer 484 andleg 638 continues substantially vertically into contacting section 656.The other two legs 640, 642 are directed (for example, by directionallydrilling the wellbores for the legs) to intercept leg 638 in contactingsection 656.

Each leg 638, 640, 642 may be one leg of a three-phase heater embodimentso that the legs are substantially electrically isolated from otherheaters in the formation and are substantially electrically isolatedfrom the formation. Legs 638, 640, 642 may be arranged in a triangularpattern so that the three legs form a triangular shaped three-phaseheater. In an embodiment, legs 638, 640, 642 are arranged in atriangular pattern with 12 m spacing between the legs (each side of thetriangle has a length of 12 m).

FIG. 85 depicts a side view representation of an embodiment ofcentralizer 558 on heater 438. FIG. 86 depicts an end viewrepresentation of the embodiment of centralizer 558 on heater 438depicted in FIG. 85. In certain embodiments, centralizers 558 are madeof three or more parts coupled to heater 438 so that the parts arespaced around the outside diameter of the heater. Having spaces betweenthe parts of a centralizer allows debris to fall along the heater (whenthe heater is vertical or substantially vertical) and inhibit debrisfrom collecting at the centralizer. In certain embodiments, thecentralizer is installed on a long heater without inserting a ring. Incertain embodiments, heater 438, as depicted in FIGS. 85 and 86, is anelectrical conductor used as part of a heater (for example, theelectrical conductor of a conductor-in-conduit heater). In certainembodiments, centralizer 558 includes three centralizer parts 558A,558B, and 558C. In other embodiments, centralizer 558 includes four ormore centralizer parts. Centralizer parts 558A, 558B, 558C may be evenlydistributed around the outside diameter of heater 438.

In certain embodiments, centralizer parts 558A, 558B, 558C includeinsulators 660 and weld bases 662. Insulators 660 may be made ofelectrically insulating material such as, but not limited to, ceramic(for example, magnesium oxide) or silicon nitride. Weld bases 662 may bemade of weldable metal such as, but not limited to, Alloy 625, the samemetal used for heater 438, or another metal that may be brazed or solidstate welded to insulators 660 and welded to a metal used for heater438.

In certain embodiments, insulators 660 are brazed, or otherwise coupled,to weld bases 662 to form centralizer parts 558A, 558B, 558C. In someembodiments, weld bases 662 are coupled to heater 438 first and theninsulators 660 are coupled to the weld bases to form centralizer parts558A, 558B, 558C. Insulators 660 may be coupled to weld bases 662 as theheater is being installed into the formation.

In certain embodiments, centralizer parts 558A, 558B, 558C are spacedevenly around the outside diameter of heater 438, as shown in FIGS. 85and 86. In other embodiments, centralizer parts 558A, 558B, 558C haveother spacings around the outside diameter of heater 438.

Having space between centralizer parts 558A, 558B, 558C allowsinstallation of the heaters and centralizers from a spool or coiledtubing installation of the heaters and centralizers. Centralizer parts558A, 558B, 558C also allow debris (for example, metal dust or pieces offormation) to fall along heater 438 through the area of the centralizer.Thus, debris is inhibited from collecting at or near centralizer 558. Inaddition, centralizer parts 558A, 558B, 558C may be inexpensive tomanufacture and install and easy to replace if broken.

FIG. 87 depicts a side view representation of an embodiment of asubstantially u-shaped three-phase heater. First ends of legs 638, 640,642 are coupled to transformer 648 at first location 664. In anembodiment, transformer 648 is a three-phase AC transformer. Ends oflegs 638, 640, 642 are electrically coupled together with connector 666at second location 668. Connector 666 electrically couples the ends oflegs 638, 640, 642 so that the legs can be operated in a three-phaseconfiguration. In certain embodiments, legs 638, 640, 642 are coupled tooperate in a three-phase wye configuration. In certain embodiments, legs638, 640, 642 are substantially parallel in hydrocarbon layer 484. Incertain embodiments, legs 638, 640, 642 are arranged in a triangularpattern in hydrocarbon layer 484. In certain embodiments, heatingelements 644 include thin electrically insulating material (such as aporcelain enamel coating) to inhibit current leakage from the heatingelements. In certain embodiments, the thin electrically insulating layerallows for relatively long, substantially horizontal heater leg lengthsin the hydrocarbon layer with a substantially u-shaped heater. Incertain embodiments, legs 638, 640, 642 are electrically coupled so thatthe legs are substantially electrically isolated from other heaters inthe formation and are substantially electrically isolated from theformation.

In certain embodiments, overburden casings (for example, overburdencasings 564, depicted in FIGS. 84 and 87) in overburden 482 includematerials that inhibit ferromagnetic effects in the casings. Inhibitingferromagnetic effects in casings 564 reduces heat losses to theoverburden. In some embodiments, casings 564 may include non-metallicmaterials such as fiberglass, polyvinylchloride (PVC), chlorinatedpolyvinylchloride (CPVC), or high-density polyethylene (HDPE). HDPEswith working temperatures in a range for use in overburden 482 includeHDPEs available from Dow Chemical Co., Inc. (Midland, Mich., U.S.A.). Anon-metallic casing may also eliminate the need for an insulatedoverburden conductor. In some embodiments, casings 564 include carbonsteel coupled on the inside diameter of a non-ferromagnetic metal (forexample, carbon steel clad with copper or aluminum) to inhibitferromagnetic effects or inductive effects in the carbon steel. Othernon-ferromagnetic metals include, but are not limited to, manganesesteels with at least 10% by weight manganese, iron aluminum alloys withat least 18% by weight aluminum, and austentitic stainless steels suchas 304 stainless steel or 316 stainless steel.

In certain embodiments, one or more non-ferromagnetic materials used incasings 564 are used in a wellhead coupled to the casings and legs 638,640, 642. Using non-ferromagnetic materials in the wellhead inhibitsundesirable heating of components in the wellhead. In some embodiments,a purge gas (for example, carbon dioxide, nitrogen or argon) isintroduced into the wellhead and/or inside of casings 564 to inhibitreflux of heated gases into the wellhead and/or the casings.

In certain embodiments, one or more of legs 638, 640, 642 are installedin the formation using coiled tubing. In certain embodiments, coiledtubing is installed in the formation, the leg is installed inside thecoiled tubing, and the coiled tubing is pulled out of the formation toleave the leg installed in the formation. The leg may be placedconcentrically inside the coiled tubing. In some embodiments, coiledtubing with the leg inside the coiled tubing is installed in theformation and the coiled tubing is removed from the formation to leavethe leg installed in the formation. The coiled tubing may extend only toa junction of the hydrocarbon layer and the contacting section, or to apoint at which the leg begins to bend in the contacting section.

FIG. 88 depicts a top view representation of an embodiment of aplurality of triads of three-phase heaters in the formation. Each triad670 includes legs A, B, C (which may correspond to legs 638, 640, 642depicted in FIGS. 84 and 87) that are electrically coupled by linkage674. Each triad 670 is coupled to its own electrically isolatedthree-phase transformer so that the triads are substantiallyelectrically isolated from each other. Electrically isolating the triadsinhibits net current flow between triads.

The phases of each triad 670 may be arranged so that legs A, B, Ccorrespond between triads as shown in FIG. 88. In FIG. 88, legs A, B, Care arranged such that a phase leg (for example, leg A) in a given triadis about two triad heights from a same phase leg (leg A) in an adjacenttriad. The triad height is the distance from a vertex of the triad to amidpoint of the line intersecting the other two vertices of the triad.In certain embodiments, the phases of triads 670 are arranged to inhibitnet current flow between individual triads. There may be some leakage ofcurrent within an individual triad but little net current flows betweentwo triads due to the substantial electrical isolation of the triadsand, in certain embodiments, the arrangement of the triad phases.

In the early stages of heating, an exposed heating element (for example,heating element 644 depicted in FIGS. 84 and 87) may leak some currentto water or other fluids that are electrically conductive in theformation so that the formation itself is heated. After water or otherelectrically conductive fluids are removed from the wellbore (forexample, vaporized or produced), the heating elements becomeelectrically isolated from the formation. Later, when water is removedfrom the formation, the formation becomes even more electricallyresistant and heating of the formation occurs even more predominantlyvia thermally conductive and/or radiative heating. Typically, theformation (the hydrocarbon layer) has an initial electrical resistancethat averages at least 10 ohm·m. In some embodiments, the formation hasan initial electrical resistance of at least 100 ohm·m or of at least300 ohm·m.

Using the temperature limited heaters as the heating elements limits theeffect of water saturation on heater efficiency. With water in theformation and in heater wellbores, there is a tendency for electricalcurrent to flow between heater elements at the top of the hydrocarbonlayer where the voltage is highest and cause uneven heating in thehydrocarbon layer. This effect is inhibited with temperature limitedheaters because the temperature limited heaters reduce localizedoverheating in the heating elements and in the hydrocarbon layer.

In certain embodiments, production wells are placed at a location atwhich there is relatively little or zero voltage potential. Thislocation minimizes stray potentials at the production well. Placingproduction wells at such locations improves the safety of the system andreduces or inhibits undesired heating of the production wells caused byelectrical current flow in the production wells. FIG. 89 depicts a topview representation of the embodiment depicted in FIG. 88 withproduction wells 206. In certain embodiments, production wells 206 arelocated at or near center of triad 670. In certain embodiments,production wells 206 are placed at a location between triads at whichthere is relatively little or zero voltage potential (at a location atwhich voltage potentials from vertices of three triads average out torelatively little or zero voltage potential). For example, productionwell 206 may be at a location equidistant from legs A of one triad, legB of a second triad, and leg C of a third triad, as shown in FIG. 89.

FIG. 90 depicts a top view representation of an embodiment of aplurality of triads of three-phase heaters in a hexagonal pattern in theformation. FIG. 91 depicts a top view representation of an embodiment ofa hexagon from FIG. 90. Hexagon 672 includes two triads of heaters. Thefirst triad includes legs A1, B1, C1 electrically coupled together bylinkages 674 in a three-phase configuration. The second triad includeslegs A2, B2, C2 electrically coupled together by linkages 674 in athree-phase configuration. The triads are arranged so that correspondinglegs of the triads (for example, A1 and A2, B1 and B2, C1 and C2) are atopposite vertices of hexagon 672. The triads are electrically coupledand arranged so that there is relatively little or zero voltagepotential at or near the center of hexagon 672.

Production well 206 may be placed at or near the center of hexagon 672.Placing production well 206 at or near the center of hexagon 672 placesthe production well at a location that reduces or inhibits undesiredheating due to electromagnetic effects caused by electrical current flowin the legs of the triads and increases the safety of the system. Havingtwo triads in hexagon 672 provides for redundant heating aroundproduction well 206. Thus, if one triad fails or has to be turned off,production well 206 still remains at a center of one triad.

As shown in FIG. 90, hexagons 672 may be arranged in a pattern in theformation such that adjacent hexagons are offset. Using electricallyisolated transformers on adjacent hexagons may inhibit electricalpotentials in the formation so that little or no net current leaksbetween hexagons.

Triads of heaters and/or heater legs may be arranged in any shape ordesired pattern. For example, as described above, triads may includethree heaters and/or heater legs arranged in an equilateral triangularpattern. In some embodiments, triads include three heaters and/or heaterlegs arranged in other triangular shapes (for example, an isoscelestriangle or a right angle triangle). In some embodiments, heater legs inthe triad cross each other (for example, criss-cross) in the formation.In certain embodiments, triads includes three heaters and/or heater legsarranged sequentially along a straight line.

Distal sections of the heater legs may be electrically coupled together.The distal sections may be electrically coupled to a connector or toeach other. In certain embodiments, contacting elements of the heaterlegs are physically coupled to establish the electrical coupling. Forexample, heater legs may be electrically coupled by soldering, bywelding, by explosive crimping, by interconnecting brush contacts and/orby other techniques that involve physically attaching the legs to eachother or to a connector. In some embodiments, the contacting elements ofthe heater legs are placed in a contacting solution or otherelectrically conductive material to electrically couple the heater legstogether.

FIG. 92 depicts an embodiment with triads coupled to a horizontalconnector well. Triad 670A includes legs 638A, 640A, 642A. Triad 670Bincludes legs 638B, 640B, 642B. Legs 638A, 640A, 642A and legs 638B,640B, 642B may be arranged along a straight line on the surface of theformation. In some embodiments, legs 638A, 640A, 642A are arranged alonga straight line and offset from legs 638B, 640B, 642B, which may bearranged along a straight line. Legs 638A, 640A, 642A and legs 638B,640B, 642B include heating elements 644 located in hydrocarbon layer484. Lead-in conductors 650 couple heating elements 644 to the surfaceof the formation. Heating elements 644 are coupled to contactingelements 646 at or near the underburden of the formation. In certainembodiments, transition sections (for example, transition sections 652depicted in FIG. 84) are located between lead-in conductors 650 andheating elements 644, and/or between heating elements 644 and contactingelements 646.

Contacting elements 646 are coupled to contactor 654 in contactingsection 656 to electrically couple legs 638A, 640A, 642A to each otherto form triad 670A and electrically couple legs 638B, 640B, 642B to eachother to form triad 670B. In certain embodiments, contactor 654 is aground conductor so that triad 670A and/or triad 670B may be coupled inthree-phase wye configurations. In certain embodiments, triad 670A andtriad 670B are electrically isolated from each other. In someembodiments, triad 670A and triad 670B are electrically coupled to eachother (for example, electrically coupled in series or parallel).

In certain embodiments, contactor 654 is a substantially horizontalcontactor located in contacting section 656. Contactor 654 may be acasing or a solid rod placed in a wellbore drilled substantiallyhorizontally in contacting section 656. Legs 638A, 640A, 642A and legs638B, 640B, 642B may be electrically coupled to contactor 654 by anymethod described herein or any method known in the art. For example,containers with thermite powder are coupled to contactor 654 (forexample, by welding or brazing the containers to the contactor); legs638A, 640A, 642A and legs 638B, 640B, 642B are placed inside thecontainers; and the thermite powder is activated to electrically couplethe legs to the contactor. The containers may be coupled to contactor654 by, for example, placing the containers in holes or recesses incontactor 654 or coupled to the outside of the contactor and thenbrazing or welding the containers to the contactor.

In certain embodiments, two legs in separate wellbores intercept in asingle contacting section. FIG. 93 depicts an embodiment of twotemperature limited heaters coupled in a single contacting section. Legs638 and 640 include one or more heating elements 644. Heating elements644 may include one or more electrical conductors. In certainembodiments, legs 638 and 640 are electrically coupled in a single-phaseconfiguration with one leg positively biased versus the other leg sothat current flows downhole through one leg and returns through theother leg.

Heating elements 644 in legs 638 and 640 may be temperature limitedheaters. In certain embodiments, heating elements 644 are solid rodheaters. For example, heating elements 644 may be rods made of a singleferromagnetic conductor element or composite conductors that includeferromagnetic material. During initial heating when water is present inthe formation being heated, heating elements 644 may leak current intohydrocarbon layer 484. The current leaked into hydrocarbon layer 484 mayresistively heat the hydrocarbon layer.

In some embodiments (for example, in oil shale formations), heatingelements 644 do not need support members. Heating elements 644 may bepartially or slightly bent, curved, made into an S-shape, or made into ahelical shape to allow for expansion and/or contraction of the heatingelements. In certain embodiments, solid rod heating elements 644 areplaced in small diameter wellbores (for example, about 3¾″ (about 9.5cm) diameter wellbores). Small diameter wellbores may be less expensiveto drill or form than larger diameter wellbores, and there will be lesscuttings to dispose of.

In certain embodiments, portions of legs 638 and 640 in overburden 482have insulation (for example, polymer insulation) to inhibit heating theoverburden. Heating elements 644 may be substantially vertical andsubstantially parallel to each other in hydrocarbon layer 484. At ornear the bottom of hydrocarbon layer 484, leg 638 may be directionallydrilled towards leg 640 to intercept leg 640 in contacting section 656.Drilling two wellbores to intercept each other may be easier and lessexpensive than drilling three or more wellbores to intercept each other.The depth of contacting section 656 depends on the length of bend in leg638 needed to intercept leg 640. For example, for a 40 ft (about 12 m)spacing between vertical portions of legs 638 and 640, about 200 ft(about 61 m) is needed to allow the bend of leg 638 to intercept leg640. Coupling two legs may require a thinner contacting section 656 thancoupling three or more legs in the contacting section.

FIG. 94 depicts an embodiment for coupling legs 638 and 640 incontacting section 656. Heating elements 644 are coupled to contactingelements 646 at or near junction of contacting section 656 andhydrocarbon layer 484. Contacting elements 646 may be copper or anothersuitable electrical conductor. In certain embodiments, contactingelement 646 in leg 640 is a liner with opening 676. Contacting element646 from leg 638 passes through opening 676. Contactor 654 is coupled tothe end of contacting element 646 from leg 638. Contactor 654 provideselectrical coupling between contacting elements in legs 638 and 640.

In certain embodiments, contacting elements 646 include one or more finsor projections. The fins or projections may increase an electricalcontact area of contacting elements 646. In some embodiments, contactingelement 646 of leg 640 has an opening or other orifice that allows thecontacting element of 638 to couple to the contacting element of leg640.

In certain embodiments, legs 638 and 640 are coupled together to form adiad. Three diads may be coupled to a three-phase transformer to powerthe legs of the heaters. FIG. 95 depicts an embodiment of three diadscoupled to a three-phase transformer. In certain embodiments,transformer 648 is a delta three-phase transformer. Diad 678A includeslegs 638A and 640A. Diad 678B includes legs 638B and 640B. Diad 678Cincludes legs 638C and 640C. Diads 678A, 678B, 678C are coupled to thesecondaries of transformer 648. Diad 678A is coupled to the “A”secondary. Diad 678B is coupled to the “B” secondary. Diad 678C iscoupled to the “C” secondary.

Coupling the diads to the secondaries of the delta three-phasetransformer isolates the diads from ground. Isolating the diads fromground inhibits leakage to the formation from the diads. Coupling thediads to different phases of the delta three-phase transformer alsoinhibits leakage between the heating legs of the diads in the formation.

In some embodiments, diads are used for treating formations usingtriangular or hexagonal heater patterns. FIG. 96 depicts an embodimentof groups of diads in a hexagonal pattern. Heaters may be placed at thevertices of each of the hexagons in the hexagonal pattern. Each group680 of diads (enclosed by dashed circles) may be coupled to a separatethree-phase transformer. “A”, “B”, and “C” inside groups 680 representeach diad (for example, diads 678A, 678B, 678C depicted in FIG. 95) thatis coupled to each of the three secondary phases of the transformer witheach phase coupled to one diad (with the heaters at the vertices of thehexagon). The numbers “1”, “2”, and “3” inside the hexagons representthe three repeating types of hexagons in the pattern depicted in FIG.96.

FIG. 97 depicts an embodiment of diads in a triangular pattern. Threediads 678A, 678B, 678C may be enclosed in each group 680 of diads(enclosed by dashed rectangles). Each group 680 may be coupled to aseparate three-phase transformer.

In certain embodiments, exposed metal heating elements are used insubstantially horizontal sections of u-shaped wellbores. Substantiallyu-shaped wellbores may be used in tar sands formations, oil shaleformation, or other formations with relatively thin hydrocarbon layers.Tar sands or thin oil shale formations may have thin shallow layers thatare more easily and uniformly heated using heaters placed insubstantially u-shaped wellbores. Substantially u-shaped wellbores mayalso be used to process formations with thick hydrocarbon layers. Insome embodiments, substantially u-shaped wellbores are used to accessrich layers in a thick hydrocarbon formation.

Heaters in substantially u-shaped wellbores may have long lengthscompared to heaters in vertical wellbores because horizontal heatingsections do not have problems with creep or hanging stress encounteredwith vertical heating elements. Substantially u-shaped wellbores maymake use of natural seals in the formation and/or the limited thicknessof the hydrocarbon layer. For example, the wellbores may be placed aboveor below natural seals in the formation without punching large numbersof holes in the natural seals, as would be needed with verticallyoriented wellbores. Using substantially u-shaped wellbores instead ofvertical wellbores may also reduce the number of wells needed to treat asurface footprint of the formation. Using less wells reduces capitalcosts for equipment and reduces the environmental impact of treating theformation by reducing the amount of wellbores on the surface and theamount of equipment on the surface. Substantially u-shaped wellbores mayalso utilize a lower ratio of overburden section to heated section thanvertical wellbores.

Substantially u-shaped wellbores may allow for flexible placement ofopening of the wellbores on the surface. Openings to the wellbores maybe placed according to the surface topology of the formation. In certainembodiments, the openings of wellbores are placed at geographicallyaccessible locations such as topological highs (for examples, hills).For example, the wellbore may have a first opening on a first topologichigh and a second opening on a second topologic high and the wellborecrosses beneath a topologic low (for example, a valley with alluvialfill) between the first and second topologic highs. This placement ofthe openings may avoid placing openings or equipment in topologic lowsor other inaccessible locations. In addition, the water level may not beartesian in topologically high areas. Wellbores may be drilled so thatthe openings are not located near environmentally sensitive areas suchas, but not limited to, streams, nesting areas, or animal refuges.

FIG. 98 depicts a cross-sectional representation of an embodiment of aheater with an exposed metal heating element placed in a substantiallyu-shaped wellbore. Heaters 438A, 438B, 438C have first end portions atfirst location 664 on surface 568 of the formation and second endportions at second location 668 on the surface. Heaters 438A, 438B, 438Chave sections 682 in overburden 482. Sections 682 are configured toprovide little or no heat output. In certain embodiments, sections 682include an insulated electrical conductor such as insulated copper.Sections 682 are coupled to heating elements 644.

In certain embodiments, portions of heating elements 644 aresubstantially parallel in hydrocarbon layer 484. In certain embodiments,heating elements 644 are exposed metal heating elements. In certainembodiments, heating elements 644 are exposed metal temperature limitedheating elements. Heating elements 644 may include ferromagneticmaterials such as 9% by weight to 13% by weight chromium stainless steellike 410 stainless steel, chromium stainless steels such as T/P91 orT/P92, 409 stainless steel, VM12 (Vallourec and Mannesmann Tubes,France) or iron-cobalt alloys for use as temperature limited heaters. Insome embodiments, heating elements 644 are composite temperature limitedheating elements such as 410 stainless steel and copper compositeheating elements or 347H, iron, copper composite heating elements.Heating elements 644 may have lengths of at least about 100 m, at leastabout 500 m, or at least about 1000 m, up to lengths of about 6000 m.

Heating elements 644 may be solid rods or tubulars. In certainembodiments, solid rod heating elements have diameters several times theskin depth at the Curie temperature of the ferromagnetic material.Typically, the solid rod heating elements may have diameters of 1.91 cmor larger (for example, 2.5 cm, 3.2 cm, 3.81 cm, or 5.1 cm). In certainembodiments, tubular heating elements have wall thicknesses of at leasttwice the skin depth at the Curie temperature of the ferromagneticmaterial. Typically, the tubular heating elements have outside diametersof between about 2.5 cm and about 15.2 cm and wall thickness in rangebetween about 0.13 cm and about 1.01 cm.

In certain embodiments, tubular heating elements 644 allow fluids to beconvected through the tubular heating elements. Fluid flowing throughthe tubular heating elements may be used to preheat the tubular heatingelements to initially heat the formation and/or to recover heat from theformation after heating is completed for the in situ heat treatmentprocess. Fluids that may flow through the tubular heating elementsinclude, but are not limited to, air, water, steam, helium, carbondioxide or other fluids. In some embodiments, a hot fluid, such ascarbon dioxide or helium, flows through the tubular heating elements toprovide heat to the formation. The hot fluid may be used to provide heatto the formation before electrical heating is used to provide heat tothe formation. In some embodiments, the hot fluid is used to provideheat in addition to electrical heating. Using the hot fluid to provideheat to the formation in addition to providing electrical heating may beless expensive than using electrical heating alone to provide heat tothe formation. In some embodiments, water and/or steam flows through thetubular heating element to recover heat from the formation. The heatedwater and/or steam may be used for solution mining and/or otherprocesses.

Transition sections 684 may couple heating elements 644 to sections 682.In certain embodiments, transition sections 684 include material thathas a high electrical conductivity but is corrosion resistant, such as347 stainless steel over copper. In an embodiment, transition sectionsinclude a composite of stainless steel clad over copper. Transitionsections 684 inhibit overheating of copper and/or insulation in sections682.

FIG. 99 depicts a top view representation of an embodiment of a surfacepattern of the heaters depicted in FIG. 98. Heaters 438A-L may bearranged in a repeating triangular pattern on the surface of theformation. A triangle may be formed by heaters 438A, 438B, and 438C anda triangle formed by heaters 438C, 438D, and 438E. In some embodiments,heaters 438A-L are arranged in a straight line on the surface of theformation. Heaters 438A-L have first end portions at first location 664on the surface and second end portions at second location 668 on thesurface. Heaters 438A-L are arranged such that (a) the patterns at firstlocation 664 and second location 668 correspond to each other, (b) thespacing between heaters is maintained at the two locations on thesurface, and/or (c) the heaters all have substantially the same length(substantially the same horizontal distance between the end portions ofthe heaters on the surface as shown in the top view of FIG. 99).

As depicted in FIGS. 98 and 99, cables 686, 688 may be coupled totransformer 580 and one or more heater units, such as the heater unitincluding heaters 438A, 438B, 438C. Cables 686, 688 may carry a largeamount of power. In certain embodiments, cables 686, 688 are capable ofcarrying high currents with low losses. For example, cables 686, 688 maybe thick copper or aluminum conductors. The cables may also have thickinsulation layers. In some embodiments, cable 686 and/or cable 688 maybe superconducting cables. The superconducting cables may be cooled byliquid nitrogen. Superconducting cables are available from Superpower,Inc. (Schenectady, N.Y., U.S.A.). Superconducting cables may minimizepower loss and reduce the size of the cables needed to coupletransformer 580 to the heaters. In some embodiments, cables 686, 688 maybe made of carbon nanotubes. Carbon nanotubes as conductors may haveabout 1000 times the conductivity of copper for the same diameter. Also,carbon nanotubes may not require refrigeration during use.

In certain embodiments, bus bar 690A is coupled to first end portions ofheaters 438A-L and bus bar 690B is coupled to second end portions ofheaters 438A-L. Bus bars 690A,B electrically couple heaters 438A-L tocables 686, 688 and transformer 580. Bus bars 690A,B distribute power toheaters 438A-L. In certain embodiments, bus bars 690A,B are capable ofcarrying high currents with low losses. In some embodiments, bus bars690A,B are made of superconducting material such as the superconductormaterial used in cables 686, 688. In some embodiments, bus bars 690A,Bmay include carbon nanotube conductors.

As shown in FIGS. 98 and 99, heaters 438A-L are coupled to a singletransformer 580. In certain embodiments, transformer 580 is a source oftime-varying current. In certain embodiments, transformer 580 is anelectrically isolated, single-phase transformer. In certain embodiments,transformer 580 provides power to heaters 438A-L from an isolatedsecondary phase of the transformer. First end portions of heaters 438A-Lmay be coupled to one side of transformer 580 while second end portionsof the heaters are coupled to the opposite side of the transformer.Transformer 580 provides a substantially common voltage to the first endportions of heaters 438A-L and a substantially common voltage to thesecond end portions of heaters 438A-L. In certain embodiments,transformer 580 applies a voltage potential to the first end portions ofheaters 438A-L that is opposite in polarity and substantially equal inmagnitude to a voltage potential applied to the second end portions ofthe heaters. For example, a +660 V potential may be applied to the firstend portions of heaters 438A-L and a −660 V potential applied to thesecond end portions of the heaters at a selected point on the wave oftime-varying current (such as AC or modulated DC). Thus, the voltages atthe two end portion of the heaters may be equal in magnitude andopposite in polarity with an average voltage that is substantially atground potential.

Applying the same voltage potentials to the end portions of all heaters438A-L produces voltage potentials along the lengths of the heaters thatare substantially the same along the lengths of the heaters. FIG. 100depicts a cross-sectional representation, along a vertical plane, suchas the plane A-A shown in FIG. 98, of substantially u-shaped heaters ina hydrocarbon layer. The voltage potential at the cross-sectional pointshown in FIG. 100 along the length of heater 438A is substantially thesame as the voltage potential at the corresponding cross-sectionalpoints on heaters 438A-L shown in FIG. 100. At lines equidistant betweenheater wellheads, the voltage potential is approximately zero. Otherwells, such as production wells or monitoring wells, may be locatedalong these zero voltage potential lines, if desired. Production wells206 located close to the overburden may be used to transport formationfluid that is initially in a vapor phase to the surface. Productionwells located close to a bottom of the heated portion of the formationmay be used to transport formation fluid that is initially in a liquidphase to the surface.

In certain embodiments, the voltage potential at the midpoint of heaters438A-L is about zero. Having similar voltage potentials along thelengths of heaters 438A-L inhibits current leakage between the heaters.Thus, there is little or no current flow in the formation and theheaters may have long lengths as described above. Having the oppositepolarity and substantially equal voltage potentials at the end portionsof the heaters also halves the voltage applied at either end portion ofthe heater versus having one end portion of the heater grounded and oneend portion at full potential. Reducing (halving) the voltage potentialapplied to an end portion of the heater generally reduces currentleakage, reduces insulator requirements, and/or reduces arcing distancesbecause of the lower voltage potential to ground applied at the endportions of the heaters.

In certain embodiments, substantially vertical heaters are used toprovide heat to the formation. Opposite polarity and substantially equalvoltage potentials, as described above, may be applied to the endportions of the substantially vertical heaters. FIG. 101 depicts a sideview representation of substantially vertical heaters coupled to asubstantially horizontal wellbore. Heaters 438A, 438B, 438C, 438D, 438E,438F are located substantially vertical in hydrocarbon layer 484. Firstend portions of heaters 438A, 438B, 438C, 438D, 438E, 438F are coupledto bus bar 690A on a surface of the formation. Second end portions ofheaters 438A, 438B, 438C, 438D, 438E, 438F are coupled to bus bar 690Bin contacting section 656.

Bus bar 690B may be a bus bar located in a substantially horizontalwellbore in contacting section 656. Second end portions of heaters 438A,438B, 438C, 438D, 438E, 438F may be coupled to bus bar 690B by anymethod described herein or any method known in the art. For example,containers with thermite powder are coupled to bus bar 690B (forexample, by welding or brazing the containers to the bus bar), endportions of heaters 438A, 438B, 438C, 438D, 438E, 438F are placed insidethe containers, and the thermite powder is activated to electricallycouple the heaters to the bus bar. The containers may be coupled to busbar 690B by, for example, placing the containers in holes or recesses inbus bar 690B or coupled to the outside of the bus bar and then brazingor welding the containers to the bus bar.

Bus bar 690A and bus bar 690B may be coupled to transformer 580 withcables 686, 688, as described above. Transformer 580 may providevoltages to bar 690A and bus bar 690B as described above for theembodiments depicted in FIGS. 98 and 99. For example, transformer 580may apply a voltage potential to the first end portions of heaters438A-F that is opposite in polarity and substantially equal in magnitudeto a voltage potential applied to the second end portions of theheaters. Applying the same voltage potentials to the end portions of allheaters 438A-F may produce voltage potentials along the lengths of theheaters that are substantially the same along the lengths of theheaters. Applying the same voltage potentials to the end portions of allheaters 438A-F may inhibit current leakage between the heaters and/orinto the formation. In some embodiments, heaters 438A-F are electricallycoupled in pairs to the isolated delta winding on the secondary of athree-phase transformer.

In certain embodiments, it may be advantageous to allow some currentleakage into the formation during early stages of heating to heat theformation at a faster rate. Current leakage from the heaters into theformation electrically heats the formation directly. The formation isheated by direct electrical heating in addition to conductive heatprovided by the heaters. The formation (the hydrocarbon layer) may havean initial electrical resistance that averages at least 10 ohm·m. Insome embodiments, the formation has an initial electrical resistance ofat least 100 ohm·m or of at least 300 ohm·m. Direct electrical heatingis achieved by having opposite potentials applied to adjacent heaters inthe hydrocarbon layer. Current may be allowed to leak into the formationuntil a selected temperature is reached in the heaters or in theformation. The selected temperature may be below or near the temperaturethat water proximate one or more heaters boils off. After water boilsoff, the hydrocarbon layer is substantially electrically isolated fromthe heaters and direct heating of the formation is inefficient. Afterthe selected temperature is reached, the voltage potential is applied inthe opposite polarity and substantially equal magnitude manner describedabove for FIGS. 98 and 99 so that adjacent heaters will have the samevoltage potential along their lengths.

Current is allowed to leak into the formation by reversing the polarityof one or more heaters shown in FIG. 99 so that a first group of heatershas a positive voltage potential at first location 664 and a secondgroup of heaters has a negative voltage potential at the first location.The first end portions, at first location 664, of a first group ofheaters (for example, heaters 438A, 438B, 438D, 438E, 438G, 438H, 438J,438K, depicted in FIG. 99) are applied with a positive voltage potentialthat is substantially equal in magnitude to a negative voltage potentialapplied to the second end portions, at second location 668, of the firstgroup of heaters. The first end portions, at first location 664, of thesecond group of heaters (for example, heaters 438C, 438F, 4381, 438L)are applied with a negative voltage potential that is substantiallyequal in magnitude to the positive voltage potential applied to thefirst end portions of the first group of heaters. Similarly, the secondend portions, at second location 668, of the second group of heaters areapplied with a positive voltage potential substantially equal inmagnitude to the negative potential applied to the second end portionsof the first group of heaters. After the selected temperature isreached, the first end portions of both groups of heaters are appliedwith voltage potential that is opposite in polarity and substantiallysimilar in magnitude to the voltage potential applied to the second endportions of both groups of heaters.

In some embodiments, the heating elements have thin electricallyinsulating material, described above, to inhibit current leakage fromthe heating elements. In some embodiments, the thin electricallyinsulating layer is aluminum oxide or thermal spray coated aluminumoxide. In some embodiments, the thin electrically insulating layer is anenamel coating of a ceramic composition. The thin electricallyinsulating layer may inhibit heating elements of a three-phase heaterfrom leaking current between the elements, from leaking current into theformation, and from leaking current to other heaters in the formation.Thus, the three-phase heater may have a longer heater length.

In certain embodiments, a plurality of substantially horizontal (orinclined) heaters are coupled to a single substantially horizontal busbar in the subsurface formation. Having the plurality of substantiallyhorizontal heaters connected to a single bus bar in the subsurfacereduces the overall footprint of heaters on the surface of the formationand the number of wells drilled in the formation. In addition, theamount of subsurface space used to couple the heaters may be minimizedso that more of the formation is treated with heat to recoverhydrocarbons (for example, there is less unheated depth in theformation). The number and spacing of heaters coupled to the single busbar may be varied depending on factors such as, but not limited to, sizeof the treatment area, vertical thickness of the formation, heatingrequirements for the formation, number of layers in the formation, andcapacity limitations of a surface power supply.

FIG. 102 depicts an embodiment of pluralities of substantiallyhorizontal heaters 438A,B coupled to bus bars 690A,B in hydrocarbonlayer 484. Heaters 438A,B have sections 682 in the overburden ofhydrocarbon layer 484. Sections 682 may include high electricalconductivity, low thermal loss electrical conductors such as copper orcopper clad carbon steel. Heaters 438A,B enter hydrocarbon layer 484with substantially vertical sections and then redirect so that theheaters have substantially horizontal sections in hydrocarbon layer 484.The substantially horizontal sections of heaters 438A,B in hydrocarbonlayer 484 may provide the majority of the heat to the hydrocarbon layer.Heaters 438A,B may be coupled to bus bars 690A,B, which are locateddistant from each other in the formation while being substantiallyparallel to each other.

In certain embodiments, heaters 438A,B include exposed metal heatingelements. In certain embodiments, heaters 438A,B include exposed metaltemperature limited heating elements. The heating elements may includeferromagnetic materials such as 9% by weight to 13% by weight chromiumstainless steel like 410 stainless steel, chromium stainless steels suchas T/P91 or T/P92, 409 stainless steel, VM12 (Vallourec and MannesmannTubes, France) or iron-cobalt alloys for use as temperature limitedheaters. In some embodiments, the heating elements are compositetemperature limited heating elements such as 410 stainless steel andcopper composite heating elements or 347H, iron, copper compositeheating elements. The substantially horizontal sections of heaters438A,B in hydrocarbon layer 484 may have lengths of at least about 100m, at least about 500 m, or at least about 1000 m, up to lengths ofabout 6000 m.

In some embodiments, two groups of heaters 438A,B enter the subsurfacenear each other and then branch away from each other in hydrocarbonlayer 484. Having the surface portions of more than one group of heaterslocated near each other creates less of a surface footprint of theheaters and allows a single group of surface facilities to be used forboth groups of heaters.

In certain embodiments, the groups of heaters 438A or 438B are eachcoupled to a single transformer. In some embodiments, three heaters inthe groups are coupled in a triad configuration (each heater is coupledto one of the phases (A, B, or C) of a three phase transformer and thebus bar is coupled to the neutral, or center point, of the transformer).Each phase of the three-phase transformer may be coupled to more thanone heater in each group of heaters (for example, phase A may be coupledto 5 heaters in the group of heaters 438A). In some embodiments, theheaters are coupled to a single phase transformer (either in series orin parallel configurations).

FIG. 103 depicts an embodiment of pluralities of substantiallyhorizontal heaters 438A,B coupled to bus bars 690A,B in hydrocarbonlayer 484. In such an embodiment, two groups of heaters 438A,B enter theformation at distal locations on the surface of the formation. Heaters438A,B branch towards each other in hydrocarbon layer 484 so that theends of the heaters are directed towards each other. Heaters 438A,B maybe coupled to bus bars 690A,B, which are located proximate each otherand substantially parallel to each other. Bus bars 690A,B may enter thesubsurface in proximity to each other so that the footprint of the busbars on the surface is small.

In certain embodiments, heaters 438A,B are coupled to a single phasetransformer in series or parallel. The heaters may be coupled so thatthe polarity (direction of current flow) alternates in the row ofheaters so that each heater has a polarity opposite the heater adjacentto it. Additionally, heaters 438A,B and bus bars 690A,B may beelectrically coupled such that the bus bars are opposite in polarityfrom each other (the current flows in opposite directions at any pointin time in each bus bar). Coupling the heaters and the bus bars in sucha manner inhibits current leakage into and/or through the formation.

As shown in FIGS. 102 and 103, heaters 438A may be electrically coupledto bus bar 690A and heaters 438B may be electrically coupled to bus bar690B. Bus bars 690A,B may electrically couple to the ends of heaters438A,B and be a return or neutral connection for the heaters with busbar 690A being the neutral connection for heaters 438A and bus bar 690Bbeing the neutral connection for heaters 438B. Bus bars 690A,B may belocated in wellbores that are formed substantially perpendicular to thepath of wellbores with heaters 438A,B, as shown in FIG. 102. Directionaldrilling and/or magnetic steering may be used so that the wells for busbars 690A,B and the wellbores for heaters 438A,B intersect.

In certain embodiments, heaters 438A,B are coupled to bus bars 690A,Busing “mousetrap” type connectors 692. In some embodiments, othercouplings, such as those described herein or known in the art, are usedto couple heaters 438A,B to bus bars 690A,B. For example, a molten metalor a liquid conducting fluid may fill up the connection space (in thewellbores) to electrically couple the heaters and the bus bars.

FIG. 104 depicts an enlarged view of an embodiment of bus bar 690coupled to heaters 438 with connectors 692. In certain embodiments, busbar 690 includes carbon steel or other electrically conducting metals.In some embodiments, a high electrical conductivity conductor or metalis coupled to or included in bus bar 690. For example, bus bar 690 mayinclude carbon steel with copper cladded to the carbon steel.

In some embodiments, a centralizer or other centralizing device is usedto locate or guide heaters 438 and/or bus bars 690 so that the heatersand bus bars can be coupled. FIG. 105 depicts an enlarged view of anembodiment of bus bar 690 coupled to heater 438 with connectors 692 andcentralizers 558. Centralizers 558 may locate heater 438 and/or bus bar690 so that connectors 692 easily couple the heater and the bus bar.Centralizers 558 may ensure proper spacing of heater 438 and/or bus bar690 so that the heater and the bus bar can be coupled with connectors692. Centralizers 558 may inhibit heater 438 and/or bus bar 690 fromcontacting the sides of the wellbores at or near connectors 692.

FIG. 106 depicts a cross-sectional representation of connector 692coupling to bus bar 690. FIG. 107 depicts a three-dimensionalrepresentation of connector 692 coupling to bus bar 690. Connectors 692are shown in proximity to bus bar 690 (before the connector clampsaround the bus bar). Connector 692 is connected or directly attached tothe heater so that the connector is rotatable around the end of theheater while maintaining electrical contact with the heater. In someembodiments, the connector and the end of the heater are twisted intoposition to align with the bus bar. Connector 692 includes collets 694.Collets 694 are shaped (for example, diagonally cut or helicallyprofiled) so that as the connector is pushed onto bus bar 690, the shapeof the collets rotates the head of the connector as the collets slideover the bus bar. Collets 694 may be spring loaded so that the colletshold down against bus bar 690 after the collets slide over the bus bar.Thus, connector 692 clamps to bus bar 690 using collets 694. Connector692, including collets 694, is made of electrically conductive materialsso that the connector electrically couples bus bar 690 to the heaterattached to the connector.

In some embodiments, an explosive element is added to connector 692,shown in FIGS. 106 and 107. Connector 692 is used to position bus bar690 and the heater in proper positions for explosive bonding of the busbar to the heater. The explosive element may be located on connector692. For example, the explosive element may be located on one or both ofcollets 694. The explosive element may be used to explosively bondconnector 692 to bus bar 690 so that the heater is metallically bondedto the bus bar.

In some embodiment, the explosive bonding is applied along the axialdirection of bus bar 690. In some embodiments, the explosive bondingprocess is a self cleaning process. For example, the explosive bondingprocess may drive out air and/or debris from between components duringthe explosion. In some embodiments, the explosive element is a shapecharge explosive element. Using the shape charge element may focus theexplosive energy in a desired direction.

FIG. 108 depicts an embodiment of three u-shaped heaters with commonoverburden sections coupled to a single three-phase transformer. Incertain embodiments, heaters 438A, 438B, 438C are exposed metal heaters.In some embodiments, heaters 438A, 438B, 438C are exposed metal heaterswith a thin, electrically insulating coating on the heaters. Forexample, heaters 438A, 438B, 438C may be 410 stainless steel, carbonsteel, 347H stainless steel, or other corrosion resistant stainlesssteel rods or tubulars (such as 1″ or 1.25″ diameter rods). The rods ortubulars may have porcelain enamel coatings on the exterior of the rodsto electrically insulate the rods.

In some embodiments, heaters 438A, 438B, 438C are insulated conductorheaters. In some embodiments, heaters 438A, 438B, 438C areconductor-in-conduit heaters. Heaters 438A, 438B, 438C may havesubstantially parallel heating sections in hydrocarbon layer 484.Heaters 438A, 438B, 438C may be substantially horizontal or at anincline in hydrocarbon layer 484. In some embodiments, heaters 438A,438B, 438C enter the formation through common wellbore 428A. Heaters438A, 438B, 438C may exit the formation through common wellbore 428B. Incertain embodiments, wellbores 428A, 428B are uncased (for example, openwellbores) in hydrocarbon layer 484.

Openings 556A, 556B, 556C span between wellbore 428A and wellbore 428B.Openings 556A, 556B, 556C may be uncased openings in hydrocarbon layer484. In certain embodiments, openings 556A, 556B, 556C are formed bydrilling from wellbore 428A and/or wellbore 428B. In some embodiments,openings 556A, 556B, 556C are formed by drilling from each wellbore 428Aand 428B and connecting at or near the middle of the openings. Drillingfrom both sides towards the middle of hydrocarbon layer 484 allowslonger openings to be formed in the hydrocarbon layer. Thus, longerheaters may be installed in hydrocarbon layer 484. For example, heaters438A, 438B, 438C may have lengths of at least about 1500 m, at leastabout 3000 m, or at least about 4500 m.

Having multiple long, substantially horizontal or inclined heatersextending from only two wellbores in hydrocarbon layer 484 reduces thefootprint of wells on the surface needed for heating the formation. Thenumber of overburden wellbores that need to be drilled in the formationis reduced, which reduces capital costs per heater in the formation.Heating the formation with long, substantially horizontal or inclinedheaters also reduces overall heat losses in the overburden when heatingthe formation because of the reduced number of overburden sections usedto treat the formation (for example, losses in the overburden are asmaller fraction of total power supplied to the formation).

In some embodiments, heaters 438A, 438B, 438C are installed in wellbores428A, 428B and openings 556A, 556B, 556C by pulling the heaters throughthe wellbores and the openings from one end to the other. For example,an installation tool may be pushed through the openings and coupled to aheater in wellbore 428A. The heater may then be pulled through theopenings towards wellbore 428B using the installation tool. The heatermay be coupled to the installation tool using a connector such as aclaw, a catcher, or other devices known in the art.

In some embodiments, the first half of an opening is drilled fromwellbore 428A and then the second half of the opening is drilled fromwellbore 428B through the first half of the opening. The drill bit maybe pushed through to wellbore 428A and a first heater may be coupled tothe drill bit to pull the first heater back through the opening andinstall the first heater in the opening. The first heater may be coupledto the drill bit using a connector such as a claw, a catcher, or otherdevices known in the art.

After the first heater is installed, a tube or other guide may be placedin wellbore 428A and/or wellbore 428B to guide drilling of a secondopening. FIG. 109 depicts a top view of an embodiment of heater 438A anddrilling guide 696 in wellbore 428. Drilling guide 696 may be used toguide the drilling of the second opening in the formation and theinstallation of a second heater in the second opening. Insulator 534Amay electrically and mechanically insulate heater 438A from drillingguide 696. Drilling guide 696 and insulator 534A may protect heater 438Afrom being damaged while the second opening is being drilled and thesecond heater is being installed.

After the second heater is installed, drilling guide 696 may be placedin wellbore 428 to guide drilling of a third opening, as shown in FIG.110. Drilling guide 696 may be used to guide the drilling of the thirdopening in the formation and the installation of a third heater in thethird opening. Insulators 534A and 534B may electrically andmechanically insulate heaters 438A and 438B, respectively, from drillingguide 696. Drilling guide 696 and insulators 534A and 534B may protectheaters 438A and 438B from being damaged while the third opening isbeing drilled and the third heater is being installed. After the thirdheater is installed, centralizer 558 may be placed in wellbore 428 toseparate and space heaters 438A, 438B, 438C in the wellbore, as shown inFIG. 111.

In some embodiments, all the openings are formed in the formation andthen the heaters are installed in the formation. In certain embodiments,one of the openings is formed and one of the heaters is installed in theformation before the other openings are formed and the other heaters areinstalled. The first installed heater may be used as a guide during theformation of additional openings. The first installed heater may beenergized to produce an electromagnetic field that is used to guide theformation of the other openings. For example, the first installed heatermay be energized with a bipolar DC current to magnetically guidedrilling of the other openings.

In certain embodiments, heaters 438A, 438B, 438C are coupled to a singlethree-phase transformer 580 at one end of the heaters, as shown in FIG.108. Heaters 438A, 438B, 438C may be electrically coupled in a triadconfiguration, as described herein. In some embodiments, two heaters arecoupled together in a diad configuration, as described herein.Transformer 580 may be a three-phase wye transformer. The heaters mayeach be coupled to one phase of transformer 580. Using three-phase powerto power the heaters may be more efficient than using single-phasepower. Using three-phase connections for the heaters allows the magneticfields of the heaters in wellbore 428A to cancel each other. Thecancelled magnetic fields may allow overburden casing 564A to beferromagnetic (for example, carbon steel) in wellbore 428A. Usingferromagnetic casings in the wellbores may be less expensive and/oreasier to install than non-ferromagnetic casings (such as fiberglasscasings).

In some embodiments, the overburden section of heaters 438A, 438B, 438Care coated with an insulator, such as a polymer or an enamel coating, toinhibit shorting between the overburden sections of the heaters. In someembodiments, only the overburden sections of the heaters in wellbore428A are coated with the insulator as the heater sections in wellbore428B may not have significant electrical losses. In some embodiments,ends of heaters 438A, 438B, 438C in wellbore 428A are at least onediameter of the heaters away from overburden casing 564A so that noinsulator is needed. The ends of heaters 438A, 438B, 438C may be, forexample, centralized in wellbore 428A using a centralizer to keep theheaters the desired distance away from overburden casing 564A.

In some embodiments, the ends of heaters 438A, 438B, 438C passingthrough wellbore 428B are electrically coupled together and groundedoutside of the wellbore, as shown in FIG. 108. The magnetic fields ofthe heaters may cancel each other in wellbore 428B. Thus, overburdencasing 564B may be ferromagnetic (carbon steel) in wellbore 428B. Incertain embodiments, the overburden section of heaters 438A, 438B, 438Care copper rods or tubulars. The build sections of the heaters (thetransition sections between the overburden sections and the heatingsections) may also be made of copper or similar electrically conductivematerial.

In some embodiments, the ends of heaters 438A, 438B, 438C passingthrough wellbore 428B are electrically coupled together inside thewellbore. The ends of the heaters may be coupled inside the wellbore ator near the bottom of the overburden. Coupling the heaters together ator near the overburden reduces electrical losses in the overburdensection of the wellbore.

FIG. 112 depicts an embodiment for coupling ends of heaters 438A, 438B,438C in wellbore 428B. Plate 698 may be located at or near the bottom ofthe overburden section of wellbore 428B. Plate 698 may be have openingssized to allow heaters 438A, 438B, 438C to be inserted through theplate. Plate 698 may be slid down along heaters 438A, 438B, 438C intoposition in wellbore 428B. Plate 698 may be made of copper or anotherelectrically conductive material.

Balls 700 may be placed into the overburden section of wellbore 428B.Plate 698 may allow balls 700 to settle in the overburden section ofwellbore 428B around heaters 438A, 438B, 438C. Balls 700 may be made ofelectrically conductive material such as copper or nickel-plated copper.Balls 700 and plate 698 may electrically couple heaters 438A, 438B, 438Cto each other so that the heaters are grounded. In some embodiments,portions of the heaters above plate 698 (the overburden sections of theheaters) are made of carbon steel while portions of the heaters belowthe plate (build sections of the heaters) are made of copper.

In some embodiments, heaters 438A, 438B, 438C, as depicted in FIG. 108,provide varying heat outputs along the lengths of the heaters. Forexample, heaters 438A, 438B, 438C may have varying dimensions (forexample, thicknesses or diameters) along the lengths of the heater. Thevarying thicknesses may provide different electrical resistances alongthe length of the heater and, thus, different heat outputs along thelength of the heaters.

In some embodiments, heaters 438A, 438B, 438C are divided into two ormore sections of heating. In some embodiments, the heaters are dividedinto repeating sections of different heat outputs (for example,alternating sections of two different heat outputs that are repeated).The repeating sections of different heat outputs may be used, in someembodiments, to heat the formation in stages (for example, in a stagedheating process as described herein). In one embodiment, the halves ofthe heaters closest to wellbore 428A may provide heat in a first sectionof hydrocarbon layer 484 and the halves of the heaters closest towellbore 428B may provide heat in a second section of hydrocarbon layer484. Hydrocarbons in the formation may be mobilized by the heat providedin the first section. Hydrocarbons in the second section may be heatedto higher temperatures than the first section to upgrade thehydrocarbons in the second section (for example, the hydrocarbons may befurther mobilized and/or pyrolyzed). Hydrocarbons from the first sectionmay move, or be moved, into the second section for the upgrading. Forexample, a drive fluid may be provided through wellbore 428A to move thefirst section mobilized hydrocarbons to the second section.

In some embodiments, more than three heaters extend from wellbore 428Aand/or 428B. If multiples of three heaters extend from the wellbores andare coupled to transformer 580, the magnetic fields may cancel in theoverburden sections of the wellbores as in the case of three heaters inthe wellbores. For example, six heaters may be coupled to transformer580 with two heaters coupled to each phase of the transformer to cancelthe magnetic fields in the wellbores.

In some embodiments, multiple heaters extend from one wellbore indifferent directions. FIG. 113 depicts a schematic of an embodiment ofmultiple heaters extending in different directions from wellbore 428A.Heaters 438A, 438B, 438C may extend to wellbore 428B. Heaters 438D,438E, 438F may extend to wellbore 428C in the opposite direction ofheaters 438A, 438B, 438C. Heaters 438A, 438B, 438C and heaters 438D,438E, 438F may be coupled to a single, three-phase transformer so thatmagnetic fields are cancelled in wellbore 428A.

In some embodiments, heaters 438A, 438B, 438C may have different heatoutputs from heaters 438D, 438E, 438F so that hydrocarbon layer 484 isdivided into two heating sections with different heating rates and/ortemperatures (for example, a mobilization and a pyrolyzation section).In some embodiments, heaters 438A, 438B, 438C and/or heaters 438D, 438E,438F may have heat outputs that vary along the lengths of the heaters tofurther divide hydrocarbon layer 484 into more heating sections. In someembodiments, additional heaters may extend from wellbore 428B and/orwellbore 428C to other wellbores in the formation as shown by the dashedlines in FIG. 113.

In some embodiments, multiple levels of heaters extend between twowellbores. FIG. 114 depicts a schematic of an embodiment of multiplelevels of heaters extending between wellbore 428A and wellbore 428B.Heaters 438A, 438B, 438C may provide heat to a first level ofhydrocarbon layer 484. Heaters 438D, 438E, 438F may branch off andprovide heat to a second level of hydrocarbon layer 484. Heaters 438G,438H, 438I may further branch off and provide heat to a third level ofhydrocarbon layer 484. In some embodiments, heaters 438A, 438B, 438C,heaters 438D, 438E, 438F, and heaters 438G, 438H, 438I provide heat tolevels in the formation with different properties. For example, thedifferent groups of heaters may provide different heat outputs to levelswith different properties in the formation so that the levels are heatedat or about the same rate.

In some embodiments, the levels are heated at different rates to createdifferent heating zones in the formation. For example, the first level(heated by heaters 438A, 438B, 438C) may be heated so that hydrocarbonsare mobilized, the second level (heated by heaters 438D, 438E, 438F) maybe heated so that hydrocarbons are somewhat upgraded from the firstlevel, and the third level (heated by heaters 438G, 438H, 438I) may beheated to pyrolyze hydrocarbons. As another example, the first level maybe heated to create gases and/or drive fluid in the first level andeither the second level or the third level may be heated to mobilizeand/or pyrolyze fluids or just to a level to allow production in thelevel. In addition, heaters 438A, 438B, 438C, heaters 438D, 438E, 438F,and/or heaters 438G, 438H, 438I may have heat outputs that vary alongthe lengths of the heaters to further divide hydrocarbon layer 484 intomore heating sections.

FIG. 115 depicts an embodiment of a u-shaped heater that has aninductively energized tubular. Heater 438 includes electrical conductor572 and tubular 702 in an opening that spans between wellbore 428A andwellbore 428B. In certain embodiments, electrical conductor 572 and/orthe current carrying portion of the electrical conductor is electricallyinsulated from tubular 702. Electrical conductor 572 and/or the currentcarrying portion of the electrical conductor is electrically insulatedfrom tubular 702 such that electrical current does not flow from theelectrical conductor to the tubular, or vice versa (for example, thetubular is not electrically connected to the electrical conductor).

In some embodiments, electrical conductor 572 is centralized insidetubular 702 (for example, using centralizers 558 or other supportstructures, as shown in FIG. 116). Centralizers 558 may electricallyinsulate electrical conductor 572 from tubular 702. In some embodiments,tubular 702 contacts electrical conductor 572. For example, tubular 702may hang, drape, or otherwise touch electrical conductor 572. In someembodiments, electrical conductor 572 includes electrical insulation(for example, magnesium oxide or porcelain enamel) that insulates thecurrent carrying portion of the electrical conductor from tubular 702.The electrical insulation inhibits current from flowing between thecurrent carrying portion of electrical conductor 572 and tubular 702 ifthe electrical conductor and the tubular are in physical contact witheach other.

In some embodiments, electrical conductor 572 is an exposed metalconductor heater or a conductor-in-conduit heater. In certainembodiments, electrical conductor 572 is an insulated conductor such asa mineral insulated conductor. The insulated conductor may have a coppercore, copper alloy core, or a similar electrically conductive, lowresistance core that has low electrical losses. In some embodiments, thecore is a copper core with a diameter between about 0.5″ (1.27 cm) andabout 1″ (2.54 cm). The sheath or jacket of the insulated conductor maybe a non-ferromagnetic, corrosion resistant steel such as 347 stainlesssteel, 625 stainless steel, 825 stainless steel, 304 stainless steel, orcopper with a protective layer (for example, a protective cladding). Thesheath may have an outer diameter of between about 1″ (2.54 cm) andabout 1.25″ (3.18 cm).

In some embodiments, the sheath or jacket of the insulated conductor isin physical contact with the tubular 702 (for example, the tubular is inphysical contact with the sheath along the length of the tubular) or thesheath is electrically connected to the tubular. In such embodiments,the electrical insulation of the insulated conductor electricallyinsulates the core of the insulated conductor from the jacket and thetubular. FIG. 117 depicts an embodiment of an induction heater with thesheath of an insulated conductor in electrical contact with tubular 702.Electrical conductor 572 is the insulated conductor. The sheath of theinsulated conductor is electrically connected to tubular 702 usingelectrical contactors 704. In some embodiments, electrical contactors704 are sliding contactors. In certain embodiments, electricalcontactors 704 electrically connect the sheath of the insulatedconductor to tubular 702 at or near the ends of the tubular.Electrically connecting at or near the ends of tubular 702 substantiallyequalizes the voltage along the tubular with the voltage along thesheath of the insulated conductor. Equalizing the voltages along tubular702 and along the sheath may inhibit arcing between the tubular and thesheath.

Tubular 702, shown in FIGS. 115, 116, and 117, may be ferromagnetic orinclude ferromagnetic materials. Tubular 702 may have a thickness suchthat when electrical conductor 572 is energized with time-varyingcurrent, the electrical conductor induces electrical current flow on thesurfaces of tubular 702 due to the ferromagnetic properties of thetubular (for example, current flow is induced on both the inside of thetubular and the outside of the tubular). Current flow is induced in theskin depth of the surfaces of tubular 702 so that the tubular operatesas a skin effect heater. In certain embodiments, the induced currentcirculates axially (longitudinally) on the inside and/or outsidesurfaces of tubular 702. Longitudinal flow of current through electricalconductor 572 induces primarily longitudinal current flow in tubular 702(the majority of the induced current flow is in the longitudinaldirection in the tubular). Having primarily longitudinal induced currentflow in tubular 702 may provide a higher resistance per foot than if theinduced current flow is primarily angular current flow.

In certain embodiments, current flow in tubular 702 is induced with lowfrequency current in electrical conductor 572 (for example, from 50 Hzor 60 Hz up to about 1000 Hz). In some embodiments, induced currents onthe inside and outside surfaces of tubular 702 are substantially equal.

In certain embodiments, tubular 702 has a thickness that is greater thanthe skin depth of the ferromagnetic material in the tubular at or nearthe Curie temperature of the ferromagnetic material or at or near thephase transformation temperature of the ferromagnetic material. Forexample, tubular 702 may have a thickness of at least 2.1, at least 2.5times, at least 3 times, or at least 4 times the skin depth of theferromagnetic material in the tubular near the Curie temperature or thephase transformation temperature of the ferromagnetic material. Incertain embodiments, tubular 702 has a thickness of at least 2.1 times,at least 2.5 times, at least 3 times, or at least 4 times the skin depthof the ferromagnetic material in the tubular at about 50° C. below theCurie temperature or the phase transformation temperature of theferromagnetic material.

In certain embodiments, tubular 702 is carbon steel. In someembodiments, tubular 702 is coated with a corrosion resistant coating(for example, porcelain or ceramic coating) and/or an electricallyinsulating coating. In some embodiments, electrical conductor 572 has anelectrically insulating coating. Examples of the electrically insulatingcoating on tubular 702 and/or electrical conductor 572 include, but arenot limited to, a porcelain enamel coating, alumina coating, oralumina-titania coating. In some embodiments, tubular 702 and/orelectrical conductor 572 are coated with a coating such as polyethyleneor another suitable low friction coefficient coating that may melt ordecompose when the heater is energized. The coating may facilitateplacement of the tubular and/or the electrical conductor in theformation.

In some embodiments, tubular 702 includes corrosion resistantferromagnetic material such as, but not limited to, 410 stainless steel,446 stainless steel, T/P91 stainless steel, T/P92 stainless steel, alloy52, alloy 42, and Invar 36. In some embodiments, tubular 702 is astainless steel tubular with cobalt added (for example, between about 3%by weight and about 10% by weight cobalt added) and/or molybdenum (forexample, about 0.5% molybdenum by weight).

At or near the Curie temperature or the phase transformation temperatureof the ferromagnetic material in tubular 702, the magnetic permeabilityof the ferromagnetic material decreases rapidly. When the magneticpermeability of tubular 702 decreases at or near the Curie temperatureor the phase transformation temperature, there is little or no currentflow in the tubular because, at these temperatures, the tubular isessentially non-ferromagnetic and electrical conductor 572 is unable toinduce current flow in the tubular. With little or no current flow intubular 702, the temperature of the tubular will drop to lowertemperatures until the magnetic permeability increases and the tubularbecomes ferromagnetic. Thus, tubular 702 self-limits at or near theCurie temperature or the phase transformation temperature and operatesas a temperature limited heater due to the ferromagnetic properties ofthe ferromagnetic material in the tubular. Because current is induced intubular 702, the turndown ratio may be higher and the drop in currentsharper for the tubular than for temperature limited heaters that applycurrent directly to the ferromagnetic material. For example, heaterswith current induced in tubular 702 may have turndown ratios of at leastabout 5, at least about 10, or at least about 20 while temperaturelimited heaters that apply current directly to the ferromagneticmaterial may have turndown ratios that are at most about 5.

When current is induced in tubular 702, the tubular provides heat tohydrocarbon layer 484 and defines the heating zone in the hydrocarbonlayer. In certain embodiments, tubular 702 heats to temperatures of atleast about 300° C., at least about 500° C., or at least about 700° C.Because current is induced on both the inside and outside surfaces oftubular 702, the heat generation of the tubular is increased as comparedto temperature limited heaters that have current directly applied to theferromagnetic material and current flow is limited to one surface. Thus,less current may be provided to electrical conductor 572 to generate thesame heat as heaters that apply current directly to the ferromagneticmaterial. Using less current in electrical conductor 572 decreases powerconsumption and reduces power losses in the overburden of the formation.

In certain embodiments, tubulars 702 have large diameters. The largediameters may be used to equalize or substantially equalize highpressures on the tubular from either the inside or the outside of thetubular. In some embodiments, tubular 702 has a diameter in a rangebetween about 1.5″ (about 3.8 cm) and about 5″ (about 12.7 cm). In someembodiments, tubular 702 has a diameter in a range between about 3 cmand about 13 cm, between about 4 cm and about 12 cm, or between about 5cm and about 11 cm. Increasing the diameter of tubular 702 may providemore heat output to the formation by increasing the heat transfersurface area of the tubular.

In some embodiments, fluids flow through the annulus of tubular 702 orthrough another conduit inside the tubular. The fluids may be used, forexample, to cool down the heater, to recover heat from the heater,and/or to initially heat the formation before energizing the heater.

In certain embodiments, tubular 702 has surfaces that are shaped toincrease the resistance of the tubular. FIG. 118 depicts an embodimentof a heater with tubular 702 having radial grooved surfaces. Heater 438may include electrical conductors 572A,B coupled to tubular 702.Electrical conductors 572A,B may be insulated conductors. Electricalcontactors 704 may electrically and physically couple electricalconductors 572A,B to tubular 702. In certain embodiments, electricalcontactors 704 are attached to ends of electrical conductors 572A,B.Electrical contactors 704 have a shape such that when the ends ofelectrical conductors 572A,B are pushed into the ends of tubular 702,the electrical contactors physically and electrically couple theelectrical conductors to the tubular. For example, electrical contactors704 may be cone shaped.

In certain embodiments, tubular 702 includes grooves 706. Grooves 706may be formed as a part of the surface of tubular 702 (for example, thetubular is formed with grooved surfaces) or the grooves may be formed byadding or removing (for example, milling) material on the surface of thetubular. For example, grooves 706 may be located on a piece of tubularthat is welded to tubular 702.

In certain embodiments, grooves 706 are on the outer surface of tubular702. In some embodiments, the grooves are on the inner surface of thetubular. In some embodiments, the grooves are on both the inner andouter surfaces of the tubular.

In certain embodiments, grooves 706 are radial grooves (grooves thatwrap around the circumference of tubular 702). In certain embodiments,grooves 706 are straight, angled, or spiral grooves or protrusions. Insome embodiments, grooves 706 are evenly spaced grooves along thesurface of tubular 702. In some embodiments, grooves 706 are part of athreaded surface on tubular 702 (the grooves are formed as a windingthread on the surface). Grooves 706 may have a variety of shapes asdesired. For example, grooves 706 may have square edges, rectangularedges, v-shaped edges, u-shaped edges, or have rounded edges.

Grooves 706 increase the effective resistance of tubular 702 byincreasing the path length of induced current on the surface of thetubular. Grooves 706 increase the effective resistance of tubular 702 ascompared to a tubular with the same inside and outside diameters withsmooth surfaces. Because induced current travels axially, the inducedcurrent has to travel up and down the grooves along the surface of thetubular. Thus, the depth of grooves 706 may be varied to provide aselected resistance in tubular 702. For example, increasing the groovesdepth increases the path length and the resistance.

Increasing the resistance of tubular 702 with grooves 706 increases theheat generation of the tubular as compared to a tubular with smoothsurfaces. Thus, the same electrical current in electrical conductor 572will provide more heat output in the radial grooved surface tubular thanthe smooth surface tubular. Therefore, to provide the same heat outputwith the radial grooved surface tubular as the smooth surface tubular,less current is needed in electrical conductor 572 with the radialgrooved surface tubular.

In some embodiments, grooves 706 are filled with materials thatdecompose at lower temperatures to protect the grooves duringinstallation of tubular 702. For example, grooves 706 may be filled withpolyethylene or asphalt. The polyethylene or asphalt may melt and/ordesorb when heater 438 reaches normal operating temperatures of theheater.

Heater 438, shown in FIG. 118, generates heat when current is applieddirectly to tubular 702. Current is provided to tubular 702 usingelectrical conductors 572A,B. It is to be understood that grooves 706may be used in other embodiments of tubulars 702 described herein toincrease the resistance of such tubulars. For example, grooves 706 maybe used in embodiments of tubulars 702 depicted in FIGS. 115, 116, and117.

FIG. 119 depicts an embodiment of heater 438 divided into tubularsections to provide varying heat outputs along the length of the heater.Heater 438 may include tubular sections 702A, 702B, and 702C that havedifferent properties to provide different heat outputs in each tubularsection. Examples of properties that may be varied include, but are notlimited to, thicknesses, diameters, cross-sectional areas, resistances,materials, number of grooves, depth of grooves. The different propertiesin tubular sections 702A, 702B, and 702C may provide different maximumoperating temperatures (for example, different Curie temperatures orphase transformation temperatures) along the length of heater 438. Thedifferent maximum temperatures of the tubular sections providesdifferent heat outputs from the tubular sections.

Providing different heat outputs along heater 438 may provide differentheating sections in one or more hydrocarbon layers. For example, heater438 may be divided into two or more sections of heating to providedifferent heat outputs to different sections of a hydrocarbon layerand/or different hydrocarbon layers.

In one embodiment, a first portion of heater 438 may provide heat to afirst section of the hydrocarbon layer and a second portion of theheater may provide heat to a second section of the hydrocarbon layer.Hydrocarbons in the first section may be mobilized by the heat providedby the first portion of the eater. Hydrocarbons in the second sectionmay be heated by the second portion of the heater to a highertemperature than the first section. The higher temperature in the secondsection may upgrade hydrocarbons in the second section relative to thefirst section. For example, the hydrocarbons may be mobilized,visbroken, and/or pyrolyzed in the second section. Hydrocarbons from thefirst section may be moved into the second section by, for example, adrive fluid provided to the first section. As another example, heater438 may have end sections that provide higher heat outputs to counteractheat losses at the ends of the heater to maintain a more constanttemperature in the heated portion of the formation.

In certain embodiments, three, or multiples of three, electricalconductors enter and exit the formation through common wellbores withtubulars surrounding the electrical conductors in the portion of theformation to be heated. FIG. 120 depicts an embodiment of threeelectrical conductors 572A,B,C entering the formation through firstcommon wellbore 428A and exiting the formation through second commonwellbore 428C with three tubulars 702A,B,C surrounding the electricalconductors in hydrocarbon layer 484. In some embodiments, electricalconductors 572A,B,C are powered by a single, three-phase wyetransformer. Tubulars 702A,B,C and portions of electrical conductors572A,B,C may be in three separate wellbores in hydrocarbon layer 484(for example, three openings 556A, 556B, 556C depicted in FIG. 108). Thethree separate wellbores may be formed by drilling the wellbores fromfirst common wellbore 428A to second common wellbore 428B, vice versa,or drilling from both common wellbores and connecting the drilledopenings in the hydrocarbon layer.

Having multiple induction heaters extending from only two wellbores inhydrocarbon layer 484 reduces the footprint of wells on the surfaceneeded for heating the formation. The number of overburden wellboresdrilled in the formation is reduced, which reduces capital costs perheater in the formation. Power losses in the overburden may be a smallerfraction of total power supplied to the formation because of the reducednumber of wells through the overburden used to treat the formation. Inaddition, power losses in the overburden may be smaller because thethree phases in the common wellbores substantially cancel each other andinhibit induced currents in the casings or other structures of thewellbores.

In some embodiments, three, or multiples of three, electrical conductorsand tubulars are located in separate wellbores in the formation. FIG.121 depicts an embodiment of three electrical conductors 572A,B,C andthree tubulars 702A,B,C in separate wellbores in the formation.Electrical conductors 572A,B,C may be powered by single, three-phase wyetransformer 580 with each electrical conductor coupled to one phase ofthe transformer. In some embodiments, the single, three-phase wyetransformer is used to power 6, 9, 12, or other multiples of three ofelectrical conductors. Connecting multiples of three electricalconductors to the single, three-phase wye transformer may reduceequipment costs for providing power to the induction heaters.

In some embodiments, two, or multiples of two, electrical conductorsenter the formation from a first common wellbore and exit the formationfrom a second common wellbore with tubulars surrounding each electricalconductor in the hydrocarbon layer. The multiples of two electricalconductors may be powered by a single, two-phase transformer. In suchembodiments, the electrical conductors may be homogenous electricalconductors (for example, insulated conductors using the same materialsthroughout) in the overburden sections and heating sections of theinsulated conductor. The reverse flow of current in the overburdensections may reduce power losses in the overburden sections of thewellbores because the currents reduce or cancel inductive effects in theoverburden sections.

In certain embodiments, tubulars 702 depicted in FIGS. 115-120 includemultiple layers of ferromagnetic materials separated by electricalinsulators. FIG. 122 depicts an embodiment of a multilayered inductiontubular. Tubular 702 includes ferromagnetic layers 708A,B,C separated byelectrical insulators 534A,B. Three ferromagnetic layers and two layersof electrical insulators are shown in FIG. 122. Tubular 702 may includeadditional ferromagnetic layers and/or electrical insulators as desired.For example, the number of layers may be chosen to provide a desiredheat output from the tubular.

Ferromagnetic layers 708A,B,C are electrically insulated from electricalconductor 572 by, for example, an air gap. Ferromagnetic layers 708A,B,Care electrically insulated from each other by electrical insulator 534Aand electrical insulator 534B. Thus, direct flow of current is inhibitedbetween ferromagnetic layers 708A,B,C and electrical conductor 572. Whencurrent is applied to electrical conductor 572, electrical current flowis induced in ferromagnetic layers 708A,B,C because of the ferromagneticproperties of the layers. Having two or more ferromagnetic layersprovides multiple current induction loops for the induced current. Themultiple current induction loops may effectively appear as electricalloads in series to a power source for electrical conductor 572. Themultiple current induction loops may increase the heat generation perunit length of tubular 702 as compared to a tubular with only onecurrent induction loop. For the same heat output, the tubular withmultiple layers may have a higher voltage and lower current as comparedto the single layer tubular.

In certain embodiments, ferromagnetic layers 708A,B,C include the sameferromagnetic material. In some embodiments, ferromagnetic layers708A,B,C include different ferromagnetic materials. Properties offerromagnetic layers 708A,B,C may be varied to provide different heatoutputs from the different layers. Examples of properties offerromagnetic layers 708A,B,C that may be varied include, but are notlimited to, ferromagnetic material and thicknesses of the layers.

Electrical insulators 534A and 534B may be magnesium oxide, porcelainenamel, and/or another suitable electrical insulator. The thicknessesand/or materials of electrical insulators 534A and 534B may be varied toprovide different operating parameters for tubular 702.

In some embodiments, fluids are circulated through tubulars 702 depictedin FIGS. 115-120. In some embodiments, fluids are circulated through thetubulars to add heat to the formation. For example, fluids may becirculated through the tubulars to preheat the formation prior toenergizing the tubulars (providing current to the heating system). Insome embodiments, fluids are circulated through the tubulars to recoverheat from the formation. The recovered heat may be used to provide heatto other portions of the formation and/or surface processes used totreat fluids produced from the formation.

In certain embodiments, insulated conductors are operated as inductionheaters. FIG. 123 depicts a cross-sectional end view of an embodiment ofinsulated conductor 574 that is used as an induction heater. FIG. 124depicts a cross-sectional side view of the embodiment of depicted inFIG. 123. Insulated conductor 574 includes core 542, electricalinsulator 534, and jacket 540. Core 542 may be copper or anothernon-ferromagnetic electrical conductor with low resistance that provideslittle or no heat output. Electrical insulator 534 is magnesium oxide oranother suitable electrical insulator that inhibits arcing at highvoltages.

Jacket 540 includes at least one ferromagnetic material. In certainembodiments, jacket 540 includes carbon steel or another ferromagneticsteel (for example, 410 stainless steel, 446 stainless steel, T/P91stainless steel, T/P92 stainless steel, alloy 52, alloy 42, and Invar36). In some embodiments, jacket 540 includes an outer layer ofcorrosion resistant material (for example, stainless steel such as 347Hstainless steel or 304 stainless steel). The outer layer may be clad tothe ferromagnetic material or otherwise coupled to the ferromagneticmaterial using methods known in the art.

In certain embodiments, jacket 540 has a thickness of at least about 2skin depths of the ferromagnetic material in the jacket. In someembodiments, jacket 540 has a thickness of at least about 3 skin depths,at least about 4 skin depths, or at least about 5 skin depths.Increasing the thickness of jacket 540 may increase the heat output frominsulated conductor 574.

In one embodiment, core 542 is copper with a diameter of about 0.5″(1.27 cm), electrical insulator 534 is magnesium oxide with a thicknessof about 0.20″ (0.5 cm) (the outside diameter is about 0.9″ (2.3 cm)),and jacket 540 is carbon steel with an outside diameter of about 1.6″(4.1 cm) (the thickness is about 0.35″ (0.88 cm)). A thin layer (about0.1″ (0.25 cm) thickness (outside diameter of about 1.7″ (4.3 cm)) ofcorrosion resistant material 347H stainless steel may be clad on theoutside of jacket 540.

In another embodiment, core 542 is copper with a diameter of about0.338″ (0.86 cm), electrical insulator 534 is magnesium oxide with athickness of about 0.096″ (0.24 cm) (the outside diameter is about 0.53″(1.3 cm)), and jacket 540 is carbon steel with an outside diameter ofabout 1.13″ (2.9 cm) (the thickness is about 0.30″ (0.76 cm)). A thinlayer (about 0.065″ (0.17 cm) thickness (outside diameter of about 1.26″(3.2 cm)) of corrosion resistant material 347H stainless steel may beclad on the outside of jacket 540.

In another embodiment, core 542 is copper, electrical insulator 534 ismagnesium oxide, and jacket 540 is a thin layer of copper surrounded bycarbon steel. Core 542, electrical insulator 534, and the thin copperlayer of jacket 540 may be obtained as a single piece of insulatedconductor. Such insulated conductors may be obtained as long pieces ofinsulated conductors (for example, lengths of about 500′ (about 150 m)or more). The carbon steel layer of jacket 540 may be added by drawingdown the carbon steel over the long insulated conductor. Such aninsulated conductor may only generate heat on the outside of jacket 540as the thin copper layer in the jacket shorts to the inside surface ofthe jacket.

In some embodiments, jacket 540 is made of multiple layers offerromagnetic material. The multiple layers may be the sameferromagnetic material or different ferromagnetic materials. Forexample, in one embodiment, jacket 540 is a 0.35″ (0.88 cm) thick carbonsteel jacket made from three layers of carbon steel. The first andsecond layers are 0.10″ (0.25 cm) thick and the third layer is 0.15″(0.38 cm) thick. In another embodiment, jacket 540 is a 0.3″ (0.76 cm)thick carbon steel jacket made from three 0.10″ (0.25 cm) thick layersof carbon steel.

In certain embodiments, jacket 540 and core 542 are electricallyinsulated such that there is no direct electrical connection between thejacket and the core. Core 542 may be electrically coupled to a singlepower source with each end of the core being coupled to one pole of thepower source. For example, insulated conductor 574 may be a u-shapedheater located in a u-shaped wellbore with each end of core 542 beingcoupled to one pole of the power source.

When core 542 is energized with time-varying current, the core induceselectrical current flow on the surfaces of jacket 540 (as shown by thearrows in FIG. 124) due to the ferromagnetic properties of theferromagnetic material in the jacket. In certain embodiments, currentflow is induced on both the inside and outside surfaces of jacket 540.In these induction heater embodiments, jacket 540 operates as theheating element of insulated conductor 574.

At or near the Curie temperature or the phase transformation temperatureof the ferromagnetic material in jacket 540, the magnetic permeabilityof the ferromagnetic material decreases rapidly. When the magneticpermeability of jacket 540 decreases at or near the Curie temperature orthe phase transformation temperature, there is little or no current flowin the jacket because, at these temperatures, the jacket is essentiallynon-ferromagnetic and core 542 is unable to induce current flow in thetubular. With little or no current flow in jacket 540, the temperatureof the jacket will drop to lower temperatures until the magneticpermeability increases and the jacket becomes ferromagnetic. Thus,jacket 540 self-limits at or near the Curie temperature or the phasetransformation temperature and insulated conductor 574 operates as atemperature limited heater due to the ferromagnetic properties of thejacket. Because current is induced in jacket 540, the turndown ratio maybe higher and the drop in current sharper for the jacket than if currentis directly applied to the jacket.

In certain embodiments, portions of jacket 540 in the overburden of theformation do not include ferromagnetic material (for example, arenon-ferromagnetic). Having the overburden portions of jacket 540 made ofnon-ferromagnetic material inhibits current induction in the overburdenportions of the jackets. Power losses in the overburden are inhibited orreduced by inhibiting current induction in the overburden portions.

FIG. 125 depicts a cross-sectional view of an embodiment of two-leginsulated conductor 574 that is used as an induction heater. FIG. 126depicts an end cross-sectional view of the embodiment of depicted inFIG. 125. Insulated conductor 574 is a two-leg insulated conductor thatincludes two cores 542A,B; two electrical insulators 534A,B; and twojackets 540A,B. The two legs of insulated conductor 574 may be inphysical contact with each other such that jacket 540A contacts jacket540B along their lengths. Cores 542A,B; electrical insulators 534A,B;and jackets 540A,B may include materials such as those used in theembodiment of insulated conductor 574 depicted in FIGS. 124 and 123.

As shown in FIG. 126, core 542A and core 542B are coupled to transformer580 and terminal block 634. Thus, core 542A and core 542B areelectrically coupled in series such that current in core 542A flows inan opposite direction from current in core 542B, as shown by the arrowsin FIG. 126. Current flow in cores 542A,B induces current flow injackets 540A,B, respectively, as shown by the arrows in FIG. 126.

In certain embodiments, portions of jacket 540A and/or jacket 540B arecoated with an electrically insulating coating (for example, a porcelainenamel coating, alumina coating, and/or alumina-titania coating). Theelectrically insulating coating may inhibit the currents in one jacketfrom affecting current in the other jacket or vice versa (for example,current in one jacket cancelling out current in the other jacket).Electrically insulating the jackets from each other may inhibit theturndown ratio of the heater from being reduced by the interaction ofinduced currents in the jackets.

Because core 542A and core 542B are electrically coupled in series to asingle transformer (transformer 580), insulated conductor 574 may belocated in a wellbore that terminates in the formation (for example, awellbore with a single surface opening such as an L-shaped or J-shapedwellbore). Insulated conductor 574, as depicted in FIG. 126, may beoperated as a subsurface termination induction heater with electricalconnections between the heater and the power source (the transformer)being made through one surface opening.

Portions of jackets 540A,B in the overburden of the formation may benon-ferromagnetic to inhibit induction currents in the overburdenportion of the jackets. Inhibiting induction currents in the overburdenportion of the jackets inhibits inductive heating and/or power losses inthe overburden. Induction effects in other structures in the overburdenthat surround insulated conductor 574 (for example, overburden casings)may be inhibited because the current in core 542A flows in an oppositedirection from the current in core 542B.

FIG. 127 depicts a cross-sectional view of an embodiment of amultilayered insulated conductor that is used as an induction heater.Insulated conductor 574 includes core 542 surrounded by electricalinsulator 534A and jacket 540A. Electrical insulator 534A and jacket540A comprise a first layer of insulated conductor 574. The first layeris surrounded by a second layer that includes electrical insulator 534Band jacket 540B. Two layers of electrical insulators and jackets areshown in FIG. 127. The insulated conductor may include additional layersas desired. For example, the number of layers may be chosen to provide adesired heat output from the insulated conductor.

Jacket 540A and jacket 540B are electrically insulated from core 542 andeach other by electrical insulator 534A and electrical insulator 534B.Thus, direct flow of current is inhibited between jacket 540A and jacket540B and core 542. When current is applied to core 542, electricalcurrent flow is induced in both jacket 540A and jacket 540B because ofthe ferromagnetic properties of the jackets. Having two or more layersof electrical insulators and jackets provides multiple current inductionloops. The multiple current induction loops may effectively appear aselectrical loads in series to a power source for insulated conductor574. The multiple current induction loops may increase the heatgeneration per unit length of insulated conductor 574 as compared to aninsulated conductor with only one current induction loop. For the sameheat output, the insulated conductor with multiple layers may have ahigher voltage and lower current as compared to the single layerinsulated conductor.

In certain embodiments, jacket 540A and jacket 540B include the sameferromagnetic material. In some embodiments, jacket 540A and jacket 540Binclude different ferromagnetic materials. Properties of jacket 540A andjacket 540B may be varied to provide different heat outputs from thedifferent layers. Examples of properties of jacket 540A and jacket 540Bthat may be varied include, but are not limited to, ferromagneticmaterial and thicknesses of the layers.

Electrical insulators 534A and 534B may be magnesium oxide, porcelainenamel, and/or another suitable electrical insulator. The thicknessesand/or materials of electrical insulators 534A and 534B may be varied toprovide different operating parameters for insulated conductor 574.

FIG. 128 depicts an end view of an embodiment of three insulatedconductors 574 located in a coiled tubing conduit and used as inductionheaters. Insulated conductors 574 may each be, for example, theinsulated conductor depicted in FIGS. 124, 123, and 127. The cores ofinsulated conductors 574 may be coupled to each other such that theinsulated conductors are electrically coupled in a three-phase wyeconfiguration. FIG. 129 depicts a representation of cores 542 ofinsulated conductors 574 being coupled together at their ends.

As shown in FIG. 128, insulated conductors 574 are located in tubular702. Tubular 702 may be a coiled tubing conduit or other coiled tubingtubular or casing. Insulated conductors 574 may be in a spiral or helixformation inside tubular 702 to reduce stresses on the insulatedconductors when the insulated conductors are coiled, for example, on acoiled tubing reel. Tubular 702 allows the insulated conductors to beinstalled in the formation using a coiled tubing rig and protects theinsulated conductors during installation into the formation.

FIG. 130 depicts an end view of an embodiment of three insulatedconductors 574 located on a support member and used as inductionheaters. Insulated conductors 574 may each be, for example, theinsulated conductor depicted in FIGS. 124, 123, and 127. The cores ofinsulated conductors 574 may be coupled to each other such that theinsulated conductors are electrically coupled in a three-phase wyeconfiguration. For example, the cores may be coupled together as shownin FIG. 129.

As shown in FIG. 130, insulated conductors 574 are coupled to supportmember 548. Support member 548 provides support for insulated conductors574. Insulated conductors 574 may be wrapped around support member 548in a spiral or helix formation. In some embodiments, support member 548includes ferromagnetic material. Current flow may be induced in theferromagnetic material of support member 548. Thus, support member 548may generate some heat in addition to the heat generated in the jacketsof insulated conductors 574.

In certain embodiments, insulated conductors 574 are held together onsupport member 548 with band 584. Band 584 may be stainless steel oranother non-corrosive material. In some embodiments, band 584 includes aplurality of bands that hold together insulated conductors 574. Thebands may be periodically placed around insulated conductors 574 to holdthe conductors together.

In some embodiments, jacket 540, depicted in FIGS. 124 and 123, orjackets 540A,B, depicted in FIG. 126, include grooves or otherstructures on the outer surface and/or the inner surface of the jacketto increase the effective resistance of the jacket. Increasing theresistance of jacket 540 and/or jackets 540A,B with grooves increasesthe heat generation of the jackets as compared to jackets with smoothsurfaces. Thus, the same electrical current in core 542 and/or cores542A,B will provide more heat output in the grooved surface jackets thanthe smooth surface jackets.

In some embodiments, jacket 540, depicted in FIGS. 124 and 123, orjackets 540A,B, depicted in FIG. 126, are divided into sections toprovide varying heat outputs along the length of the heaters. Forexample, jacket 540 and/or jackets 540A,B may be divided into sectionssuch as tubular sections 702A, 702B, and 702C, depicted in FIG. 119. Thesections of the jackets 540 depicted in FIGS. 124, 123, and 126 may havedifferent properties to provide different heat outputs in each section.Examples of properties that may be varied include, but are not limitedto, thicknesses, diameters, resistances, materials, number of grooves,depth of grooves. The different properties in the sections may providedifferent maximum operating temperatures (for example, different Curietemperatures or phase transformation temperatures) along the length ofinsulated conductor 574. The different maximum temperatures of thesections provides different heat outputs from the sections.

In some embodiments, portions of casings in the overburden sections ofheater wellbores have surfaces that are shaped to increase the effectivediameter of the casing. Casings in the overburden sections of heaterwellbores may include, but not be limited to, overburden casings, heatercasings, heater tubulars, and/or jackets of insulated conductors.Increasing the effective diameter of the casing may reduce inductiveeffects in the casing when current used to power heater(s) below theoverburden is transmitted through the casing (for example, when onephase of power is being transmitted through the overburden section).When current is transmitted in only one direction through theoverburden, the current may induce other currents in ferromagnetic orother electrically conductive materials such as those found inoverburden casings. These induced currents may provide undesired powerlosses and/or undesired heating in the overburden of the formation.

FIG. 131 depicts an embodiment of casing 710 having a grooved orcorrugated surface. In certain embodiments, casing 710 includes grooves712. In some embodiments, grooves 712 are corrugations or includecorrugations. Grooves 712 may be formed as a part of the surface ofcasing 710 (for example, the casing is formed with grooved surfaces) orthe grooves may be formed by adding or removing (for example, milling)material on the surface of the casing. For example, grooves 712 may belocated on a long piece of tubular that is welded to casing 710.

In certain embodiments, grooves 712 are on the outer surface of casing710. In some embodiments, grooves 712 are on the inner surface of casing710. In some embodiments, grooves 712 are on both the inner and outersurfaces of casing 710.

In certain embodiments, grooves 712 are axial grooves (grooves that golongitudinally along the length of casing 710). In certain embodiments,grooves 712 are straight, angled, or longitudinally spiral grooves orprotrusions. In some embodiments, grooves 712 are substantially axialgrooves or spiral grooves with a significant longitudinal component. Insome embodiments, grooves 712 extend substantially axially along thelength of casing 710. In some embodiments, grooves 712 are evenly spacedgrooves along the surface of casing 710. Grooves 712 may have a varietyof shapes as desired. For example, grooves 712 may have square edges,v-shaped edges, u-shaped edges, rectangular edges, or have roundededges.

Grooves 712 increase the effective circumference of casing 710. Grooves712 increase the effective circumference of casing 710 as compared tothe circumference of a casing with the same inside and outside diametersand smooth surfaces. The depth of grooves 712 may be varied to provide aselected effective circumference of casing 710. For example, axialgrooves that are ¼″ wide and ¼″ deep, and spaced ¼″ apart may increasethe effective circumference of a 6″ (15.24 cm) diameter pipe from 18.84″(47.85 cm) to 37.68″ (95.71 cm) (or the circumference of a 12″ (30.48cm) diameter pipe).

In certain embodiments, grooves 712 increase the effective circumferenceof casing 710 by a factor of at least about 2 as compared to a casingwith the same inside and outside diameters and smooth surfaces. In someembodiments, grooves 712 increase the effective circumference of casing710 by a factor of at least about 3, at least about 4, or at least about6 as compared to a casing with the same inside and outside diameters andsmooth surfaces.

Increasing the effective circumference of casing 710 with grooves 712increases the surface area of the casing. Increasing the surface area ofcasing 710 reduces the induced current in the casing for a given currentflux. Power losses associated with inductive heating in casing 710 arereduced as compared to a casing with smooth surfaces because of thereduce induced current. Thus, the same electrical current will provideless heat output from inductive heating in the axial grooved surfacecasing than the smooth surface casing. Reducing the heat output in theoverburden section of the heater will increase the efficiency of, andreduce the costs associated with, operating the heater. Increasing theeffective circumference of casing 710 and reducing inductive effects inthe casing allows the casing to be made with less expensive materialssuch as carbon steel.

In some embodiments, an electrically insulating coating (for example, aporcelain enamel coating) is placed on one or more surfaces of casing710 to inhibit current and/or power losses from the casing. In someembodiments, casing 710 is formed from two or more longitudinal sectionsof casing (for example, longitudinal sections welded or threadedtogether end to end). The longitudinal sections may be aligned so thatthe grooves on the sections are aligned. Aligning the sections may allowfor cement or other material to flow along the grooves.

In some embodiments, an insulated conductor heater is placed in theformation by itself and the outside of the insulated conductor heater iselectrically isolated from the formation because the heater has littleor no voltage potential on the outside of the heater. FIG. 132 depictsan embodiment of a single-ended, substantially horizontal insulatedconductor heater that electrically isolates itself from the formation.In such an embodiment, heater 438 is insulated conductor 574. Insulatedconductor 574 may be a mineral insulated conductor heater (for example,insulated conductor 574 depicted in FIGS. 133A and 133B). Insulatedconductor 574 is located in opening 556 in hydrocarbon layer 484. Incertain embodiments, opening 556 is an uncased or open wellbore. In someembodiments, opening 556 is a cased or lined wellbore. In someembodiments, insulated conductor heater 574 is a substantially u-shapedheater and is located in a substantially u-shaped opening.

Insulated conductor 574 has little or no current flowing along theoutside surface of the insulated conductor so that the insulatedconductor is electrically isolated from the formation and leaks littleor no current into the formation. The outside surface (or jacket) ofinsulated conductor 574 is a metal or thermal radiating body so thatheat is radiated from the insulated conductor to the formation.

FIGS. 133A and 133B depict cross-sectional representations of anembodiment of insulated conductor 574 that is electrically isolated onthe outside of jacket 540. In certain embodiments, jacket 540 is made offerromagnetic materials. In one embodiment, jacket 540 is made of 410stainless steel. In other embodiments, jacket 540 is made of T/P91 orT/P92 stainless steel. In some embodiments, jacket 540 may includecarbon steel. Core 542 is made of a highly conductive material such ascopper or a copper alloy. Electrical insulator 534 is an electricallyinsulating material such as magnesium oxide. Insulated conductor 574 maybe an inexpensive and easy to manufacture heater.

In the embodiment depicted in FIGS. 133A and 133B, core 542 bringscurrent into the formation, as shown by the arrow. Core 542 and jacket540 are electrically coupled at the distal end (bottom) of the heater.Current returns to the surface of the formation through jacket 540. Theferromagnetic properties of jacket 540 confine the current to the skindepth along the inside diameter of the jacket, as shown by arrows 714 inFIG. 133A. Jacket 540 has a thickness at least 2 or 3 times the skindepth of the ferromagnetic material used in the jacket at 25° C. and atthe design current frequency so that most of the current is confined tothe inside surface of the jacket and little or no current flows on theoutside diameter of the jacket. Thus, there is little or no voltagepotential on the outside of jacket 540. Having little or no voltagepotential on the outside surface of insulated conductor 574 does notexpose the formation to any high voltages, inhibits current leakage tothe formation, and reduces or eliminates the need for isolationtransformers, which decrease energy efficiency.

Because core 542 is made of a highly conductive material such as copperand jacket 540 is made of more resistive ferromagnetic material, amajority of the heat generated by insulated conductor 574 is generatedin the jacket. Generating the majority of the heat in jacket 540increases the efficiency of heat transfer from insulated conductor 574to the formation over an insulated conductor (or other heater) that usesa core or a center conductor to generate the majority of the heat.

In certain embodiments, core 542 is made of copper. Using copper in core542 allows the heating section of the heater and the overburden sectionto have identical core materials. Thus, the heater may be made from onelong core assembly. The long single core assembly reduces or eliminatesthe need for welding joints in the core, which can be unreliable andsusceptible to failure. Additionally, the long, single core assemblyheater may be manufactured remote from the installation site andtransported in a final assembly (ready to install assembly) to theinstallation site. The single core assembly also allows for long heaterlengths (for example, about 1000 m or longer) depending on the breakdownvoltage of the electrical insulator.

In certain embodiments, jacket 540 is made from two or more layers ofthe same materials and/or different materials. Jacket 540 may be formedfrom two or more layers to achieve thicknesses needed for the jacket(for example, to have a thickness at least 3 times the skin depth of theferromagnetic material used in the jacket at 25° C. and at the designcurrent frequency). Manufacturing and/or material limitations may limitthe thickness of a single layer of jacket material. For example, theamount each layer can be strained during manufacturing (forming) thelayer on the heater may limit the thickness of each layer. Thus, toreach jacket thicknesses needed for certain embodiments of insulatedconductor 574, jacket 540 may be formed from several layers of jacketmaterial. For example, three layers of T/P92 stainless steel may be usedto form jacket 540 with a thickness of about 3 times the skin depth ofthe T/P92 stainless steel at 25° C. and at the design current frequency.

In some embodiments, jacket 540 includes two or more differentmaterials. In some embodiments, jacket 540 includes different materialsin different layers of the jacket. For example, jacket 540 may have oneor more inner layers of ferromagnetic material chosen for theirelectrical and/or electromagnetic properties and one or more outerlayers chosen for its non-corrosive properties.

In some embodiments, the thickness of jacket 540 and/or the material ofthe jacket are varied along the heater length. The thickness and/ormaterial of jacket 540 may be varied to vary electrical propertiesand/or mechanical properties along the length of the heater. Forexample, the thickness and/or material of jacket 540 may be varied tovary the turndown ratio or the Curie temperature along the length of theheater. In some embodiments, the inner layer of jacket 540 includescopper or other highly conductive metals in the overburden section ofthe heater. The inner layer of copper limits heat losses in theoverburden section of the heater.

FIGS. 134 and 135 depict an embodiment of insulated conductor 574 insidetubular 702. Insulated conductor 574 may include core 542, electricalinsulator 534, and jacket 540. Core 542 and jacket 540 may beelectrically coupled (shorted) at a distal end of the insulatedconductor. FIG. 136 depicts a cross-sectional representation of anembodiment of the distal end of insulated conductor 574 inside tubular702. Endcap 630 may electrically couple core 542 and jacket 540 totubular 702 at the distal end of insulated conductor 574 and thetubular. Endcap 630 may include electrical conducting materials such ascopper or steel.

In certain embodiments, core 542 is copper, electrical insulator 534 ismagnesium oxide, and jacket 540 is non-ferromagnetic stainless steel(for example, 347H stainless steel, 204-Cu stainless steel, or 204 Mstainless steel). Insulated conductor 574 may be placed in tubular 702to protect the insulated conductor, increase heat transfer to theformation, and/or allow for coiled tubing or continuous installation ofthe insulated conductor. Tubular 702 may be made of ferromagneticmaterial such as 410 stainless steel, T/P91 stainless steel, or carbonsteel. In certain embodiments, tubular 702 is made of corrosionresistant materials. In some embodiments, tubular 702 is made ofnon-ferromagnetic materials.

In certain embodiments, jacket 540 of insulated conductor 574 islongitudinally welded to tubular 702 along weld joint 716, as shown inFIG. 135. The longitudinal weld may be a laser weld, a tandem GTAW (gastungsten arc welding) weld, or an electron beam weld that welds thesurface of jacket 540 to tubular 702. In some embodiments, tubular 702is made from a longitudinal strip of metal. Tubular 702 may be made byrolling the longitudinal strip to form a cylindrical tube and thenwelding the longitudinal ends of the strip together to make the tubular.

In certain embodiments, insulated conductor 574 is welded to tubular 702as the longitudinal ends of the strip are welded together (in the samewelding process). For example, insulated conductor 574 is placed alongone of the longitudinal ends of the strip so that jacket 540 is weldedto tubular 702 at the location where the ends are welded together. Insome embodiments, insulated conductor 574 is welded to one of thelongitudinal ends of the strip before the strip is rolled to form thecylindrical tube. The ends of the strip may then be welded to formtubular 702.

In some embodiments, insulated conductor 574 is welded to tubular 702 atanother location (for example, at a circumferential location away fromthe weld joining the ends of the strip used to form the tubular). Forexample, jacket 540 of insulated conductor 574 may be welded to tubular702 diametrically opposite from where the longitudinal ends of the stripused to form the tubular are welded. In some embodiments, tubular 702 ismade of multiple strips of material that are rolled together and coupled(for example, welded) to form the tubular with a desired thickness.Using more than one strip of metal may be easier to roll into thecylindrical tube used to form the tubular.

Jacket 540 and tubular 702 may be electrically and mechanically coupledat weld joint 716. Longitudinally welding jacket 540 to tubular 702inhibits arcing between insulated conductor 574 and the tubular. Tubular702 may return electrical current from core 542 along the inside of thetubular if the tubular is ferromagnetic. If tubular 702 isnon-ferromagnetic, a thin electrically insulating layer such as aporcelain enamel coating or a spray coated ceramic may be put on theoutside of the tubular to inhibit current leakage from the tubular intothe formation. In some embodiments, a fluid is placed in tubular 702 toincrease heat transfer between insulated conductor 574 and the tubularand/or to inhibit arcing between the insulated conductor and thetubular. Examples of fluids include, but are not limited to, thermallyconductive gases such as helium, carbon dioxide, or steam. Fluids mayalso include fluids such as oil, molten metals, or molten salts (forexample, solar salt (60% NaNO₃/40% KNO₃)). In some embodiments, heattransfer fluids are transported inside tubular 702 and heated inside thetubular (in the space between the tubular and insulated conductor 574).In some embodiments, an optical fiber, thermocouple, or othertemperature sensor is placed inside tubular 702.

In certain embodiments, the heater depicted in FIGS. 134, 135, and 136is energized with AC current (or time-varying electrical current). Amajority of the heat is generated in tubular 702 when the heater isenergized with AC current. If tubular 702 is ferromagnetic and the wallthickness of the tubular is at least about twice the skin depth at 25°C. and at the design current frequency, then the heater will operate asa temperature limited heater. Generating the majority of the heat intubular 702 improves heat transfer to the formation as compared to aheater that generates a majority of the heat in the insulated conductor.

FIGS. 134 and 135 depict an embodiment of insulated conductor 574 insidetubular 702. Insulated conductor 574 may include core 542, electricalinsulator 534, and jacket 540. Core 542 and jacket 540 may beelectrically coupled (shorted) at a distal end of the insulatedconductor. FIG. 136 depicts a cross-sectional representation of anembodiment of the distal end of insulated conductor 574 inside tubular702. Endcap 630 may electrically couple core 542 and jacket 540 totubular 702 at the distal end of insulated conductor 574 and thetubular. Endcap 630 may include electrical conducting materials such ascopper or steel.

In certain embodiments, core 542 is copper, electrical insulator 534 ismagnesium oxide, and jacket 540 is non-ferromagnetic stainless steel(for example, 347H stainless steel, 204-Cu stainless steel, or 204 Mstainless steel). Insulated conductor 574 may be placed in tubular 702to protect the insulated conductor, increase heat transfer to theformation, and/or allow for coiled tubing or continuous installation ofthe insulated conductor. Tubular 702 may be made of ferromagneticmaterial such as 410 stainless steel, T/P91 stainless steel, or carbonsteel. In certain embodiments, tubular 702 is made of corrosionresistant materials. In some embodiments, tubular 702 is made ofnon-ferromagnetic materials.

In certain embodiments, jacket 540 of insulated conductor 574 islongitudinally welded to tubular 702 along weld joint 716, as shown inFIG. 135. The longitudinal weld may be a laser weld, a tandem GTAW (gastungsten arc welding) weld, or an electron beam weld that welds thesurface of jacket 540 to tubular 702. In some embodiments, tubular 702is made from a longitudinal strip of metal. Tubular 702 may be made byrolling the longitudinal strip to form a cylindrical tube and thenwelding the longitudinal ends of the strip together to make the tubular.

In certain embodiments, insulated conductor 574 is welded to tubular 702as the longitudinal ends of the strip are welded together (in the samewelding process). For example, insulated conductor 574 is placed alongone of the longitudinal ends of the strip so that jacket 540 is weldedto tubular 702 at the location where the ends are welded together. Insome embodiments, insulated conductor 574 is welded to one of thelongitudinal ends of the strip before the strip is rolled to form thecylindrical tube. The ends of the strip may then be welded to formtubular 702.

In some embodiments, insulated conductor 574 is welded to tubular 702 atanother location (for example, at a circumferential location away fromthe weld joining the ends of the strip used to form the tubular). Forexample, jacket 540 of insulated conductor 574 may be welded to tubular702 diametrically opposite from where the longitudinal ends of the stripused to form the tubular are welded. In some embodiments, tubular 702 ismade of multiple strips of material that are rolled together and coupled(for example, welded) to form the tubular with a desired thickness.Using more than one strip of metal may be easier to roll into thecylindrical tube used to form the tubular.

Jacket 540 and tubular 702 may be electrically and mechanically coupledat weld joint 716. Longitudinally welding jacket 540 to tubular 702inhibits arcing between insulated conductor 574 and the tubular. Tubular702 may return electrical current from core 542 along the inside of thetubular if the tubular is ferromagnetic. If tubular 702 isnon-ferromagnetic, a thin electrically insulating layer such as aporcelain enamel coating or a spray coated ceramic may be put on theoutside of the tubular to inhibit current leakage from the tubular. Insome embodiments, a fluid is placed in tubular 702 to increase heattransfer between insulated conductor 574 and the tubular and/or toinhibit arcing between the insulated conductor and the tubular. Examplesof fluids include, but are not limited to, conductive gases such ashelium, molten metals, and molten salts. In some embodiments, heattransfer fluids are transported inside tubular 702 and heated inside thetubular (in the space between the tubular and insulated conductor 574).In some embodiments, an optical fiber, thermocouple, or othertemperature sensor is placed inside tubular 702.

In certain embodiments, the heater depicted in FIGS. 134, 135, and 136is energized with AC current (or time-varying electrical current). Amajority of the heat is generated in tubular 702 when the heater isenergized with AC current. If tubular 702 is ferromagnetic and the wallthickness of the tubular is at least about twice the skin depth at atemperature near the Curie temperature (for example, 50° C. below theCurie temperature), then the heater will operate as a temperaturelimited heater. Generating the majority of the heat in tubular 702improves heat transfer to the formation as compared to a heater thatgenerates a majority of the heat in the insulated conductor.

In certain embodiments, portions of the wellbore that extend through theoverburden include casings. The casings may include materials thatinhibit inductive effects in the casings. Inhibiting inductive effectsin the casings may inhibit induced currents in the casing and/or reduceheat losses to the overburden. In some embodiments, the overburdencasings may include non-metallic materials such as fiberglass,polyvinylchloride (PVC), chlorinated PVC (CPVC), high-densitypolyethylene (HDPE), high temperature polymers (such as nitrogen basedpolymers), or other high temperature plastics. HDPEs with workingtemperatures in a usable range include HDPEs available from Dow ChemicalCo., Inc. (Midland, Mich., U.S.A.). The overburden casings may be madeof materials that are spoolable so that the overburden casings can bespooled into the wellbore. In some embodiments, overburden casings mayinclude non-magnetic metals such as aluminum or non-magnetic alloys suchas manganese steels having at least 10% manganese, iron aluminum alloyswith at least 18% aluminum, or austentitic stainless steels such as 304stainless steel or 316 stainless steel. In some embodiments, overburdencasings may include carbon steel or other ferromagnetic material coupledon the inside diameter to a highly conductive non-ferromagnetic metal(for example, copper or aluminum) to inhibit inductive effects or skineffects. In some embodiments, overburden casings are made of inexpensivematerials that may be left in the formation (sacrificial casings).

In certain embodiments, wellheads for the wellbores may be made of oneor more non-ferromagnetic materials. FIG. 137 depicts an embodiment ofwellhead 718. The components in the wellheads may include fiberglass,PVC, CPVC, HDPE, high temperature polymers (such as nitrogen basedpolymers), and/or non-magnetic alloys or metals. Some materials (such aspolymers) may be extruded into a mold or reaction injection molded (RIM)into the shape of the wellhead. Forming the wellhead from a mold may bea less expensive method of making the wellhead and save in capital costsfor providing wellheads to a treatment site. Using non-ferromagneticmaterials in the wellhead may inhibit undesired heating of components inthe wellhead. Ferromagnetic materials used in the wellhead may beelectrically and/or thermally insulated from other components of thewellhead. In some embodiments, an inert gas (for example, nitrogen orargon) is purged inside the wellhead and/or inside of casings to inhibitreflux of heated gases into the wellhead and/or the casings.

In some embodiments, ferromagnetic materials in the wellhead areelectrically coupled to a non-ferromagnetic material (for example,copper) to inhibit skin effect heat generation in the ferromagneticmaterials in the wellhead. The non-ferromagnetic material is inelectrical contact with the ferromagnetic material so that current flowsthrough the non-ferromagnetic material. In certain embodiments, as shownin FIG. 137, non-ferromagnetic material 720 is coupled (and electricallycoupled) to the inside walls of conduit 552 and wellhead walls 722. Insome embodiments, copper may be plasma sprayed, coated, clad, or linedon the inside and/or outside walls of the wellhead. In some embodiments,a non-ferromagnetic material such as copper is welded, brazed, clad, orotherwise electrically coupled to the inside and/or outside walls of thewellhead. For example, copper may be swaged out to line the inside wallsin the wellhead. Copper may be liquid nitrogen cooled and then allowedto expand to contact and swage against the inside walls of the wellhead.In some embodiments, the copper is hydraulically expanded or explosivelybonded to contact against the inside walls of the wellhead.

In some embodiments, two or more substantially horizontal wellbores arebranched off of a first substantially vertical wellbore drilleddownwards from a first location on a surface of the formation. Thesubstantially horizontal wellbores may be substantially parallel througha hydrocarbon layer. The substantially horizontal wellbores mayreconnect at a second substantially vertical wellbore drilled downwardsat a second location on the surface of the formation. Having multiplewellbores branching off of a single substantially vertical wellboredrilled downwards from the surface reduces the number of openings madeat the surface of the formation.

In certain embodiments, a horizontal heater, or a heater at an inclineis installed in more than one part. FIG. 138 depicts an embodiment ofheater 438 that has been installed in two parts. Heater 438 includesheating section 438A and lead-in section 438B. Heating section 438A maybe located horizontally or at an incline in a hydrocarbon layer in theformation. Lead-in section 438B may be the overburden section or lowresistance section of the heater (for example, the section of the heaterwith little or no electrical heat output).

During installation of heater 438, heating section 438A may be installedfirst into the formation. Heating section 438A may be installed bypushing the heating section into the opening in the formation using adrill pipe or other installation tool that pushes the heating sectioninto the opening. After installation of heating section 438A, theinstallation tool may be removed from the opening in the formation.Installing only heating section 438A with the installation tool at thistime may allow the heating section to be installed further into theformation than if the heating section and the lead-in section areinstalled together because a higher compressive strength may be appliedto the heating section alone (the installation tool only has to push inthe horizontal or inclined direction).

In some embodiments, heating section 438A is coupled to mechanicalconnector 692. Connector 692 may be used to hold heating section 438A inthe opening. In some embodiments, connector 692 includes copper or otherelectrically conductive materials so that the connector is used as anelectrical connector (for example, as an electrical ground). In someembodiments, connector 692 is used to couple heating section 438A to abus bar or electrical return rod located in an opening perpendicular tothe opening of the heating section.

Lead-in section 438B may be installed after installation of heatingsection 438A. Lead-in section 438B may be installed with a drill pipe orother installation tool. In some embodiments, the installation tool maybe the same tool used to install heating section 438A.

Lead-in section 438B may couple to heating section 438A as the lead-insection is installed into the opening. In certain embodiments, couplingjoint 724 is used to couple lead-in section 438B to heating section438A. Coupling joint 724 may be located on either lead-in section 438Bor heating section 438A. In some embodiments, coupling joint 724includes portions located on both sections. Coupling joint 724 may be acoupler such as, but not limited to, a wet connect or wet stab. In someembodiments, heating section 438A includes a catcher or other tool thatguides an end of lead-in section 438B to form coupling joint 724.

In some embodiments, coupling joint 724 includes a container (forexample, a can) located on heating section 438A that accepts the end oflead-in section 438B. Electrically conductive beads (for example, balls,spheres, or pebbles) may be located in the container. The beads may movearound as the end of lead-in section 438B is pushed into the containerto make electrical contact between the lead-in section and heatingsection 438A. The beads may be made of, for example, copper or aluminum.The beads may be coated or covered with a corrosion inhibitor such asnickel. In some embodiments, the beads are coated with a solder materialthat melts at lower temperatures (for example, below the boiling pointof water in the formation). A high electrical current may be applied tothe container to melt the solder. The melted solder may flow and fillvoid spaces in the container and be allowed to solidify beforeenergizing the heater. In some embodiments, sacrificial beads are put inthe container. The sacrificial beads may corrode first so that copper oraluminum beads in the container are less likely to be corroded duringoperation of the heater.

Continuous tubulars, such as coil tubing, have been used for many years.Running continuous tubulars into and/or out of a wellbore may be simplerand faster than running tubing formed of conventional jointed pipe.

Continuous tubulars may be run into and/or out of wellbores usinginjectors. Injectors may force the continuous tubulars into the wellsthrough a lubricator assembly or stuffing box to overcome any wellpressure until the weight of the continuous tubulars exceeds the forceapplied by the well pressure that acts against the cross-sectional areaof the continuous tubulars. Once the weight of the continuous tubularovercomes the pressure, the continuous tubular may need to be supportedby the injector. The process may be reversed as the continuous tubularis removed from the well.

A method for running dual jointed tubing strings into and out of wellsis described in U.S. Pat. No. 4,474,236 to Kellett, which isincorporated by reference as if fully set forth herein. Kellettdescribes a method and apparatus for completing a well using jointedproduction and service strings of different diameters. The methodincludes steps of running the production string on a main tubing stringhanger while maintaining control with a variable bore blowout preventer,and running the service string into the main tubing string hanger whilemaintaining control with a dual bore blowout preventer.

Continuous tubulars have been used for various well treatment processessuch as fracturing, acidizing, and gravel packing. Typically, severalthousand feet of flexible, seamless tubing is coiled onto a large reelthat is mounted on a truck or skid. A continuous tubular injector with achain-track drive, or equivalent, may be mounted above the wellhead. Thecontinuous tubular may be fed to the injector for injection into thewell. The continuous tubular may be straightened as it is removed fromthe reel by a continuous tubular guide that aligns the continuoustubular with the wellbore and the injector mechanism.

The use of dual continuous tubulars for well servicing and production isknown in the art. Recent developments in well completion and wellworkover have demonstrated the utility of using two continuous tubularsconcurrently for many downhole operations. A difficulty with injectingdual continuous tubulars into a wellbore is the proximity of therespective continuous tubulars and the lack of working space to deploy apair of continuous tubular injector assemblies mounted above thewellhead. This problem was apparently resolved with a coil tubing stringinjector assembly adapted to simultaneously inject dual string coiltubing into a wellbore, as disclosed in U.S. Pat. No. 6,516,891 toDallas, which is incorporated herein by reference.

Another problem associated with the injection of dual continuoustubulars into a wellbore is the prevention of fluid leakage during theinjection of the dual continuous tubulars, especially when a longdownhole tool is connected to one or both of the continuous tubulars.Downhole tools typically have a larger diameter than the continuoustubular and cannot be plastically deformed, which presents certaindifficulties. It is known in the art how to overcome these difficultieswhile injecting a single continuous tubular. For example, U.S. Pat. No.4,940,095 to Newman, which is incorporated herein by reference,discloses a method of inserting a well service tool connected to acoiled tubing string, which avoids the high and/or remote mounting of aheavy coiled tubing injector drive mechanism. A closed-end lubricator isused to house the tool until it is run down through a blowout preventerconnected to a top of the well. The pipe rams of the blowout preventerare closed around the tool to support it while a tubing injector ismounted to the wellhead and the coil tubing string is connected to thetool. The blowout preventer is then opened and the coil tubing stringinjector is used to run the tool into the well. However, Newman fails toaddress the use of dual string continuous tubulars.

Many subsurface wells are fitted with permanent sensors, such aspressure and temperature sensors, which require electrical power totransmit signals from the sensors to a remote point at the surface.Subsurface wells may employ subsurface equipment such as pumps orheaters, which may also require electrical power. To supply power tothese subsurface pieces of equipment, electric current from a sourceoutside of the wellhead must be transferred through the wellhead to theelectrically responsive device. Electrical power can be supplieddownhole by several methods. These methods include, but are not limitedto, electrical umbilical cords, rigid tubular conductors, or coiledtubing. The power supply may be transferred through either the tubinghanger or the casing hanger.

The extreme environmental conditions inside the wellhead coupled withthe rough nature of completion operations may cause damage to devicesused to supply electrical power. Damaged equipment may potentially leadto electrical short-circuits that can present a hazard to personsworking around the wellhead. Since the majority of wellhead equipment isconstructed of conductive materials, an electrical short inside of thewellhead may charge the outer surface of the wellhead. Unprotectedpersons may be exposed to electrical shock if contact is made with thewellhead's outer surface. Continuous tubulars subjected to electricalcharge (for example, heaters) may be insulated from the wellhead of thewellbore.

Typically, a continuous tubular is inserted into a wellhead through alubricator assembly or a stuffing box because there is a pressuredifferential between the wellbore and atmosphere. The pressuredifferential may be naturally or artificially created. The pressuredifferential may produce oil, gas, or a mixture thereof, from thepressurized well. Wellhead mechanisms may inhibit movement of continuoustubulars upward and out of the wellbore as well as inhibit downwardmovement into the wellbore.

In certain embodiments, a suspension mechanism is capable of suspendingdual continuous tubulars (for example, dual insulated conductorheaters). In some embodiments, the suspension mechanism includes slipsor special fittings. With slips, a radial gripping force keeps dualcontinuous tubulars suspended and inhibits downward movement. In someembodiments, the slips inhibit upward movement (for example, upwardmovement of the dual continuous tubulars). Inhibiting upward movementmay be accomplished by using a reverse slip arrangement. Conventionalwellheads and hangers may not be designed to restrain movement ofcontinuous tubulars in the upward direction. Instead, conventionalwellheads and hangers may be only designed to suspend the strings due tothe gravitational load of the continuous tubulars.

Deployment and suspension of continuous tubulars in the wellbore mayrequire a mechanism that suspends the dual continuous tubulars in thewellhead by some suitable hanging mechanism or hanger. Thehanging/suspension mechanisms may function when the dual legs of thecontinuous tubulars are deployed simultaneously. Conventionally, dualcontinuous tubulars are not deployed simultaneously. In someembodiments, a suspension mechanism is able to suspend the verticaldownward load of both the tubulars as well as inhibit the upwardmovement of the tubulars.

FIG. 139 depicts an embodiment of a dual continuous tubular suspensionmechanism 726 for inhibiting movement of at least two continuoustubulars 702. Suspension mechanism 726 may be formed or positionedwithin wellhead 476. Suspension mechanism 726 may include threading cutalong at least a portion of dual continuous tubulars 702 over expandedportion 702A of the tubular. In some embodiments, the tubular is aheater. In some embodiments, expanded portion 702A includes a threadedtubular portion to which a threaded collar is coupled. Suspensionmechanism 726 may include lower portion 726A and upper portion 726B.Upper portion 726B may include at least two openings with diameterslarge enough to allow passage of the tubulars but small enough toinhibit passage of expanded portions of the tubulars. Lower portion 726Amay include lip 726A′. Lip 726A′ may inhibit movement of the threadedcollars in a downward direction. Lip 726A′ restricts movement of thetubulars in a downward direction once the expanded portion of thetubulars are threaded into the collars.

The wellhead and the suspension mechanism may include one or more seals728. Seals 728 may inhibit wellbore fluids from migrating upwards. Seals728 may help maintain a desired pressure in the wellbore. Wellcap 474keeps the suspension mechanism in place and inhibits upward movement.Wellhead 476 may include an opening in which the suspension mechanism ispositioned. The opening may narrow to a diameter less than that of thesuspension mechanism to inhibit downward movement of the suspensionmechanism.

FIG. 140 depicts an embodiment of dual continuous tubular suspensionmechanism 726 for inhibiting movement of at least two continuoustubulars 702. Suspension mechanism 726 may be formed or positionedwithin wellhead 476. Continuous tubulars 702 may include expandedportion 702A and function in a similar fashion as is described in theembodiment depicted in FIG. 139. Expanded portion 702A depicted in FIG.140, however, may be formed by welding or otherwise attaching two piecesof split cylinder to tubular 702.

FIGS. 141A and 141B depict embodiments of dual continuous tubularsuspension mechanisms 726. Suspension mechanisms 726 include slipmechanisms that inhibit upward and downward movement of tubulars 702.The slip mechanisms may include inhibitors 730. Inhibitors 730 may allowmovement in a first direction while inhibiting movement in a seconddirection. The second direction may be in a direction opposite to thefirst direction. Inhibitors 730 may include upper inhibitors 730B andlower inhibitors 730A. Upper inhibitors 730B may allow movement of thetubulars in a downward direction while inhibiting movement of thetubulars in an upward direction. Lower inhibitors 730A may allowmovement of the tubulars in an upward direction, while inhibitingmovement of the tubulars in a downward direction. Inhibitors 730 mayinhibit movement using serrations angled such that the serrations engagea tubular when the tubular moves in a first direction, but not when thetubular moves in a second direction that is substantially opposite tothe first direction.

In some embodiments, inhibitors include coatings. The coating may impartspecific desirable properties to the inhibitor to which the coating isapplied. For example, a coating may include a temperature resistantpolymer coating.

Suspension mechanism 726 may include lower portion 726A and upperportion 726B. Upper portion 726B may include at least two openings withdiameters large enough to allow passage of the tubulars at both ends ofeach opening, but small enough at the proximal ends of the openings toinhibit passage of upper inhibitors 730B in an upward direction. Thedistal ends of the openings may be large enough to allow the upperinhibitors to sit within the openings of the upper portion 730B ofsuspension mechanism 726. Lower portion 726A may include at least twoopenings with diameters large enough to allow passage of the tubulars atboth ends of the openings, but small enough at the distal end of eachopening to inhibit passage of lower inhibitors 730A in a downwarddirection. The proximal ends of the openings may be large enough toallow the lower inhibitors to sit within the openings of lower portion726A of suspension mechanism 726.

Suspension mechanism 726 may include locks 732. In some embodiments,locks 732 are screws, bolts, or other types of fasteners. Locks 732inhibit movement of one or more portions of suspension mechanism 726within wellhead 476. Wellhead 476 may include an opening in whichsuspension mechanism 726 is positioned. The opening may narrow to adiameter less than that of suspension mechanism 726 to inhibit downwardmovement of the suspension mechanism.

FIGS. 142-143 depict embodiments of dual continuous tubular suspensionmechanisms 726 within wellhead 476. As detailed in FIGS. 141A-B,suspension mechanisms 726 employs a slip mechanism using upper and lowerinhibitors 730. In FIG. 142, wellcap 474 of wellhead 476 assists inkeeping suspension mechanism 726 in position. Lock 732 inhibits upwardmovement of the wellcap and suspension mechanism 726. In the embodimentdepicted in FIG. 142, wellcap 474 is a part of a seal assembly usingseals 728.

FIG. 143 depicts an embodiment of suspension mechanisms 726 in wellhead476. Wellcap 474 may be sandwiched between upper portion 726A and lowerportion 726B of suspension mechanism 726. Lock 732 inhibits upwardmovement of upper portion 726A of the suspension mechanism, and thewellcap and suspension mechanism as a whole. Locks 732′ inhibit movementof upper portion 726A and lower portion 726B of suspension mechanism 726and wellcap 474 in relation to one another.

FIG. 144 depicts an embodiment of pass-through fitting 734 used tosuspend tubulars 702. Pass-through fitting 734 may function to suspendtubulars 702. Pass-through fitting 734 may include commerciallyavailable products (for example, available from Swagelok Company (Solon,Ohio, USA) or VULKAN LOKRING Rohrverbindung GmbH & Co.KG (Herne,Germany)). Pass-through fitting 734 may inhibit movement of tubulars 702in the downward direction. A second mechanism may be utilized to inhibitmovement of the tubulars in the upward direction. The second mechanismmay be a reverse configuration of the pass-through fittings 734.

FIG. 145 depicts an embodiment of dual slip suspension mechanism 726 forinhibiting movement of tubulars 702 positioned in an opening of wellhead476. FIG. 145 depicts a two-way lock arrangement using a slip mechanism.Bottom threading has right-handed threading, and top threading hasleft-handed threading. Rotation of the center nut in the clockwisedirection (when viewed from top) causes the fittings to be drawntogether, tightening the slips and causing the slips to grip thetubular/rod/heater. The entire assembly can then be suspended in awellhead housing as shown. The entire assembly can be locked into placeusing two lock-screws 726. Lock-screws 726 may suspend thetubular/rod/heater and restrict downward and upward movement of thetubular/rod/heater.

FIGS. 146A and 146B depict embodiments of lower portion of splitsuspension mechanisms 726A and lower split inhibitor assemblies 730A forhanging dual continuous tubulars 702. Lower inhibitor assemblies 730Aand lower portion of suspension mechanisms 726A may be split such thatthey fit together around tubulars 702. When the assembly is positionedin a wellhead the assembly may function as a compression fitting toinhibit downward movement of the tubulars. Lower inhibitor assemblies730A may include special non-marking dies or surfaces (for example, WCparticles (tungsten carbide particles) embedded in mild steel) thatfunction to simultaneously hold both the tubulars. Lower inhibitorassemblies 730A may include a specific taper angle that sits in lowerportion of suspension mechanisms 726A. In this configuration, the lowerinhibitor assemblies 730A are shown to have special grit-facednon-marking surface.

FIG. 147 depicts an embodiment of dual slip suspension mechanisms 726for inhibiting movement of tubulars 702 with a reverse configurationrelative to the embodiment depicted in FIG. 143. Upper inhibitor 730B,which prevents upward movement, is deployed first and locked into placewith bottom locks 732′ and lower portion of suspension mechanism 726A.Lower inhibitor 730A, which hangs the weight of the pipe and inhibitsdownward movement of pipe, is deployed in reverse order and locked inplace with bottom locks 732″ and upper portion of suspension mechanism726B. Wellcap 474 including seals 728 are introduced next from the top.The suspension mechanism 726 may be locked in position using locks 732″.A third or middle portion 726C of the suspension mechanism cradles boththe upper and lower inhibitors while the upper portion 730B and lowerportion 730A of the suspension mechanism inhibit movement of theinhibitors within openings in middle portion 726C of the suspensionmechanism.

FIG. 148 depicts an embodiment of a two-part dual slip mechanism ofsuspension mechanism 726 for inhibiting movement of tubulars 702. Middleportion 726C of the suspension mechanism is divided into two portions,lower portion 726C′ and upper portion 726C″. The two portions of middleportion 726C may be coupled together using lock 732C. Lock 732C mayinclude threaded studs as depicted in FIG. 148. The top half of eachstud 732C may have left-handed threading and the bottom half of eachstud may have right-handed threading. Each stud 732C screws into thebottom and top of upper portion 726C″ and lower portion 726C′ ofsuspension mechanism 726. When the stud is rotated in the clockwisedirection when viewed from the top, both upper portion 726C″ and lowerportion 726C′ approach each other. Each stud is rotated a little eachtime in sequence going around such that the upper portion 726C″ andlower portion 726C′ move towards each other gradually and substantiallyuniformly. The movement causes the inhibitors to tighten and grip thetubulars.

In some embodiments, the above operation is done in a ‘false wellheadhousing’ (not shown) just above the wellhead after the inhibitors aretightened together, the tubulars are lifted, until they clear thefalse-wellhead, which is then removed. The tubulars along with thesuspension mechanism are lowered into a wellhead housing and the load istransferred to the shoulder (for example, a protrusion or narrowing ofthe opening in the wellhead which inhibits movement of the suspensionmechanism beyond the protrusion). The locks 732″ are tightened toinhibit movement of the suspension mechanism relative to the wellhead.

FIG. 149 depicts an embodiment of two-part dual slip suspensionmechanism 726 for inhibiting movement of tubulars 702 with separatelocks 732. FIG. 149 depicts an embodiment with a reverse configurationof inhibitors 730 from the configuration depicted in FIGS. 147-148. InFIG. 149, the suspension mechanism is depicted in two distinct sections.The two sections may be activated separately. Lower portion 726A of asuspension mechanism may include lower portion 726A′ and upper portion726A″. Portions 726A′ and 726A″ function in combination when activatedto inhibit movement of inhibitors 730B and hence inhibit upward movementof tubulars 702. Lower portion 726A may be activated by assemblingportions 726A′, 726A″ and inhibitors 730B, inserting the assembly untildownward movement is inhibited by lip 736′, and upon positioningtubulars 702 and activating lock 732′. Activating lock 732′ may compresslower portion assembly together such that inhibitors 730B grip tubulars702. Upper portion 726B may be activated by assembling portion 726B andinhibitors 730A, inserting the assembly until downward movement isinhibited by lip 736″, and activating lock 732″ after positioningtubulars 702. Activating lock 732″ may compress upper portion 726Bagainst lip 736″. Inhibitors 730A may be held in position within openingin upper portion 726B by gravity.

FIG. 150 depicts an embodiment of dual slip suspension mechanism 726with locking upper plate 726B for inhibiting movement of tubulars 702.The embodiment of lower portion 726A depicted in FIG. 150 may functionin a similar manner to upper portion 726B of the suspension mechanismdepicted in FIG. 149. Inhibitors 730A inhibit downward movement oftubulars 702. However, instead of including a second set of inhibitorsto inhibit upward movement as in FIG. 149, upper portion 726B (forexample, a plate) is positioned above lower portion 726A. Upper portion726B locks inhibitors 730A in place to inhibit upward movement oftubulars 702 upon activation of locks. Activating locks 732″ couplesupper portion 726B to lower portion 726A.

In some embodiments, lower portion 726A may include a tapered openingextending through it. The lower portion may include a carrier with atapered shape complementary to the tapered opening in the lower portion.The carrier may sit within the tapered opening of the lower portion.Inhibitors 730A fit in complementary tapered openings through thecarrier. The load of the tubulars, once positioned, is transferred fromthe inhibitors to the carrier to the lower portion, and then to thewellhead. Using a lower portion with a carrier for the inhibitors may beadvantageous when the distance between tubulars is small.

FIG. 151 depicts an embodiment of segmented dual slip suspensionmechanism 726 with locking screws 732 for inhibiting movement oftubulars 702. FIG. 151 depicts an arrangement where inhibitors 730 areshown in six separate segments that are individually controlled by sixlocks 732. The profile on inhibitors 730 are such that when all theinhibitor segments are in-place, the inhibitor segments conform exactlyto the contours of the dual tubulars and grip them tight to preventmotion in both the upward and downward directions. The weight of thetubulars is transferred by the inhibitors to a load shoulder (forexample, lip 736) in the wellhead.

Power supplies are used to provide power to downhole power devices(downhole loads) such as, but not limited to, reservoir heaters,electric submersible pumps (ESPs), compressors, electric drills,electrical tools for construction and maintenance, diagnostic systems,sensors, or acoustic wave generators. Surface based power supplies mayhave long supply cabling (power cables) that contribute to problems suchas voltage drops and electrical losses. Thus, it may be necessary toprovide power to the downhole loads at high voltages to reduceelectrical losses. However, many downhole loads are limited by anacceptable supply voltage level to the load. Therefore, an efficienthigh-voltage energy supply may not be viable without furtherconditioning. In such cases, a system for stepping down the voltage fromthe high voltage supply cable to the low voltage load may be necessary.The system may be a transformer.

The electrical power supply for downhole loads is typically providedusing alternating voltage (AC voltage) from supply grids of 50 Hz or 60Hz frequency. The voltage of the supply grid may correspond to thevoltage of the downhole load. High supply voltages may reduce loss andvoltage drop in the supply cable and/or allow the use of supply cableswith relatively small cross sections. High supply voltages, however, maycause technical difficulties and require cost intensive isolationefforts at the load. Voltage drops, electrical losses, and supply cablecross section limits may limit the length of the supply cable and, thus,the wellbore depth or depth of the downhole load. Locating thetransformer downhole may reduce the amount of cabling needed to providepower to the downhole loads and allow deeper wellbore depths and/ordownhole load depths while minimizing voltage drops and electricallosses in the power system.

Current technical solutions for offshore-applications make use ofsea-bed mounted step-down transformers to reduce cable loss (forexample, “Converter-Fed Subsea Motor Drives”, Raad, R. O.; Henriksen,T.; Raphael, H. B.; Hadler-Jacobsen, A.; Industry Applications, IEEETransactions on Volume 32, Issue 5, September-October 1996 Page(s):1069-1079, which is incorporated by reference as if fully set forthherein). However, these sea-bed mounted transformers may not be usefulto drive downhole loads under solid ground (for example, in a subsurfacewellbore).

FIGS. 152 and 153 depict an embodiment of transformer 580 that may belocated in a subsurface wellbore. FIG. 152 depicts a top viewrepresentation of the embodiment of transformer 580 showing the windingsand core of the transformer. FIG. 153 depicts a side view representationof the embodiment of transformer 580 showing the windings, the core, andthe power leads. Transformer 580 includes primary windings 738A andsecondary windings 738B. Primary windings 738A and secondary windings738B may have different cross-sectional areas.

Core 740 may include two half-shell core sections 740A and 740B aroundprimary windings 738A and secondary windings 738B. In certainembodiments, core sections 740A and 740B are semicircular, symmetricshells. Core sections 740A and 740B may be single pieces that extend thefull length of transformer 580 or the core sections may be assembledfrom multiple shell segments put together (for example, multiple piecesstrung together to make the core sections). In certain embodiments, acore section is formed by putting together the section from two halves.The two halves of the core section may be put together after thewindings, which may be pre-fabricated, are placed in the transformer.

In certain embodiments, core sections 740A and 740B have about the samecross section on the circumference of transformer 580 so that the coreproperly guides the magnetic flux in the transformer. Core sections 740Aand 740B may be made of several layers of core material. Certainorientations of these layers may be designed to minimize eddy currentlosses in transformer 580. In some embodiments, core sections 740A and740B are made of continuous ribbons and windings 738A and 738B are woundinto the core sections.

Transformer 580 may have certain advantages over current transformerconfigurations (such as a toroid core design with the winding on theoutside of the cores). Core sections 740A and 740B have outer surfacesthat offer large surface areas for cooling transformer 580.Additionally, transformer 580 may be sealed so that a cooling liquid maybe continuously run across the outer surfaces of the transformer to coolthe transformer. Transformer 580 may be sealed so that cooling liquidsdo not directly contact the inside of the core and/or the windings. Incertain embodiments, transformer is sealed in an epoxy resin or otherelectrically insulating sealing material. Cooling transformer 580 allowsthe transformer to operate at higher power densities. In certainembodiments, windings 738A and 738B are substantially isolated from coresections 740A and 740B so that the outside surfaces of transformer 580may touch the walls of a wellbore without causing electrical problems inthe wellbore.

In some embodiments, the profile of the core of transformer 580 and/orthe winding window profile are made with clearances to allow foradditional cooling devices, mechanical supports, and/or electricalcontacts on the transformer. In some embodiments, transformer 580 iscoupled to one or more additional transformers in the subsurfacewellbore to increase power in the wellbore and/or phase options in thewellbore. Transformer 580 and/or the phases of the transformer may becoupled to the additional transformers, and/or the varying phases of theadditional transformers, in either series or parallel configurations asneeded to provide power to the downhole load.

FIG. 154 depicts an embodiment of transformer 580 in a wellbore 742.Transformer 580 is located in the overburden section of wellbore 742.The overburden section of wellbore 742 has overburden casing 564.Overburden casing 564 electrically and thermally insulates theoverburden from the inside of wellbore 742. Packing material 566 islocated at the bottom of the overburden section of wellbore 742. Packingmaterial 566 inhibits fluid flow between the overburden section ofwellbore 742 and the heating section of the wellbore.

Power lead 744 may be coupled to transformer 580 and pass throughpacking material 566 to provide power to the downhole load (for example,a downhole heater). In certain embodiments, cooling fluid 746 is locatedin wellbore 742. Transformer 580 may be immersed in cooling fluid 746.Cooling fluid 746 may cool transformer 580 by removing heat from thetransformer and moving the heat away from the transformer. Cooling fluid746 may be circulated in wellbore 742 to increase heat transfer betweentransformer 580 and the cooling fluid. In some embodiments, coolingfluid 746 is circulated to a chiller or other heat exchanger to removeheat from the cooling fluid and maintain a temperature of the coolingfluid at a selected temperature. Maintaining cooling fluid 746 at aselected temperature may provide efficient heat transfer between thecooling fluid and transformer 580 so that the transformer is maintainedat a desired operating temperature.

In certain embodiments, cooling fluid 746 maintains a temperature oftransformer 580 below a selected temperature. The selected temperaturemay be a maximum operating temperature of the transformer. In someembodiments, the selected temperature is a maximum temperature thatallows for a selected operational efficiency of the transformer. In someembodiments, transformer 580 operates at an efficiency of at least 95%,at least 90%, at least 80%, or at least 70% when the transformeroperates below the selected temperature.

In certain embodiments, cooling fluid 746 is water. In some embodiments,cooling fluid 746 is another heat transfer fluid such as, but notlimited to, oil, ammonia, helium, or Freon® (E. I. du Pont de Nemoursand Company, Wilmington, Del., U.S.A.). In some embodiments, thewellbore adjacent to the overburden functions as a heat pipe.Transformer 580 boils cooling fluid 746. Vaporized cooling fluid 746rises in the wellbore, condenses, and flows back to transformer 580.Vaporization of cooling fluid 746 transfers heat to the cooling fluidand condensation of the cooling fluid allows heat to transfer to theoverburden. Transformer 580 may operate near the vaporizationtemperature of cooling fluid 746.

In some embodiments, cooling fluid is circulated in a pipe thatsurrounds the transformer. The pipe may be in direct thermal contactwith the transformer so that heat is removed from the transformer intothe cooling fluid circulating through the pipe. In some embodiments, thetransformer includes fans, heat sinks, fins, or other devices thatassist in transferring heat away from the transformer. In someembodiments, the transformer is, or includes, a solid state transformerdevice such as an AC to DC converter.

In certain embodiments, the cooling fluid for the downhole transformeris circulated using a heat pipe in the wellbore. FIG. 155 depicts anembodiment of transformer 580 in wellbore 742 with heat pipes 748A,B.Lid 750 is placed at the top of a reservoir of cooling fluid 746 thatsurrounds transformer 580. Heated cooling fluid expands and flows upheat pipe 748A. The heated cooling fluid 746 cools adjacent to theoverburden and flows back to lid 750. The cooled cooling fluid 746 flowsback into the reservoir through heat pipe 748B. Heat pipes 748A,B act tocreate a flow path for the cooling fluid so that the cooling fluidcirculates around transformer 580 and maintains a temperature of thetransformer below the selected temperature.

Computational analysis has shown that a circulated water column wassufficient to cool a 60 Hz transformer that was 125 feet in length andgenerated 80 W/ft of heat. The transformer and the formation wereinitially at ambient temperatures. The water column was initially at anelevated temperature. The water column and transformer cooled over aperiod of about 1 to 2 hours. The transformer initially heated up (butwas still at operable temperatures) but then was cooled by the watercolumn to lower operable temperatures. The computations also showed thatthe transformer would be cooled by the water column when the transformerand the formation were initially at higher than normal temperatures.

Modern utility voltage regulators have microprocessor controllers thatmonitor output voltage and adjust taps up or down to match a desiredsetting. Typical controllers include current monitoring and may beequipped with remote communications capabilities. The controllerfirmware may be modified for current based control (for example, controldesired for maintaining constant wattage as heater resistances vary withtemperature). Load resistance monitoring as well as other electricalanalysis based evaluation are a possibility because of the availabilityof both current and voltage sensing by the controller. Typical tapchangers have a 200% of nominal, short time current rating. Thus, theregulator controller may be programmed to respond to overload currentsby means of tap changer operation.

Electronic heater controls such as silicon-controlled rectifiers (SCRs)may be used to provide power to and control subsurface heaters. SCRs maybe expensive to use and may waste electrical energy in the powercircuit. SCRs may also produce harmonic distortions during power controlof the subsurface heaters. Harmonic distortion may put noise on thepower line and stress heaters. In addition, SCRs may overly stressheaters by switching the power between being full on and full off ratherthan regulating the power at or near the ideal current setting. Thus,there may be significant overshooting and/or undershooting at the targetcurrent for temperature limited heaters (for example, heaters usingferromagnetic materials for self-limiting temperature control).

A variable voltage, load tap changing transformer, which is based on aload tap changing regulator design, may be used to provide power to andcontrol subsurface heaters more simply and without the harmonicdistortion associated with electronic heater control. The variablevoltage transformer may be connected to power distribution systems bysimple, inexpensive fused cutouts. The variable voltage transformer mayprovide a cost effective, stand alone, full function heater controllerand isolation transformer.

FIG. 156 depicts a schematic for a conventional design of tap changingvoltage regulator 752. Regulator 752 provides plus or minus 10%adjustment of the input or line voltage. Regulator 752 includes primarywinding 754 and tap changer section 756, which includes the secondarywinding of the regulator. Primary winding 754 is a series windingelectrically coupled to the secondary winding of tap changer section756. Tap changer section 756 includes eight taps 758A-H that separatethe voltage on the secondary winding into voltage steps. Moveable tapchanger 760 is a moveable preventive autotransformer with a balancewinding. Tap changer 760 may be a sliding tap changer that moves betweentaps 758A-H in tap changer section 756. Tap changer 760 may be capableof carrying high currents up to, for example, 668 A or more.

Tap changer 760 contacts either one tap 758 or bridges between two tapsto provide a midpoint between the two tap voltages. Thus, 16 equivalentvoltage steps are created for tap changer 760 to couple to in tapchanger section 756. The voltage steps divide the 10% range ofregulation equally (⅝% per step). Switch 762 changes the voltageadjustment between plus and minus adjustment. Thus, voltage can beregulated plus 10% or minus 10% from the input voltage.

Voltage transformer 764 senses the potential at bushing 766. Thepotential at bushing 766 may be used for evaluation by a microprocessorcontroller. The controller adjusts the tap position to match a presetvalue. Control power transformer 768 provides power to operate thecontroller and the tap changer motor. Current transformer 770 is used tosense current in the regulator.

FIG. 157 depicts a schematic for variable voltage, load tap changingtransformer 772. The schematic for transformer 772 is based on the loadtap changing regulator schematic depicted in FIG. 156. Primary winding754 is isolated from the secondary winding of tap changer section 756 tocreate distinct primary and secondary windings. Primary winding 754 maybe coupled to a voltage source using bushings 774, 776. The voltagesource may provide a first voltage across primary winding 754. The firstvoltage may be a high voltage such as voltages of at least 5 kV, atleast 10 kV, at least 25 kV, or at least 35 kV up to about 50 kV. Thesecondary winding in tap changer section 756 may be coupled to anelectrical load (for example, one or more subsurface heaters) usingbushings 778, 780. The electrical load may include, but not be limitedto, an insulated conductor heater (for example, mineral insulatedconductor heater), a conductor-in-conduit heater, a temperature limitedheater, a dual leg heater, or one heater leg of a three-phase heaterconfiguration. The electrical load may be other than a heater (forexample, a bottom hole assembly for forming a wellbore).

The secondary winding in tap changer section 756 steps down the firstvoltage across primary winding 754 to a second voltage (for example,voltage lower than the first voltage or a second voltage). In certainembodiments, the secondary winding in tap changer section 756 steps downthe voltage from primary winding 754 to the second voltage that isbetween 5% and 20% of the first voltage across the primary winding. Insome embodiments, the secondary winding in tap changer section 756 stepsdown the voltage from primary winding 754 to the second voltage that isbetween 1% and 30% or between 3% and 25% of the first voltage across theprimary winding. In one embodiment, the secondary winding in tap changersection 756 steps down the voltage from primary winding 754 to thesecond voltage that is 10% of the first voltage across the primarywinding. For example, a first voltage of 7200 V across the primarywinding may be stepped down to a second voltage of 720 V across thesecondary winding in tap changer section 756.

In some embodiments, the step down percentage in tap changer section 756is preset. In some embodiments, the step down percentage in tap changersection 756 may be adjusted as needed for desired operation of a loadcoupled to transformer 772.

Taps 758A-H (or any other number of taps) divide the second voltage onthe secondary winding in tap changer section 756 into voltage steps. Thesecond voltage is divided into voltage steps from a selected minimumpercentage of the second voltage up to the full value of the secondvoltage. In certain embodiments, the second voltage is divided intoequivalent voltage steps between the selected minimum percentage and thefull second voltage value. In some embodiments, the selected minimumpercentage is 0% of the second voltage. For example, the second voltagemay be equally divided by the taps in voltage steps ranging between 0 Vand 720 V. In some embodiments, the selected minimum percentage is 25%or 50% of the second voltage.

Transformer 772 includes tap changer 760 that contacts either one tap758 or bridges between two taps to provide a midpoint between the twotap voltages. The position of tap changer 760 on the taps determines thevoltage provided to an electrical load coupled to bushings 778, 780. Asan example, an arrangement with 8 taps in tap changer section 756provides 16 voltage steps for tap changer 760 to couple to in tapchanger section 756. Thus, the electrical load may be provided with 16different voltages varying between the selected minimum percentage andthe second voltage.

In certain embodiments of transformer 772, the voltage steps divide therange between the selected minimum percentage and the second voltageequally (the voltage steps are equivalent). For example, eight taps maydivide a second voltage of 720 V into 16 voltage steps between 0 V and720 V so that each tap increments the voltage provided to the electricalload by 45V. In some embodiments, the voltage steps divide the rangebetween the selected minimum percentage and the second voltage innon-equal increments (the voltage steps are not equivalent).

Switch 762 may be used to electrically disconnect bushing 780 from thesecondary winding and taps 758. Electrically isolating bushing 780 fromthe secondary winding turns off the power (voltage) provided to theelectrical load coupled to bushings 778, 780. Thus, switch 762 providesan internal disconnect in transformer 772 to electrically isolate andturn off power (voltage) to the electrical load coupled to thetransformer.

In transformer 772, voltage transformer 764, control power transformer768, and current transformer 770 are electrically isolated from primarywinding 754. Electrical isolation protects voltage transformer 764,control power transformer 768, and current transformer 770 from currentand/or voltage overloads caused by primary winding 754.

In certain embodiments, transformer 772 is used to provide power to avariable electrical load (for example, a subsurface heater such as, butnot limited to, a temperature limited heater using ferromagneticmaterial that self-limits at the Curie temperature or a phase transitiontemperature range). Transformer 772 allows power to the electrical loadto be adjusted in small voltage increments (voltage steps) by moving tapchanger 760 between taps 758. Thus, the voltage supplied to theelectrical load may be adjusted incrementally to provide constantcurrent to the electrical load in response to changes in the electricalload (for example, changes in resistance of the electrical load).Voltage to the electrical load may be controlled from a minimum voltage(the selected minimum percentage) up to full potential (the secondvoltage) in increments. The increments may be equal increments ornon-equal increments. Thus, power to the electrical load does not haveto be turned full on or off to control the electrical load such as isdone with a SCR controller. Using small increments may reduce cyclingstress on the electrical load and may increase the lifetime of thedevice that is the electrical load. Transformer 772 changes the voltageusing mechanical operation instead of the electrical switching used inSCRs. Electrical switching can add harmonics and/or noise to the voltagesignal provided to the electrical load. The mechanical switching oftransformer 772 provides clean, noise free, incrementally adjustablecontrol of the voltage provided to the electrical load.

Transformer 772 may be controlled by controller 782. Controller 782 maybe a microprocessor controller. Controller 782 may be powered by controlpower transformer 768. Controller 782 may assess properties oftransformer 772, including tap changer section 756, and/or theelectrical load coupled to the transformer. Examples of properties thatmay be assessed by controller 782 include, but are not limited to,voltage, current, power, power factor, harmonics, tap change operationcount, maximum and minimum value recordings, wear of the tap changercontacts, and electrical load resistance.

In certain embodiments, controller 782 is coupled to the electrical loadto assess properties of the electrical load. For example, controller 782may be coupled to the electrical load using an optical fiber. Theoptical fiber allows measurement of properties of the electrical loadsuch as, but not limited to, electrical resistance, impedance,capacitance, and/or temperature. In some embodiments, controller 782 iscoupled to voltage transformer 764 and/or current transformer 770 toassess the voltage and/or current output of transformer 772. In someembodiments, the voltage and current are used to assess a resistance ofthe electrical load over one or more selected period of times. In someembodiments, the voltage and current are used to assess or diagnoseother properties of the electrical load (for example, temperature).

In certain embodiments, controller 782 adjusts the voltage output oftransformer 772 in response to changes in the electrical load coupled tothe transformer or other changes in the power distribution system suchas, but not limited to, input voltage to the primary winding or otherpower supply changes. For example, controller 782 may adjust the voltageoutput of transformer 772 in response to changes in the electricalresistance of the electrical load. Controller 782 may adjust the outputvoltage by controlling the movement of control tap changer 760 betweentaps 758 to adjust the voltage output of transformer 772. In someembodiments, controller 782 adjusts the voltage output of transformer772 so that the electrical load (for example, a subsurface heater) isoperated at a relatively constant current. In some embodiments,controller 782 may adjust the voltage output of transformer 772 bymoving tap changer 760 to a new tap, assess the resistance and/or powerat the new tap, and move the tap changer to another new tap if needed.

In some embodiments, controller 782 assesses the electrical resistanceof the load (for example, by measuring the voltage and current using thevoltage and current transformers or by measuring the resistance of theelectrical load using the optical fiber) and compares the assessedelectrical resistance to a theoretical resistance. Controller 782 mayadjust the voltage output of transformer 772 in response to differencesbetween the assessed resistance and the theoretical resistance. In someembodiments, the theoretical resistance is an ideal resistance foroperation of the electrical load. In some embodiments, the theoreticalresistance varies over time due to other changes in the electrical load(for example, temperature of the electrical load).

In some embodiments, controller 782 is programmable to cycle tap changer760 between two or more taps 758 to achieve intermediate voltage outputs(for example, a voltage output between two tap voltage outputs).Controller 782 may adjust the time tap changer 760 is on each of thetaps cycled between to obtain an average voltage at or near the desiredintermediate voltage output. For example, controller 782 may keep tapchanger 760 at two taps approximately 50% of the time each to maintainan average voltage approximately midway between the voltages at the twotaps.

In some embodiments, controller 782 is programmable to limit the numbersof voltage changes (movement of tap changer 760 between taps 758 orcycles of tap changes) over a period of time. For example, controller782 may only allow 1 tap change every 30 minutes or 2 tap changes perhour. Limiting the number of tap changes over the period of time reducesthe stress on the electrical load (for example, a heater) from changesin voltage to the load. Reducing the stresses applied to the electricalload may increase the lifetime of the electrical load. Limiting thenumber of tap changes may also increase the lifetime of the tap changerapparatus. In some embodiments, the number of tap changes over theperiod of time is adjustable using the controller. For example, a usermay be allowed to adjust the cycle limit for tap changes on transformer772.

In some embodiments, controller 782 is programmable to power theelectrical load in a start up sequence. For example, subsurface heatersmay require a certain start up protocol (such as high current duringearly times of heating and lower current as the temperature of theheater reaches a set point). Ramping up power to the heaters in adesired procedure may reduce mechanical stresses on the heaters frommaterials expanding at different rates. In some embodiments, controller782 ramps up power to the electrical load with controlled increases involtage steps over time. In some embodiments, controller 782 ramps uppower to the electrical load with controlled increases in watts perhour. Controller 782 may be programmed to automatically start up theelectrical load according to a user input start up procedure or apre-programmed start up procedure.

In some embodiments, controller 782 is programmable to turn off power tothe electrical load in a shut down sequence. For example, subsurfaceheaters may require a certain shut down protocol to inhibit the heatersfrom cooling to quickly. Controller 782 may be programmed toautomatically shut down the electrical load according to a user inputshut down procedure or a pre-programmed shut down procedure.

In some embodiments, controller 782 is programmable to power theelectrical load in a moisture removal sequence. For example, subsurfaceheaters or motors may require start up at second voltages to removemoisture from the system before application of higher voltages. In someembodiments, controller 782 inhibits increases in voltage until requiredelectrical load resistance values are met. Limiting increases in voltagemay inhibit transformer 772 from applying voltages that cause shortingdue to moisture in the system. Controller 782 may be programmed toautomatically start up the electrical load according to a user inputmoisture removal sequence or a pre-programmed moisture removalprocedure.

In some embodiments, controller 782 is programmable to reduce power tothe electrical load based on changes in the voltage input to primarywinding 754. For example, the power to the electrical load may bereduced during brownouts or other power supply shortages. Reducing thepower to the electrical load may compensate for the reduced powersupply.

In some embodiments, controller 782 is programmable to protect theelectrical load from being overloaded. Controller 782 may be programmedto automatically and immediately reduce the voltage output if thecurrent to the electrical load increases above a selected value. Thevoltage output may be stepped down as fast as possible while sensing thecurrent. Sensing of the current occurs on a faster time scale than thestep downs in voltage so the voltage may be stepped down as fast aspossible until the current drops below a selected level. In someembodiments, tap changes (voltage steps) may be inhibited above highercurrent levels. At the higher current levels, secondary fusing may beused to limit the current. Reducing the tap setting in response to thehigher current levels may allow for continued operation of thetransformer even after partial failure or quenching of electrical loadssuch as heaters.

In some embodiments, controller 782 records or tracks data from theoperation of the electrical load and/or transformer 772. For example,controller 782 may record changes in the resistance or other propertiesof the electrical load or transformer 772. In some embodiments,controller 782 records faults in operation of transformer 772 (forexample, missed step changes).

In certain embodiments, controller 782 includes communication modules.The communication modules may be programmed to provide status, data,and/or diagnostics for any device or system coupled to the controllersuch as the electrical load or transformer 772. The communicationmodules may communicate using RS485 serial communication, Ethernet,fiber, wireless, and/or other communication technologies known in theart. The communication modules may be used to transmit informationremotely to another site so that controller 782 and transformer 772 areoperated in a self-contained or automatic manner but are able to reportto another location (for example, a central monitoring location). Thecentral monitoring location may monitor several controllers andtransformers (for example, controllers and transformers located in ahydrocarbon processing field). In some embodiments, users or equipmentat the central monitoring location are able to remotely operate one ormore of the controllers using the communications modules.

FIG. 158 depicts a representation of an embodiment of transformer 772and controller 782. In certain embodiments, transformer 772 is enclosedin. Enclosure 784 may be a cylindrical can. Enclosure 784 may be anyother suitable enclosure known in the art (for example, a substationstyle rectangular enclosure). Controller 782 may be mounted to theoutside of. Bushings 774, 776, 778, and 780 may be open air, highvoltage bushings located on the outside of for coupling transformer 772to the power supply and the electrical load.

In certain embodiments, is mounted on a pole or otherwise supported offthe ground. In some embodiments, one or more enclosures 784 are mountedon an elevated platform supported by a pole or elevated mountingsupport. Mounting on a pole or mounting support increases aircirculation around and in the enclosure and transformer 772. Increasingair circulation decreases operating temperatures and increasesefficiency of the transformer. In certain embodiments, components oftransformer 772 are coupled to the top of so that the components areremoved as a single unit from the enclosure by removing the top of theenclosure.

In certain embodiments, three transformers 772 are used to operatethree, or multiples of three, electrical loads in a three-phaseconfiguration. The three transformers may be monitored to assess if thetap positions in each transformer are in sync (at the same tapposition). In some embodiments, one controller 782 is used to controlthe three transformers. The controller may monitor the transformers toensure that the transformers are in sync.

In certain embodiments, a temperature limited heater is utilized forheavy oil applications (for example, treatment of relatively permeableformations or tar sands formations). A temperature limited heater mayprovide a relatively low Curie temperature and/or phase transformationtemperature range so that a maximum average operating temperature of theheater is less than 350° C., 300° C., 250° C., 225° C., 200° C., or 150°C. In an embodiment (for example, for a tar sands formation), a maximumtemperature of the temperature limited heater is less than about 250° C.to inhibit olefin generation and production of other cracked products.In some embodiments, a maximum temperature of the temperature limitedheater is above about 250° C. to produce lighter hydrocarbon products.In some embodiments, the maximum temperature of the heater may be at orless than about 500° C.

A heater may heat a volume of formation adjacent to a productionwellbore (a near production wellbore region) so that the temperature offluid in the production wellbore and in the volume adjacent to theproduction wellbore is less than the temperature that causes degradationof the fluid. The heat source may be located in the production wellboreor near the production wellbore. In some embodiments, the heat source isa temperature limited heater. In some embodiments, two or more heatsources may supply heat to the volume. Heat from the heat source mayreduce the viscosity of crude oil in or near the production wellbore. Insome embodiments, heat from the heat source mobilizes fluids in or nearthe production wellbore and/or enhances the flow of fluids to theproduction wellbore. In some embodiments, reducing the viscosity ofcrude oil allows or enhances gas lifting of heavy oil (at most about 10°API gravity oil) or intermediate gravity oil (approximately 12° to 20°API gravity oil) from the production wellbore. In certain embodiments,the initial API gravity of oil in the formation is at most 10°, at most20°, at most 25°, or at most 30°. In certain embodiments, the viscosityof oil in the formation is at least 0.05 Pa·s (50 cp). In someembodiments, the viscosity of oil in the formation is at least 0.10 Pa·s(100 cp), at least 0.15 Pa·s (150 cp), or at least at least 0.20 Pa·s(200 cp). Large amounts of natural gas may have to be utilized toprovide gas lift of oil with viscosities above 0.05 Pa·s. Reducing theviscosity of oil at or near the production wellbore in the formation toa viscosity of 0.05 Pa·s (50 cp), 0.03 Pa·s (30 cp), 0.02 Pa·s (20 cp),0.01 Pa·s (10 cp), or less (down to 0.001 Pa·s (1 cp) or lower) lowersthe amount of natural gas or other fluid needed to lift oil from theformation. In some embodiments, reduced viscosity oil is produced byother methods such as pumping.

The rate of production of oil from the formation may be increased byraising the temperature at or near a production wellbore to reduce theviscosity of the oil in the formation in and adjacent to the productionwellbore. In certain embodiments, the rate of production of oil from theformation is increased by 2 times, 3 times, 4 times, or greater, or upto 20 times over standard cold production, which has no external heatingof formation during production. Certain formations may be moreeconomically viable for enhanced oil production using the heating of thenear production wellbore region. Formations that have a cold productionrate approximately between 0.05 m³/(day per meter of wellbore length)and 0.20 m³/(day per meter of wellbore length) may have significantimprovements in production rate using heating to reduce the viscosity inthe near production wellbore region. In some formations, productionwells up to 775 m, up to 1000 m, or up to 1500 m in length are used.Thus, a significant increase in production is achievable in someformations. Heating the near production wellbore region may be used informations where the cold production rate is not between 0.05 m³/(dayper meter of wellbore length) and 0.20 m³/(day per meter of wellborelength), but heating such formations may not be as economicallyfavorable. Higher cold production rates may not be significantlyincreased by heating the near wellbore region, while lower productionrates may not be increased to an economically useful value.

Using the temperature limited heater to reduce the viscosity of oil ator near the production well inhibits problems associated withnon-temperature limited heaters and heating the oil in the formation dueto hot spots. One possible problem is that non-temperature limitedheaters can cause coking of oil at or near the production well if theheater overheats the oil because the heaters are at too high atemperature. Higher temperatures in the production well may also causebrine to boil in the well, which may lead to scale formation in thewell. Non-temperature limited heaters that reach higher temperatures mayalso cause damage to other wellbore components (for example, screensused for sand control, pumps, or valves). Hot spots may be caused byportions of the formation expanding against or collapsing on the heater.In some embodiments, the heater (either the temperature limited heateror another type of non-temperature limited heater) has sections that arelower because of sagging over long heater distances. These lowersections may sit in heavy oil or bitumen that collects in lower portionsof the wellbore. At these lower sections, the heater may develop hotspots due to coking of the heavy oil or bitumen. A standardnon-temperature limited heater may overheat at these hot spots, thusproducing a non-uniform amount of heat along the length of the heater.Using the temperature limited heater may inhibit overheating of theheater at hot spots or lower sections and provide more uniform heatingalong the length of the wellbore.

In certain embodiments, fluids in the relatively permeable formationcontaining heavy hydrocarbons are produced with little or nopyrolyzation of hydrocarbons in the formation. In certain embodiments,the relatively permeable formation containing heavy hydrocarbons is atar sands formation. For example, the formation may be a tar sandsformation such as the Athabasca tar sands formation in Alberta, Canadaor a carbonate formation such as the Grosmont carbonate formation inAlberta, Canada. The fluids produced from the formation are mobilizedfluids. Producing mobilized fluids may be more economical than producingpyrolyzed fluids from the tar sands formation. Producing mobilizedfluids may also increase the total amount of hydrocarbons produced fromthe tar sands formation.

FIGS. 159-162 depict side view representations of embodiments forproducing mobilized fluids from tar sands formations. In FIGS. 159-162,heaters 438 have substantially horizontal heating sections inhydrocarbon layer 484 (as shown, the heaters have heating sections thatgo into and out of the page). Hydrocarbon layer 484 may be belowoverburden 482. FIG. 159 depicts a side view representation of anembodiment for producing mobilized fluids from a tar sands formationwith a relatively thin hydrocarbon layer. FIG. 160 depicts a side viewrepresentation of an embodiment for producing mobilized fluids from ahydrocarbon layer that is thicker than the hydrocarbon layer depicted inFIG. 159. FIG. 161 depicts a side view representation of an embodimentfor producing mobilized fluids from a hydrocarbon layer that is thickerthan the hydrocarbon layer depicted in FIG. 160. FIG. 162 depicts a sideview representation of an embodiment for producing mobilized fluids froma tar sands formation with a hydrocarbon layer that has a shale break.

In FIG. 159, heaters 438 are placed in an alternating triangular patternin hydrocarbon layer 484. In FIGS. 160, 161, and 162, heaters 438 areplaced in an alternating triangular pattern in hydrocarbon layer 484that repeats vertically to encompass a majority or all of thehydrocarbon layer. In FIG. 162, the alternating triangular pattern ofheaters 438 in hydrocarbon layer 484 repeats uninterrupted across shalebreak 786. In FIGS. 159-162, heaters 438 may be equidistantly spacedfrom each other. In the embodiments depicted in FIGS. 159-162, thenumber of vertical rows of heaters 438 depends on factors such as, butnot limited to, the desired spacing between the heaters, the thicknessof hydrocarbon layer 484, and/or the number and location of shale breaks786. In some embodiments, heaters 438 are arranged in other patterns.For example, heaters 438 may be arranged in patterns such as, but notlimited to, hexagonal patterns, square patterns, or rectangularpatterns.

In the embodiments depicted in FIGS. 159-162, heaters 438 provide heatthat mobilizes hydrocarbons (reduces the viscosity of the hydrocarbons)in hydrocarbon layer 484. In certain embodiments, heaters 438 provideheat that reduces the viscosity of the hydrocarbons in hydrocarbon layer484 below about 0.50 Pa·s (500 cp), below about 0.10 Pa·s (100 cp), orbelow about 0.05 Pa·s (50 cp). The spacing between heaters 438 and/orthe heat output of the heaters may be designed and/or controlled toreduce the viscosity of the hydrocarbons in hydrocarbon layer 484 todesirable values. Heat provided by heaters 438 may be controlled so thatlittle or no pyrolyzation occurs in hydrocarbon layer 484. Superpositionof heat between the heaters may create one or more drainage paths (forexample, paths for flow of fluids) between the heaters. In certainembodiments, production wells 206A and/or production wells 206B arelocated proximate heaters 438 so that heat from the heaters superimposesover the production wells. The superimposition of heat from heaters 438over production wells 206A and/or production wells 206B creates one ormore drainage paths from the heaters to the production wells. In certainembodiments, one or more of the drainage paths converge. For example,the drainage paths may converge at or near a bottommost heater and/orthe drainage paths may converge at or near production wells 206A and/orproduction wells 206B. Fluids mobilized in hydrocarbon layer 484 tend toflow towards the bottommost heaters 438, production wells 206A and/orproduction wells 206B in the hydrocarbon layer because of gravity andthe heat and pressure gradients established by the heaters and/or theproduction wells. The drainage paths and/or the converged drainage pathsallow production wells 206A and/or production wells 206B to collectmobilized fluids in hydrocarbon layer 484.

In certain embodiments, hydrocarbon layer 484 has sufficientpermeability to allow mobilized fluids to drain to production wells 206Aand/or production wells 206B. For example, hydrocarbon layer 484 mayhave a permeability of at least about 0.1 darcy, at least about 1 darcy,at least about 10 darcy, or at least about 100 darcy. In someembodiments, hydrocarbon layer 484 has a relatively large verticalpermeability to horizontal permeability ratio (K_(v)/K_(h)). Forexample, hydrocarbon layer 484 may have a K_(v)/K_(h) ratio betweenabout 0.01 and about 2, between about 0.1 and about 1, or between about0.3 and about 0.7.

In certain embodiments, fluids are produced through production wells206A located near heaters 438 in the lower portion of hydrocarbon layer484. In some embodiments, fluids are produced through production wells206B located below and approximately midway between heaters 438 in thelower portion of hydrocarbon layer 484. At least a portion of productionwells 206A and/or production wells 206B may be oriented substantiallyhorizontal in hydrocarbon layer 484 (as shown in FIGS. 159-162, theproduction wells have horizontal portions that go into and out of thepage). Production wells 206A and/or 206B may be located proximate lowerportion heaters 438 or the bottommost heaters.

In some embodiments, production wells 206A are positioned substantiallyvertically below the bottommost heaters in hydrocarbon layer 484.Production wells 206A may be located below heaters 438 at the bottomvertex of a pattern of the heaters (for example, at the bottom vertex ofthe triangular pattern of heaters depicted in FIGS. 159-162). Locatingproduction wells 206A substantially vertically below the bottommostheaters may allow for efficient collection of mobilized fluids fromhydrocarbon layer 484.

In certain embodiments, the bottommost heaters are located between about2 m and about 10 m from the bottom of hydrocarbon layer 484, betweenabout 4 m and about 8 m from the bottom of the hydrocarbon layer, orbetween about 5 m and about 7 m from the bottom of the hydrocarbonlayer. In certain embodiments, production wells 206A and/or productionwells 206B are located at a distance from the bottommost heaters 438that allows heat from the heaters to superimpose over the productionwells but at a distance from the heaters that inhibits coking at theproduction wells. Production wells 206A and/or production wells 206B maybe located a distance from the nearest heater (for example, thebottommost heater) of at most ¾ of the spacing between heaters in thepattern of heaters (for example, the triangular pattern of heatersdepicted in FIGS. 159-162). In some embodiments, production wells 206Aand/or production wells 206B are located a distance from the nearestheater of at most %, at most ½, or at most ⅓ of the spacing betweenheaters in the pattern of heaters. In certain embodiments, productionwells 206A and/or production wells 206B are located between about 2 mand about 10 m from the bottommost heaters, between about 4 m and about8 m from the bottommost heaters, or between about 5 m and about 7 m fromthe bottommost heaters. Production wells 206A and/or production wells206B may be located between about 0.5 m and about 8 m from the bottom ofhydrocarbon layer 484, between about 1 m and about 5 m from the bottomof the hydrocarbon layer, or between about 2 m and about 4 m from thebottom of the hydrocarbon layer.

In some embodiments, at least some production wells 206A are locatedsubstantially vertically below heaters 438 near shale break 786, asdepicted in FIG. 162. Production wells 206A may be located betweenheaters 438 and shale break 786 to produce fluids that flow and collectabove the shale break. Shale break 786 may be an impermeable barrier inhydrocarbon layer 484. In some embodiments, shale break 786 has athickness between about 1 m and about 6 m, between about 2 m and about 5m, or between about 3 m and about 4 m. Production wells 206A betweenheaters 438 and shale break 786 may produce fluids from the upperportion of hydrocarbon layer 484 (above the shale break) and productionwells 206A below the bottommost heaters in the hydrocarbon layer mayproduce fluids from the lower portion of the hydrocarbon layer (belowthe shale break), as depicted in FIG. 162. In some embodiments, two ormore shale breaks may exist in a hydrocarbon layer. In such anembodiment, production wells are placed at or near each of the shalebreaks to produce fluids flowing and collecting above the shale breaks.

In some embodiments, shale break 786 breaks down (is desiccated ordecomposes) as the shale break is heated by heaters 438 on either sideof the shale break. As shale break 786 breaks down, the permeability ofthe shale break increases and fluids flow through the shale break. Oncefluids are able to flow through shale break 786, production wells abovethe shale break may not be needed for production as fluids can flow toproduction wells at or near the bottom of hydrocarbon layer 484 and beproduced there.

In certain embodiments, the bottommost heaters above shale break 786 arelocated between about 2 m and about 10 m from the shale break, betweenabout 4 m and about 8 m from the bottom of the shale break, or betweenabout 5 m and about 7 m from the shale break. Production wells 206A maybe located between about 2 m and about 10 m from the bottommost heatersabove shale break 786, between about 4 m and about 8 m from thebottommost heaters above the shale break, or between about 5 m and about7 m from the bottommost heaters above the shale break. Production wells206A may be located between about 0.5 m and about 8 m from shale break786, between about 1 m and about 5 m from the shale break, or betweenabout 2 m and about 4 m from the shale break.

In some embodiments, heat is provided in production wells 206A and/orproduction wells 206B, depicted in FIGS. 159-162. Providing heat inproduction wells 206A and/or production wells 206B may maintain and/orenhance the mobility of the fluids in the production wells. Heatprovided in production wells 206A and/or production wells 206B maysuperimpose with heat from heaters 438 to create the flow path from theheaters to the production wells. In some embodiments, production wells206A and/or production wells 206B include a pump to move fluids to thesurface of the formation. In some embodiments, the viscosity of fluids(oil) in production wells 206A and/or production wells 206B is loweredusing heaters and/or diluent injection (for example, using a conduit inthe production wells for injecting the diluent).

In certain embodiments, in situ heat treatment of the relativelypermeable formation containing hydrocarbons (for example, the tar sandsformation) includes heating the formation to visbreaking temperatures.For example, the formation may be heated to temperatures between about100° C. and 260° C., between about 150° C. and about 250° C., betweenabout 200° C. and about 240° C., between about 205° C. and 230° C.,between about 210° C. and 225° C. In one embodiment, the formation isheated to a temperature of about 220° C. In one embodiment, theformation is heated to a temperature of about 230° C. At visbreakingtemperatures, fluids in the formation have a reduced viscosity (versustheir initial viscosity at initial formation temperature) that allowsfluids to flow in the formation. The reduced viscosity at visbreakingtemperatures may be a permanent reduction in viscosity as thehydrocarbons go through a step change in viscosity at visbreakingtemperatures (versus heating to mobilization temperatures, which mayonly temporarily reduce the viscosity). The visbroken fluids may haveAPI gravities that are relatively low (for example, at most about 10°,about 12°, about 15°, or about 19° API gravity), but the API gravitiesare higher than the API gravity of non-visbroken fluid from theformation. The non-visbroken fluid from the formation may have an APIgravity of 7° or less.

In some embodiments, heaters in the formation are operated at full poweroutput to heat the formation to visbreaking temperatures or highertemperatures. Operating at full power may rapidly increase the pressurein the formation. In certain embodiments, fluids are produced from theformation to maintain a pressure in the formation below a selectedpressure as the temperature of the formation increases. In someembodiments, the selected pressure is a fracture pressure of theformation. In certain embodiments, the selected pressure is betweenabout 1000 kPa and about 15000 kPa, between about 2000 kPa and about10000 kPa, or between about 2500 kPa and about 5000 kPa. In oneembodiment, the selected pressure is about 10000 kPa. Maintaining thepressure as close to the fracture pressure as possible may minimize thenumber of production wells needed for producing fluids from theformation.

In certain embodiments, treating the formation includes maintaining thetemperature at or near visbreaking temperatures (as described above)during the entire production phase while maintaining the pressure belowthe fracture pressure. The heat provided to the formation may be reducedor eliminated to maintain the temperature at or near visbreakingtemperatures. Heating to visbreaking temperatures but maintaining thetemperature below pyrolysis temperatures or near pyrolysis temperatures(for example, below about 230° C.) inhibits coke formation and/or higherlevel reactions. Heating to visbreaking temperatures at higher pressures(for example, pressures near but below the fracture pressure) keepsproduced gases in the liquid oil (hydrocarbons) in the formation andincreases hydrogen reduction in the formation with higher hydrogenpartial pressures. Heating the formation to only visbreakingtemperatures also uses less energy input than heating the formation topyrolysis temperatures.

Fluids produced from the formation may include visbroken fluids,mobilized fluids, and/or pyrolyzed fluids. In some embodiments, aproduced mixture that includes these fluids is produced from theformation. The produced mixture may have assessable properties (forexample, measurable properties). The produced mixture properties aredetermined by operating conditions in the formation being treated (forexample, temperature and/or pressure in the formation). In certainembodiments, the operating conditions may be selected, varied, and/ormaintained to produce desirable properties in hydrocarbons in theproduced mixture. For example, the produced mixture may includehydrocarbons that have properties that allow the mixture to be easilytransported (for example, sent through a pipeline without adding diluentor blending the mixture and/or resulting hydrocarbons with anotherfluid).

In some embodiments, after the formation reaches visbreakingtemperatures, the pressure in the formation is reduced. In certainembodiments, the pressure in the formation is reduced at temperaturesabove visbreaking temperatures. Reducing the pressure at highertemperatures allows more of the hydrocarbons in the formation to beconverted to higher quality hydrocarbons by visbreaking and/orpyrolysis. Allowing the formation to reach higher temperatures beforepressure reduction, however, may increase the amount of carbon dioxideproduced and/or the amount of coking in the formation. For example, insome formations, coking of bitumen (at pressures above 700 kPa) beginsat about 280° C. and reaches a maximum rate at about 340° C. Atpressures below about 700 kPa, the coking rate in the formation isminimal. Allowing the formation to reach higher temperatures beforepressure reduction may decrease the amount of hydrocarbons produced fromthe formation.

In certain embodiments, the temperature in the formation (for example,an average temperature of the formation) when the pressure in theformation is reduced is selected to balance one or more factors. Thefactors considered may include: the quality of hydrocarbons produced,the amount of hydrocarbons produced, the amount of carbon dioxideproduced, the amount hydrogen sulfide produced, the degree of coking inthe formation, and/or the amount of water produced. Experimentalassessments using formation samples and/or simulated assessments basedon the formation properties may be used to assess results of treatingthe formation using the in situ heat treatment process. These resultsmay be used to determine a selected temperature, or temperature range,for when the pressure in the formation is to be reduced. The selectedtemperature, or temperature range, may also be affected by factors suchas, but not limited to, hydrocarbon or oil market conditions and othereconomic factors. In certain embodiments, the selected temperature is ina range between about 275° C. and about 305° C., between about 280° C.and about 300° C., or between about 285° C. and about 295° C.

In certain embodiments, an average temperature in the formation isassessed from an analysis of fluids produced from the formation. Forexample, the average temperature of the formation may be assessed froman analysis of the fluids that have been produced to maintain thepressure in the formation below the fracture pressure of the formation.

In some embodiments, values of the hydrocarbon isomer shift in fluids(for example, gases) produced from the formation is used to indicate theaverage temperature in the formation. Experimental analysis and/orsimulation may be used to assess one or more hydrocarbon isomer shiftsand relate the values of the hydrocarbon isomer shifts to the averagetemperature in the formation. The assessed relation between thehydrocarbon isomer shifts and the average temperature may then be usedin the field to assess the average temperature in the formation bymonitoring one or more of the hydrocarbon isomer shifts in fluidsproduced from the formation. In some embodiments, the pressure in theformation is reduced when the monitored hydrocarbon isomer shift reachesa selected value. The selected value of the hydrocarbon isomer shift maybe chosen based on the selected temperature, or temperature range, inthe formation for reducing the pressure in the formation and theassessed relation between the hydrocarbon isomer shift and the averagetemperature. Examples of hydrocarbon isomer shifts that may be assessedinclude, but are not limited to, n-butane-δ¹³C₄ percentage versuspropane-δ¹³C₃ percentage, n-pentane-δ¹³C₅ percentage versuspropane-δ¹³C₃ percentage, n-pentane-δ¹³C₅ percentage versusn-butane-δ¹³C₄ percentage, and i-pentane-δ¹³C₅ percentage versusi-butane-δ¹³C₄ percentage. In some embodiments, the hydrocarbon isomershift in produced fluids is used to indicate the amount of conversion(for example, amount of pyrolysis) that has taken place in theformation.

In some embodiments, weight percentages of saturates in fluids producedfrom the formation is used to indicate the average temperature in theformation. Experimental analysis and/or simulation may be used to assessthe weight percentage of saturates as a function of the averagetemperature in the formation. For example, SARA (Saturates, Aromatics,Resins, and Asphaltenes) analysis (sometimes referred to asAsphaltene/Wax/Hydrate Deposition analysis) may be used to assess theweight percentage of saturates in a sample of fluids from the formation.In some formations, the weight percentage of saturates has a linearrelationship to the average temperature in the formation. The relationbetween the weight percentage of saturates and the average temperaturemay then be used in the field to assess the average temperature in theformation by monitoring the weight percentage of saturates in fluidsproduced from the formation. In some embodiments, the pressure in theformation is reduced when the monitored weight percentage of saturatesreaches a selected value. The selected value of the weight percentage ofsaturates may be chosen based on the selected temperature, ortemperature range, in the formation for reducing the pressure in theformation and the relation between the weight percentage of saturatesand the average temperature. In some embodiments, the selected value ofweight percentage of saturates is between about 20% and about 40%,between about 25% and about 35%, or between about 28% and about 32%. Forexample, the selected value may be about 30% by weight saturates.

In some embodiments, weight percentages of n-C₇ in fluids produced fromthe formation is used to indicate the average temperature in theformation. Experimental analysis and/or simulation may be used to assessthe weight percentages of n-C₇ as a function of the average temperaturein the formation. In some formations, the weight percentages of n-C₇ hasa linear relationship to the average temperature in the formation. Therelation between the weight percentages of n-C₇ and the averagetemperature may then be used in the field to assess the averagetemperature in the formation by monitoring the weight percentages ofn-C₇ in fluids produced from the formation. In some embodiments, thepressure in the formation is reduced when the monitored weightpercentage of n-C₇ reaches a selected value. The selected value of theweight percentage of n-C₇ may be chosen based on the selectedtemperature, or temperature range, in the formation for reducing thepressure in the formation and the relation between the weight percentageof n-C₇ and the average temperature. In some embodiments, the selectedvalue of weight percentage of n-C₇ is between about 50% and about 70%,between about 55% and about 65%, or between about 58% and about 62%. Forexample, the selected value may be about 60% by weight n-C₇.

The pressure in the formation may be reduced by producing fluids (forexample, visbroken fluids and/or mobilized fluids) from the formation.In some embodiments, the pressure is reduced below a pressure at whichfluids coke in the formation to inhibit coking at pyrolysistemperatures. For example, the pressure is reduced to a pressure belowabout 1000 kPa, below about 800 kPa, or below about 700 kPa (forexample, about 690 kPa). In certain embodiments, the selected pressureis at least about 100 kPa, at least about 200 kPa, or at least about 300kPa. The pressure may be reduced to inhibit coking of asphaltenes orother high molecular weight hydrocarbons in the formation. In someembodiments, the pressure may be maintained below a pressure at whichwater passes through a liquid phase at downhole (formation) temperaturesto inhibit liquid water and dolomite reactions. After reducing thepressure in the formation, the temperature may be increased to pyrolysistemperatures to begin pyrolyzation and/or upgrading of fluids in theformation. The pyrolyzed and/or upgraded fluids may be produced from theformation.

In certain embodiments, the amount of fluids produced at temperaturesbelow visbreaking temperatures, the amount of fluids produced atvisbreaking temperatures, the amount of fluids produced before reducingthe pressure in the formation, and/or the amount of upgraded orpyrolyzed fluids produced may be varied to control the quality andamount of fluids produced from the formation and the total recovery ofhydrocarbons from the formation. For example, producing more fluidduring the early stages of treatment (for example, producing fluidsbefore reducing the pressure in the formation) may increase the totalrecovery of hydrocarbons from the formation while reducing the overallquality (lowering the overall API gravity) of fluid produced from theformation. The overall quality is reduced because more heavyhydrocarbons are produced by producing more fluids at the lowertemperatures. Producing less fluids at the lower temperatures mayincrease the overall quality of the fluids produced from the formationbut may lower the total recovery of hydrocarbons from the formation. Thetotal recovery may be lower because more coking occurs in the formationwhen less fluids are produced at lower temperatures.

In certain embodiments, the formation is heated using isolated cells ofheaters (cells or sections of the formation that are not interconnectedfor fluid flow). The isolated cells may be created by using largerheater spacings in the formation. For example, large heater spacings maybe used in the embodiments depicted in FIGS. 159-162. These isolatedcells may be produced during early stages of heating (for example, attemperatures below visbreaking temperatures). Because the cells areisolated from other cells in the formation, the pressures in theisolated cells are high and more liquids are producible from theisolated cells. Thus, more liquids may be produced from the formationand a higher total recovery of hydrocarbons may be reached. During laterstages of heating, the heat gradient may interconnect the isolated cellsand pressures in the formation will drop.

In certain embodiments, the heat gradient in the formation is modifiedso that a gas cap is created at or near an upper portion of thehydrocarbon layer. For example, the heat gradient made by heaters 438depicted in the embodiments depicted in FIGS. 159-162 may be modified tocreate the gas cap at or near overburden 482 of hydrocarbon layer 484.The gas cap may push or drive liquids to the bottom of the hydrocarbonlayer so that more liquids may be produced from the formation. In situgeneration of the gas cap may be more efficient than introducingpressurized fluid into the formation. The in situ generated gas capapplies force evenly through the formation with little or no channelingor fingering that may reduce the effectiveness of introduced pressurizedfluid.

In certain embodiments, the number and/or location of production wellsin the formation is varied based on the viscosity of fluid in theformation. The viscosities in the zones may be assessed before placingthe production wells in the formation, before heating the formation,and/or after heating the formation. In some embodiments, more productionwells are located in zones in the formation that have lower viscosities.For example, in certain formations, upper portions, or zones, of theformation may have lower viscosities. Thus, in some embodiments, moreproduction wells are located in the upper zones. Producing throughproduction wells in the less viscous zones of the formation may resultin production of higher quality (more upgraded) oil from the formation.

In some embodiments, more production wells are located in zones in theformation that have higher viscosities. Pressure propagation may beslower in the zones with higher viscosities. The slower pressurepropagation may make it more difficult to control pressure in the zoneswith higher viscosities. Thus, more production wells may be located inthe zones with higher viscosities to provide better pressure control inthese zones.

In some embodiments, zones in the formation with different assessedviscosities are heated at different rates. In certain embodiments, zonesin the formation with higher viscosities are heated at higher heatingrates than zones with lower viscosities. Heating the zones with higherviscosities at the higher heating rates mobilizes and/or upgrades thesezones at a faster rate so that these zones may “catch up” in viscosityand/or quality to the slower heated zones.

In some embodiments, the heater spacing is varied to provide differentheating rates to zones in the formation with different assessedviscosities. For example, denser heater spacings (less spaces betweenheaters) may be used in zones with higher viscosities to heat thesezones at higher heating rates. In some embodiments, a production well(for example, a substantially vertical production well) is located inthe zones with denser heater spacings and higher viscosities. Theproduction well may be used to remove fluids from the formation andrelieve pressure from the higher viscosity zones. In some embodiments,one or more substantially vertical openings, or production wells, arelocated in the higher viscosity zones to allow fluids to drain in thehigher viscosity zones. The draining fluids may be produced from theformation through production wells located near the bottom of the higherviscosity zones.

In certain embodiments, production wells are located in more than onezone in the formation. The zones may have different initialpermeabilities. In certain embodiments, a first zone has an initialpermeability of at least about 1 darcy and a second zone has an initialpermeability of at most about 0.1 darcy. In some embodiments, the firstzone has an initial permeability of between about 1 darcy and about 10darcy. In some embodiments, the second zone has an initial permeabilitybetween about 0.01 darcy and 0.1 darcy. The zones may be separated by asubstantially impermeable barrier (with an initial permeability of about10 darcy or less). Having the production well located in both zonesallows for fluid communication (permeability) between the zones and/orpressure equalization between the zones.

In some embodiments, openings (for example, substantially verticalopenings) are formed between zones with different initial permeabilitiesthat are separated by a substantially impermeable barrier. Bridging thezones with the openings allows for fluid communication (permeability)between the zones and/or pressure equalization between the zones. Insome embodiments, openings in the formation (such as pressure reliefopenings and/or production wells) allow gases or low viscosity fluids torise in the openings. As the gases or low viscosity fluids rise, thefluids may condense or increase viscosity in the openings so that thefluids drain back down the openings to be further upgraded in theformation. Thus, the openings may act as heat pipes by transferring heatfrom the lower portions to the upper portions where the fluids condense.The wellbores may be packed and sealed near or at the overburden toinhibit transport of formation fluid to the surface.

In some embodiments, production of fluids is continued after reducingand/or turning off heating of the formation. The formation may be heatedfor a selected time. The formation may be heated until it reaches aselected average temperature. Production from the formation may continueafter the selected time. Continuing production may produce more fluidfrom the formation as fluids drain towards the bottom of the formationand/or as fluids are upgraded by passing by hot spots in the formation.In some embodiments, a horizontal production well is located at or nearthe bottom of the formation (or a zone of the formation) to producefluids after heating is turned down and/or off.

In certain embodiments, initially produced fluids (for example, fluidsproduced below visbreaking temperatures), fluids produced at visbreakingtemperatures, and/or other viscous fluids produced from the formationare blended with diluent to produce fluids with lower viscosities. Insome embodiments, the diluent includes upgraded or pyrolyzed fluidsproduced from the formation. In some embodiments, the diluent includesupgraded or pyrolyzed fluids produced from another portion of theformation or another formation. In certain embodiments, the amount offluids produced at temperatures below visbreaking temperatures and/orfluids produced at visbreaking temperatures that are blended withupgraded fluids from the formation is adjusted to create a fluidsuitable for transportation and/or use in a refinery. The amount ofblending may be adjusted so that the fluid has chemical and physicalstability. Maintaining the chemical and physical stability of the fluidmay allow the fluid to be transported, reduce pre-treatment processes ata refinery and/or reduce or eliminate the need for adjusting therefinery process to compensate for the fluid.

In certain embodiments, formation conditions (for example, pressure andtemperature) and/or fluid production are controlled to produce fluidswith selected properties. For example, formation conditions and/or fluidproduction may be controlled to produce fluids with a selected APIgravity and/or a selected viscosity. The selected API gravity and/orselected viscosity may be produced by combining fluids produced atdifferent formation conditions (for example, combining fluids producedat different temperatures during the treatment as described above). Asan example, formation conditions and/or fluid production may becontrolled to produce fluids with an API gravity of about 190 and aviscosity of about 0.35 Pa·s (350 cp) at 5° C.

In certain embodiments, a drive process (for example, a steam injectionprocess such as cyclic steam injection, a steam assisted gravitydrainage process (SAGD), a solvent injection process, a vapor solventand SAGD process, or a carbon dioxide injection process) is used totreat the tar sands formation in addition to the in situ heat treatmentprocess. In some embodiments, heaters are used to create highpermeability zones (or injection zones) in the formation for the driveprocess. Heaters may be used to create a mobilization geometry orproduction network in the formation to allow fluids to flow through theformation during the drive process. For example, heaters may be used tocreate drainage paths between the heaters and production wells for thedrive process. In some embodiments, the heaters are used to provide heatduring the drive process. The amount of heat provided by the heaters maybe small compared to the heat input from the drive process (for example,the heat input from steam injection).

The concentration of components in the formation and/or produced fluidsmay change during an in situ heat treatment process. As theconcentration of the components in the formation and/or produced fluidsand/or hydrocarbons separated from the produced fluid changes due toformation of the components, solubility of the components in theproduced fluids and/or separated hydrocarbons tends to change.Hydrocarbons separated from the produced fluid may be hydrocarbons thathave been treated to remove salty water and/or gases from the producedfluid to facilitate transportation the hydrocarbons. For example, theproduced fluids and/or separated hydrocarbons may contain componentsthat are soluble in the condensable hydrocarbon portion of the producedfluids at the beginning of processing. As properties of the hydrocarbonsin the produced fluids change (for example, TAN, asphaltenes, P-value,olefin content, mobilized fluids content, visbroken fluids content,pyrolyzed fluids content, or combinations thereof), the components maytend to become less soluble in the produced fluids and/or in thehydrocarbon stream separated from the produced fluids. In someinstances, components in the produced fluids and/or components in theseparated hydrocarbons may form two phases and/or become insoluble.Formation of two phases, through flocculation of asphaltenes, change inconcentration of components in the produced fluids, change inconcentration of components in separated hydrocarbons, and/orprecipitation of components may result in hydrocarbons that do not meetpipeline, transportation, and/or refining specifications. Additionally,the efficiency of the process may be reduced. For example, furthertreatment of the produced fluids and/or separated hydrocarbons may benecessary to produce products with desired properties.

During processing, the P-value of the separated hydrocarbons may bemonitored and the stability of the produced fluids and/or separatedhydrocarbons may be assessed. Typically, a P-value that is at most 1.0indicates that flocculation of asphaltenes from the separatedhydrocarbons generally occurs. If the P-value is initially at least 1.0,and such P-value increases or is relatively stable during heating, thenthis indicates that the separated hydrocarbons are relatively stabile.Stability of separated hydrocarbons, as assessed by P-value, may becontrolled by controlling operating conditions in the formation such astemperature, pressure, hydrogen uptake, hydrocarbon feed flow, orcombinations thereof.

In some embodiments, change in API gravity may not occur unless theformation temperature is at least 100° C. For some formations,temperatures of at least 220° C. may be required to produce hydrocarbonsthat meet desired specifications. At increased temperatures cokeformation may occur, even at elevated pressures. As the properties ofthe formation are changed, the P-value of the separated hydrocarbons maydecrease below 1.0 and/or sediment may form, causing the separatedhydrocarbons to become unstable.

In some embodiments, olefins may form during heating of formation fluidsto produce fluids having a reduced viscosity. Separated hydrocarbonsthat include olefins may be unacceptable for processing facilities.Olefins in the separated hydrocarbons may cause fouling and/or cloggingof processing equipment. For example, separated hydrocarbons thatcontains olefins may cause coking of distillation units in a refinery,which results in frequent down time to remove the coked material fromthe distillation units.

During processing, the olefin content of separated hydrocarbons may bemonitored and quality of the separated hydrocarbons assessed. Typically,separated hydrocarbons having a bromine number of 3% and/or a CAPPolefin number of 3% as 1-decene equivalent indicates that olefinproduction is occurring. If the olefin value decreases or is relativelystable during producing, then this indicates that a minimal orsubstantially low amount of olefins are being produced. Olefin content,as assessed by bromine value and/or CAPP olefin number, may becontrolled by controlling operating conditions in the formation such astemperature, pressure, hydrogen uptake, hydrocarbon feed flow, orcombinations thereof.

In some embodiments, the P-value and/or olefin content may be controlledby controlling operating conditions. For example, if the temperatureincreases above 225° C. and the P-value drops below 1.0 the separatedhydrocarbons may become unstable. Alternatively, the bromine numberand/or CAPP olefin number may increase to above 3%. If the temperatureis maintained below 225° C., minimal changes to the hydrocarbonproperties may occur. In certain embodiments, operating conditions areselected, varied, and/or maintained to produce separated hydrocarbonshaving a P-value of at least about 1, at least about 1.1, at least about1.2, or at least about 1.3. In certain embodiments, operating conditionsare selected, varied, and/or maintained to produce separatedhydrocarbons having a bromine number of at most about 3%, at most about2.5%, at most about 2%, or at most about 1.5%. Heating of the formationat controlled operating conditions includes operating at temperaturesbetween about 100° C. and about 260° C., between about 150° C. and about250° C., between about 200° C. and about 240° C., between about 210° C.and about 230° C., or between about 215° C. and about 225° C. andpressures between about 1000 kPa and about 15000 kPa, between about 2000kPa and about 10000 kPa, or between about 2500 kPa and about 5000 kPa orat or near a fracture pressure of the formation. In certain embodiments,the selected pressure of about 10000 kPa produces separated hydrocarbonshaving properties acceptable for transportation and/or refineries (forexample, viscosity, P-value, API gravity, olefin content, orcombinations thereof).

Examples of produced mixture properties that may be measured and used toassess the separated hydrocarbon portion of the produced mixtureinclude, but are not limited to, liquid hydrocarbon properties such asAPI gravity, viscosity, asphaltene stability (P-value), and olefincontent (bromine number and/or CAPP number). In certain embodiments,operating conditions in the formation are selected, varied, and/ormaintained to produce an API gravity of at least about 15°, at leastabout 17°, at least about 19°, or at least about 20° in the producedmixture. In certain embodiments, operating conditions in the formationare selected, varied, and/or maintained to produce a viscosity (measuredat 1 atm and 5° C.) of at most about 400 cp, at most about 350 cp, atmost about 250 cp, or at most about 100 cp in the produced mixture. Asan example, the initial viscosity of fluid in the formation is aboveabout 1000 cp or, in some cases, above about 1 million cp. In certainembodiments, operating conditions are selected, varied, and/ormaintained to produce an asphaltene stability (P-value) of at leastabout 1, at least about 1.1, at least about 1.2, or at least about 1.3in the produced mixture. In certain embodiments, operating conditionsare selected, varied, and/or maintained to produce a bromine number ofat most about 3%, at most about 2.5%, at most about 2%, or at most about1.5% in the produced mixture.

In certain embodiments, the mixture is produced from one or moreproduction wells located at or near the bottom of the hydrocarbon layerbeing treated. In other embodiments, the mixture is produced from otherlocations in the hydrocarbon layer being treated (for example, from anupper portion of the layer or a middle portion of the layer).

In one embodiment, the formation is heated to 220° C. or 230° C. whilemaintaining the pressure in the formation below 10000 kPa. The separatedhydrocarbon portion of the mixture produced from the formation may haveseveral desirable properties such as, but not limited to, an API gravityof at least 19°, a viscosity of at most 350 cp, a P-value of at least1.1, and a bromine number of at most 2%. Such separated hydrocarbons maybe transportable through a pipeline without adding diluent or blendingthe mixture with another fluid. The mixture may be produced from one ormore production wells located at or near the bottom of the hydrocarbonlayer being treated.

The in situ heat treatment process may provide less heat to theformation (for example, use a wider heater spacing) if the in situ heattreatment process is followed by a drive process. The drive process mayinvolve introducing a hot fluid into the formation to increase theamount of heat provided to the formation. In some embodiments, theheaters of the in situ heat treatment process may be used to pretreatthe formation to establish injectivity for the subsequent drive process.In some embodiments, the in situ heat treatment process creates orproduces the drive fluid in situ. The in situ produced drive fluid maymove through the formation and move mobilized hydrocarbons from oneportion of the formation to another portion of the formation.

FIG. 163 depicts a top view representation of an embodiment forpreheating using heaters before using the drive process (for example, asteam drive process). Injection wells 788 and production wells 206 aresubstantially vertical wells. Heaters 438 are long substantiallyhorizontal heaters positioned so that the heaters pass in the vicinityof injection wells 788. Heaters 438 intersect the vertical well patternsslightly displaced from the vertical wells.

The vertical location of heaters 438 with respect to injection wells 788and production wells 206 depends on, for example, the verticalpermeability of the formation. In formations with at least some verticalpermeability, injected steam will rise to the top of the permeable layerin the formation. In such formations, heaters 438 may be located nearthe bottom of the hydrocarbon layer 484, as shown in FIG. 164. Informations with very low vertical permeabilities, more than onehorizontal heater may be used with the heaters stacked substantiallyvertically or with heaters at varying depths in the hydrocarbon layer(for example, heater patterns as shown in FIGS. 159-162). The verticalspacing between the horizontal heaters in such formations may correspondto the distance between the heaters and the injection wells. Heaters 438are located in the vicinity of injection wells 788 and/or productionwells 206 so that sufficient energy is delivered by the heaters toprovide flow rates for the drive process that are economically viable.The spacing between heaters 438 and injection wells 788 or productionwells 206 may be varied to provide an economically viable drive process.The amount of preheating may also be varied to provide an economicallyviable process.

In some embodiments, the steam injection (or drive) process (forexample, SAGD, cyclic steam soak, or another steam recovery process) isused to treat the formation and produce hydrocarbons from the formation.The steam injection process may recover a low amount of oil in placefrom the formation (for example, less than 20% recovery of oil in placefrom the formation). The in situ heat treatment process may be usedfollowing the steam injection process to increase the recovery of oil inplace from the formation. In certain embodiments, the steam injectionprocess is used until the steam injection process is no longer efficientat removing hydrocarbons from the formation (for example, until thesteam injection process is no longer economically feasible). The in situheat treatment process is used to produce hydrocarbons remaining in theformation after the steam injection process. Using the in situ heattreatment process after the steam injection process may allow recoveryof at least about 25%, at least about 50%, at least about 55%, or atleast about 60% of oil in place in the formation.

In some embodiments, the formation has been at least somewhat heated bythe steam injection process before treating the formation using the insitu heat treatment process. For example, the steam injection processmay heat the formation to an average temperature between about 200° C.and about 250° C., between about 175° C. and about 265° C., or betweenabout 150° C. and about 270° C. In certain embodiments, the heaters areplaced in the formation after the steam injection process is at least50% completed, at least 75%, completed, or near 100% completion of thesteam injection process. The heaters provide heat for treating theformation using the in situ heat treatment process. In some embodiments,the heaters are already in place in the formation during the steaminjection process. In such embodiments, the heaters may be energizedafter the steam injection process is completed or when production ofhydrocarbons using the steam injection process is reduced below adesired level. In some embodiments, steam injection wells from the steaminjection process are converted to heater wells for the in situ heattreatment process.

Treating the formation with the in situ heat treatment process after thesteam injection process may be more efficient than only treating theformation with the in situ heat treatment process. The steam injectionprocess may provide some energy (heat) to the formation with the steam.Any energy added to the formation during the steam injection processreduces the amount of energy needed to be supplied by heaters for the insitu heat treatment process. Reducing the amount of energy supplied byheaters reduces costs for treating the formation using the in situ heattreatment process.

In certain embodiments, treating the formation using the steam injectionprocess does not treat the formation uniformly. For example, steaminjection may not be uniform throughout the formation. Variations in theproperties of the formation (for example, fluid injectivities,permeabilities, and/or porosities) may result in non-uniform injectionof the steam through the formation. Because of the non-uniform injectionof the steam, the steam may remove hydrocarbons from different portionsof the formation at different rates or with different results. Forexample, some portions of the formation may have little or no steaminjectivity, which inhibits the hydrocarbon production from theseportions. After the steam injection process is completed, the formationmay have portions that have lower amounts of hydrocarbons produced (morehydrocarbons remaining) than other parts of the formation.

FIG. 165 depicts a side view representation of an embodiment of a tarsands formation subsequent to a steam injection process. Injection well788 is used to inject steam into hydrocarbon layer 484 below overburden482. Portion 790 may have little or no steam injectivity and have smallamounts of hydrocarbons or no hydrocarbons at all removed by the steaminjection process. Portions 792 may include portions that have steaminjectivity and measurable amounts of hydrocarbons are removed by thesteam injection process. Thus, portion 790 may have a greater amount ofhydrocarbons remaining than portions 792 following treatment with thesteam injection process. In some embodiments, hydrocarbon layer 484includes two or more portions 790 with more hydrocarbons remaining thanportions 792.

In some embodiments, the portions with more hydrocarbons remaining (suchas portion 790, depicted in FIG. 165) are large portions of theformation. In some embodiments, the amount of hydrocarbons remaining inthese portions is significantly higher than other portions of theformation (such as portions 792, depicted in FIG. 165). For example,portions 790 may have a recovery of at most about 10% of the oil inplace and portions 792 may have a recovery of at least about 30% of theoil in place. In some embodiments, portions 790 have a recovery ofbetween about 0% and about 10% of the oil in place, between about 0% andabout 15% of the oil in place, or between about 0% and about 20% of theoil in place. The portions 792 may have a recovery of between about 20%and about 25% of the oil in place, between about 20% and about 40% ofthe oil in place, or between about 20% and about 50% of the oil inplace. Coring, logging techniques, and/or seismic imaging may be used toassess hydrocarbons remaining in the formation and assess the locationof one or more of the first and/or second portions.

In certain embodiments, during the in situ heat treatment process, moreheat is provided to the first portions of the formation that have morehydrocarbons remaining than the second portions with less hydrocarbonsremaining. In some embodiments, heaters are located in the firstportions but not in the second portions. In some embodiments, heatersare located in both the first portions and the second portions but theheaters in the first portions are designed or operated to provide moreheat than the heaters in the second portions. In some embodiments,heaters pass through both first portions and second portions and theheaters are designed or operated to provide more heat in the firstportions than the second portions.

In some embodiments, steam injection is continued during the in situheat treatment process. For example, steam injection may be continuedwhile liquids are being produced from the formation. The steam injectionmay increase the production of liquids from the formation. In certainembodiments, steam injection may be reduced or stopped when gasproduction from the formation begins.

In some embodiments, the formation is treated using the in situ heattreatment process a significant time after the formation has beentreated using the steam injection process. For example, the in situ heattreatment process is used 1 year, 2 years, 3 years, or longer (forexample, 10 years to 20 years) after a formation has been treated usingthe steam injection process. During this dormant period, heat from thesteam injection process may diffuse to cooler parts of the formation andresult in a more uniform preheating of the formation prior to in situheat treatment. The in situ heat treatment process may be used onformations that have been left dormant after the steam injection processtreatment because further hydrocarbon production using the steaminjection process is not possible and/or not economically feasible. Insome embodiments, the formation remains at least somewhat heated fromthe steam injection process even after the significant time.

In certain embodiments, a fluid is injected into the formation (forexample, a drive fluid or an oxidizing fluid) to move hydrocarbonsthrough the formation from a first section to a second section. In someembodiments, the hydrocarbons are moved from the first section to thesecond section through a third section. FIG. 166 depicts a side viewrepresentation of an embodiment using at least three treatment sectionsin a tar sands formation. Hydrocarbon layer 484 may be divide into threeor more treatment sections. In certain embodiments, hydrocarbon layer484 includes three different types of treatment sections: section 794A,section 794B, and section 794C. Section 794C and sections 794A areseparated by sections 794B. Section 794C, sections 794A, and sections794B may be horizontally displaced from each other in the formation. Insome embodiments, one side of section 794C is adjacent to an edge of thetreatment area of the formation or an untreated section of the formationis left on one side of section 794C before the same or a differentpattern is formed on the opposite side of the untreated section.

In certain embodiments, sections 794A and 794C are heated at or near thesame time to similar temperatures (for example, pyrolysis temperatures).Sections 794A and 794C may be heated to mobilize and/or pyrolyzehydrocarbons in the sections. The mobilized and/or pyrolyzedhydrocarbons may be produced (for example, through one or moreproduction wells) from section 794A and/or section 794C. Section 794Bmay be heated to lower temperatures (for example, mobilizationtemperatures). Little or no production of hydrocarbons to the surfacemay take place through section 794B. For example, sections 794A and 794Cmay be heated to average temperatures of about 300° C. while section794B is heated to an average temperature of about 100° C. and noproduction wells are operated in section 794B.

In certain embodiments, heating and producing hydrocarbons from section794C creates fluid injectivity in the section. After fluid injectivityhas been created in section 794C, a fluid such as a drive fluid (forexample, steam, water, or hydrocarbons) and/or an oxidizing fluid (forexample, air, oxygen, enriched oxygen, or other oxidants) may beinjected into the section. The fluid may be injected through heaters438, a production well, and/or an injection well located in section794C. In some embodiments, heaters 438 continue to provide heat whilethe fluid is being injected. In other embodiments, heaters 438 may beturned down or off before or during fluid injection.

In some embodiments, providing oxidizing fluid such as air to section794C causes oxidation of hydrocarbons in the section. For example, cokedhydrocarbons and/or heated hydrocarbons in section 794C may oxidize ifthe temperature of the hydrocarbons is above an oxidation ignitiontemperature. In some embodiments, treatment of section 794C with theheaters creates coked hydrocarbons with substantially uniform porosityand/or substantially uniform injectivity so that heating of the sectionis controllable when oxidizing fluid is introduced to the section. Theoxidation of hydrocarbons in section 794C will maintain the averagetemperature of the section or increase the average temperature of thesection to higher temperatures (for example, about 400° C. or above).

In some embodiments, injection of the oxidizing fluid is used to heatsection 794C and a second fluid is introduced into the formation afteror with the oxidizing fluid to create drive fluids in the section.During injection of air, excess air and/or oxidation products may beremoved from section 794C through one or more production wells. Afterthe formation is raised to a desired temperature, a second fluid may beintroduced into section 794C to react with coke and/or hydrocarbons andgenerate drive fluid (for example, synthesis gas). In some embodiments,the second fluid includes water and/or steam. Reactions of the secondfluid with carbon in the formation may be endothermic reactions thatcool the formation. In some embodiments, oxidizing fluid is added withthe second fluid so that some heating of section 794C occurssimultaneous with the endothermic reactions. In some embodiments,section 794C may be treated in alternating steps of adding oxidant toheat the formation, and then adding second fluid to generate drivefluids.

The generated drive fluids in section 794C may include steam, carbondioxide, carbon monoxide, hydrogen, methane, and/or pyrolyzedhydrocarbons. The high temperature in section 794C and the generation ofdrive fluid in the section may increase the pressure of the section sothe drive fluids move out of the section into adjacent sections. Theincreased temperature of section 794C may also provide heat to section794B through conductive heat transfer and/or convective heat transferfrom fluid flow (for example, hydrocarbons and/or drive fluid) tosection 794B.

In some embodiments, hydrocarbons (for example, hydrocarbons producedfrom section 794C) are provided as a portion of the drive fluid. Theinjected hydrocarbons may include at least some pyrolyzed hydrocarbonssuch as pyrolyzed hydrocarbons produced from section 794C. In someembodiments, steam or water are provided as a portion of the drivefluid. Providing steam or water in the drive fluid may be used tocontrol temperatures in the formation. For example, steam or water maybe used to keep temperatures lower in the formation. In someembodiments, water injected as the drive fluid is turned into steam inthe formation due to the higher temperatures in the formation. Theconversion of water to steam may be used to reduce temperatures ormaintain lower temperatures in the formation.

Fluids injected in section 794C may flow towards section 794B, as shownby the arrows in FIG. 166. Fluid movement through the formationtransfers heat convectively through hydrocarbon layer 484 into sections794B and/or 794A. In addition, some heat may transfer conductivelythrough the hydrocarbon layer between the sections.

Low level heating of section 794B mobilizes hydrocarbons in the section.The mobilized hydrocarbons in section 794B may be moved by the injectedfluid through the section towards section 794A, as shown by the arrowsin FIG. 166. Thus, the injected fluid is pushing hydrocarbons fromsection 794C through section 794B to section 794A. Mobilizedhydrocarbons may be upgraded in section 794A due to the highertemperatures in the section. Pyrolyzed hydrocarbons that move intosection 794A may also be further upgraded in the section. The upgradedhydrocarbons may be produced through production wells located in section794A.

In certain embodiments, at least some hydrocarbons in section 794B aremobilized and drained from the section prior to injecting the fluid intothe formation. Some formations may have high oil saturation (forexample, the Grosmont formation has high oil saturation). The high oilsaturation corresponds to low gas permeability in the formation that mayinhibit fluid flow through the formation. Thus, mobilizing and draining(removing) some oil (hydrocarbons) from the formation may create gaspermeability for the injected fluids.

Fluids in hydrocarbon layer 484 may preferentially move horizontallywithin the hydrocarbon layer from the point of injection because tarsands tend to have a larger horizontal permeability than verticalpermeability. The higher horizontal permeability allows the injectedfluid to move hydrocarbons between sections preferentially versus fluidsdraining vertically due to gravity in the formation. Providingsufficient fluid pressure with the injected fluid may ensure that fluidsare moved to section 794A for upgrading and/or production.

In certain embodiments, section 794B has a larger volume than section794A and/or section 794C. Section 794B may be larger in volume than theother sections so that more hydrocarbons are produced for less energyinput into the formation. Because less heat is provided to section 794B(the section is heated to lower temperatures), having a larger volume insection 794B reduces the total energy input to the formation per unitvolume. The desired volume of section 794B may depend on factors suchas, but not limited to, viscosity, oil saturation, and permeability. Inaddition, the degree of coking is much less in section 794B due to thelower temperature so less hydrocarbons are coked in the formation whensection 794B has a larger volume. In some embodiments, the lower degreeof heating in section 794B allows for cheaper capital costs as lowertemperature materials (cheaper materials) may be used for heaters usedin section 794B.

In some embodiments, karsted formations or karsted layers in formationshave vugs in one or more layers of the formations. The vugs may befilled with viscous fluids such as bitumen or heavy oil. In someembodiments, the karsted layers have a porosity of at least about 20porosity units, at least about 30 porosity units, or at least about 35porosity units. The karsted formation may have a porosity of at mostabout 15 porosity units, at most about 10 porosity units, or at mostabout 5 porosity units. Vugs filled with viscous fluids may inhibitsteam or other fluids from being injected into the formation or thelayers. In certain embodiments, the karsted formation or karsted layersof the formation are treated using the in situ heat treatment process.

Heating of these formations or layers may decrease the viscosity of theviscous fluids in the vugs and allow the fluids to drain (for example,mobilize the fluids). Formations with karsted layers may have sufficientpermeability so that when the viscosity of fluids (hydrocarbons) in theformation is reduced, the fluids drain and/or move through the formationrelatively easily (for example, without a need for creating higherpermeability in the formation).

In some embodiments, the relative amount (the degree) of karst in theformation is assessed using techniques known in the art (for example, 3Dseismic imaging of the formation). The assessment may give a profile ofthe formation showing layers or portions with varying amounts of karstin the formation. In certain embodiments, more heat is provided toselected karsted portions of the formation than other karsted portionsof the formation. In some embodiments, selective amounts of heat areprovided to portions of the formation as a function of the degree ofkarst in the portions. Amounts of heat may be provided by varying thenumber and/or density of heaters in the portions with varying degrees ofkarst.

In certain embodiments, the hydrocarbon fluids in karsted portions havehigher viscosities than hydrocarbons in other non-karsted portions ofthe formation. Thus, more heat may be provided to the karsted portionsto reduce the viscosity of the hydrocarbons in the karsted portions.

In certain embodiments, only the karsted layers of the formation aretreated using the in situ heat treatment process. Other non-karstedlayers of the formation may be used as seals for the in situ heattreatment process. For example, karsted layers with different quantitiesof hydrocarbons in the layers may be treated while other layers are usedas natural seals for the treatment process. In some embodiments, karstedlayers with low quantities of hydrocarbons as compared to the otherkarsted and/or non-karsted layers are used as seals for the treatmentprocess. The quantity of hydrocarbons in the Karsted layer may bedetermined using logging methods and/or Dean Stark distillation methods.The quantity of hydrocarbons may be reported as a volume percent ofhydrocarbons per volume percent of rock, or as volume of hydrocarbonsper mass of rock.

In some embodiments, karsted layers with fewer hydrocarbons are treatedalong with karsted layers with more hydrocarbons. In some embodiments,karsted layers with fewer hydrocarbons are above and below a karstedlayer with more hydrocarbons (the middle karsted layer). Less heat maybe provided to the upper and lower karsted layers than the middlekarsted layer. Less heat may be provided in the upper and lower karstedlayers by having greater heat spacing and/or less heaters in the upperand lower karsted layers as compared to the middle karsted layer. Insome embodiments, less heating of the upper and lower karsted layersincludes heating the layers to mobilization and/or visbreakingtemperatures, but not to pyrolysis temperatures. In some embodiments,the upper and/or lower karsted layers are heated with heaters and theresidual heat from the upper and/or lower layers transfers to the middlelayer.

One or more production wells may be located in the middle karsted layer.Mobilized and/or visbroken hydrocarbons from the upper karsted layer maydrain to the production wells in the middle karsted layer. Heat providedto the lower karsted layer may create a thermal expansion drive and/or agas pressure drive in the lower karsted layer. The thermal expansionand/or gas pressure may drive fluids from the lower karsted layer to themiddle karsted layer. These fluids may be produced through theproduction wells in the middle karsted layer. Providing some heat to theupper and lower karsted layers may increase the total recovery of fluidsfrom the formation by, for example, 25% or more.

In some embodiments, the karsted layers with fewer hydrocarbons arefurther heated to pyrolysis temperatures after production from thekarsted layer with more hydrocarbons is completed or almost completed.The karsted layers with fewer hydrocarbons may also be further treatedby producing fluids through production wells located in the layers.

In some embodiments, a drive process, a solvent injection process and/ora pressurizing fluid process is used after the in situ heat treatment ofthe karsted formation or karsted layers. A drive process may includeinjection of a drive fluid such as steam. A drive process includes, butis not limited to, a steam injection process such as cyclic steaminjection, a steam assisted gravity drainage process (SAGD), and a vaporsolvent and SAGD process. A drive process may drive fluids from oneportion of the formation towards a production well.

A solvent injection process may include injection of a solvating fluid.A solvating fluid includes, but is not limited to, water, emulsifiedwater, hydrocarbons, surfactants, alkaline water solutions (for example,sodium carbonate solutions), caustic, polymers, carbon disulfide, carbondioxide, or mixtures thereof. The solvation fluid may mix with, solvateand/or dilute the hydrocarbons to form a mixture of condensablehydrocarbons and solvation fluids. The mixture may have a reducedviscosity as compared to the initial viscosity of the fluids in theformation. The mixture may flow and/or be mobilized towards productionwells in the formation.

A pressurizing process may include moving hydrocarbons in the formationby injection of a pressurized fluid. The pressurizing fluid may include,but is not limited to, carbon dioxide, nitrogen, steam, methane, and/ormixtures thereof.

In some embodiments, the drive process (for example, the steam injectionprocess) is used to mobilize fluids before the in situ heat treatmentprocess. Steam injection may be used to get hydrocarbons (oil) away fromrock or other strata in the formation. The steam injection may mobilizethe hydrocarbons without significantly heating the rock.

In some embodiments, fluid injected in the formation (for example, steamand/or carbon dioxide) may absorb heat from the formation and cool theformation depending on the pressure in the formation and the temperatureof the injected fluid. In some embodiments, the injected fluid is usedto recover heat from the formation. The recovered heat may be used insurface processing fluids and/or to preheat other portions of theformation using the drive process.

In some embodiments, heaters are used to preheat the karsted formationor karsted layers to create injectivity in the formation. In situ heattreatment of karsted formations and/or karsted layers may allow fordrive fluid injection, solvent injection and/or pressurizing fluidinjection where it was previously unfavorable or unmanageable.Typically, karsted formations were unfavorable for drive processesbecause channeling of the fluid injected in the formation inhibitedpressure build-up in the formation. In situ heat treatment of karstedformations may allow for injection of a drive fluid, a solvent and/or apressurizing fluid by reducing the viscosity of hydrocarbons in theformation and allowing pressure to build in the formations withoutsignificant bypass of the fluid through channels in the formations. Forexample, heating a section of the formation using in situ heat treatmentmay heat and mobilize heavy hydrocarbons (bitumen) by reducing theviscosity of the heavy hydrocarbons in the karsted layer. Some of theheated less viscous heavy hydrocarbons may flow from the karsted layerinto other portions of the formation that are cooler than the heatedkarsted portion. The heated less viscous heavy hydrocarbons may flowthrough channels and/or fractures. The heated heavy hydrocarbons maycool and solidify in the channels, thus creating a temporary seal forthe drive fluid, solvent, and/or pressurizing fluid.

In certain embodiments, the karsted formation or karsted layers areheated to temperatures below the decomposition temperature of mineralsin the formation (for example, rock minerals such as dolomite and/orclay minerals such as kaolinite, illite, or smectite). In someembodiments, the karsted formation or karsted layers are heated totemperatures of at most 400° C., at most 450° C., or at most 500° C.(for example, to a temperature below a dolomite decompositiontemperature at formation pressure). In some embodiments, the karstedformation or karsted layers are heated to temperatures below adecomposition temperature of clay minerals (such as kaolinite) atformation pressure.

In some embodiments, heat is preferentially provided to portions of theformation with low weight percentages of clay minerals (for example,kaolinite) as compared to the content of clay in other portions of theformation. For example, more heat may be provided to portions of theformation with at most 1% by weight clay minerals, at most 2% by weightclay minerals, or at most 3% by weight clay minerals than portions ofthe formation with higher weight percentages of clay minerals. In someembodiments, the rock and/or clay mineral distribution is assessed inthe formation prior to designing a heater pattern and installing theheaters. The heaters may be arranged to preferentially provide heat tothe portions of the formation that have been assessed to have lowerweight percentages of clay minerals as compared to other portions of theformation. In certain embodiments, the heaters are placed substantiallyhorizontally in layers with low weight percentages of clay minerals.

Providing heat to portions with low weight percentages of clay mineralsmay minimize changes in the chemical structure of the clays. Forexample, heating clays to high temperatures may drive water from theclays and change the structure of the clays. The change in structure ofthe clay may adversely affect the porosity and/or permeability of theformation. If the clays are heated in the presence of air, the clays mayoxidize and the porosity and/or permeability of the formation may beadversely affected. Portions of the formation with a high weightpercentage of clay minerals may be inhibited from reaching temperaturesabove temperatures that effect the chemical composition of the clayminerals at formation pressures. For example, portions of the formationwith large amounts of kaolinite relative to other portions of theformation may be inhibited from reaching temperatures above 240° C. Insome embodiments, portions of the formation with a high quantity of clayminerals relative to other portions of the formation may be inhibitedfrom reaching temperatures above 200° C., above 220° C., above 240° C.,or above 300° C.

In some embodiments, karsted formations may include water. Minerals (forexample, carbonate minerals) in the formation may at least partiallydissociate in the water to form carbonic acid. The concentration ofcarbonic acid in the water may be sufficient to make the water acidic.At pressure greater than ambient formation pressures, dissolution ofminerals in the water may be enhanced, thus formation of acidic water isenhanced. Acidic water may react with other minerals in the formationsuch as dolomite (MgCa(CO₃)₂) and increase the solubility of theminerals. Water at lower pressures, or non-acidic water, may notsolubilize the minerals in the formation. Dissolution of the minerals inthe formation may form fractures in the formation. Thus, controlling thepressure and/or the acidity of water in the formation may control thesolubilization of minerals in the formation. In some embodiments, otherinorganic acids in the formation enhance the solubilization of mineralssuch as dolomite.

In some embodiments, the karsted formation or karsted layers are heatedto temperatures above the decomposition temperature of minerals in theformation. At temperatures above the minerals decomposition temperature,the minerals may decompose to produce carbon dioxide or other products.The decomposition of the minerals and the carbon dioxide production maycreate permeability in the formation and mobilize viscous fluids in theformation. In some embodiments, the produced carbon dioxide ismaintained in the formation to generate a gas cap in the formation. Thecarbon dioxide may be allowed to rise to the upper portions of thekarsted layers to generate the gas cap.

In some embodiments, the production front of the drive process followsbehind the heat front of the in situ heat treatment process. In someembodiments, areas behind the production front are further heated toproduce more fluids from the formation. Further heating behind theproduction front may also maintain the gas cap behind the productionfront and/or maintain quality in the production front of the driveprocess.

In certain embodiments, the drive process is used before the in situheat treatment of the formation. In some embodiments, the drive processis used to mobilize fluids in a first section of the formation. Themobilized fluids may then be pushed into a second section by heating thefirst section with heaters. Fluids may be produced from the secondsection. In some embodiments, the fluids in the second section arepyrolyzed and/or upgraded using the heaters.

In formations with low permeabilities, the drive process may be used tocreate a “gas cushion” or pressure sink before the in situ heattreatment process. The gas cushion may inhibit pressures from increasingquickly to fracture pressure during the in situ heat treatment process.The gas cushion may provide a path for gases to escape or travel duringearly stages of heating during the in situ heat treatment process.

In some embodiments, the drive process (for example, the steam injectionprocess) is used to mobilize fluids before the in situ heat treatmentprocess. Steam injection may be used to get hydrocarbons (oil) away fromrock or other strata in the formation. The steam injection may mobilizethe oil without significantly heating the rock.

In some embodiments, injection of a fluid (for example, steam or carbondioxide) may consume heat in the formation and cool the formationdepending on the pressure in the formation. In some embodiments, theinjected fluid is used to recover heat from the formation. The recoveredheat may be used in surface processing fluids and/or to preheat otherportions of the formation using the drive process.

FIG. 167 depicts a representation of an embodiment for producinghydrocarbons from a hydrocarbon containing formation (for example, a tarsands formation). Hydrocarbon layer 484 includes one or more portionswith heavy hydrocarbons. Hydrocarbons may be produced from hydrocarbonlayer 484 using more than one process. In certain embodiments,hydrocarbons are produced from a first portion of hydrocarbon layer 484using a steam injection process (for example, cyclic steam injection orsteam assisted gravity drainage) and a second portion of the hydrocarbonlayer using an in situ heat treatment process. In the steam injectionprocess, steam is injected into the first portion of hydrocarbon layer484 through injection well 788. First hydrocarbons are produced from thefirst portion through production well 206A. The first hydrocarbonsinclude hydrocarbons mobilized by the injection of steam. In certainembodiments, the first hydrocarbons have an API gravity of at most 15°,at most 10°, at most 8°, or at most 6°.

Heaters 438 are used to heat the second portion of hydrocarbon layer 484to mobilization, visbreaking, and/or pyrolysis temperatures. Secondhydrocarbons are produced from the second portion through productionwell 206B. In some embodiments, the second hydrocarbons include at leastsome pyrolyzed hydrocarbons. In certain embodiments, the secondhydrocarbons have an API gravity of at least 15°, at least 20°, or atleast 25°.

In some embodiments, the first portion of hydrocarbon layer 484 istreated using heaters after the steam injection process. Heaters may beused to increase the temperature of the first portion and/or treat thefirst portion using an in situ heat treatment process. Secondhydrocarbons (including at least some pyrolyzed hydrocarbons) may beproduced from the first portion through production well 206A.

In some embodiments, the second portion of hydrocarbon layer 484 istreated using the steam injection process before using heaters 438 totreat the second portion. The steam injection process may be used toproduce some fluids (for example, first hydrocarbons or hydrocarbonsmobilized by the steam injection) through production well 206B from thesecond portion and/or preheat the second portion before using heaters438. In some embodiments, the steam injection process may be used afterusing heaters 438 to treat the first portion and/or the second portion.

Producing hydrocarbons through both processes increases the totalrecovery of hydrocarbons from hydrocarbon layer 484 and may be moreeconomical than using either process alone. In some embodiments, thefirst portion is treated with the in situ heat treatment process afterthe steam injection process is completed. For example, after the steaminjection process no longer produces viable amounts of hydrocarbon fromthe first portion, the in situ heat treatment process may be used on thefirst portion.

Steam is provided to injection well 788 from facility 796. Facility 796is a steam and electricity cogeneration facility. Facility 796 may burnhydrocarbons in generators to make electricity. Facility 796 may burngaseous and/or liquid hydrocarbons to make electricity. The electricitygenerated is used to provide electrical power for heaters 438. Wasteheat from the generators is used to make steam. In some embodiments,some of the hydrocarbons produced from the formation are used to providegas for heaters 438, if the heaters utilize gas to provide heat to theformation. The amount of electricity and steam generated by facility 796may be controlled to vary the production rate and/or quality ofhydrocarbons produced from the first portion and/or the second portionof hydrocarbon layer 484. The production rate and/or quality ofhydrocarbons produced from the first portion and/or the second portionmay be varied to produce a selected API gravity in a mixture made byblending the first hydrocarbons with the second hydrocarbons. The firsthydrocarbon and the second hydrocarbons may be blended after productionto produce the selected API gravity. The production from the firstportion and/or the second portion may be varied in response to changesin the marketplace for either first hydrocarbons, second hydrocarbons,and/or a mixture of the first and second hydrocarbons.

First hydrocarbons produced from production well 206A and/or secondhydrocarbons produced from production well 206B may be used as fuel forfacility 796. In some embodiments, first hydrocarbons and/or secondhydrocarbons are treated (for example, removing undesirable products)before being used as fuel for facility 796. In some embodiments, coke orother hydrocarbon residue produced or removed from the formation (forexample, mined from the formation) may provide fuel for facility 796.The hydrocarbon residue may be gasified or burned in a residue burningfacility before providing the hydrocarbons to facility 796. The residueburning facility may produce hydrocarbon gases (such as natural gas)and/or other products (such as carbon dioxide or syngasproducts(synthesis gas products)). The carbon dioxide may be sequesteredin the formation after treatment of the formation.

The amount of first hydrocarbons and second hydrocarbons used as fuelfor facility 796 may be determined, for example, by economics for theoverall process, the marketplace for either first or secondhydrocarbons, availability of treatment facilities for either first orsecond hydrocarbons, and/or transportation facilities available foreither first or second hydrocarbons. In some embodiments, most or allthe hydrocarbon gas produced from hydrocarbon layer 484 is used as fuelfor facility 796. Burning all the hydrocarbon gas in facility 796eliminates the need for treatment and/or transportation of gasesproduced from hydrocarbon layer 484.

The produced first hydrocarbons and the second hydrocarbons may betreated and/or blended in facility 798. In some embodiments, the firstand second hydrocarbons are blended to make a mixture that istransportable through a pipeline. In some embodiments, the first andsecond hydrocarbons are blended to make a mixture that is useable as afeedstock for a refinery. The amount of first and second hydrocarbonsproduced may be varied based on changes in the requirements fortreatment and/or blending of the hydrocarbons. In some embodiments,treated hydrocarbons are used in facility 796.

In some embodiments, the steam injection process and the in situ heattreatment process (for example, the in situ conversion process) are usedsynergistically in different layers (for example, vertically displacedlayers) in the formation. For example, in a karsted formation, differentzones or layers in the formation may have different oil saturations,water saturations, porosities, and/or permeabilities. Some layers mayhave good steam injectivities while others have near zero steaminjectivity. The steam injectivity may depend on the water saturation ofthe zone and the permeability. Thus, varying the use of the steaminjection process and the in situ heat treatment process in these layersmay be economically advantageous by, for example, producing morehydrocarbons with less energy input into the formation. The steaminjection process may include steam drive, cyclic steam injection, SAGD,or other process of steam injection into the formation.

FIG. 168 depicts a representation of an embodiment for producinghydrocarbons from multiple layers in a tar sands formation. Hydrocarbonlayers 484A,B,C include one or more portions with heavy hydrocarbons.Hydrocarbon layers 484A,B,C may have different oil saturations, watersaturations, porosities, and/or permeabilities. In one embodiment,hydrocarbon layers 484A,C have lower oil saturations, higher watersaturations, and lower porosities than hydrocarbon layer 484B. The steaminjection process may be used in hydrocarbon layers 484A,C usinginjection wells 788A,C and production wells 206A,C. The in situ heattreatment process may be used in hydrocarbon layer 484B using heaters438 and production well 206B. In some embodiments, the in situ heattreatment process is used in hydrocarbon layer 484B, which has high oilsaturation and low steam injectivity. After in situ heat treatment ofhydrocarbon layer 484B, the layer may have steam injectivity. Thehydrocarbon layer 484B may be treated using the steam injection processfor a selected time (for example, one year, two years, three years, orlonger).

Injecting steam into hydrocarbon layers 484A,C above and belowhydrocarbon layer 484B may increase the efficiency of producinghydrocarbons from the formation. Steam injection in hydrocarbon layers484A,C lowers the viscosity and increases the pressures in these layersso that hydrocarbons move into hydrocarbon layer 484B. Heat fromhydrocarbon layer 484B may conduct and/or convect into hydrocarbonlayers 484A,C and preheat these layers to lower the oil viscosity and/orincrease the steam injectivity in hydrocarbon layers 484A,C.Additionally, some steam may rise from hydrocarbon layer 484C intohydrocarbon layer 484B. This steam may provide additional heat andincreased mobilization in hydrocarbon layer 484B. The steam injectionprocess and/or the in situ heat treatment process may be used (forexample, varied) as described above for the embodiment depicted in FIG.167. Hydrocarbons produced from any of hydrocarbon layers 484A,B,C maybe used and/or processed in facility 796 and/or facility 798, asdescribed above for the embodiment depicted in FIG. 167.

In some embodiments, impermeable shale layers exist between hydrocarbonlayer 484B and hydrocarbon layers 484A,C. Using the in situ heattreatment process on hydrocarbon layer 484B may desiccate the shalelayers and increase the permeability of the shale layers to allow fluidto flow through the shale layers. The increased permeability in theshale layers allows mobilized hydrocarbons to flow from hydrocarbonlayer 484A into hydrocarbon layer 484B. These hydrocarbons may beupgraded and produced in hydrocarbon layer 484B.

FIG. 169 depicts an embodiment for heating and producing from theformation with the temperature limited heater in a production wellbore.Production conduit 800 is located in wellbore 742. In certainembodiments, a portion of wellbore 742 is located substantiallyhorizontally in formation 524. In some embodiments, the wellbore islocated substantially vertically in the formation. In an embodiment, atleast a portion of wellbore 742 is an open wellbore (an uncasedwellbore). In some embodiments, the wellbore has a casing or liner withperforations or openings to allow fluid to flow into the wellbore.

Conduit 800 may be made from carbon steel or more corrosion resistantmaterials such as stainless steel. Conduit 800 may include apparatus andmechanisms for gas lifting or pumping produced oil to the surface. Forexample, conduit 800 includes gas lift valves used in a gas liftprocess. Examples of gas lift control systems and valves are disclosedin U.S. Pat. Nos. 6,715,550 to Vinegar et al. and U.S. Pat. No.7,259,688 to Hirsch et al., and U.S. Patent Application Publication No.2002-0036085 to Bass et al., each of which is incorporated by referenceas if fully set forth herein. Conduit 800 may include one or moreopenings (perforations) to allow fluid to flow into the productionconduit. In certain embodiments, the openings in conduit 800 are in aportion of the conduit that remains below the liquid level in wellbore742. For example, the openings are in a horizontal portion of conduit800.

Heater 802 is located in conduit 800, as shown in FIG. 169. In someembodiments, heater 802 is located outside conduit 800, as shown in FIG.170. The heater located outside the production conduit may be coupled(strapped) to the production conduit. In some embodiments, more than oneheater (for example, two, three, or four heaters) are placed aboutconduit 800. The use of more than one heater may reduce bowing orflexing of the production conduit caused by heating on only one side ofthe production conduit. In an embodiment, heater 802 is a temperaturelimited heater. Heater 802 provides heat to reduce the viscosity offluid (such as oil or hydrocarbons) in and near wellbore 742. In certainembodiments, heater 802 raises the temperature of the fluid in wellbore742 up to a temperature of 250° C. or less (for example, 225° C., 200°C., or 150° C.). Heater 802 may be at higher temperatures (for example,275° C., 300° C., or 325° C.) because the heater provides heat toconduit 800 and there is some temperature differential between theheater and the conduit. Thus, heat produced from the heater does notraise the temperature of fluids in the wellbore above 250° C.

In certain embodiments, heater 802 includes ferromagnetic materials suchas Carpenter Temperature Compensator “32”, Alloy 42-6, Alloy 52, Invar36, or other iron-nickel or iron-nickel-chromium alloys. In certainembodiments, nickel or nickel-chromium alloys are used in heater 802. Insome embodiments, heater 802 includes a composite conductor with a morehighly conductive material such as copper on the inside of the heater toimprove the turndown ratio of the heater. Heat from heater 802 heatsfluids in or near wellbore 742 to reduce the viscosity of the fluids andincrease a production rate through conduit 800.

In certain embodiments, portions of heater 802 above the liquid level inwellbore 742 (such as the vertical portion of the wellbore depicted inFIGS. 169 and 170) have a lower maximum temperature than portions of theheater located below the liquid level. For example, portions of heater802 above the liquid level in wellbore 742 may have a maximumtemperature of 100° C. while portions of the heater located below theliquid level have a maximum temperature of 250° C. In certainembodiments, such a heater includes two or more ferromagnetic sectionswith different Curie temperatures and/or phase transformationtemperature ranges to achieve the desired heating pattern. Providingless heat to portions of wellbore 742 above the liquid level and closerto the surface may save energy.

In certain embodiments, heater 802 is electrically isolated on theoutside surface of the heater and allowed to move freely in conduit 800.In some embodiments, electrically insulating centralizers are placed onthe outside of heater 802 to maintain a gap between conduit 800 and theheater.

In some embodiments, heater 802 is cycled (turned on and off) so thatfluids produced through conduit 800 are not overheated. In anembodiment, heater 802 is turned on for a specified amount of time untila temperature of fluids in or near wellbore 742 reaches a desiredtemperature (for example, the maximum temperature of the heater). Duringthe heating time (for example, 10 days, 20 days, or 30 days), productionthrough conduit 800 may be stopped to allow fluids in the formation to“soak” and obtain a reduced viscosity. After heating is turned off orreduced, production through conduit 800 is started and fluids from theformation are produced without excess heat being provided to the fluids.During production, fluids in or near wellbore 742 will cool down withoutheat from heater 802 being provided. When the fluids reach a temperatureat which production significantly slows down, production is stopped andheater 802 is turned back on to reheat the fluids. This process may berepeated until a desired amount of production is reached. In someembodiments, some heat at a lower temperature is provided to maintain aflow of the produced fluids. For example, low temperature heat (forexample, 100° C., 125° C., or 150° C.) may be provided in the upperportions of wellbore 742 to keep fluids from cooling to a lowertemperature.

In some embodiments, a temperature limited heater positioned in awellbore heats steam that is provided to the wellbore. The heated steammay be introduced into a portion of the formation. In certainembodiments, the heated steam may be used as a heat transfer fluid toheat a portion of the formation. In some embodiments, the steam is usedto solution mine desired minerals from the formation. In someembodiments, the temperature limited heater positioned in the wellboreheats liquid water that is introduced into a portion of the formation.

In an embodiment, the temperature limited heater includes ferromagneticmaterial with a selected Curie temperature and/or a selected phasetransformation temperature range. The use of a temperature limitedheater may inhibit a temperature of the heater from increasing beyond amaximum selected temperature (for example, a temperature at or about theCurie temperature and/or the phase transformation temperature range).Limiting the temperature of the heater may inhibit potential burnout ofthe heater. The maximum selected temperature may be a temperatureselected to heat the steam to above or near 100% saturation conditions,superheated conditions, or supercritical conditions. Using a temperaturelimited heater to heat the steam may inhibit overheating of the steam inthe wellbore. Steam introduced into a formation may be used forsynthesis gas production, to heat the hydrocarbon containing formation,to carry chemicals into the formation, to extract chemicals or mineralsfrom the formation, and/or to control heating of the formation.

A portion of the formation where steam is introduced or that is heatedwith steam may be at significant depths below the surface (for example,greater than about 1000 m, about 2500, or about 5000 m below thesurface). If steam is heated at the surface of the formation andintroduced to the formation through a wellbore, a quality of the heatedsteam provided to the wellbore at the surface may have to be relativelyhigh to accommodate heat losses to the wellbore casing and/or theoverburden as the steam travels down the wellbore. Heating the steam inthe wellbore may allow the quality of the steam to be significantlyimproved before the steam is provided to the formation. A temperaturelimited heater positioned in a lower section of the overburden and/oradjacent to a target zone of the formation may be used to controllablyheat steam to improve the quality of the steam injected into theformation and/or inhibit condensation along the length of the heater. Incertain embodiments, the temperature limited heater improves the qualityof the steam injected and/or inhibits condensation in the wellbore forlong steam injection wellbores (especially for long horizontal steaminjection wellbores).

A temperature limited heater positioned in a wellbore may be used toheat the steam to above or near 100% saturation conditions orsuperheated conditions. In some embodiments, a temperature limitedheater may heat the steam so that the steam is above or nearsupercritical conditions. The static head of fluid above the temperaturelimited heater may facilitate producing 100% saturation, superheated,and/or supercritical conditions in the steam. Supercritical or nearsupercritical steam may be used to strip hydrocarbon material and/orother materials from the formation. In certain embodiments, steamintroduced into the formation may have a high density (for example, aspecific gravity of about 0.8 or above). Increasing the density of thesteam may improve the ability of the steam to strip hydrocarbon materialand/or other materials from the formation.

In some embodiments, the tar sands formation may be treated by the insitu heat treatment process to produce pyrolyzed product from theformation. A significant amount of carbon in the form of coke may remainin tar sands formation when production of pyrolysis product from theformation is complete. In some embodiments, the coke in the formationmay be utilized to produce heat and/or additional products from theheated coke containing portions of the formation.

In some embodiments, air, oxygen enriched air, and/or other oxidants maybe introduced into the treatment area that has been pyrolyzed to reactwith the coke in the treatment area. The temperature of the treatmentarea may be sufficiently hot to support burning of the coke withoutadditional energy input from heaters. The oxidation of the coke maysignificantly heat the portion of the formation. Some of the heat maytransfer to portions of the formation adjacent to the treatment area.The transferred heat may mobilize fluids in portions of the formationadjacent to the treatment area. The mobilized fluids may flow into andbe produced from production wells near the perimeter of the treatmentarea.

Gases produced from the formation heated by combusting coke in theformation may be at high temperature. The hot gases may be utilized inan energy recovery cycle (for example, a Kalina cycle or a Rankinecycle) to produce electricity.

The air, oxygen enriched air and/or other oxidants may be introducedinto the formation for a sufficiently long period of time to heat aportion of the treatment area to a desired temperature sufficient toallow for the production of synthesis gas of a desired composition. Thetemperature may be from 500° C. to about 1000° C. or higher. When thetemperature of the portion is at or near the desired temperature, asynthesis gas generating fluid, such as water, may be introduced intothe formation to result in the formation of synthesis gas. Synthesis gasproduced from the formation may be sent to a treatment facility and/orbe sent through a pipeline to a desired location. During introduction ofthe synthesis gas generating fluid, the introduction of air, oxygenenriched air, and/or other oxidants may be stopped, reduced, ormaintained. If the temperature of the formation reduces so that thesynthesis gas produced from the formation does not have the desiredcomposition, introduction of the syntheses gas generating fluid may bestopped or reduced, and the introduction of air, enriched air and/orother oxidants may be started or increased so that oxidation of coke inthe formation reheats portions of the treatment area. The introductionof oxidant to heat the formation and the introduction of synthesis gasgenerating fluid to produce synthesis gas may be cycled until all or asignificant portion of the treatment area is treated.

In certain embodiments, a tar sands formation is treated in stages. Thetreatment may be initiated with electrical heating with further heatinggenerated from oxidation of hydrocarbons and hot gas production from theformation. FIG. 171 depicts an embodiment of a first stage of treatingthe tar sands formation with electrical heaters. Hydrocarbon layer 484may be separated into sections 794A,B. Heaters 438 may be located insection 794A. Production wells 206 may be located in section 794B. Insome embodiments, production wells 206 overlap into section 794A, asshown in FIG. 171.

Heaters 438 may be used to heat and treat portions of section 794Athrough conductive heat transfer. For example, heaters 438 may mobilize,visbreak, and/or pyrolyze hydrocarbons in section 794A. Production wells206 may be used to produce mobilized, visbroken, and/or pyrolyzedhydrocarbons from section 794A.

FIG. 172 depicts an embodiment of a second stage of treating a tar sandsformation with fluid injection and oxidation. After at least somehydrocarbons from section 794A have been produced (for example, amajority of hydrocarbons in the section or almost all produciblehydrocarbons in the section), the heaters in section 794A may beconverted to injection wells 788.

Injection wells 788 may be used to inject air (or other oxidizingfluids) and/or water into the formation. In some embodiments, carbondioxide or other fluids are injected into the formation to controlheating/production in the formation. Air or oxidizing fluids may oxidize(combust) hydrocarbons remaining in the formation (for example, coke).Water may react with the hot formation to produce syngas in theformation. Production wells 206 in section 794B may be converted to gasheater/producer wells 804. Wells 804 may be used to produce oxidationgases and/or syngas products from the formation. Producing the hotoxidation gases and/or syngas through wells 804 in section 794B may heatthe section to higher temperatures so that hydrocarbons in the sectionare mobilized, visbroken, and/or pyrolyzed in the section. Productionwells 206 in section 794C may be used to produce mobilized, visbroken,and/or pyrolyzed hydrocarbons from section 794B.

In certain embodiments, the pressure of the injected fluids and thepressure in formation are controlled to control the heating in theformation. The pressure in the formation may be controlled bycontrolling the production rate of fluids from the formation (forexample, the production rate of oxidation gases and/or syngas products).Heating in the formation may be controlled so that there is enoughhydrocarbon volume in the formation to maintain the oxidation reactionsin the formation. Heating in the formation may also be controlled sothat enough heat is generated to conductively heat the formation tomobilize, visbreak, and/or pyrolyze hydrocarbons in adjacent sections ofthe formation.

The process of injecting air and/or water one section, producingoxidation gases and/or syngas products in an adjacent section to heatthe adjacent section, and producing upgraded hydrocarbons (mobilized,visbroken, and/or pyrolyzed hydrocarbons) from a subsequent section maybe continued in further sections of the tar sands formation. Forexample, FIG. 173 depicts an embodiment of a third stage of treating thetar sands formation with fluid injection and oxidation. The gasheater/producer wells in section 794B are converted to injection wells788 to inject air and/or water. The producer wells in section 794C areconverted to gas heater/producer wells 804 to produce oxidation gasesand/or syngas products. Producer wells are formed in section 794D toproduce upgraded hydrocarbons.

Treating the tar sands formation, as shown by the embodiments of FIGS.171, 172, and 173, may utilize carbon remaining after production ofmobilized, visbroken, and/or pyrolyzed hydrocarbons for heat generationin the formation. Using the remaining hydrocarbons for heat generationand only using electrical heating for the initial heating stage mayimprove the energy balance for treating the formation. Using electricalheating only in the initial step may decrease the electrical power needsfor treating the formation. In addition, forming wells that are used forthe combination of production, injection, and gas heating/production maydecrease well construction costs. In some embodiments, hot gasesproduced from the formation are provided to turbines. Providing the hotgases to turbines may collect more energy from the hot gases and, thus,improve energy collection from the formation.

A downhole heater assembly may include 5, 10, 20, 40, or more heaterscoupled together. For example, a heater assembly may include between 10and 40 heaters. Heaters in a downhole heater assembly may be coupled inseries. In some embodiments, heaters in a heater assembly may be spacedfrom about 8 meters (about 25 feet) to about 60 meters (about 195 feet)apart. For example, heaters in a heater assembly may be spaced about 15meters (about 50 feet) apart. Spacing between heaters in a heaterassembly may be a function of heat transfer from the heaters to theformation. Spacing between heaters may be chosen to limit temperaturevariation along a length of a heater assembly to acceptable limits.Heaters in a heater assembly may include, but are not limited to,electrical heaters, flameless distributed combustors, naturaldistributed combustors, and/or oxidizers. In some embodiments, heatersin a downhole heater assembly may include only oxidizers.

FIG. 174 depicts a schematic of an embodiment of downhole oxidizerassembly 612 including oxidizers 614 connected in series. In someembodiments, oxidizer assembly 612 may include oxidizers 614 andflameless distributed combustors. Oxidizer assembly 612 may be loweredinto an opening in a formation and positioned as desired. In someembodiments, a portion of the opening in the formation may besubstantially parallel to the surface of the Earth. In some embodiments,the opening of the formation may be otherwise angled with respect to thesurface of the Earth. In an embodiment, the opening may include asignificant vertical portion and a portion otherwise angled with respectto the surface of the Earth. In certain embodiments, the opening may bea branched opening. Oxidizer assemblies may branch from common fueland/or oxidant conduits in a central portion of the opening.

Oxidizing fluid 806 may be supplied to oxidizer assembly 612 throughoxidant conduit 618. In some embodiments, fuel conduit 616 and/oroxidizers 614 may be positioned concentrically, or substantiallyconcentrically, in oxidant conduit 618. In some embodiments, fuelconduit 616 and/or oxidizers 614 may be arranged other thanconcentrically with respect to oxidant conduit 618. In certain branchedopening embodiments, fuel conduit 616 and/or oxidant conduit 618 mayhave a weld or coupling to allow placement of oxidizer assemblies 612 inbranches of the opening. Exhaust gas 808 may pass through outer conduit620 and out of the formation.

In some embodiments, the downhole oxidizer assembly includes a waterconduit positioned in the oxidant conduit that is configured to deliverwater to the fuel conduit prior to the first oxidizer in the oxidizerassembly. A portion of the water conduit may pass through a heated zonegenerated by the first oxidizer prior to a water entry point into thefuel conduit. In some embodiments, the fuel conduit is positionedadjacent to the oxidizers, and branches from the fuel conduit providefuel to the other oxidizers. In some embodiments, the fuel conduit maycomprise one or more orifices to selectively control the pressure lossalong the fuel conduit.

Fuel 810 may be supplied to oxidizers 614 through fuel conduit 616. Insome embodiments, the fuel for the oxidizers includes synthesis gas. Insome embodiments, the fuel includes synthesis gas (for example, amixture that includes hydrogen and carbon monoxide) that was producedusing an in situ heat treatment process. In certain embodiments, thefuel may comprise natural gas mixed with heavier components such asethane, propane, butane, or carbon monoxide. In some embodiments, thefuel and/or synthesis gas may include non-combustible gases such asnitrogen. In some embodiments, the fuel contains products from a coal orheavy oil gasification process. The coal or heavy oil gasificationprocess may be an in situ process or an ex situ process. Afterinitiation of combustion of fuel and oxidant mixture in oxidizers 614,composition of the fuel may be varied to enhance operational stabilityof the oxidizers.

In certain embodiments, fuel used to initiate combustion may be enrichedto decrease the temperature required for ignition or otherwisefacilitate startup of oxidizers 614. In some embodiments, hydrogen orother hydrogen rich fluids may be used to enrich fuel initially suppliedto the oxidizers. After ignition of the oxidizers, enrichment of thefuel may be stopped. In some embodiments, a portion or portions of fuelconduit 616 may include a catalytic surface (for example, a catalyticouter surface) to decrease an ignition temperature of fuel 810.

In some embodiments, non-condensable gases produced from treatment areasof in situ heat treatment processes are used as fuel for heaters thatheat treatment areas in the formation. The heaters may be burners. Theburners may be oxidizers of downhole oxidizer assemblies, flamelessdistributed combustors and/or burners that heat a heat transfer fluidused to heat the treatment areas. The non-condensable gases may includecombustible gases (for example, hydrogen, hydrogen sulfide, methane andother hydrocarbon gases) and noncombustible gases (for example, carbondioxide). The presence of noncombustible gases may inhibit coking of thefuel and/or may reduce the flame zone temperature of oxidizers when thefuel is used as fuel for oxidizers of downhole oxidizer assemblies. Thereduced flame zone temperature may inhibit formation of NO_(x) compoundsand/or other undesired combustion products by the oxidizers. Othercomponents such as water may be included in the fuel supplied to theburners. Combustion of in situ heat treatment process gas may reduceand/or eliminate the need for gas treatment facilities and/or the needto treat the non-condensable portion of formation fluid produced usingthe in situ heat treatment process to obtain pipeline gas and/or othergas products. Combustion of in situ heat treatment process gas inburners may create concentrated carbon dioxide and/or SO_(x) effluentsthat may be used in other processes, sequestered and/or treated toremove undesired components.

In some embodiments, use of non-condensable fluids from in situ heattreatment processes in burners reduces or eliminates the need to buildpower plants near the in situ heat treatment processes. Heat initiallyused to increase the temperature of treatment areas in the formation maybe provided by burning pipeline gas or other fuel. After the formationbegins producing formation fluid, a portion or all of thenon-condensable fluids produced from the formation may replace orsupplement the pipeline gas or other fuel used to heat treatment areas.

In some embodiments, the oxidizing fluid supplied to the burners is airor enriched air. In some embodiments, the oxidizing fluid is produced byblending oxygen with a carrier fluid such as carbon dioxide to reduce oreliminate the presence of nitrogen in the oxidizing fluid. For example,the oxidizing fluid may be about 50% by volume oxygen and about 50% byvolume carbon dioxide. Eliminating or reducing nitrogen in the oxidizingfluid may eliminate or reduce the amount of NO_(x) compounds generatedby the burners. Eliminating or educing nitrogen in the oxidizing fluidmay also enable transporting and geologically storing exhaust gases fromthe burners without having to separate nitrogen from the exhaust gases.

FIG. 175 depicts an embodiment of a system that uses non-condensablefluid from an in situ heat treatment process to heat a treatment area ina formation. Formation fluid 212 produced from treatment areas in theformation enters separation unit 214. Separation unit 214 may separatethe formation fluid into in situ heat treatment process liquid stream216, in situ heat treatment process gas 218, and aqueous stream 220. Insitu heat treatment process gas 218 may entrain some water and/orcondensable hydrocarbons. In situ heat treatment process gas 218 entersgas separation unit 222. Gas separation unit 222 may remove one or morecomponents from in situ heat treatment process gas 218 to produce fuel812 and one or more other streams 814. Fuel 812 may include, but is notlimited to, hydrogen, sulfur compounds, hydrocarbons having a carbonnumber of at most 5, carbon oxides, nitrogen compounds, or mixturesthereof. In some embodiments, gas separation unit 222 uses chemicaland/or physical treatment systems and/or systems described in FIGS. 3-8to remove or reduce the amount of carbon dioxide in fuel 812. In someembodiments, in situ heat treatment process gas 218 is minimally treatedbefore being used as a fuel. For example, gas separation unit 222 mayminimally treat in situ heat treatment process gas 218 to remove waterand/or hydrocarbons having a carbon number greater than 5. In someembodiments, in situ heat treatment process gas 218 is suitable for useas a fuel so the gas separation unit 222 is not necessary.

Fuel 812 may enter fuel conduit 616 that provides fuel to oxidizers ofoxidizer assemblies (for example, a plurality of oxidizer assembliessuch as downhole oxidizer assembly 612 depicted in FIG. 174) that heattreatment area 816. Air stream 818 and/or diluent fluid 820 may be mixedwith oxidizing fluid 806 to form mixed oxidizing fluid 822 that isprovided to the oxidizers of the downhole oxidizing assemblies. Diluentfluid 820 may be, but is not limited to, carbon oxides separated from insitu heat treatment process gas 218, a portion of stream 814 from gasseparation unit 222, carbon dioxide 824 from the exhaust of the downholeoxidizing assemblies, separated gas streams from gas separation systemsdescribed in FIGS. 3-8, or mixtures thereof. In some embodiments,diluent fluid 820 includes sufficient amounts of carbon dioxide toinhibit oxidation of conduits and/or metal parts in fuel conduit 616that come in contact with oxidizing fluid 806. In some embodiments, theamount of excess oxidant supplied to the downhole oxidizers is reducedto less than about 50% excess oxidant by volume by mixing oxidizingfluid 806 with the diluent fluid 820.

Initially, pipeline gas or other fuel may be supplied to treatment area816. Valves 826 may be adjusted to control the amount of initial fuelsupplied to treatment area 816 as fuel 812 becomes available. Initially,air stream 818 may be supplied to treatment area 816 as the oxidizingfluid. After additional oxidant sources become available, valves 826′may be adjusted to control the composition of oxidizing fluid 822provided to treatment area 816.

Exhaust gas 808 from burners used to heat treatment area 816 may bedirected to exhaust treatment unit 828. Exhaust gas 808 may include, butis not limited to, carbon dioxide and/or SO_(x). In exhaust separationunit 828, carbon dioxide stream 824 is separated from SO_(x) stream 830.Separated carbon dioxide stream 824 may be mixed with diluent fluid 820,may be used as a carrier fluid for oxidizing fluid 806, may be used as adrive fluid for producing hydrocarbons, and/or may be sequestered.SO_(x) stream 830 may be treated using known SO_(x) treatment methods(for example, sent to a Claus plant). Formation fluid 212′ produced fromheat treatment area 816 may be mixed with formation fluid 212 from othertreatment areas and/or formation fluid 212′ may enter separation unit214.

In some embodiments, onsite production of oxygen gas is desirable.Production of oxygen gas at or proximate downhole oxidizer assembliesmay reduce production costs and/or enhance efficiency of operation ofthe production of formation fluids. Oxygen gas may be produced byseparation of oxygen from air using cryogenic and/or non-cryogenicsystems. Non-cryogenic systems include, but are not limited to, pressureswing adsorption, vacuum swing adsorption, vacuum-pressure swingadsorption, membranes, or combinations thereof. Cryogenic systems relyon differences in boiling points to separate and purify the desiredproducts.

FIG. 176 depicts a schematic representation of an embodiment of a systemfor producing oxygen for use as a portion of oxidizing fluid 822provided to burners used to heat treatment area 816. Air stream 818enters air separation unit 832. In air separation unit 832, air 818 isseparated into oxygen steam 834 and nitrogen stream 836.

Oxygen stream 834 enters mixed oxidizing fluid 822 and/or is mixed withoxidizing fluid 806. A portion of nitrogen stream 836 may be recycled toair separation unit 832 for use as a coolant. Nitrogen stream 836 may beused as a drive fluid, as a reactant to produce ammonia, as a coolantfor forming a low temperature barrier, as a fluid used during drilling,or as a fluid for other processes.

In some embodiments, oxygen is produce through the decomposition ofwater. For example, electrolysis of water produces oxygen and hydrogen.Using water as a source of oxygen provides a source of oxidant withminimal or no carbon dioxide emissions. The produced hydrogen may beused as a hydrogenation fluid for treating hydrocarbon fluids in situ orex situ, a fuel source and/or for other purposes. FIG. 177 depicts aschematic representation of an embodiment of a system for producingoxygen using electrolysis of water for use in an oxidizing fluidprovided to burners that heat treatment area 816. As shown in FIG. 177,water stream 838 enters electrolysis unit 840. In electrolysis unit 840,current is applied to water stream 838 and produces oxygen stream 842and hydrogen stream 844. In some embodiments, electrolysis of waterstream 838 is performed at temperatures ranging from about 600° C. toabout 1000° C., from about 700° C. to about 950° C., or from 800° C. toabout 900° C. In some embodiments, electrolysis unit 840 is powered bynuclear energy and/or a solid oxide fuel cell. The use of nuclear energyand/or a solid oxide fuel cell provides a heat source with minimaland/or no carbon dioxide emissions. High temperature electrolysis maygenerate hydrogen and oxygen more efficiently than conventionalelectrolysis because energy losses resulting from the conversion of heatto electricity and electricity to heat are avoided by directly utilizingthe heat produced from the nuclear reactions without producingelectricity. Oxygen steam 842 enters mixed oxidizing fluid 822 and/or ismixed with oxidizing fluid 806. A portion or all of hydrogen stream 844is recycled to electrolysis unit 840 and used as an energy source. Aportion or all of hydrogen stream 844 may be used for other purposessuch as, but not limited to, a fuel for burners and/or a hydrogen sourcefor in situ or ex situ hydrogenation of hydrocarbons.

In some embodiments, on site production of hydrogen as a fuel forburners is desirable. The use of hydrogen as the fuel for burners mayallow exhaust streams from the burners to be vented to the atmospherewith little or no treatment of the exhaust streams. Hydrogen may beproduced by reformation of hydrocarbons, by partial oxidation ofhydrocarbons or by a combination of reformation and partial oxidation.Water-gas shift reactions may be used after reformation and/or partialoxidation of hydrocarbons to maximize hydrogen production. For example,autothermal reformation of hydrocarbons having a carbon number of atmost 5 produces hydrogen and carbon oxides. The produced hydrogen may beused as a hydrogenation fluid for treating hydrocarbon fluids in situ orex situ, a fuel source, and/or for other purposes.

FIG. 178 depicts a schematic representation of an embodiment of a systemfor producing hydrogen for use as a fuel for burners that heat treatmentarea 816. In situ heat treatment process gas 218 and/or fuel 812 maypass to reformation unit 846. In some embodiments, in situ heattreatment process gas 218 is mixed with fuel 812 and then passed toreformation unit 846. A portion of in situ heat treatment process gas218 enters gas separation unit 222. Gas separation unit 222 may removeone or more components from in situ heat treatment process gas 218 toproduce fuel 812 and one or more other streams 814. Other streams 814may include carbon dioxide and/or hydrogen sulfide. The carbon dioxidemay be mixed with diluent fluid 820, may be used as a carrier fluid foroxidizing fluid 806, may be used as a drive fluid for producinghydrocarbons, may be vented, and/or may be sequestered. Hydrogen sulfidemay be sent to a Claus plant for conversion to sulfur compounds orsulfur, may be burned to produce heat, and/or may be sequestered in aformation. Fuel 812 may include, but is not limited to, hydrogen,hydrocarbons having a carbon number of at most 5, or mixtures thereof.Some or all of fuel 812 may pass to fuel conduit 616.

Reformer unit 846 may be, for example, an autothermal reformer and/or asteam reformer. Reformer unit 846 may include one or more catalysts thatenhance the production of hydrogen and carbon dioxide from hydrocarbons.For example, reformation unit 846 may include water gas shift catalysts.Reformation unit 846 may include one or more separation systems (forexample, membranes and/or a pressure swing adsorption system) capable ofseparating hydrogen from other components. Reformation of fuel 812and/or in situ heat treatment process gas 218 may produce hydrogenstream 844 and carbon oxide stream 848. Reformation of fuel 812 and/orin situ heat treatment process gas 218 may be performed using techniquesknown in the art for catalytic and/or thermal reformation ofhydrocarbons to produce hydrogen. In some embodiments, fuel 812 and/orin situ heat treatment process gas 218 is passed through a drying systemprior to entering reformation unit 846 to remove water in the fueland/or gas.

Hydrogen stream 844 may be provided to fuel conduit 616. A portion orall of hydrogen stream 844 may be used for other purposes such as, butnot limited to, an energy source and/or a hydrogen source for in situ orex situ hydrogenation of hydrocarbons. Valves 826 may be adjusted tocontrol the amount of initial fuel supplied to treatment area 816 asfuel 812 and/or hydrogen stream 844 become available.

Carbon oxide stream 848 may include, but is not limited to, carbondioxide and carbon monoxide. Carbon oxide stream 848 may be mixed withdiluent fluid 820, may be used as a carrier fluid for oxidizing fluid806, may be used as a drive fluid for producing hydrocarbons, may bevented, and/or may be sequestered.

Combinations of processes described in FIGS. 175 through 178 may be usedto produce fuel and/or oxidizing fluid for burners that provide heat toheat treatment area 816.

Coke formation may occur inside the fuel conduit if the fuel containshydrocarbons and the heat flux is sufficiently high. After oxidizerignition, steps may be taken to reduce coking. For example, steam orwater may be added to the fuel conduit. In some embodiments, coking isinhibited by decreasing a residence time of fuel in the fuel conduit.The residence time of fuel in the fuel conduit may be decreased byvarying the size of the fuel conduit. For example, one portion of thefuel conduit may be approximately ¾ inch (approximately 1.9 cm) indiameter while another portion may be approximately ⅜ inch(approximately 0.95 cm) in diameter. Alternatively, the thickness andlength of all or portions of the fuel conduit may be varied.

In some embodiments, coking is inhibited by insulating portions of thefuel conduit that pass through high temperature zones proximate theoxidizers. For example, a portion of the fuel conduit may be coated withan insulating layer and/or a conductive layer. The insulating layer maybe made from thermal insulating materials such as silicon carbide,alumina, mullite, zirconia, and other material known in the art. Theconductive layer may be made from commercially available highlyconductive materials such as ceramics and/or high temperature metals,including but not limited to Hexyloy (available from Arklay S. RichardsCo., Inc.). The insulating layer and/or the conductive layer may beapplied to the fuel conduit using a high velocity oxygen fuel or airplasma process. The resulting layer or layers may be heat treated.

In some embodiments, the fuel conduit is treated to remove coke formedin the fuel conduit by decoking. Decoking may be performed throughmechanical means and/or chemical means. For example, coke may be removedfrom the fuel conduit by pumping a metal studded, foam or plastic pigthrough the fuel conduit. In an embodiment, a rod is inserted into fuelconduit 616 to dislodge coke particles and push them towards the lastoxidizer in the oxidizer assembly. The rod may be a hydrolance or otherhigh pressure pipe or tube used to direct high pressure water, air,nitrogen, and/or other gas to dislodge the coke.

FIG. 179 and FIG. 180 depict embodiments of oxidizers 614 of oxidizerassemblies positioned in outer conduits 620. Oxidizer 614 may be coupledto fuel conduit 616 that is positioned in oxidant conduit 618. Oxidantand fuel enter mix chamber 850 of oxidizer 614. A combustible mixture offuel and oxidant passes from mix chamber 850 into the space between fuelconduit 616 and shield 852. Shield 852 surrounds a portion of fuelconduit 616. Shield 852 may allow development of flame zone 622 inoxidizer 614. Shield 852 may inhibit gas flowing in the oxidant conduitfrom extinguishing flame zone 622 formed in oxidizer 614. Spacers mayposition oxidizer 614 in oxidant conduit 618. The spacers may be coupledto shield 852 and/or to oxidizer conduit 618. An igniter and/orcombusting fuel in flame zone 622 oxidizes the mixture of fuel andoxidant in the flame zone.

Insulating layer 854 may be placed around fuel conduit 616 to at leastpartially surround a portion of the fuel conduit. Insulating layer 854may be made of a material with low thermal conductivity. Insulatinglayer 854 may inhibit coking in fuel conduit 616. Insulating layer 854may only surround portions of fuel conduit 616 that pass throughoxidizers 614. In some embodiments, the insulating layer covers theportion of the fuel conduit passing through the oxidizer and a portionof the fuel conduit before and/or after the oxidizer. In someembodiments, the entire fuel conduit is insulated.

Thermally conductive layer 856 may surround or partially surroundinsulating layer 854. Thermally conductive layer 856 may be locatedadjacent to flame zone 622. Thermally conductive layer 856 may spreadthe heat of flame zone 622 over a large area to help reduce thetemperature applied to insulating layer 854 below the flame zone. Insome embodiments, the insulating layer does not include a thermallyconductive layer.

FIG. 180 depicts a cross-sectional representation of an embodiment ofoxidizer 614 with gas cooled sleeve 858. A portion of sleeve 858 maypass through oxidizer 614 to form an annular space. One or more spacersmay be located between fuel conduit 616 and sleeve 858 to position thesleeve relative to the fuel conduit. One or more feedthroughs 860 maydirect fuel from fuel conduit 616 to mix chamber 850 and/or to the areabetween shield 852 and the fuel conduit of oxidizer 614. Some gasflowing in oxidant conduit 618 passes between fuel conduit 616 andinsulating sleeve 854. Insulating sleeve 854 may include thermallyconductive layer 856 to dissipate some of the heat from flame zone 622over a large area. Gas passing between fuel conduit 616 and insulatingsleeve 854 may inhibit excessive heating of the fuel conduit adjacent toflame zone 622.

The flow of fuel in fuel conduit 616 is represented by arrow 862, andthe flow of gas (for example, air and exhaust products and unburned fuelfrom previous oxidizers) in oxidant conduit 618 is represented by arrow864. Exhaust gases from all oxidizers in the oxidizer assembly passthrough outer conduit 620 in the direction indicated by arrow 866. Flowof gas between fuel conduit 616 and insulating sleeve 854 may reduce theamount of heat transfer from the insulating sleeve to the fuel conduit.Flame zone 622 may have a temperature of about 1100° C. (about 2000° F.)while the temperature in oxidant conduit adjacent to the shield ofoxidizer 614 may be about 700° C. (about 1300° F.).

Oxidant may be supplied through the oxidant conduit to the oxidizers.Oxidizing fluid may include, but is not limited to, air, oxygen enrichedair, and/or hydrogen peroxide. Depletion of oxygen in the oxidant mayoccur toward a terminal end of an oxidizer assembly. In someembodiments, the amount of excess oxidant supplied to the oxidizers isreduced to less than about 50% excess oxidant by weight by controllingthe pressure, temperature, and flow rate of the oxidant in the oxidantconduit. For example, after ignition, the amount of oxidant can bereduced when the temperature of the fuel conduit reaches about 650° C.(about 1200° F.). In some embodiments, the amount of excess oxidant isreduced to less than about 25% excess oxidant by weight. In otherembodiments, the amount of excess oxidant is reduced to less than about10% excess oxidant by weight.

In some embodiments, the amount of excess oxidant is reduced when thetemperature downstream of the oxidizers becomes sufficiently hot tosupport reaction of oxidant and fuel outside of the oxidizers. Oxidantand fuel may react in regions between oxidizers. During such operation,the oxidizer assembly functions much like a flameless distributedcombustor. Generating heat in the regions between the oxidizers mayresult in a smoother temperature profile along the length of theoxidizer assembly. The excess oxidant may be reduced such that the lastoxidizer in the oxidizer assembly substantially eliminates the remainingoxidant in the oxidant conduit. The last oxidizer may be a catalyticoxidizer to minimize or eliminate oxidant remaining in the oxidantconduit.

When the temperature along the length of the oxidizer assembly increasesto a temperature sufficient to support reaction of oxidant with fueloutside of the shields of the oxidizers, the mode of operation of theoxidizer assembly may shift from a series of individual oxidizers withaerodynamically staged flames to a more uniformly distributed or“reactor-stable” mode of operation. During the reactor-stable mode ofoperation, combustion may take place outside the shield along the entirelength of the oxidant conduit. Under this condition stability isachieved by balancing overall heat loss and heat generation over thebroad reaction zone. Local recirculation of hot combustion products toincoming reactants enables minimum reaction temperature wherefuel-oxidant mixtures will oxidize without aerodynamic stabilization. Inthis mode of operation, the oxidizers may still serve as a “safety” ormeans of continuing stabilization, if the temperature falls below thetemperature needed to sustain oxidation of the fuel and oxidant in oneor more regions of the oxidizer. During reactor-stable mode ofoperation, the amount of excess oxygen supplied to the oxidizer assemblymay be reduced. Having the ability to reduce the amount of excess oxygensupplied to the oxidizer assembly may significantly improve the overalleconomics of the system used to heat the formation.

A common problem associated with the operation of gas burners employinga flame mechanism is that at high temperatures, particularly above about1500° C. (about 2730° F.), oxygen and nitrogen present in the aircombine by a thermal formation mechanism to form pollutants such as NOand NO₂, commonly referred to as NO_(x). By controlling the flow of fueland oxidant, and by maintaining a distributed temperature, the formationof NO_(x) may be inhibited. In some embodiments, the flow of fuel andoxidant is controlled to produce less than about 10 parts per million byweight of NO_(x) from the gas burner. The flow of oxidant may becontrolled by having openings in shields of the oxidizers sized to bringa sufficient flow rate to the flame zone to dilute the flame withoutcausing the flame to be extinguished. Additionally, water added to thefuel conduit may inhibit NO_(x) formation.

In some embodiments, initiation of the burner assembly is accomplishedby initializing combustion in a specified sequence beginning with thelast oxidizer in the assembly. Referring to FIG. 174, oxidizer assembly612 includes first oxidizer 868, last oxidizer 870, and second-to-lastoxidizer 872. In some embodiments, fuel is supplied through fuel conduit616, and oxidant is supplied through oxidant conduit 618 to provide afirst combustible mixture to last oxidizer 870. Combustion is initiatedin last oxidizer 870 and the supply of oxidant is adjusted to supplysecond-to-last oxidizer 872 with a second combustible mixture. Ignitionof last oxidizer 870 is maintained as second-to-last oxidizer 872 isignited. Thereafter this process of adjusting the supply of oxidant toprovide a combustible fuel and oxidant mixture to the next unignitedoxidizer and initiating combustion in the unignited oxidizer is repeateduntil first oxidizer 868 is ignited. In some embodiments, the fuelpressure is greater than the oxidant pressure at an oxidizer beforeinitiating combustion in the oxidizer.

In an embodiment, the start up sequence is optimized by controlling theoxidant and fuel pressure differential along the length of the oxidizerassembly. Because the pressure differential varies over the length ofthe burner assembly, a planned sequential ignition from oxidizer tooxidizer, starting with last (most remote) oxidizer 870 may be achieved.In this embodiment, the fuel-oxidant mixture in the ignition region isoptimized at last oxidizer 870, then at the second to last oxidizer 872,and so on, with the fuel-to-oxidant ratio being least optimal at firstoxidizer 868. The profiles may be controlled to change the sequence ofignition. In an embodiment, the profiles may be reversed so that firstoxidizer 868 is ignited first. Altering the profiles may comprisealtering the pressure differential along the oxidizer assembly length bydesign of the fuel conduit diameter coupled with optimization of openingsizes that provide fuel to the oxidizers, of opening sizes that provideoxidant to the mix chambers of the oxidizers, and of openings in theshields that supply oxidant to the flame zone. In addition, control maybe facilitated by flow restrictions positioned in fuel conduit 616.

FIG. 181 depicts a perspective view of an embodiment of oxidizer 614 ofthe downhole oxidizer assembly. Oxidizer 614 may include mix chamber850, igniter holder 874, ignition chamber 876, and shield 852. Fuelconduit 616 may pass through oxidizer 614. Fuel conduit 616 may have oneor more fuel openings 878 within mix chamber 850 (as shown in FIG. 179).In some embodiments, additional openings in fuel conduit 616 allowadditional fuel to pass into the space between the fuel conduit andshield 852. Openings 880 allow oxidant to flow into mix chamber 850.Opening 882 allows a portion of the igniter supported on igniter holder874 to pass into oxidizer 614. Shield 852 may include openings 884.Openings 884 may provide additional oxidant to a flame in shield 852.Openings 884 may stabilize the flame in oxidizer 614 and moderate thetemperature of the flame. Spacers 886 may be positioned on shield 852 tokeep oxidizer 614 positioned in oxidant conduit 618.

In some embodiments, flame stabilizers may be added to the oxidizers.The flame stabilizers may attach the flame to the shield. The highbypass flow around the oxidizer cools the shield and protects theinternals of the oxidizer from damage enabling long term operation.FIGS. 182-187 depict various embodiments of shields 852 with flamestabilizers 888. Flame stabilizer 888 depicted in FIG. 182 is a ringsubstantially perpendicular to shield 852. The ring shown in FIG. 183 isangled away from openings 884. The rings may amount to up to about 25%annular area blockage. The rings may establish a recirculation zone nearshield 852 and away from the fuel conduit passing through the center ofthe shield.

FIG. 184 depicts an embodiment of flame stabilizer 888 in shield 852.Flame stabilizer 888 is positioned at an angle over the openings. Flamestabilizer 888 may divert incoming fluid flow through openings 884 in anupstream direction. The diverted incoming fluid may set up a flowcondition somewhat analogous to high swirl recirculation (reverse flow).One or more stagnation zones may develop where a flame front is stable.

FIG. 185 depicts an embodiment of multiple flame stabilizers 888 inshield 852. Shield 852 may have two or more sets of openings 884 alongan axial length of the shield. Rings may be positioned behind one ormore of the sets of openings 884. In some embodiments, adjacent ringsmay cause too much gas flow interference. To inhibit gas flowinterference, 3 partial rings (each ring being about ⅙ thecircumference) may be evenly spaced about the circumference instead ofone complete ring. The next set of 3 partial rings along the axiallength of heat shield may be staggered (for example, the partial ringsmay be rotated by 120° relative to the first set of 3 partial rings).FIG. 186 depicts a cross-sectional representation of shield 852 showingthe last set of openings 884 and the last set of flame stabilizers 888.Shield 852 includes spacers 886. In other embodiments, fewer or morethan 3 partial rings may be used (for example, two partial rings may beused for the first set of openings, and four partial rings may be usedfor the next set of openings). Flame stabilizers 888 may beperpendicular to shield 852, angled towards openings 884, angled awayfrom the openings (as depicted in FIG. 185) or positioned ascombinations of perpendicular and angled orientations.

FIG. 187 depicts an embodiment wherein flame stabilizers 888 aredeflector plates or baffles extending over all or portions of openings884. The portions of flame stabilizers 888 positioned over the openingsmay be cylindrical sections with the concave portions facing openings884. Flame stabilizers 888 may divert incoming fluid flow and allow theflame root area to develop around the deflectors. Some openings in theshield may not include flame stabilizers.

In some embodiments, deflectors may be positioned on the outer surfaceof the shield near to openings in the shield. The deflectors may directsome of the gas flowing through the oxidant conduit through the openingsin the shield.

In one embodiment, one or more of the oxidizers have flame stabilizersthat utilize a louvered design to direct flow into the shield. FIG. 188depicts oxidizer 614 with louvered openings 884 in shield 852. Louveredopenings 884 are in communication with the oxidant conduit. An extensionon the inside wall of shield 852 directs gas flow into shield 852 in adirection opposite to the direction of flow in the oxidant conduit. FIG.189 depicts a cross-sectional representation of a portion of shield 852with louvered opening 884. Gas with oxidant entering shield 852 may bedirected by extension 890 in a desired direction. Arrow 892 indicatesthe direction of gas flow from the oxidant conduit to the inside ofshield. Arrow 894 indicates the direction of gas flow in the oxidantconduit.

As depicted in FIGS. 181-189, shield 852 may include opening 884. Thesize and/or number of openings 884 may be varied depending on positionof the oxidizer in the oxidizer assembly to moderate the temperature andensure fuel combustion. In some embodiments, the geometry and size ofopenings 884 on a single oxidizer may be varied to compensate forchanging conditions and needs along the length of the oxidizer.

FIGS. 190-192 depict perspective views of various sectioned oxidizerembodiments. Oxidizers 614 include oxidant openings 880, mix chambers850, ignition chamber 876, and shield 852. FIGS. 190-192 depict variouspositions and sizes for openings 884 in shield 852.

In some embodiments, one or more of the openings in the shield may beangled in a non-perpendicular direction relative to the longitudinalaxis of the shield. Angled openings act as nozzles to alter the entrypath of gas into the shield. Angled openings may promote formation ofinternal low velocity recirculation zones where the reaction front canstabilize and improve the stability and reliability of the oxidizer.

The use of flame stabilizers, various sizes of openings in the shieldand/or angled openings may establish the flame zone of the oxidizerclose to the shield and as far away from the fuel conduit to maximizeradial separation of the flame zone from the fuel conduit to minimizedirect heating of the fuel conduit by the flame zone. The use of flamestabilizers, various sizes of openings in the shield and/or angledopenings may also achieve lower NO_(x) emissions by effectivelyaerodynamically staging the combustion zone and creating fuel rich andlean zones. In fuel rich zones, N₂ formation (instead of NO_(x)) will befavored and aerodynamic staging will control peak temperatures andthermal NO_(x) formation. Such configurations can also enable control ofthe peak longitudinal temperature profile and flame radiation, thussuppressing overheating of the fuel conduit.

In some embodiments, fuel passes through a heated region before beingsupplied to the first oxidizer (oxidizer 868 in FIG. 174). Passing thefuel through the heated region may preheat the fuel and ensure that thefuel and additives in the fuel (for example, water to inhibit coking)are in the gas phase. Ensuring gas phase fuel may avoid plugging infirst oxidizer 868. FIG. 193 depicts an embodiment of first oxidizer 868and fuel conduit 616. Fuel conduit 616 may include sleeve 896. Fuel mayflow through sleeve 896, and a portion of the fuel may flow in theopposite direction in the annular space between the sleeve and fuelconduit 616. A portion of the fuel flowing in the annular space betweensleeve 896 and fuel conduit 616 passes through openings 878 into mixchamber 850.

In some embodiments, a portion of the fuel flowing in the annular spacebetween sleeve 896 and fuel conduit 616 passes through openings 878 intothe annular space between the fuel conduit and shield 852. Supplyingfuel into this annular space may allow flame zone 622 to extend througha significant portion of first oxidizer 868 so that the first oxidizeris able to input more heat into the formation. First oxidizer 868 may beconfigured to input more heat into the formation to help compensate forheat losses attributable to the oxidizer being the first oxidizer of theoxidizer assembly. Having first oxidizer configured to input more heatinto the formation than other oxidizers of the oxidizer assembly mayallow for a decrease in the total number of oxidizers needed in thedownhole assembly.

One or more of the oxidizers in an oxidizer assembly may be a catalyticburner. The catalytic burners may include a catalytic portion (forexample, a catalyst chamber) followed by a homogenous portion (forexample, an ignition chamber). Catalytic burners may be started late inan ignition sequence, and may ignite without igniters. Oxidant for thecatalytic burners may be sufficiently hot from upstream burners (forexample, the oxidant may be at a temperature of about 370° F. (about700° C.) if the fuel is primarily methane) so that a primary mixturewould react over the catalyst in the catalyst portion and produce enoughheat so that exiting products ignite a secondary mixture in thehomogenous portion of the oxidizer. In some embodiments, the fuel mayinclude enough hydrogen to allow the needed temperature of the oxidantto be lower. Catalysts used for this purpose may include palladium,platinum, platinum/iridium, platinum/rhodium or mixtures thereof.

FIG. 194 depicts a cross-sectional representation of catalytic burner898. Oxidant may enter mix chamber 850 through openings 880. Fuel mayenter mix chamber 850 from fuel conduit 616 through fuel openings 878′.Fuel and oxidizer may flow to catalyst chamber 902. Catalyst chamber 902contains catalyst which reacts a mixture from mix chamber 850 to producereaction products at a temperature that is sufficient to ignite fuel andoxidant. In some embodiments, the catalyst includes palladium on ahoneycomb ceramic support. The fuel and oxidant react in catalystchamber 902 to form hot reaction products. The hot reaction products maybe directed to the annular space between shield 852 and fuel conduit616. Additional fuel enters the annular space through openings 878″ infuel conduit 616. Additional oxidant enters the annular space throughopenings 884. The hot reaction products generated by catalyst 902 mayignite fuel and oxidant in autoignition zone 904. Autoignition zone 904may allow fuel and oxidant to form flame zone 622. In some embodiments,the catalytic burner includes flame stabilizers or other types of gasflow modifiers.

In some embodiments a catalytic burner may include an igniter tosimplify startup procedures. FIG. 195 depicts catalytic burner 898 thatincludes igniter 900. Igniter 900 is positioned in mix chamber 850.Catalytic burner 898 includes catalyst chamber 902. Catalyst chambercontains a catalyst that reacts a mixture from mix chamber 850 toproduce reaction products at a temperature that is sufficient to ignitefuel and oxidant. Oxidant enters mix chamber through openings 880A. Fuelenters the mix chamber from fuel line through fuel openings 878A. Thefuel input into mixture chamber 850 may be only a small fraction of thefuel input for catalytic burner 898. Igniter 900 raises the temperatureof the fuel and oxidant to combustion temperatures in pre-heat zone 906.Flame stabilizer 888 may be positioned in mixing chamber 850. Heat frompre-heat zone 906 and/or combustion products may heat additional fuelthat enters mixing chamber 850 through fuel openings 878B and additionaloxidant that enters the mixing chamber through openings 880B. Openings878B and openings 880B may be upstream of flame stabilizer 888. Theadditional fuel and oxidant are heated to a temperature sufficient tosupport reaction on catalyst 902.

Heated fuel and oxidant from mixing chamber 850 pass to catalyst 902.The fuel and oxidant react on catalyst 902 to form hot reactionproducts. The hot reaction products may be directed to heat shield 852.Additional fuel enters heat shield 852 through openings 878C in fuelconduit 616. Additional oxidant enters heat shield 852 through openings884. The hot reaction products generated by catalyst 902 may ignite fueland oxidant in autoignition zone 904. Autoignition zone 904 may allowfuel and oxidant to form main combustion zone 622. In some embodiments,the catalytic burner includes flame stabilizers or other types of gasflow modifiers.

In some embodiments, all of the oxidizers in the oxidizer assembly arecatalytic burners. In some embodiments, the first or the first severaloxidizers in the oxidizer assembly are catalytic burners. The oxidantsupplied to these burners may be at a lower temperature than subsequentburners. Using catalytic burners with igniters may stabilize the initialperformance of the first several oxidizers in the oxidizer assembly.Catalytic burners may be used in-line with other burners to reduceemissions by allowing lower flame temperatures while still havingsubstantially complete combustion.

In some embodiments, a catalytic converter may be positioned at the endof the oxidizer assembly or in the exhaust gas return. The catalyticconverter may remove unburned hydrocarbons and/or remaining NO_(x)compounds or other pollutants. The catalytic converter may benefit fromthe relatively high temperature of the exhaust gas. In some embodiments,catalytic burners in series may be integrated with coupled catalyticconverters to limit undesired emissions from the oxidizer assembly. Insome embodiments, a selectively permeable material may be used to allowcarbon dioxide or other fluids to be separated from the exhaust gas.

In one embodiment, initiation of the burner assembly may be accomplishedby initializing combustion with hydrogen and later switching to naturalgas or another fuel. The use of hydrogen-enriched fuel may suppressflame radiation and reduce heating of the fuel conduit. Oxidizers of theoxidizer assembly may be ignited using hydrogen or fuel that is highlyenriched with hydrogen. Once ignited, the composition of fuel may beadjusted to comprise natural gas and/or other fuels. The initial use ofhydrogen or hydrogen-enriched fuel widens the flammability envelopeenabling much easier startup. An initial fuel composition could then be“chased” with production gas or other more economical gases.Alternatively, the entire system could burn hydrogen. With no carbon inthe fuel, there would be no need for additional decoking methods.

FIG. 196 depicts a cross-sectional representation of an embodiment ofoxidizer 614 of oxidizer assembly 612 with the section takensubstantially perpendicular to a central axis of the oxidizer throughfuel conduit 616 that enters mix chamber 850 of the oxidizer. Oxidizer614 is positioned in oxidant conduit 618. Supports 908 position oxidizer614 in oxidant conduit 618. Supports 908 may be welded or otherwisesecured to oxidizer 614 and/or oxidant conduit 618. In some embodiments,one or more supports or spacers may be positioned in the space betweenoxidant conduit 618 and outer conduit 620 to position the oxidantconduit in the outer conduit.

Oxidant conduit 618 is positioned in outer conduit 620. Fuel conduits616 are positioned in the space between oxidant conduit 618 and outerconduit 620. In the depicted embodiment, four fuel conduits 616 areshown. More than four fuel conduits or less than four fuel conduits maybe positioned in the oxidizer assembly in other embodiments. Fuel taps910 may pass from fuel conduits 616 through oxidant conduit 618 to a mixchamber of an oxidizer. In some embodiments, each fuel conduit 616supplies a single oxidizer. In some embodiments, one fuel conduitsupplies two or more oxidizers of the oxidizer assembly. Portions or allof fuel conduits 616 and/or portions or all of fuel taps 910 may beinsulated. In some embodiments, fuel conduits 616 are positionedradially away from oxidant conduit 618 so that exhaust gas returningthrough the space between outer conduit 620 and the oxidant conduittransfers heat with the fuel conduits to limit the upper temperatureattained by the fuel conduits.

Using multiple fuel conduits may allow the supply of fuel to beinterrupted to one or more of oxidizers without adversely affecting allof the oxidizers. Multiple fuel conduits also allow for adjustment offuel mixtures supplied to the oxidizers during startup and after steadyoperation of the oxidizers is established.

Igniter supply conduits 912 may be positioned in the space betweenoxidant conduit 618 and outer conduit 620. In some embodiments, theigniter supply conduits are positioned in the oxidant conduit. Igniters900 may branch from igniter supply conduits 912 into ignition chamber876 of the oxidizers. In the depicted embodiment, four igniter supplyconduits 912 are shown. More than four igniter supply conduits or lessthan four igniter supply conduits may be positioned in the oxidizerassembly in other embodiments. Igniter supply conduits may be conduitsthat convey a fuel (for example, hydrogen) to a catalyst in the igniter.Igniter supply conduits may hold insulated conductors that provideelectricity to the igniters. The igniters may be glow plugs, sparkplugs, or other types of igniters that use electricity to ignite theoxidizers. In some embodiments, the igniter supply conduit is aninsulated conductor. In some embodiments, some igniter supply conduitsmay convey fuel and other igniter supply conduits of the oxidizerassembly may transmit electricity.

FIG. 197 depicts a cross-sectional representation of an embodiment ofoxidizer 614 of oxidizer assembly 612 with the section takensubstantially along the central axis of the oxidizer. Additionaloxidizers may be positioned above and/or below the oxidizer shown.Supports 908 position oxidizer 614 in oxidant conduit 618. Oxidizer 614includes mix chamber 850, ignition chamber 876 and shield 852. Oxidantconduit 618 is positioned in outer conduit 620. Fuel conduit 616 ispositioned in the space between outer conduit 620 and oxidant conduit618. One or more fuel taps 910 from fuel conduit 616 pass throughoxidant conduit 618 to mix chamber 850. Mix chamber 850 has one or moreopenings 880 that allow passage of oxidant from oxidant conduit 618 intothe mix chamber. The size and/or number of openings may be set for eachoxidizer so that the oxidizer receives an appropriate inflow into mixchamber 850. In some embodiments, the amount of flow into the mixchamber of one or more oxidizers is adjusted by a control system that isable to change the size of the openings into the mix chamber.

A mixture of fuel and oxidant passes from mix chamber 850 to ignitionchamber 876 through mixture opening 914. Mixture opening 914 may bepositioned along a central axis of oxidizer 614 as depicted in FIG. 196and FIG. 197. Positioning mixture opening 914 allows flame zone 622generated by ignited fuel mixture to be substantially axisymmetricwithin oxidizer 614. Flame zone 622 may be stable and result in theproduction of low amount of NO_(x) compounds. Flame zone 622 may havethe potential for swirl applications.

In some embodiments, igniter 900 branches from igniter supply conduit912 through oxidant conduit 618 into ignition chamber 876. Igniter 900may be used during start up of the oxidizer assembly to initiatecombustion of fuel and oxidant mixture passing through opening 914. Insome embodiments, use of the igniters is stopped after start up of theoxidizers in the oxidizer assembly. Flame zone 622 generated bycombusting the oxidant and fuel mixture may extend through ignitionchamber 876 into shield 852. Shield 852 may stabilize flame zone 622 andinhibit blow out of the flame zone by oxidant and exhaust gas flowingthrough oxidant conduit 618.

In some embodiments, one or more small oxidant conduit lines may bepositioned in the oxidizer assembly to provide additional oxidizingfluid to the oxidizers located near the end of the oxidizer assembly.Small oxidant lines may be positioned in the main oxidant conduit and/orin the space between the oxidant conduit and the outer conduit.Additional oxidizing fluid may be introduced into the exhaust andoxidizing fluid flowing through the main oxidant conduit. The additionaloxidizing fluid may result in combustion of all of the fuel supplied tothe oxidizers.

In some embodiments, oxidizers that produce a flame are used aspreheaters upstream of flameless distributed combustors. The oxidizerspreheat the oxidizing fluid and/or the fuel supplied to the flamelessdistributed combustors above a temperature of about 815° C., which isabove the auto-ignition temperature of a mixture of oxidant fluid andfuel.

The flameless distributed combustor segments may be 100 ft to 500 ft inlength. Shorter or longer flameless distributed combustor segmentlengths may also be used. The oxidizer assembly may have less than tenoxidizers. FIG. 198 depicts a schematic representation of oxidizerassembly 612 with oxidizers 614 that preheat fuel and oxidant suppliedto flameless distributed combustors 916. Oxidizers 614 may be similar tothe oxidizer depicted in FIG. 181.

Flameless distributed combustors 916 depicted in FIG. 198 may include aseries of orifices 918 in central fuel conduit 616. Orifices 918 may becritical flow orifices. Orifices 918 allow heated fuel to mix withheated oxidizing fluid so that the mixture reacts to produce additionalheat. Flameless distributed combustors 916 may operate at much lowertemperature than oxidizers 614 since no flame is present. The lowertemperature may result in the production of less NO_(x) compounds if theoxidizing fluid includes, or the fuel includes, nitrogen or nitrogencompounds.

In some embodiments, one or more additional fuel conduits may bepositioned in the space between the oxidant conduit and the outerconduit. Taps from the additional fuel conduits may pass through theoxidant conduit to provide fuel to the oxidizers and/or to the centralfuel conduit prior to one of the oxidizers.

In some embodiments, pulverized coal is the fuel used to heat thesubsurface formation. The pulverized coal may be carried into thewellbores with a non-oxidizing fluid (for example, carbon dioxide and/ornitrogen). An oxidant may be mixed with the pulverized coal at severallocations in the wellbore. The oxidant may be air, oxygen enriched airand/or other types of oxidizing fluids. Igniters located at or near themixing locations initiate oxidation of the coal and oxidant. Theigniters may be catalytic igniters, glow plugs, spark plugs, and/orelectrical heaters (for example, an insulated conductor temperaturelimited heater with heating sections located at mixing locations ofpulverized coal and oxidant) that are able to initiate oxidation of theoxidant with the pulverized coal.

The particles of the pulverized coal may be small enough to pass throughflow orifices and achieve rapid combustion in the oxidant. Thepulverized coal may have a particle size distribution from about 1micron to about 300 microns, from about 5 microns to about 150 microns,or from about 10 microns to about 100 microns. Other pulverized coalparticle size distributions may also be used. At 600° C., the time toburn the volatiles in pulverized coal with a particle size distributionfrom about 10 microns to about 100 microns may be about one second.

FIG. 199 depicts a representation of oxidizer assembly 612 in inclinedor substantially horizontal wellbore 428. FIG. 200 depicts arepresentation of downhole oxidizer assembly 612 in u-shaped wellbore428. Pulverized coal entrained in a carrier fluid may be fuel 810supplied to oxidizers 614 through fuel conduit 616. Oxidizing fluid 806may be supplied to oxidizers through oxidant conduit 618. Initially,oxidizer assembly 612 may be started using hydrogen, natural gas, orother fuel. After temperatures of oxidizers 614 are hot enough tosupport rapid pulverized coal oxidation (for example, the temperature inand adjacent to oxidizers 614 is above about 600° C.), the fuel may bechanged to pulverized coal and carrier gas. In FIG. 199, exhaust gas 808may flow through outer conduit 620 to the surface. Exhaust gas 808passing conduit 618 may help to inhibit formation of hot spots adjacentto oxidizers 614. In FIG. 200, fuel 810 and oxidizing fluid 806 mayenter u-shaped wellbore at location 664. Exhaust gas may flow to thesurface to location 668 through conduit 618. In some embodiments, afluid (for example, a molten salt or a molten metal) may be positionedin outer conduit 620 to inhibit formation of hot spots adjacent tooxidizers 614. In some embodiments, oxidant conduit 618 may bepositioned directly in u-shaped wellbore 428 without being positioned inan outer conduit.

Exhaust gas 808 from oxidizer assemblies 612 depicted in FIG. 199 andFIG. 200 may be treated to remove unreacted coal, ash, fines and/orother particles in the exhaust gas. In some embodiments, exhaust gas 808passes through one or more cyclones to remove particles from the exhaustgas. Exhaust 808 gas may be further processed to remove selectedcompounds (for example, sulfur and/or nitrogen compounds), may be usedas a drive fluid for mobilizing hydrocarbons in a formation, may besequestered in a subsurface formation, and/or may be otherwise handled.

In other embodiments, other types of downhole oxidizers are used for thesubsurface oxidation of coal to heat selected portions of the formation.FIG. 201 depicts a schematic representation of heater 920 that usespulverized coal as fuel. Heater 920 may include outer conduit 620, firstconduit 922, and second conduit 924. First conduit 922 is positioned inouter conduit 620, and second conduit 924 is positioned in the firstconduit. The end of second conduit 924 may be closed. Second conduit 924may include critical flow orifices 926. The flow rate and/or pressuresof the fluids flowing through first conduit 922 and second conduit 924may be controlled to allow for mixing of fluid from the first conduitwith fluid from the second conduit at desired locations in the firstconduit.

In an embodiment, coal and carrier gas is introduced into heater 920through first conduit 922, and oxidant is introduced through secondconduit 924. The flow rate and/or pressure in first conduit 922 andsecond conduit 924 are controlled so that the oxidant flows throughcritical flow orifices 926 into the coal and carrier gas flowing throughfirst conduit 922. Reaction of the coal and oxidant occurs in firstconduit 922. Exhaust gas 808 pass through outer conduit 620 to thesurface. Passing the exhaust gases past the locations where oxidant andcoal are oxidized may reduce temperature variations along the length ofthe heated section of heater 920.

In an embodiment, oxidant is introduced into heater 920 through firstconduit 922, and coal and carrier gas is introduced through secondconduit 924. The flow rate and/or pressure in first conduit 922 andsecond conduit 924 are controlled so that the coal and carrier gas flowsthrough critical flow orifices 926 into the oxidant flowing throughfirst conduit 922. Reaction of the coal and oxidant occurs in firstconduit 922. Exhaust gases pass through outer conduit 620 to thesurface.

FIG. 202 depicts a schematic representation of heater 920 that usespulverized coal as fuel. Heater 920 may include outer conduit 620, firstconduit 922, and second conduit 924. First conduit 922 is positioned inouter conduit 620, and second conduit 924 is positioned in the firstconduit. The end of first conduit 922 may be sealed closed againstsecond conduit 924. Second conduit 924 may include critical floworifices 926. The flow rate and/or pressures of the fluids flowingthrough first conduit 922 and second conduit 924 may be controlled toallow for mixing of fluid from the first conduit with fluid from thesecond conduit at desired locations in the second conduit.

In an embodiment, oxidant is introduced into heater 920 through firstconduit 922, and coal and carrier gas is introduced through secondconduit 924. The flow rate and/or pressure in first conduit 922 andsecond conduit 924 are controlled so that the oxidant flows throughcritical flow orifices 926 into the coal and carrier gas flowing throughsecond conduit 924. Reaction of the coal and oxidant occurs in secondconduit 924. Reacting coal and oxidant in second conduit 924 and passingexhaust gases through outer conduit 620 to the surface may reduce theformation of hot zones adjacent to sections of heater 920 whereoxidation occurs.

In an embodiment, coal and carrier gas is introduced into heater 920through first conduit 922, and oxidant is introduced through secondconduit 924. The flow rate and/or pressure in first conduit 922 andsecond conduit 924 are controlled so that the coal and carrier gas flowsthrough critical flow orifices 926 into oxidant flowing through secondconduit 924. Reaction of the coal and oxidant occurs in second conduit924. Exhaust gases pass through outer conduit 620 to the surface.

In some embodiments, fast fluidized transport line systems may be usedfor subsurface heating. Fast fluidized transport line systems may havesignificantly higher overall energy efficiency as compared to usingelectrical heating. The systems may have high heat transfer efficiency.Low value fuel (for example, bitumen or pulverized coal) may be used asthe heat source. Solid transport line circulation is commercially proventechnology having relatively reliable operation.

FIG. 203 depicts a schematic representation of a portion of a fastfluidized transport line heating system. Fast fluidized transportsystems 928 may include combustion unit 930, supply conduit 932, returnconduit 934, wellbores having inlet legs 936 and outlet legs 938,replenishment line 940, treatment unit 942, oxidant supply line 944 andgas lift supply line 946. Each combustion unit 930 may provide hotfluidized material to a large number of u-shaped wellbores. For example,one combustion unit 930 may supply hot fluidized material to 20 or moreu-shaped wellbores. In some embodiments, the u-shaped wellbores areformed so that the surface footprint has long rows of inlet legs 936 andexit legs 938 of u-shaped wellbores. The exit legs and inlet legs ofthese u-shaped wellbores are located in adjacent rows. FIG. 203 depictsa portion of fast fluidized transport systems 928 adjacent to a portionof a row of inlet legs 936 and outlet legs 938. Additional fluidizedtransport systems would be located on the same row to supply all of theu-shaped wellbores on the row. Also, additional fluidized transportsystems would be positioned on adjacent rows to supply inlet legs andoutlet legs of the adjacent rows.

In some embodiments, one or more of combustion units 930 used to heatthe formation are fluidized combustors. A portion of the fluidizedmaterial from the fluidized bed reactor flows into supply conduit 932,and from the supply conduit to inlet legs 936 of u-shaped wellbores inthe formation. In some embodiments, one or more of combustion units 930used to heat the formation are furnaces, nuclear reactors, or other hightemperature heat sources. Such combustion units heat fluidized materialthat passes through the combustion units. The fluidized material flowsfrom the combustion units to supply conduit 932, and from the supplyconduit to inlet legs 936 of u-shaped wellbores in the formation.

Oxidant may be supplied to combustion unit 930 through oxidant line 948.Fuel may be supplied to combustion unit 930 through fuel line 950.Exhaust gases may be removed from combustion unit 930 through exhaustline 952. The oxidant line, fuel line and exhaust line may not be neededif the combustion unit is a nuclear reactor. If combustion unit 930 is afluidized bed combustor, fuel line 950 may spray fuel oil or other fuelinto the fluidized combustor in addition to the fuel sent to thecombustion unit contained in the fluidized material in conduit 956.Fluidized material exiting combustion unit 930 may be at a hightemperature. For example, the fluidized material may be at temperaturesfrom about 300° C. to about 1000° C., from about 500° C. to about 800°C., or from about 700° C. to about 750° C.

The u-shaped conduits in the formation may have a relatively smalldiameter. For example, the diameter of the u-shaped conduits in theformation may be less than 8 cm. Heat transfers substantially byradiation and/or conduction from the u-shaped conduits to the formation.Inlet legs 936 and/or outlet legs 938 may be insulated through theoverburden to inhibit heat transfer to the overburden. In someembodiments, the direction of flow in the u-shaped conduits is reversedperiodically to promote more uniform heating of the formation from theconduits. For example, the flow may be reversed every six months. Othertime periods before reversing the flow may be used. In some embodiments,the direction of fluidized material flow in one u-shaped conduit isopposite in direction to the flow of fluidized material in an adjacentu-shaped conduit.

The inner surfaces of the u-shaped conduits may include inserts, bafflesand/or roughened surfaces. The inserts may be liners that areperiodically replaced in the conduits. The inserts, baffles and/orroughened surfaces may increase turbulence of the fluidized material inthe conduits to increase heat transfer to the conduits. Fluidizedmaterial flowing through the u-shaped conduits may impact on theinserts, baffles and/or roughened surfaces. The impacts may transferheat kinetically to the conduits. In some embodiments, portions of theoutside surfaces of the conduits may include roughening and/orprotrusions to increase heat transfer from the conduits to theformation.

Fluidized material exiting the formation may pass from the u-shapedconduits into return conduits line 934. Return conduit 934 may directthe fluidized material to treatment unit 942. Treatment unit 942 mayinclude cyclones and/or other separation units that separate fines andexhaust gas 954 from fluidized material that may be recirculated throughfast fluidized transport system 928. In some embodiments, fluidizedmaterial that is to be recirculated is coated with bitumen or otherhydrocarbons in treatment unit 942 before being sent to combustion unit930.

Replenishment line 940 may supply fresh fluidized material to line 956returning to combustion unit 930. The fresh fluidized material maycompensate for fines and exhaust gas 954 removed in treatment unit 942.

Fluidized material in line 956 may include coal particles (for example,pulverized coal), other hydrocarbon or carbon containing material (forexample, bitumen and coke), and heat carrier particles. The heat carrierparticles may include, but are not limited to, sand, silica, ceramicparticles, waste fluidized catalytic cracking catalyst, other particlesused for heat transfer, or mixtures thereof. In some embodiments, theparticle range distribution of the fluidized material may span frombetween about 5 and 200 microns.

A portion of the hydrocarbon content in fluidized material may combustand/or pyrolyze in combustion unit 930. Fluidized material may stillhave a significant carbon (coke) and/or hydrocarbon content afterpassing through combustion unit 930. Inlet legs 936 of the u-shapedconduits in the formation may be supplied with oxidant (for example,air) through oxidant supply lines 944. The oxidant may react with thecarbon and/or hydrocarbons in the fluidized material in the u-shapedconduits. In some embodiments, the temperature of the oxidant in oxidantsupply line 944 is raised by passing through combustion unit 930 orotherwise raising the temperature of the oxidant prior to introducingthe oxidant into the u-shaped conduits. Introducing heated oxidant intothe u-shaped conduits may promote oxidation of hydrocarbons and carbonin the fluidized material. The combustion of hydrocarbons and carbon inthe fluidized material may maintain a high temperature of the fluidizedmaterial and/or generate heat that transfers to the formation. In someembodiments, oxidant from oxidant supply line 944 is supplied to outerconduits that surround portions of inlet legs 936. Valves in inlet legs936 pass oxidant from the outer conduits into the inlet legs.

Gas lifting may facilitate transport of the fluidized material in theu-shaped conduits to return conduit 934. Outlet legs 938 may bepositioned in outer conduits. Multiple valves in the outlet legs 938 mayallow entry of lift gas into the outlet legs to transport the fluidizedmaterial to return conduit 934. In some embodiments, the lift gas isair. Other gases may be used as the lift gas.

In some in situ heat treatment processes, coal or biomass may be used asa fuel to directly heat a portion of the formation. The fuel may beprovided as a solid. The fuel may be ground or otherwise sized so thatthe size of the chunks, pellets, or granules provides a large surfacearea that facilities combustion of the fuel. A u-shaped wellbore may beformed in the formation. In some embodiments, the fuel is burned as thefuel is transported on a grate through the formation. In someembodiments, the fuel is burned in a batch or semi-batch operation. Fuelis placed on a train and the train is moved to a location in theformation. The fuel is combusted, and then the train is pulled out ofthe formation and another train is placed in the formation with freshfuel. Heat from the burning fuel may heat the formation. Enough fuel maybe placed on the grates so that all of the fuel is combusted before thegrate is removed from the wellbore.

Coal and/or biomass may be significantly less expensive than otherenergy sources for heating the formation (for example, electricityand/or gas). Combusting coal in the formation may improve energyefficiency and lower cost as compared with using the coal to produceelectricity that in turn is used to heat the formation.

FIG. 204 depicts a schematic representation of wellbore 958 that may beused to transport burning fuel through the formation. U-shaped wellbore958 may have a relatively large bore diameter. The casing placed in thewellbore may have a diameter that is greater than 10″. Entry leg 960 andexit leg 962 of wellbore 958 may be drilled at relative shallow angles,for example, less than 45°, less 30°, or less than 25°. Heat conductorshafts 964 may branch off from wellbore. Heat pipes and/or heatconductive gel may be placed in the heat conductor shafts 964. Heat fromheat conductor shafts 964 may transfer heat away from wellbore 958 toother portions of the formation. Heat conducted by heat conductor shafts964 may be sufficient to pyrolyze at least a portion of the formationproximate the heat conductor shafts. The heat conducted by heatconductor shafts 964 may be used in carbon dioxide compression and/orfor carbon dioxide sequestration, and/or barrier well applications. Insome embodiments, heat conductor shafts are not necessary. In someembodiments, high velocity gas (for example, pressurized carbon dioxide)may be used to move heat through the formation.

FIG. 205 depicts a top view of a portion of train 966 that may conveyburning coal and/or biomass through the wellbore to heat the treatmentarea. FIG. 206 depicts a side view representation of a portion of train966 used to heat the treatment area positioned in wellbore casing 968.Train 966 may include carriers 970, fuel 972, oxidant conduit 974,conveyor 976, and clean-up bin 978. In some embodiments, train 966includes an electrical conduit and heaters 980 that branch off of theelectrical conduit. Heaters 980 may be inductive heaters, temperaturelimited heaters or other type of electrical heaters that provide heat toinitiate combustion of fuel 972. In some embodiments, heaters 980 travelwith train 966. In some embodiments, heaters 980 are immobile. Afterfuel 972 begins combusting and/or after formation adjacent to thewellbore is hot enough to support combustion of the fuel, use of heaters980 may be stopped. In other embodiments, a downhole oxidizer or othertype of heater may be used to initiate combustion of the fuel. In someembodiments, combustion initiation is only performed in the first partof the wellbore where heat is to be applied to the formation. Aftercombustion initiation, the supply of oxidant keeps the fuel burning asthe fuel is drawn through the formation on train 966.

In some embodiments, a removable electric heater or combustor is used toinitiate combustion of the fuel. The electric heater and/or combustormay be inserted in the formation beneath the overburden. The electricheater and/or combustor may be used to raise the temperature near theinterface between the overburden and the treatment area above anauto-ignition temperature of the fuel on the grate. The fuel on thegrate may begin to combust as the fuel passes through the heated zone.Heat from combusting fuel heats the treatment area. When the treatmentarea adjacent to the entrance to the treatment area rises above theauto-ignition temperature of the fuel, use of the electric heater and/orcombustor may be stopped. In some embodiments, the electric heaterand/or combustor are removed from the wellbores.

Carriers 970 may include grates 982 and ash catchers 984. Fuel 972 maybe positioned on top of grates 982. Fuel 972 placed on grate 982 ofcarrier 970 may be pulverized, ground or otherwise sized so that theaverage particle size of the fuel is larger than the size of openingsthrough the grates. When fuel 972 burns, ash may fall through theopenings in grates to fall on ash catchers 984. Oxidant conduit 974 andheater 980 may pass through ash catchers 984.

Oxidant conduit 974 may carry an oxidant such as air, enriched air, oroxygen and a carrier fluid (for example, carbon dioxide) to fuel 972.Oxidant conduit 974 may include a number of openings that allow theoxidant to be introduced into the formation along the length of theU-shaped wellbore that is to be heated. In some embodiments, theopenings are critical flow orifices. In some embodiments, more than oneoxidant conduit 974 is placed in the U-shaped wellbore. In someembodiments, one or more oxidant conduits 974 enter the formation fromeach side of the U-shaped wellbore.

Conveyor 976 may pull train 966 through the U-shaped wellbore. In someembodiments, conveyor 976 is a belt, cable and/or chain. In someembodiments, fuel is transported pneumatically through the wellbore.Canisters with openings are loaded with fuel. Openings in the canistersallow oxidant in and exhaust products out of the canisters. Thecanisters may be pneumatically drawn through the wellbore.

Clean-up bins 978 may be positioned periodically in train 966. Clean-upbins may remove ash from the wellbore that does not fall into ashcatchers 984. Clean-up bins 978 may have an open end that substantiallyconforms to the bottom of casing 968.

Temperature sensors in the wellbore may provide information ontemperature along the wellbore to a control system. Speed, position,loading patterns of the grates, and oxidant delivery through the oxidantconduit may be adjusted by the control system to control the heating ofthe treatment area.

In some embodiments, the train is drawn in a loop through two or moreu-shaped wellbores positioned in the formation. FIG. 207 depicts anaerial view representation of a system that heats the treatment areausing burning fuel that is moved through the treatment area. The trainmay enter leg 960 of wellbore 958, and exit through leg 962. The trainmay be drawn through supply station 986 by conveyor 976. Supply stationmay include machinery that interacts with conveyor 976 to move the trainon the loop. In supply station 986, the train may be re-supplied withfuel, inspected, repaired, and/or cleaned of ash. Ash may be sent to atreatment facility or disposal site. The train may leave supply station986 and enter leg 960′ of wellbore 958′. The train travels throughwellbore 958′ and exits through leg 962′. Combustion of fuel on thetrain in the wellbore may heat the formation adjacent to the wellbore.The train may enter supply station 986′. At supply station 986′, thetrain may be re-supplied with fuel, inspected, repaired, and/or cleanedof ash. Supply station 986′ may also include machinery that interactswith conveyor 976 to move the train on the loop.

Exhaust conduits 988 may convey exhaust from the burned fuel to exhausttreatment system 990. Exhaust treatment system 990 may treat exhaust toremove noxious compounds from the exhaust (for example, NO_(x) andCO_(x)). In some embodiments, exhaust treatment system 990 may include acatalytic converter system. Treated exhaust may be used for otherprocesses (for example, the treated exhaust may be used as a drivefluid) and/or the treated exhaust may be sequestered.

In some in situ heat treatment process embodiments, a circulation systemis used to heat the formation. The circulation system may be a closedloop circulation system. FIG. 208 depicts a schematic representation ofa system for heating a formation using a circulation system. The systemmay be used to heat hydrocarbons that are relatively deep in the groundand that are in formations that are relatively large in extent. In someembodiments, the hydrocarbons may be 100 m, 200 m, 300 m or more belowthe surface. The circulation system may also be used to heathydrocarbons that are not as deep in the ground. The hydrocarbons may bein formations that extend lengthwise up to 500 m, 750 m, 1000 m, ormore. The circulation system may become economically viable informations where the length of the hydrocarbon containing formation tobe treated is long compared to the thickness of the overburden. Theratio of the hydrocarbon formation extent to be heated by heaters to theoverburden thickness may be at least 3, at least 5, or at least 10. Theheaters of the circulation system may be positioned relative to adjacentheaters so that superposition of heat between heaters of the circulationsystem allows the temperature of the formation to be raised at leastabove the boiling point of aqueous formation fluid in the formation.

In some embodiments, heaters 802 may be formed in the formation bydrilling a first wellbore and then drilling a second wellbore thatconnects with the first wellbore. Piping may be positioned in theU-shaped wellbore to form U-shaped heater 802. Heaters 802 are connectedto heat transfer fluid circulation system 992 by piping. Gas at highpressure may be used as the heat transfer fluid in the closed loopcirculation system. In some embodiments, the heat transfer fluid iscarbon dioxide. Carbon dioxide is chemically stable at the requiredtemperatures and pressures and has a relatively high molecular weightthat results in a high volumetric heat capacity. Other fluids such assteam, air, helium and/or nitrogen may also be used. The pressure of theheat transfer fluid entering the formation may be 3000 kPa or higher.The use of high pressure heat transfer fluid allows the heat transferfluid to have a greater density, and therefore a greater capacity totransfer heat. Also, the pressure drop across the heaters is less for asystem where the heat transfer fluid enters the heaters at a firstpressure for a given mass flow rate than when the heat transfer fluidenters the heaters at a second pressure at the same mass flow rate whenthe first pressure is greater than the second pressure.

In some embodiments, a liquid heat transfer fluid is used as the heattransfer file. The liquid heat transfer fluid may be a natural orsynthetic oil, molten metal, molten salt, or other type of hightemperature heat transfer fluid. A liquid heat transfer fluid may allowfor smaller diameter piping and reduced pumping/compression costs. Insome embodiments, the piping is made of a material resistant tocorrosion by the liquid heat transfer fluid. In some embodiments, thepiping is lined with a material that is resistant to corrosion by theliquid heat transfer fluid. For example, if the heat transfer fluid is amolten fluoride salt, the piping may include a 10 mil thick nickelliner. The piping may be formed by roll bonding a nickel strip onto astrip of the piping material (for example, stainless steel), rolling thecomposite strip, and longitudinally welding the composite strip to formthe piping. Other techniques may also be used. Corrosion of nickel bythe molten fluoride salt may be less than 1 mil per year at atemperature of about 840° C.

Heat transfer fluid circulation system 992 may include heat supply 994,first heat exchanger 996, second heat exchanger 998, and compressor1000. Heat supply 994 heats the heat transfer fluid to a hightemperature. Heat supply 994 may be a furnace, solar collector, chemicalreactor, nuclear reactor, fuel cell, and/or other high temperaturesource able to supply heat to the heat transfer fluid. In the embodimentdepicted in FIG. 208, heat supply 994 is a furnace that heats the heattransfer fluid to a temperature in a range from about 700° C. to about920° C., from about 770° C. to about 870° C., or from about 800° C. toabout 850° C. In an embodiment, heat supply 994 heats the heat transferfluid to a temperature of about 820° C. The heat transfer fluid flowsfrom heat supply 994 to heaters 802. Heat transfers from heaters 802 toformation 524 adjacent to the heaters. The temperature of the heattransfer fluid exiting formation 524 may be in a range from about 350°C. to about 580° C., from about 400° C. to about 530° C., or from about450° C. to about 500° C. In an embodiment, the temperature of the heattransfer fluid exiting formation 524 is about 480° C. The metallurgy ofthe piping used to form heat transfer fluid circulation system 992 maybe varied to significantly reduce costs of the piping. High temperaturesteel may be used from heat supply 994 to a point where the temperatureis sufficiently low so that less expensive steel can be used from thatpoint to first heat exchanger 996. Several different steel grades may beused to form the piping of heat transfer fluid circulation system 992.

Heat transfer fluid from heat supply 994 of heat transfer fluidcirculation system 992 passes through overburden 482 of formation 524 tohydrocarbon layer 484. Portions of heaters 802 extending throughoverburden 482 may be insulated. In some embodiments, the insulation orpart of the insulation is a polyimide insulating material. Inletportions of heaters 802 in hydrocarbon layer 484 may have taperinginsulation to reduce overheating of the hydrocarbon layer near the inletof the heater into the hydrocarbon layer.

In some embodiments, the diameter of the pipe in overburden 482 may besmaller than the diameter of pipe through hydrocarbon layer 484. Thesmaller diameter pipe through overburden 482 may allow for less heattransfer to the overburden. Reducing the amount of heat transfer tooverburden 482 reduces the amount of cooling of the heat transfer fluidsupplied to pipe adjacent to hydrocarbon layer 484. The increased heattransfer in the smaller diameter pipe due to increased velocity of heattransfer fluid through the small diameter pipe is offset by the smallersurface area of the smaller diameter pipe and the decrease in residencetime of the heat transfer fluid in the smaller diameter pipe.

After exiting formation 524, the heat transfer fluid passes throughfirst heat exchanger 996 and second heat exchanger 998 to compressor1000. First heat exchanger 996 transfers heat between heat transferfluid exiting formation 524 and heat transfer fluid exiting compressor1000 to raise the temperature of the heat transfer fluid that entersheat supply 994 and reduce the temperature of the fluid exitingformation 524. Second heat exchanger 998 further reduces the temperatureof the heat transfer fluid before the heat transfer fluid enterscompressor 1000.

In some embodiments, a liquid heat transfer fluid may be used instead ofa gas heat transfer fluid. The compressor banks represented bycompressor 1000 in FIG. 208 may be replaced by pumps or other liquidmoving devices.

FIG. 209 depicts a plan view of an embodiment of wellbore openings inthe formation that is to be heated using the circulation system. Heattransfer fluid entries 1002 into formation 524 alternate with heattransfer fluid exits 1004. Alternating heat transfer fluid entries 1002with heat transfer fluid exits 1004 may allow for more uniform heatingof the hydrocarbons in formation 524.

In some embodiments, piping for the circulation system may allow thedirection of heat transfer fluid flow through the formation to bechanged. Changing the direction of heat transfer fluid flow through theformation allows each end of a u-shaped wellbore to initially receivethe heat transfer fluid at the hottest temperature of the heat transferfluid for a period of time, which may result in more uniform heating ofthe formation. The direction of heat transfer fluid may be changed atdesired time intervals. The desired time interval may be about a year,about six months, about three months, about two months or any otherdesired time interval.

In some embodiments, the circulation system may be used in conjunctionwith electrical heating. In some embodiments, at least a portion of thepipe in the U-shaped wellbores adjacent to portions of the formationthat are to be heated is made of a ferromagnetic material. For example,the piping adjacent to a layer or layers of the formation to be heatedis made of 9% to 13% chromium steel, such as 410 stainless steel. Thepipe may be a temperature limited heater when time varying electriccurrent is applied to the piping. The time varying electric current mayresistively heat the piping, which heats the formation and the materialin the piping. In some embodiments, direct electric current may be usedto resistively heat the pipe, which heats the formation. In someembodiments, the material used to form the pipe in the U-shaped wellboredoes not include ferromagnetic material. Direct or time varying currentmay be used to resistively heat the pipe, which heats the formation.

In some embodiments, one or more insulated conductors are placed in thepiping. Electrical current may be supplied to the insulated conductorsto resistively heat at least a portion of the insulated conductors.Heated insulated conductors may provide heat to the contents of thepiping and the piping. The piping heated by the insulated conductor mayheat adjacent formation. FIG. 210 depicts insulated conductor 574positioned in heater 802. Heater 802 is piping of the circulation systempositioned in the formation. In some embodiments, one or more insulatedconductors may be strapped to the piping.

In some embodiments, the circulation system is used to heat theformation to a first temperature, and electrical energy is used tomaintain the temperature of the formation and/or heat the formation tohigher temperatures. The first temperature may be sufficient to vaporizeaqueous formation fluid in the formation. The first temperature may beat most about 200° C., at most about 300° C., at most about 350° C., orat most about 400° C. Using the circulation system to heat the formationto the first temperature allows the formation to be dry when electricityis used to heat the formation. Heating the dry formation may minimizeelectrical current leakage into the formation.

In some embodiments, the circulation system and electrical heating maybe used to heat the formation to a first temperature. The formation maybe maintained, or the temperature of the formation may be increased fromthe first temperature, using the circulation system and/or electricalheating. In some embodiments, the formation may be raised to the firsttemperature using electrical heating, and the temperature may bemaintained and/or increased using the circulation system. Economicfactors, available electricity, availability of fuel for heating theheat transfer fluid, and other factors may be used to determine whenelectrical heating and/or circulation system heating are to be used.

In some embodiments, electrical heating is used to raise the temperatureof the piping to a desired temperature. The desired temperature may be atemperature higher than a temperature needed to maintain the heattransfer fluid (for example, a molten metal or a molten salt) in aliquid phase. The electrical heating may inhibit plugging of the pipingand allow the heat transfer to flow through the piping.

FIG. 208 depicts an embodiment of a circulation system. In certainembodiments, the portion of heater 802 in hydrocarbon layer 484 iscoupled to lead-in conductors. Lead-in conductors may be located inoverburden 482. Lead-in conductors may electrically couple the portionof heater 802 in hydrocarbon layer 484 to one or more wellheads at thesurface. Electrical isolators may be located at a junction of theportion of heater 802 in hydrocarbon layer 484 with portions of heater802 in overburden 482 so that the portions of the heater in theoverburden are electrically isolated from the portion of the heater inthe hydrocarbon layer.

In embodiments where the electrical heating is needed to raise thetemperature of the piping to or above a desired temperature, the lead-inconductors are coupled to the piping at or near the surface so that allof the piping in the formation is heated to the desired temperature.Piping near the surface may include electrical insulation (for example,a porcelain coating).

In some embodiments, the lead-in conductors are placed inside of thepipe of the closed loop circulation system. In some embodiments, thelead-in conductors are positioned outside of the pipe of the closed loopcirculation system. In some embodiments, the lead-in conductors areinsulated conductors with mineral insulation, such as magnesium oxide.The lead-in conductors may include highly electrically conductivematerials such as copper or aluminum to reduce heat losses in overburden482 during electrical heating.

In certain embodiments, the portions of heater 802 in overburden 482 areused as lead-in conductors. The portions of heater 802 in overburden 482may be electrically coupled to the portion of heater 802 in hydrocarbonlayer 484. In some embodiments, one or more electrically conductingmaterials (such as copper or aluminum) are coupled (for example, claddedor welded) to the portions of heater 802 in overburden 482 to reduce theelectrical resistance of the portions of the heater in the overburden.Reducing the electrical resistance of the portions of heater 802 inoverburden 482 reduces heat losses in the overburden during electricalheating.

In some embodiments, the portion of heater 802 in hydrocarbon layer 484is a temperature limited heater with a self-limiting temperature betweenabout 600° C. and about 1000° C. The portion of heater 802 inhydrocarbon layer 484 may be a 9% to 13% chromium stainless steel. Forexample, portion of heater 802 in hydrocarbon layer 484 may be 410stainless steel. Time-varying current may be applied to the portion ofheater 802 in hydrocarbon layer 484 so that the heater operates as atemperature limited heater.

FIG. 211 depicts a side view representation of an embodiment of a systemfor heating a portion of a formation using a circulated fluid systemand/or electrical heating. Wellheads 476 of heaters 802 may be coupledto heat transfer fluid circulation system 992 by piping. Wellheads 476may also be coupled to electrical power supply system 1006. In someembodiments, heat transfer fluid circulation system 992 is disconnectedfrom the heaters when electrical power is used to heat the formation. Insome embodiments, electrical power supply system 1006 is disconnectedfrom the heaters when heat transfer fluid circulation system 992 is usedto heat the formation.

Electrical power supply system 1006 may include transformer 580 andcables 686, 688. In certain embodiments, cables 686, 688 are capable ofcarrying high currents with low losses. For example, cables 686, 688 maybe thick copper or aluminum conductors. The cables may also have thickinsulation layers. In some embodiments, cable 686 and/or cable 688 maybe superconducting cables. The superconducting cables may be cooled byliquid nitrogen. Superconducting cables are available from Superpower,Inc. (Schenectady, N.Y., U.S.A.). Superconducting cables may minimizepower loss and/or reduce the size of the cables needed to coupletransformer 580 to the heaters. In some embodiments, cables 686, 688 maybe made of carbon nanotubes.

In some embodiments, a liquid heat transfer fluid is used to heat thetreatment area. In some embodiments, the liquid heat transfer fluid is amolten salt or a molten metal. The liquid heat transfer fluid may have alow viscosity and a high heat capacity at normal operating conditions.When the liquid heat transfer fluid is a molten salt or other fluid thathas the potential to solidify in the formation, piping of the system maybe electrically coupled to an electricity source to resistively heat thepiping when needed and/or one or more heaters may be positioned in oradjacent to the piping to maintain the heat transfer fluid in a liquidstate. In some embodiments, an insulated conductor heater may be placedin the piping. The insulated conductor may melt solids in the pipe. Theinsulated conductor may be a relatively thin mineral insulated conductorpositioned in a relatively large diameter piping as shown and describedwith respect to FIG. 288.

In an embodiment, molten salt is used as the heat transfer fluid.Insulated return storage tanks receive return molten salt from theformation. Temperatures in the return storage tanks may be in thevicinity of about 350° C. Pumps may move the molten salt to furnaces.Each of the pumps may need to move 6 to 12 kg/sec of the molten salt.Each furnace may provide heat to molten salt. The molten salt may passfrom the piping to insulated feed storage tanks. Exit temperatures ofthe molten salt from the furnaces may be about 550° C. The molten saltmay pass from the furnaces to insulated feed storage tanks. Each feedstorage stank may supply molten salt to 50 or more piping systems thatenter into the formation. The molten salt flows through the formationand back to the storage tanks. The furnaces may have efficiencies thatare 90% or greater. Heat loss to the overburden may be 8% or less.

FIG. 212 depicts a schematic representation of a system for providingand removing liquid heat transfer fluid to the treatment area of aformation using gravity and gas lifting as the driving forces for movingthe liquid heat transfer fluid. The liquid heat transfer fluid may be amolten metal or a molten salt. Vessel 1008 is elevated above heatexchanger 1010. Heat transfer fluid from vessel 1008 flows through heattransfer unit 1010 to the formation by gravity drainage. In anembodiment, heat exchanger 1010 is a tube and shell heat exchanger.Input stream 1012 is a hot fluid (for example, helium) from nuclearreactor 1014. Exit stream fluid 1016 may be sent as a coolant stream tonuclear reactor 1014. In some embodiments, the heat exchanger is afurnace, solar collector, chemical reactor, fuel cell, or other hightemperature source able to supply heat to the liquid heat transferfluid.

Hot heat transfer fluid from heat exchanger 1010 may pass to a manifoldthat provides heat transfer fluid to individual heater legs positionedin the treatment area of the formation. The heat transfer fluid may passto the heater legs by gravity drainage. The heat transfer fluid may passthrough overburden 482 to hydrocarbon containing layer 484 of thetreatment area. The piping adjacent to overburden 482 may be insulated.Heat transfer fluid flows downwards to sump 1018.

Gas lift piping may include gas supply line 1020 within conduit 1022.Gas supply line 1020 may enter sump 1018. When lift chamber 1024 in sump1018 fills to a selected level with heat transfer fluid, a gas liftcontrol system operates valves of the gas lift system so that the heattransfer fluid is lifted through the space between gas supply line 1020and conduit 1022 to separator 1026. Separator 1026 may receive heattransfer fluid and lifting gas from a piping manifold that transportsthe heat transfer fluid and lifting gas from the individual heater legsin the formation. Separator 1026 separates the lift gas from the heattransfer fluid. The heat transfer fluid is sent to vessel 1008.

Conduits 1022 from sumps 1018 to separator 1026 may include one or moreinsulated conductors or other types of heaters. The insulated conductorsor other types of heaters may be placed in conduits 1022 and/or bestrapped or otherwise coupled to the outside of the conduits. Theheaters may inhibit solidification of the heat transfer fluid inconduits 1022 during the gas lift from sump 1018.

Circulation systems may be used to heat portions of the formation.Production wells in the formation are used to remove produced fluids.After production from the formation has ended, the circulation systemmay be used to recover heat from the formation. FIG. 208 depicts anembodiment of a circulation system. Heat transfer fluid may becirculated through heaters 802 after heat supply 994 is disconnectedfrom the circulation system. The heat transfer fluid may be a differentheat transfer fluid than the heat transfer fluid used to heat theformation. Heat transfers from the heated formation to the heat transferfluid. The heat transfer fluid may be used to heat another portion ofthe formation or the heat transfer fluid may be used for other purposes.In some embodiments, water is introduced into heaters 802 to producesteam. In some embodiments, low temperature steam is introduced intoheaters 802 so that the passage of the steam through the heatersincreases the temperature of the steam. Other heat transfer fluidsincluding natural or synthetic oils, such as Syltherm oil (Dow CorningCorporation (Midland, Mich., U.S.A.), may be used instead of steam orwater.

In some embodiments, nuclear energy may be used to heat the heattransfer fluid used in the circulation system to heat a portion of theformation. Heat supply 994 in FIG. 208 may be a pebble bed reactor orother type of nuclear reactor, such as a light water reactor. The use ofnuclear energy provides a heat source with little or no carbon dioxideemissions. Also, the use of nuclear energy can be more efficient becauseenergy losses resulting from the conversion of heat to electricity andelectricity to heat are avoided by directly utilizing the heat producedfrom the nuclear reactions without producing electricity.

In some embodiments, a nuclear reactor may heat helium. For example,helium flows through a pebble bed reactor, and heat transfers to thehelium. The helium may be used as the heat transfer fluid to heat theformation. In some embodiments, the nuclear reactor may heat helium, andthe helium may be passed through a heat exchanger to provide heat to theheat transfer fluid used to heat the formation. The pebble bed reactormay include a pressure vessel that contains encapsulated enricheduranium dioxide fuel. Helium may be used as a heat transfer fluid toremove heat from the pebble bed reactor. Heat may be transferred in aheat exchanger from the helium to the heat transfer fluid used in thecirculation system. The heat transfer fluid used in the circulationsystem may be carbon dioxide, a molten salt, or other fluid. Pebble bedreactor systems are available from PBMR Ltd (Centurion, South Africa).

FIG. 213 depicts a schematic diagram of a system that uses nuclearenergy to heat treatment area 1028. The system may include helium systemgas blower 1030, nuclear reactor 1032, heat exchanger units 1034, andheat transfer fluid blower 1036. Helium system gas blower 1030 may drawheated helium from nuclear reactor 1032 to heat exchanger units 1034.Helium from heat exchanger units 1034 may pass through helium system gasblower 1030 to nuclear reactor 1032. Helium from nuclear reactor 1032may be at a temperature of about 900° C. to about 1000° C. Helium fromhelium gas blower 1030 may be at a temperature of about 500° C. to about600° C. Heat transfer fluid blower 1036 may draw heat transfer fluidfrom heat exchanger units 1034 through treatment area 1028. Heattransfer fluid may pass through heat transfer fluid blower 1036 to heatexchanger units 1034. The heat transfer fluid may be carbon dioxide. Theheat transfer fluid may be at a temperature from about 850° C. to about950° C. after exiting heat exchanger units 1034.

In some embodiments, the system may include auxiliary power unit 1038.In some embodiments, auxiliary power unit 1038 generates power bypassing the helium from heat exchanger units 1034 through a generator tomake electricity. The helium may be sent to one or more compressorsand/or heat exchangers to adjust the pressure and temperature of thehelium before the helium is sent to nuclear reactor 1032. In someembodiments, auxiliary power unit 1038 generates power using a heattransfer fluid (for example, ammonia or aqua ammonia). Helium from heatexchanger units 1034 is sent to additional heat exchanger units totransfer heat to the heat transfer fluid. The heat transfer fluid istaken through a power cycle (such as a Kalina cycle) to generateelectricity. In an embodiment, nuclear reactor 1032 is a 400 MW reactorand auxiliary power unit 1038 generates about 30 MW of electricity.

FIG. 214 depicts a schematic elevational view of an arrangement for anin situ heat treatment process. U-shaped wellbores may be formed in theformation to define treatment areas 1028A, 1028B, 1028C, 1028D.Additional treatment areas could be formed to the sides of the showntreatment areas. Treatment areas 1028A, 1028B, 1028C, 1028D may havewidths of over 300 m, 500 m, 1000 m, or 1500 m. Well exits and entrancesfor the wellbores may be formed in well openings area 1040. Rail lines1042 may be formed along sides of treatment areas 1028. Warehouses,administration offices and/or spent fuel storage facilities may belocated near ends of rail lines 1042. Facilities 1044 may be formed atintervals along spurs of rail lines 1042. Each facility 1044 may includea nuclear reactor, compressors, heat exchanger units and other equipmentneeded for circulating hot heat transfer fluid to the wellbores.Facilities 1044 may also include surface facilities for treatingformation fluid produced from the formation. In some embodiments, heattransfer fluid produced in facility 1044′ may be reheated by the reactorin facility 1044″ after passing through treatment area 1028A. In someembodiments, each facility 1044 is used to provide hot treatment fluidto wells in one half of the treatment area 1028 adjacent to thefacility. Facilities 1044 may be moved by rail to another facility siteafter production from a treatment area is completed.

In some in situ heat treatment embodiments, compressors providecompressed gases to the treatment area. For example, compressors may beused to provide oxidizing fluid 806 and/or fuel 810 to a plurality ofoxidizer assemblies like oxidizer assembly 612 depicted in FIG. 174.Each oxidizer assembly 612 may include a number of oxidizers 614.Oxidizers 614 may burn a mixture of oxidizing fluid 806 and fuel 810 toproduce heat that heats the treatment area in the formation. Also,compressors 1000 may be used to supply gas phase heat transfer fluid tothe formation as depicted in FIG. 208. In some embodiments, pumpsprovide liquid phase heat transfer fluid to the treatment area.

A significant cost of the in situ heat treatment process may beoperating the compressors and/or pumps over the life of the in situ heattreatment process if conventional electrical energy sources are used topower the compressors and/or pumps of the in situ heat treatmentprocess. In some embodiments, nuclear power may be used to generateelectricity that operates the compressors and/or pumps needed for the insitu heat treatment process. The nuclear power may be supplied by one ormore nuclear reactors. The nuclear reactors may be light water reactors,pebble bed reactors, and/or other types of nuclear reactors. The nuclearreactors may be located at or near to the in situ heat treatment processsite. Locating the nuclear reactors at or near to the in situ heattreatment process site may reduce equipment costs and electricaltransmission losses over long distances. The use of nuclear power mayreduce or eliminate the amount of carbon dioxide generation associatedwith operating the compressors and/or pumps over the life of the in situheat treatment process.

Excess electricity generated by the nuclear reactors may be used forother in situ heat treatment process needs. For example, excesselectricity may be used to cool fluid for forming a low temperaturebarrier (frozen barrier) around treatment areas, and/or for providingelectricity to treatment facilities located at or near the in situ heattreatment process site. In some embodiments, the electricity or excesselectricity produced by the nuclear reactors may be used to resistivelyheat the conduits used to circulate heat transfer fluid through thetreatment area.

In some embodiments, excess heat available from the nuclear reactors maybe used for other in situ processes. For example, excess heat may beused to heat water or make steam that is used in solution miningprocesses. In some embodiments, excess heat from the nuclear reactorsmay be used to heat fluids used in the treatment facilities located nearor at the in situ heat treatment site.

In some embodiments, geothermal energy may be used to heat or preheat atreatment area of an in situ heat treatment process or a treatment areato be solution mined. Geothermal energy may have little or no carbondioxide emissions. In some embodiments, geothermally heated fluid may beproduced from a layer or layers located below or near the treatmentarea. The geothermally heated fluid includes, but is not limited to,steam, water, and/or brine. One or more of the layers may begeothermally pressurized geysers. Geothermally heated fluid may bepumped from one or more of the layers. The layer or layers may be atleast 2 km, at least 4 km, at least 8 km or more below the surface. Thegeothermally heated fluid may be at a temperature of at least 100° C.,at least 200° C., or at least 300° C.

The geothermally heated fluid may be produced and circulated throughpiping in the treatment area to raise the temperature of the treatmentarea. In some embodiments, the geothermally heated fluid is introduceddirectly into the treatment area. In some embodiments, the geothermallyheated fluid is circulated through the treatment area or piping in thetreatment area without being produced to the surface and re-introducedinto the treatment area. In some embodiments, the geothermally heatedfluid may be produced from a location near the treatment area. Thegeothermally heated fluid may be transported to the treatment area. Oncetransported to the treatment area, the geothermally heated fluid iscirculated through piping in the treatment area and/or the geothermallyheated fluid is introduced directly into the treatment area.

In some embodiments, geothermally heated fluid produced from a layer orlayers is used to solution mine minerals from the formation. Thegeothermally heated fluid may be used to raise the temperature of theformation to a temperature below the dissociation temperature of theminerals, but to a temperature high enough to increase the amount ofmineral going into solution in a first fluid introduced into theformation. The geothermally heated fluid may be introduced directly intothe formation as all or a portion of the first fluid, and/or thegeothermally heated fluid may be circulated through piping in theformation.

In some embodiments, geothermally heated fluid produced from a layer orlayers may be used to heat the treatment area before using electricalheaters, gas burners, or other types of heat sources to heat thetreatment area to pyrolysis temperatures. The geothermally heated fluidmay not be at a temperature sufficient to raise the temperature of thetreatment area to pyrolysis temperatures. Using the geothermally heatedfluid to heat the treatment area before using electrical heaters orother heat sources to heat the treatment area to pyrolysis temperaturesmay reduce energy costs for the in situ heat treatment process.

In some embodiments, hot dry rock technology may be used to producesteam or other hot heat transfer fluid from a deep portion of theformation. Injection wells may be drilled to a depth where the formationis hot. The injection wells may be at least 2 km, at least 4 km, or atleast 8 km deep. Sections of the formation adjacent to the bottomportions of the injection wells may be hydraulically, or otherwisefractured, to provide large contact area with the formation and/or toprovide flow paths to heated fluid production wells. Water, steam and/orother heat transfer fluid (for example, a synthetic oil or a naturaloil) may be introduced into the formation through the injection wells.Heat transfers to the introduced fluid from the formation. Steam and/orhot heat transfer fluid may be produced from the heated fluid productionwells. In some embodiments, the steam and/or hot heat transfer fluid isdirected into the treatment area from the production wells without firstproducing the steam and/or hot heat transfer fluid to the surface. Thesteam and/or hot heat transfer fluid may be used to heat a portion of ahydrocarbon containing formation above the deep hot portion of theformation.

In some embodiments, steam produced from heated fluid production wellsmay be used as the steam for a drive process (for example, a steam floodprocess or a steam assisted gravity drainage process). In someembodiments, steam or other hot heat transfer fluid produced throughheated fluid production wells is passed through U-shaped wellbores orother types of wellbores to provide initial heating to the formation. Insome embodiments, cooled steam or water, or cooled heat transfer fluid,resulting from the use of the steam and/or heat transfer fluid from thehot portion of the formation may be collected and sent to the hotportion of the formation to be reheated.

In certain embodiments, a controlled or staged in situ heating andproduction process is used to in situ heat treat a hydrocarboncontaining formation (for example, an oil shale formation). The stagedin situ heating and production process may use less energy input toproduce hydrocarbons from the formation than a continuous or batch insitu heat treatment process. In some embodiments, the staged in situheating and production process is about 30% more efficient in treatingthe formation than the continuous or batch in situ heat treatmentprocess. The staged in situ heating and production process may alsoproduce less carbon dioxide emissions than a continuous or batch in situheat treatment process. In certain embodiments, the staged in situheating and production process is used to treat rich layers in the oilshale formation. Treating only the rich layers may be more economicalthan treating both rich layers and lean layers because heat may bewasted heating the lean layers.

FIG. 215 depicts a top view representation of an embodiment for thestaged in situ heating and producing process for treating the formation.In certain embodiments, heaters 438 are arranged in triangular patterns.In other embodiments, heaters 438 are arranged in any other regular orirregular patterns. The heater patterns may be divided into one or moresections 1046, 1048, 1050, 1052, and/or 1054. The number of heaters 438in each section may vary depending on, for example, properties of theformation or a desired heating rate for the formation. One or moreproduction wells 206 may be located in each section 1046, 1048, 1050,1052, and/or 1054. In certain embodiments, production wells 206 arelocated at or near the centers of the sections. In some embodiments,production wells 206 are in other portions of sections 1046, 1048, 1050,1052, and 1054. Production wells 206 may be located at other locationsin sections 1046, 1048, 1050, 1052, and/or 1054 depending on, forexample, a desired quality of products produced from the sections and/ora desired production rate from the formation.

In certain embodiments, heaters 438 in one of the sections are turned onwhile the heaters in other sections remain turned off. For example,heaters 438 in section 1046 may be turned on while the heaters in theother sections are left turned off. Heat from heaters 438 in section1046 may create permeability, mobilize fluids, and/or pyrolysis fluidsin section 1046. While heat is being provided by heaters 438 in section1046, production well 206 in section 1048 may be opened to producefluids from the formation. Some heat from heaters 438 in section 1046may transfer to section 1048 and “pre-heat” section 1048. Thepre-heating of section 1048 may create permeability in section 1048,mobilize fluids in section 1048, and allow fluids to be produced fromthe section through production well 206.

In certain embodiments, a portion of section 1048 proximate productionwell 206, however, is not heated by conductive heating from heaters 438in section 1046. For example, the superposition of heat from heaters 438in section 1046 does not overlap the portion proximate production well206 in section 1048. The portion proximate production well 206 insection 1048 may be heated by fluids (such as hydrocarbons) flowing tothe production well (for example, by convective heat transfer from thefluids).

As fluids are produced from section 1048, the movement of fluids fromsection 1046 to section 1048 transfers heat between the sections. Themovement of the hot fluids through the formation increases heat transferwithin the formation. Allowing hot fluids to flow between the sectionsuses the energy of the hot fluids for heating of unheated sectionsrather than removing the heat from the formation by producing the hotfluids directly from section 1046. Thus, the movement of the hot fluidsallows for less energy input to get production from the formation thanis required if heat is provided from heaters 438 in both sections to getproduction from the sections.

In certain embodiments, the temperature of the portion proximateproduction well 206 in section 1048 is controlled so that thetemperature in the portion is at most a selected temperature. Forexample, the temperature in the portion proximate the production wellmay be controlled so that the temperature is at most about 100° C., atmost about 200° C., or at most about 250° C. In some embodiments, thetemperature of the portion proximate production well 206 in section 1048is controlled by controlling the production rate of fluids through theproduction well. In some embodiments, producing more fluids increasesheat transfer to the production well and the temperature in the portionproximate the production well.

In some embodiments, production through production well 206 in section1048 is reduced or turned off after the portion proximate the productionwell reaches the selected temperature. Reducing or turning offproduction through the production well at higher temperatures keepsheated fluids in the formation. Keeping the heated fluids in theformation keeps energy in the formation and reduces the energy inputneeded to heat the formation. The selected temperature at whichproduction is reduced or turned off may be, for example, about 100° C.,about 200° C., or about 250° C.

In some embodiments, section 1046 and/or section 1048 may be treatedprior to turning on heaters 438 to increase the permeability in thesections. For example, the sections may be dewatered to increase thepermeability in the sections. In some embodiments, steam injection orother fluid injection may be used to increase the permeability in thesections.

In certain embodiments, after a selected time, heaters 438 in section1048 are turned on. Turning on heaters 438 in section 1048 may provideadditional heat to sections 1046, 1048 and 1050 to increase thepermeability, mobility, and/or pyrolysis of fluids in these sections. Insome embodiments, as heaters 438 in section 1048 are turned on,production in section 1048 is reduced or turned off (shut down) andproduction wells 206 in section 1050 are opened to produce fluids fromthe formation. Thus, fluid flows in the formation towards productionwells 206 in section 1050, and section 1050 is heated by the flow of hotfluids as described above for section 1048. In some embodiments,production wells 206 in section 1048 may be left open after the heatersare turned on in the section, if desired. In some embodiments,production in section 1048 is reduced or turned off at the selectedtemperature, as described above.

The process of reducing or turning off heaters and shifting productionto adjacent sections may be repeated for subsequent sections in theformation. For example, after a selected time, heaters in section 1050may be turned on and fluids are produced from production wells 206 insection 1052 and so on through the formation.

In some embodiments, heat is provided by heaters 438 in alternatingsections (for example, sections 1046, 1050, and 1054) while fluids areproduced from the sections in between the heated sections (for example,sections 1048 and 1052). After a selected time, heaters 438 in theunheated sections (sections 1048 and 1052) are turned on and fluids areproduced from one or more of the sections as desired.

In certain embodiments, a smaller heater spacing is used in the stagedin situ heating and producing process than in the continuous or batch insitu heat treatment processes. For example, the continuous or batch insitu heat treatment process may use a heater spacing of about 12 m whilethe in situ staged heating and producing process uses a heater spacingof about 10 m. The staged in situ heating and producing process may usethe smaller heater spacing because the staged process allows forrelatively rapid heating of the formation and expansion of theformation.

In some embodiments, the sequence of heated sections begins with theoutermost sections and moves inwards. For example, for a selected time,heat may be provided by heaters 438 in sections 1046 and 1054 as fluidsare produced from sections 1048 and 1052. After the selected time,heaters 438 in sections 1048 and 1052 may be turned on and fluids areproduced from section 1050. After another selected amount of time,heaters 438 in section 1050 may be turned on, if needed.

In certain embodiments, sections 1046-1054 are substantially equal sizedsections. The size and/or location of sections 1046-1054 may vary basedon desired heating and/or production from the formation. For example,simulation of the staged in situ heating and production processtreatment of the formation may be used to determine the number ofheaters in each section, the optimum pattern of sections and/or thesequence for heater power up and production well startup for the stagedin situ heating and production process. The simulation may account forproperties such as, but not limited to, formation properties and desiredproperties and/or quality in the produced fluids. In some embodiments,heaters 438 at the edges of the treated portions of the formation (forexample, heaters 438 at the left edge of section 1046 or the right edgeof section 1054) may have tailored or adjusted heat outputs to producedesired heat treatment of the formation.

In some embodiments, the formation is sectioned into a checkerboardpattern for the staged in situ heating and production process. FIG. 216depicts a top view of rectangular checkerboard pattern 1056 for thestaged in situ heating and production process. In some embodiments,heaters in the “A” sections (sections 1046A, 1048A, 1050A, 1052A, and1054A) may be turned on and fluids are produced from the “B” sections(sections 1046B, 1048B, 1050B, 1052B, and 1054B). After the selectedtime, heaters in the “B” sections may be turned on. The size and/ornumber of “A” and “B” sections in rectangular checkerboard pattern 1056may be varied depending on factors such as, but not limited to, heaterspacing, desired heating rate of the formation, desired production rate,size of treatment area, subsurface geomechanical properties, subsurfacecomposition, and/or other formation properties.

In some embodiments, heaters in sections 1046A are turned on and fluidsare produced from sections 1046B and/or sections 1048B. After theselected time, heaters in sections 1048A may be turned on and fluids areproduced from sections 1048B and/or 1050B. After another selected time,heaters in sections 1050A may be turned on and fluids are produced fromsections 1050B and/or 1052B. After another selected time, heaters insections 1052A may be turned on and fluids are produced from sections1052B and/or 1054B. In some embodiments, heaters in a “B” section thathas been produced from may be turned on when heaters in the subsequent“A” section are turned on. For example, heaters in section 1046B may beturned on when the heaters in section 1048A are turned on. Otheralternating heater startup and production sequences may also becontemplated for the in situ staged heating and production processembodiment depicted in FIG. 216.

In some embodiments, the formation is divided into a circular, ring, orspiral pattern for the staged in situ heating and production process.FIG. 217 depicts a top view of the ring pattern embodiment for thestaged in situ heating and production process. Sections 1046, 1048,1050, 1052, and 1054 may be treated with heater startup and productionsequences similar to the sequences described above for the embodimentsdepicted in FIGS. 215 and 216. The heater startup and productionsequences for the embodiment depicted in FIG. 217 may start with section1046 (going inwards towards the center) or with section 1054 (goingoutwards from the center). Starting with section 1046 may allowexpansion of the formation as heating moves towards the center of thering pattern. Shearing of the formation may be minimized or inhibitedbecause the formation is allowed to expand into heated and/or pyrolyzedportions of the formation. In some embodiments, the center section(section 1054) is cooled after treatment.

FIG. 218 depicts a top view of a checkerboard ring pattern embodimentfor the staged in situ heating and production process. The embodimentdepicted in FIG. 218 divides the ring pattern embodiment depicted inFIG. 217 into a checkerboard pattern similar to the checkerboard patterndepicted in FIG. 216. Sections 1046A, 1048A, 1050A, 1052A, 1054A, 1046B,1048B, 1050B, 1052B, and 1054B, depicted in FIG. 218, may be treatedwith heater startup and production sequences similar to the sequencesdescribed above for the embodiment depicted in FIG. 216.

In some embodiments, fluids are injected to drive fluids betweensections of the formation. Injecting fluids such as steam or carbondioxide may increase the mobility of hydrocarbons and may increase theefficiency of the staged in situ heating and production process. In someembodiments, fluids are injected into the formation after the in situheat treatment process to recover heat from the formation. In someembodiments, the fluids injected into the formation for heat recoveryinclude some fluids produced from the formation (for example, carbondioxide, water, and/or hydrocarbons produced from the formation). Theembodiments depicted in FIGS. 215-218 may be used for in situ solutionmining of the formation. Hot water or another fluid may be used to getpermeability in the formation at low temperatures for solution mining.

In certain embodiments, several rectangular checkerboard patterns (forexample, rectangular checkerboard pattern 1056 depicted in FIG. 216) areused to treat a treatment area of the formation. FIG. 219 depicts a topview of a plurality of rectangular checkerboard patterns 1056(1-36) intreatment area 1028 for the staged in situ heating and productionprocess. Treatment area 1028 may be enclosed by barrier 1058. Each ofrectangular checkerboard patterns 1056(1-36) may individually be treatedaccording to embodiments described above for the rectangularcheckerboard patterns.

In certain embodiments, the startup of treatment of rectangularcheckerboard patterns 1056(1-36) proceeds in a sequential process. Thesequential process may include starting the treatment of each of therectangular checkerboard patterns one by one sequentially. For example,treatment of a second rectangular checkerboard pattern (for example, theonset of heating of the second rectangular checkerboard pattern) may bestarted after treatment of a first rectangular checkerboard pattern andso on. The startup of treatment of the second rectangular checkerboardpattern may be at any point in time after the treatment of the firstrectangular checkerboard pattern has begun. The time selected forstartup of treatment of the second rectangular checkerboard pattern maybe varied depending on factors such as, but not limited to, desiredheating rate of the formation, desired production rate, subsurfacegeomechanical properties, subsurface composition, and/or other formationproperties. In some embodiments, the startup of treatment of the secondrectangular checkerboard pattern begins after a selected amount offluids have been produced from the first rectangular checkerboardpattern area or after the production rate from the first rectangularcheckerboard pattern increases above a selected value or falls below aselected value.

In some embodiments, the startup sequence for rectangular checkerboardpatterns 1056(1-36) is arranged to minimize or inhibit expansionstresses in the formation. In an embodiment, the startup sequence of therectangular checkerboard patterns proceeds in an outward spiralsequence, as shown by the arrows in FIG. 219. The outward spiralsequence proceeds sequentially beginning with treatment of rectangularcheckerboard pattern 1056-1, followed by treatment of rectangularcheckerboard pattern 1056-2, rectangular checkerboard pattern 1056-3,rectangular checkerboard pattern 1056-4, and continuing the sequence upto rectangular checkerboard pattern 1056-36. Sequentially starting therectangular checkerboard patterns in the outwards spiral sequence mayminimize or inhibit expansion stresses in the formation.

Starting treatment in rectangular checkerboard patterns at or near thecenter of treatment area 1028 and moving outwards maximizes the startingdistance from barrier 1058. Barrier 1058 may be most likely to fail whenheat is provided at or near the barrier. Starting treatment/heating ator near the center of treatment area 1028 delays heating of rectangularcheckerboard patterns near barrier 1058 until later times of heating intreatment area 1028 or at or near the end of production from thetreatment area. Thus, if barrier 1058 does fail, the failure of thebarrier occurs after a significant portion of treatment area 1028 hasbeen treated.

Starting treatment in rectangular checkerboard patterns at or near thecenter of treatment area 1028 and moving outwards also creates open porespace in the inner portions of the outward moving startup pattern. Theopen pore space allows portions of the formation being started at latertimes to expand inwards into the open pore space and, for example,minimize shearing in the formation.

In some embodiments, support sections are left between one or morerectangular checkerboard patterns 1056(1-36). The support sections maybe unheated sections that provide support against geomechanicalshifting, shearing, and/or expansion stress in the formation. In someembodiments, some heat may be provided in the support sections. The heatprovided in the support sections may be less than heat provided insiderectangular checkerboard patterns 1056(1-36). In some embodiments, eachof the support sections may include alternating heated and unheatedsections. In some embodiments, fluids are produced from one or more ofthe unheated support sections.

In some embodiments, one or more of rectangular checkerboard patterns1056(1-36) have varying sizes. For example, the outer rectangularcheckerboard patterns (such as rectangular checkerboard patterns1056(21-26) and rectangular checkerboard patterns 1056(31-36)) may havesmaller areas and/or numbers of checkerboards. Reducing the area and/orthe number of checkerboards in the outer rectangular checkerboardpatterns may reduce expansion stresses and/or geomechanical shifting inthe outer portions of treatment area 1028. Reducing the expansionstresses and/or geomechanical shifting in the outer portions oftreatment area 1028 may minimize or inhibit expansion stress and/orshifting stress on barrier 1058.

In certain embodiments, heater spacing decreases as the heater patternmoves away from the production well. Thus, the density of heater wellsincreases as the heaters get further away from the production well. FIG.220 depicts an embodiment with increasing heater density moving awayfrom production well 206. Heaters 438 may be arranged in a geometric(for example, irregular hexagonal) pattern as shown in FIG. 220. It isto be understood that the heaters may be in any regular or irregulargeometric pattern. In FIG. 220, rows A, B, C, and D include heaters 438(represented by solid squares) arranged in an irregular geometricpattern around production well 206. In some embodiments, the number(density) of heaters in a row increases as the distance of the heatersfrom production well 206 increases (for example, the density of heatersincreases as the heaters are further away from the production well).

Decreasing the density of heaters 438 closer to production well 206provides less heating at or near the production well. Less heating at ornear the production well keeps lower temperatures in the production wellso that less energy is removed from the formation through producedfluids and more energy is kept in the formation to heat the formation.Thus, such a pattern of heaters increases waste energy recovery from theformation. Increasing waste energy recovery in the formation increasesenergy efficiency in treating the formation. For example, treating aformation using the irregular hexagonal pattern depicted in FIG. 220 maydecrease the energy required for heating by about 17% versus treatingthe formation with a regular triangular pattern of heaters.

In some embodiments, heaters 438 are turned on in a sequence fromoutside in towards production well 206. As depicted in FIG. 220, heaters438 in row D may be turned on first, followed by heaters 438 in row C,then heaters 438 in row B, and lastly heaters 438 in row A. Such aheater startup sequence may treat the formation similarly to the stagedheating method between sections described herein with one or more of theoutside heaters being spaced so that heat from the heaters does notsuperposition or conductively heat the production well and heat isprimarily transferred through convection of fluids to the productionwell. For example, heaters 438 in rows A-D may be considered to be in afirst section of the formation and production well 206 is in a secondsection adjacent to the first section. In certain embodiments, theformation has sufficient permeability to allow fluids to flow toproduction well 206.

In some embodiments, the temperature at or near production well 206 iscontrolled so that the temperature is at most a selected temperature.For example, the temperature at or near the production well may becontrolled so that the temperature is at most about 100° C., at mostabout 150° C., at most about 200° C., or at most about 250° C. Incertain embodiments, the temperature at or near production well 206 iscontrolled by reducing or turning off the heat provided by heaters 438nearest the production well (for example, the heaters in row A). In someembodiments, the temperature at or near production well 206 iscontrolled by controlling the production rate of fluids through theproduction well.

In certain embodiments, a solvation fluid and/or pressurizing fluid areused to treat the hydrocarbon formation in addition to the in situ heattreatment process. In some embodiments, a solvation fluid and/orpressurizing fluid is used after the hydrocarbon formation has beentreated using a drive process.

In some embodiments, heaters are used to heat a first section theformation. For example, heaters may be used to heat a first section offormation to pyrolysis temperatures to produce formation fluids. In someembodiments, heaters are used to heat a first section of the formationto temperatures below pyrolysis temperatures to visbreak and/or mobilizefluids in the formation. In other embodiments, a first section of aformation is heated by heaters prior to, during, or after a driveprocess is used to produce formation fluids.

Residual heat from first section may transfer to portions of theformation above, below, and/or adjacent to the first section. Thetransferred residual heat, however, may not be sufficient to mobilizethe fluids in the other portions of the formation towards productionwells so that recovery of the fluids from the colder sections fluids maybe difficult. Addition of a fluid (for example, a solvation fluid and/ora pressurizing fluid) may solubilize and/or drive the hydrocarbons inthe sections of the formation heated by residual heat towards productionwells. Addition of a solvating and/or pressurizing fluid to portions ofthe formation heated by residual heat may facilitate recovery ofhydrocarbons without requiring heaters to heat the additional sections.Addition of the fluid may allow for the recovery of hydrocarbons inpreviously produced sections and/or for the recovery of viscoushydrocarbons in colder sections of the formation.

In some embodiments, the formation is treated using the in situ heattreatment process for a significant time after the formation has beentreated with a drive process. For example, the in situ heat treatmentprocess is used 1 year, 2 years, 3 years, or longer after a formationhas been treated using drive processes. After heating the formation fora significant amount of time using heaters and/or injected fluid (forexample, steam), a solvation fluid may be added to the heated sectionand/or portions above and/or below the heated section. The in situ heattreatment process followed by addition of a solvation fluid and/or apressurizing fluid may be used on formations that have been left dormantafter the drive process treatment because further hydrocarbon productionusing the drive process is not possible and/or not economicallyfeasible. In some embodiments, the solvation fluid and/or thepressurizing fluid is used to increase the amount of heat provided tothe formation. In some embodiments, an in situ heat treatment processmay be used following addition of the solvation fluid and/orpressurizing fluid to increase the recovery of hydrocarbons from theformation.

In some embodiments, the solvation fluid forms an in situ solvationfluid mixture. Using the in situ solvation fluid may upgrade thehydrocarbons in the formation. The in situ solvation fluid may enhancesolubilization of hydrocarbons and/or and facilitate moving thehydrocarbons from one portion of the formation to another portion of theformation.

FIGS. 221 and 222 depict side view representations of embodiments forproducing a fluid mixture from the hydrocarbon formation. In FIGS. 221and 222, heaters 438 have substantially horizontal heating sectionsbelow overburden 482 in hydrocarbon layer 484 (as shown, the heatershave heating sections that go into and out of the page). Heaters 438provide heat to first section 1060 of hydrocarbon layer 484. Patterns ofheaters, such as triangles, squares, rectangles, hexagons, and/oroctagons may be used within first section 1060. First section 1060 maybe heated at least to temperatures sufficient to mobilize somehydrocarbons within the first section. A temperature of the heated firstsection 1060 may range from about 200° C. to about 240° C. In someembodiments, temperature within first section 1060 may be increased to apyrolyzation temperature (for example between 250° C. and 400° C.).

In certain embodiments, the bottommost heaters are located between about2 m and about 10 m from the bottom of hydrocarbon layer 484, betweenabout 4 m and about 8 m from the bottom of the hydrocarbon layer, orbetween about 5 m and about 7 m from the bottom of the hydrocarbonlayer. In certain embodiments, production wells 206A are located at adistance from the bottommost heaters 438 that allows heat from theheaters to superimpose over the production wells, but at a distance fromthe heaters that inhibits coking at the production wells. Productionwells 206A may be located a distance from the nearest heater (forexample, the bottommost heater) of at most ¾ of the spacing betweenheaters in the pattern of heaters (for example, the triangular patternof heaters depicted in FIGS. 221 and 222). In some embodiments,production wells 206A are located a distance from the nearest heater ofat most %, at most ½, or at most ⅓ of the spacing between heaters in thepattern of heaters. In certain embodiments, production wells 206A arelocated between about 2 m and about 10 m from the bottommost heaters,between about 4 m and about 8 m from the bottommost heaters, or betweenabout 5 m and about 7 m from the bottommost heaters. Production wells206A may be located between about 0.5 m and about 8 m from the bottom ofhydrocarbon layer 484, between about 1 m and about 5 m from the bottomof the hydrocarbon layer, or between about 2 m and about 4 m from thebottom of the hydrocarbon layer.

In some embodiments, formation fluid is produced from first section1060. The formation fluid may be produced through production wells 206A.In some embodiments, the formation fluids drain by gravity to a bottomportion of the layer. The drained fluids may be produced from productionwells 206A positioned at the bottom portion of the layer. Production ofthe formation fluids may continue until a majority of condensablehydrocarbons in the formation fluid are produced. After the majority ofthe condensable hydrocarbons have been produced, first section 1060 heatfrom heaters 438 may be reduced and/or discontinued to allow a reductionin temperature in the first section. In some embodiments, after themajority of the condensable hydrocarbons have been produced, a pressureof first section 1060 may be reduced to a selected pressure after thefirst section reaches the selected temperature. Selected pressures mayrange between about 100 kPa and about 1000 kPa, between 200 kPa and 800kPa, or below a fracture pressure of the formation.

In some embodiments, the formation fluid produced from production wells206 includes at least some pyrolyzed hydrocarbons. Some hydrocarbons maybe pyrolyzed in portions of first section 1060 that are at highertemperatures than a remainder of the first section. For example,portions of formation adjacent to heaters 438 may be at somewhat highertemperatures than the remainder of first section 1060. The highertemperature of the formation adjacent to heaters 438 may be sufficientto cause pyrolysis of hydrocarbons. Some of the pyrolysis product may beproduced through production wells 206.

One or more sections (for example, second section 1062 and/or thirdsection 1064) may be above and/or below first section 1060 (as depictedin FIG. 221). FIG. 222 depicts second section 1062 and/or third section1064 adjacent to first section 1060. In some embodiments, second sectionsecond section 1062 and third section 1064 are outside a perimeterdefined by the outermost heaters. Some residual heat from first section1060 may transfer to second section 1062 and third section 1064. In someembodiments, sufficient residual heat is transferred to heat formationfluids to a temperature that allows the fluids to move or substantiallymove in second section 1062 and/or third section 1064 towardsproductions wells 206. Utilization of residual heat from first section1060 to heat hydrocarbons in second section 1062 and/or third section1064 may allow the hydrocarbons to be produced from the second sectionand/or third section without direct heating of the sections. A minimalamount of residual heat to second section 1062 and/or third section 1064may be superposition heat from heaters 438. Areas of second section 1062and/or third section 1064 that are at a distance greater than thespacing between heaters 438 may be heated by residual heat from firstsection 1060. Second section 1062 and/or third section 1064 may beheated by conductive and/or convective heat from first section 1060. Atemperature of the sections heated by residual heat may range from 100°C. to 250° C., from 150° C. to 225° C., or from 175° C. to 200° C.depending on the proximity of heaters 438 to second section 1062 and/orthird section 1064.

In some embodiments, a salvation fluid is provided to first section 1060through injection wells 788A to solvate hydrocarbons within the firstsection. In some embodiments, solvation fluid is added to first section1060 after a majority of the condensable hydrocarbons have been producedand the first section has cooled. The salvation fluid may solvate and/ordilute the hydrocarbons in first section 1060 to form a mixture ofcondensable hydrocarbons and solvation fluids. Formation of the mixturemay increase production of hydrocarbons remaining in the first section.Solubilization of hydrocarbons in first section 1060 may allow thehydrocarbons to be produced from the first section after heat has beenremoved from the section. The mixture may be produced through productionwells 206A.

In some embodiments, a solvation fluid is provided to second section1062 and/or third section 1064 through injection wells 788B, 788C toincrease mobilization of hydrocarbons within the second section and/orthe third section. The solvation fluid may increase a flow of mobilizedhydrocarbons into first section 1060. For example, a pressure gradientmay be produced between second section 1062 and/or 1064 and firstsection 1060 such that the flow of fluids from the second section and/orthird section to the first section is increased. The solvation fluid maysolubilize a portion of the hydrocarbons in second section 1062 and/orthird section 1064 to form a mixture. Solubilization of hydrocarbons insecond section 1062 and/or third section 1064 may allow the hydrocarbonsto be produced from the second section and/or third section withoutdirect heating of the sections. In some embodiments, second section 1062and/or third section 1064 have been heated from residual heattransferred from first section 1060 prior to addition of the solvationfluid. In some embodiments, the solvation fluid is added after secondsection 1062 and/or third section 1064 have been heated to a desiredtemperature by heat from first section 1060. In some embodiments, heatfrom first section 1060 and/or heat from the solvation fluid heatssection 1062 and/or third section 1064 to temperatures sufficient tomobilize heavy hydrocarbons in the sections. In some embodiments,section 1062 and/or third section 1064 are heated to temperaturesranging from 50° C. to 250° C. In some embodiments, temperatures insection 1062 and/or third section 1064 are sufficient to mobilize heavyhydrocarbons, thus the solvation fluid may mobilize the heavyhydrocarbons by displacing the heavy hydrocarbons with minimal mixing.

In some embodiments, water and/or emulsified water may be used as asolvation fluid. Water may be injected into a portion of first section1060, second section 1062 and/or third section 1064 through injectionwells 788. Addition of water to at least a selected section of firstsection 1060, second section 1062 and/or third section 1064 may watersaturate a portion of the sections. The water saturated portions of theselected section may be pressurized by known methods and awater/hydrocarbon mixture may be collected using one or more productionwells 206.

In certain embodiments, first section 1060, second section 1062 and/orthird section 1064 may be treated with hydrocarbons (for example,naphtha, kerosene, diesel, vacuum gas oil, or a mixture thereof). Insome embodiments, the hydrocarbons have an aromatic content of at least1% by weight, at least 5% by weight, at least 10% by weight, at least20% by weight or at least 25% by weight. Hydrocarbons may be injectedinto a portion of first section 1060, second section 1062 and/or thirdsection 1064 through injection wells 788. In some embodiments, thehydrocarbons are produced from first section 1060 and/or other portionsof the formation. In certain embodiments, the hydrocarbons are producedfrom the formation, treated to remove heavy fractions of hydrocarbons(for example, asphaltenes, hydrocarbons having a boiling point of atleast 300° C., of at least 400° C., at least 500° C., or at least 600°C.) and the hydrocarbons are re-introduced into the formation. In someembodiments, one section may be treated with hydrocarbons while anothersection is treated with water. In some embodiments, water treatment of asection may be alternated with hydrocarbon treatment of the section. Insome embodiments, a first portion of hydrocarbons having a relativelyhigh boiling range distribution (for example, kerosene and/or diesel)are introduced in one section. A second portion of hydrocarbons having arelatively low boiling range distribution or hydrocarbons of loweconomic value (for example, propane) may be introduced into the sectionafter the first portion of hydrocarbons. The introduction ofhydrocarbons of different boiling range distributions may enhancerecovery of the higher boiling hydrocarbons and more economicallyvaluable hydrocarbons through production wells 206.

In an embodiment, a blend made from hydrocarbon mixtures produced fromfirst section 1060 is used as a solvation fluid. The blend may includeabout 20% by weight light hydrocarbons (or blending agent) or greater(for example, about 50% by weight or about 80% by weight lighthydrocarbons) and about 80% by weight heavy hydrocarbons or less (forexample, about 50% by weight or about 20% by weight heavy hydrocarbons).The weight percentage of light hydrocarbons and heavy hydrocarbons mayvary depending on, for example, a weight distribution (or API gravity)of light and heavy hydrocarbons, an aromatic content of thehydrocarbons, a relative stability of the blend, or a desired APIgravity of the blend. For example, the weight percentage of lighthydrocarbons in the blend may at most 50% by weight or at most 20% byweight. In certain embodiments, the weight percentage of lighthydrocarbons may be selected to mix the least amount of lighthydrocarbons with heavy hydrocarbons that produces a blend with adesired density or viscosity.

In some embodiments, polymers and/or monomers may be used as solvationfluids. Polymers and/or monomers may solvate and/or drive hydrocarbonsto allow mobilization of the hydrocarbons towards one or more productionwells. The polymer and/or monomer may reduce the mobility of a waterphase in pores of the hydrocarbon containing formation. The reduction ofwater mobility may allow the hydrocarbons to be more easily mobilizedthrough the hydrocarbon containing formation. Polymers that may be usedinclude, but are not limited to, polyacrylamides, partially hydrolyzedpolyacrylamide, polyacrylates, ethylenic copolymers, biopolymers,carboxymethylcellulose, polyvinyl alcohol, polystyrene sulfonates,polyvinylpyrrolidone, AMPS (2-acrylamide-2-methyl propane sulfonate), orcombinations thereof. Examples of ethylenic copolymers includecopolymers of acrylic acid and acrylamide, acrylic acid and laurylacrylate, lauryl acrylate and acrylamide. Examples of biopolymersinclude xanthan gum and guar gum. In some embodiments, polymers may becrosslinked in situ in the hydrocarbon containing formation. In otherembodiments, polymers may be generated in situ in the hydrocarboncontaining formation. Polymers and polymer preparations for use in oilrecovery are described in U.S. Pat. Nos. 6,427,268 to Zhang et al.; U.S.Pat. No. 6,439,308 to Wang; U.S. Pat. No. 5,654,261 to Smith; U.S. Pat.No. 5,284,206 to Surles et al.; U.S. Pat. No. 5,199,490 to Surles etal.; and U.S. Pat. No. 5,103,909 to Morgenthaler et al., each of whichis incorporated by reference as if fully set forth herein.

In some embodiments, the solvation fluid includes one or more nonionicadditives (for example, alcohols, ethoxylated alcohols, nonionicsurfactants and/or sugar based esters). In some embodiments, thesolvation fluid includes one or more anionic surfactants (for example,sulfates, sulfonates, ethoxylated sulfates, and/or phosphates).

In some embodiments, the solvation fluid includes carbon disulfide.Hydrogen sulfide, in addition to other sulfur compounds produced fromthe formation, may be converted to carbon disulfide using known methods.Suitable methods may include oxidizing sulfur compounds to sulfur and/orsulfur dioxide, and reacting sulfur and/or sulfur dioxide with carbonand/or a carbon containing compound to form carbon disulfide. Theconversion of the sulfur compounds to carbon disulfide and the use ofthe carbon disulfide for oil recovery are described in U.S. PatentPublication No. 2006-0254769 to Van Dorp et al., which is incorporatedby reference as if fully set forth herein. The carbon disulfide may beintroduced into first section 1060, second section 1062 and/or thirdsection 1064 as a solvation fluid.

In some embodiments, the solvation fluid is hydrocarbon compound that iscapable of donating a hydrogen atom to the formation fluids. In someembodiments, the solvation fluid is capable of donating hydrogen to atleast a portion of the formation fluid thus forming a mixture ofsolvating fluid and dehydrogenated solvating fluid mixture. Thesolvating fluid/dehydrogenated solvating fluid mixture may enhancesolvation and/or dissolution of a greater portion of the formationfluids as compared to the initial solvation fluid. Examples of suchhydrogen donating solvating fluids include, but are not limited to,tetralin, alkyl substituted tetralin, tetrahydroquinoline, alkylsubstituted hydroquinoline, 1,2-dihydronaphthalene, a distillate cuthaving at least 40% by weight naphthenic aromatic compounds, or mixturesthereof. In some embodiments, the hydrogen donating hydrocarbon compoundis tetralin.

In some embodiments, the first section 1060, second section 1062 and/orthird section 1064 are heated to a temperature ranging form 175° C. to350° C. in the presence of the hydrogen donating solvating fluid. Atthese temperatures at least a portion of the formation fluids may behydrogenated by hydrogen donated from the hydrogen donating solvationfluid. In some embodiments, the minerals in the formation act as acatalyst for the hydrogenation process so that elevated formationtemperatures may not be necessary. Hydrogenation of at least a portionof the formation fluids may upgrade a portion of the formation fluidsand form a mixture of upgraded fluids and formation fluids. The mixturemay have a reduced viscosity compared to the initial formation fluids.In situ upgrading and the resulting reduction in viscosity mayfacilitate mobilization and/or recovery of the formation fluids. In situupgrading products that may be separated from the formation fluids atthe surface include, but are not limited to, naphtha, vacuum gas oil,distillate, kerosene, and/or diesel. Dehydrogenation of at least aportion of the hydrogen donating solvent may form a mixture that hasincreased polarity as compared to the initial hydrogen donating solvent.The increased polarity may enhance solvation or dissolution of a portionof the formation fluids and facilitate production and/or mobilization ofthe fluids to production wells 206.

In some embodiments, the hydrogen donating hydrocarbon compound isheated in a surface facility prior to being introduced into firstsection 1060, second section 1062 and/or third section 1064. Forexample, the hydrogen donating hydrocarbon compound may be heated to atemperature ranging from 100° C. to about 180° C., 120° C. to about 170°C., or from about 130 to 160° C. Heat from the hot hydrogen donatinghydrocarbon compound may facilitate mobilization, recovery and/orhydrogenation of fluids from first section 1060, second section 1062and/or third section 1064.

In some embodiments, a pressurizing fluid is provided in second section1062 and/or third section 1064 (for example, through injection wells788) to increase mobilization of hydrocarbons within the sections. Insome embodiments, a pressurizing fluid is provided to second section1062 and/or third section 1064 in combination with the solvation fluidto increase mobility of hydrocarbons within the formation. Thepressurizing fluid may include gases such as carbon dioxide, nitrogen,steam, methane, and/or mixtures thereof. In some embodiments, fluidsproduced from the formation (for example, combustion gases, heaterexhaust gases, or produced formation fluids) may be used as pressurizingfluid.

Providing a pressurizing fluid may increase a shear rate applied tohydrocarbon fluids in the formation and decrease the viscosity ofnon-Newtonian hydrocarbon fluids within the formation. In someembodiments, pressurizing fluid is provided to the selected sectionbefore significant heating of the formation. Pressurizing fluidinjection may increase a portion of the formation available forproduction. Pressurizing fluid injection may increase a ratio of energyoutput of the formation (energy content of products produced from theformation) to energy input into the formation (energy costs for treatingthe formation).

Providing the pressurizing fluid may increase a pressure in a selectedsection of the formation. The pressure in the selected section may bemaintained below a selected pressure. For example, the pressure may bemaintained below about 150 bars absolute, about 100 bars absolute, orabout 50 bars absolute. In some embodiments, the pressure may bemaintained below about 35 bars absolute. Pressure may be varieddepending on a number of factors (for example, desired production rateor an initial viscosity of tar in the formation). Injection of a gasinto the formation may result in a viscosity reduction of some of theformation fluids.

The pressurizing fluid may enhance the pressure gradient in theformation to flow mobilized hydrocarbons into first section 1060. Incertain embodiments, the production of fluids from first section 1060allows the pressure in second section 1062 and/or third section 1064 toremain below a selected pressure (for example, a pressure below whichfracturing of the overburden and/or the underburden may occur). In someembodiments, second section 1062 and/or third section 1064 have beenheated by heat transfer from first section 1060 prior to addition of thepressurizing fluid. In some embodiments, the pressurizing fluid is addedafter second section 1062 and/or third section 1064 have been heated toa desired temperature by residual heat from first section 1060.

In some embodiments, pressure is maintained by controlling flow of thepressurizing fluid into the selected section. In other embodiments, thepressure is controlled by varying a location or locations for injectingthe pressurizing fluid. In other embodiments, pressure is maintained bycontrolling a pressure and/or production rate at production wells 206.In some embodiments, the pressurized fluid (for example, carbon dioxide)is separated from the produced fluids and re-introduced into theformation. After production has been stopped, the fluid may besequestered in the formation.

In certain embodiments, formation fluid is produced from first section1060, second section 1062 and/or third section 1064. The formation fluidmay be produced through production wells 206. The formation fluidproduced from second section 1062 and/or third section 1064 may includesolvation fluid; hydrocarbons from first section 1060, second section1062 and/or third section 1064; and/or mixtures thereof.

Producing fluid from production wells in first section 1060 may lowerthe average pressure in the formation by forming an expansion volume forfluids heated in adjacent sections of the formation. Thus, producingfluid from production wells 206 in the first section 1060 may establisha pressure gradient in the formation that draws mobilized fluid fromsecond section 1062 and/or third section 1064 into the first section.

Hydrocarbons may be produced from first section 1060, second section1062 and/or third section 1064 such that at least about 30%, at leastabout 40%, at least about 50%, at least about 60% or at least about 70%by volume of the initial mass of hydrocarbons in the formation areproduced. In certain embodiments, additional hydrocarbons may beproduced from the formation such that at least about 60%, at least about70%, or at least about 80% by volume of the initial volume ofhydrocarbons in the sections is produced from the formation through theaddition of solvation fluid.

Fluids produced from production wells described herein may betransported through conduits (pipelines) between the formation andtreatment facilities or refineries. The produced fluids may betransported through a pipeline to another location for furthertransportation (for example, the fluids can be transported to a facilityat a river or a coast through the pipeline where the fluids can befurther transported by tanker to a processing plant or refinery).Incorporation of selected solvation fluids and/or other produced fluids(for example, aromatic hydrocarbons) in the produced formation fluid maystabilize the formation fluid during transportation. In someembodiments, the solvation fluid is separated from the formation fluidsafter transportation to treatment facilities. In some embodiments, atleast a portion of the solvation fluid is separated from the formationfluids prior to transportation. In some embodiments, the fluids producedprior to solvent treatment include heavy hydrocarbons.

In some embodiments, the produced fluids may include at least 85%hydrocarbon liquids by volume and at most 15% gases by volume, at least90% hydrocarbon liquids by volume and at most 10% gases by volume, or atleast 95% hydrocarbon liquids by volume and at most 5% gases by volume.In some embodiments, the mixture produced after solvent and/or pressuretreatment includes solvation fluids, gases, bitumen, visbroken fluids,pyrolyzed fluids, or combinations thereof. The mixture may be separatedinto heavy hydrocarbon liquids, solvation fluid and/or gases. In someembodiments the heavy hydrocarbon liquids, solvation fluid and/orpressuring fluid are re-injected in another section of the formation.

The heavy hydrocarbon liquids separated from the mixture may have an APIgravity of between 10° and 25°, between 15° and 24°, or between 19° and23°. In some embodiments, the separated hydrocarbon liquids may have anAPI gravity between 19° and 25°, between 20° and 24°, or between 21° and23°. A viscosity of the separated hydrocarbon liquids may be at most 350cp at 5° C. A P-value of the separated hydrocarbon liquids may be atleast 1.1, at least 1.5 or at least 2.0. The separated hydrocarbonliquids may have bromine of at most 3% and/or CAPP number of at most 2%.In some embodiments, the separated hydrocarbon liquids have an APIgravity between 19° and 25°, a viscosity ranging at most 350 cp at 5°C., a P-value of at least 1.1, a CAPP number of at most 2% as 1-deceneequivalent, and/or a bromine number of at most 2%.

During an in situ heat treatment process, some formation fluid maymigrate outwards from the treatment area. The formation fluid mayinclude benzene and/or other contaminants. Some portions of theformation that contaminants migrate to will be subsequently treated whena new treatment area is defined and processed using the in situ heattreatment process. Such contaminants may be removed or destroyed by thesubsequent in situ heat treatment process. Some areas of the formationto which contaminants migrate may not become part of a new treatmentarea subjected to in situ heat treatment. Migration inhibition systemsmay be implemented to inhibit contaminants from migrating to areas inthe formation that are not to be subjected to in situ heat treatment.

In some embodiments, a barrier (for example, a low temperature zone orfreeze barrier) surrounds at least a portion of the perimeter of atreatment area. The barrier may be 20 m to 100 m from the closestheaters in the treatment area used in the in situ heat treatment processto heat the formation. Some contaminants may migrate outwards as vaportowards the barrier through fractures or permeable zones. Some of thecontaminants may condense in the formation.

In some in situ heat treatment embodiments, a migration inhibitionsystem may be used to minimize or eliminate migration of formation fluidfrom the treatment area of the in situ heat treatment process. FIG. 223depicts a representation of a fluid migration inhibition system. Barrier1058 may surround treatment area 1028. Migration inhibition wells 1066may be placed in the formation between barrier 1058 and treatment area1028. Migration inhibition wells 1066 may be offset from wells used toheat the formation and/or from production wells used to produce fluidfrom the formation. Migration inhibition wells 1066 may be placed information that is below pyrolysis and/or dissociation temperatures ofminerals in the formation.

In some embodiments, one or more of the migration inhibition wells 1066include heaters. The heaters may be used to heat portions of theformation adjacent to the wells to a relatively low temperature. Therelatively low temperature may be a temperature below a dissociationtemperature of minerals in the formation adjacent to the well or below apyrolysis temperature of hydrocarbons in the formation. The temperaturethat the low temperature heater wells raise the formation to may be lessthan 260° C., less than 230° C., or less than 200° C. In someembodiments, heating elements in migration inhibition wells 1066 may betailored so that the heating elements only heat portions of theformation that have permeability sufficient to allow for the migrationof fluid (for example, fracture systems) and/or to allow forintroduction of fluid from the migration inhibition wells.

In some embodiments, one or more heater wells may be installed adjacentto the migration inhibition wells 1066. The heater wells may heatadjacent formation to an average temperature less than the dissociationtemperature of minerals in the formation and/or less than the pyrolysistemperature of hydrocarbons in the formation. The heater wells mayincrease the permeability of the formation adjacent to migrationinhibition wells 1066. Heating elements in the heater wells may betailored to only heat portions of the formation that have permeabilitysufficient to allow for migration of fluid and/or introduction of fluidfrom migration inhibition wells 1066 into the formation.

The heat supplied by heaters near or from the migration inhibition wellsmay inhibit condensation of migrating vapors located adjacent to themigration inhibition wells. Sweep fluid introduced into the formationthrough the migration inhibition wells may drive migrating vapors backto the heated treatment area. At least a portion of the migrating vaporsreturned to the treatment area may react in the treatment area. At leasta portion of the migrating vapors returned to the treatment area may beproduced from the formation through production wells.

Some or all migration inhibition wells 1066 may be injector wells thatallow for the introduction of a sweep fluid into the formation. Theinjector wells may include smart well technology. Sweep fluid may beintroduced into the formation through critical orifices, perforations orother types of openings in the injector wells. In some embodiments, thesweep fluid is carbon dioxide. The carbon dioxide may be carbon dioxideproduced from an in situ heat treatment process. The sweep fluid may beor include other fluids, such as nitrogen, methane or othernon-condensable hydrocarbons, exhaust gases, air, water, and/or steam.The sweep fluid may provide positive pressure in the formation outsideof treatment area 1028. The positive pressure may inhibit migration offormation fluid from treatment area 1028 towards barrier 1058. The sweepfluid may move through fractures in the formation toward or intotreatment area 1028. The sweep fluid may carry fluids that have migratedaway from treatment area 1028 back to the treatment area. The pressureof the fluid introduced through migration inhibition wells 1066 may bemaintained below the fracture pressure of the formation.

After an in situ process, energy recovery, remediation, and/orsequestration of carbon dioxide or other fluids in the treated area; thetreatment area may still be at an elevated temperature. Sulfur may beintroduced into the formation to act as a drive fluid to removeremaining formation fluid from the formation. The sulfur may beintroduced through outermost wellbores in the formation. The wellboresmay be injection wells, production wells, monitor wells, heater wells,barrier wells, or other types of wells that are converted to use assulfur injection wells. The sulfur may be used to drive fluid inwardstowards production wells in the pattern of wells used during the in situheat treatment process. The wells used as production wells for sulfurmay be production wells, heater wells, injection wells, monitor wells,or other types of wells converted for use as sulfur production wells.

In some embodiments, sulfur may be introduced in the treatment area froman outermost set of wells. Formation fluid may be produced from a firstinward set of wellbores until substantially only sulfur is produced fromthe first inward set of wells. The first inward set of wells may beconverted to injection wells. Sulfur may be introduced in the firstinward set of wells to drive remaining formation fluid towards a secondinward set of wells. The pattern may be continued until sulfur has beenintroduced into all of the treatment area. In some embodiments, a linedrive may be used for introducing the sulfur into the treatment area.

In some embodiments, molten sulfur may be injected into the treatmentarea. The molten sulfur may act as a displacement agent that movesand/or entrains remaining fluid in the treatment area. The molten sulfurmay be injected into the formation from selected wells. The sulfur maybe at a temperature near a melting point of sulfur so that the sulfurhas a relatively low viscosity. In some embodiments, the formation maybe at a temperature above the boiling point of sulfur. Sulfur may beintroduced into the formation as a gas or as a liquid.

Sulfur may be introduced into the formation until substantially onlysulfur is produced from the last sulfur production well or productionwells. When substantially only sulfur is produced from the last sulfurproduction well or production wells, introduction of additional sulfurmay be stopped, and the production from the production well orproduction wells may be stopped. Sulfur in the formation may be allowedto remain in the formation and solidify.

Alternative energy sources may be used to supply electricity forsubsurface electric heaters. Alternative energy sources include, but arenot limited to, wind, off-peak power, hydroelectric power, geothermal,solar, and tidal wave action. Some of these alternative energy sourcesprovide intermittent, time-variable power, or power-variable power. Toprovide power for subsurface electric heaters, power provided by thesealternative energy sources may be conditioned to produce power withappropriate operating parameters (for example, voltage, frequency,and/or current) for the subsurface heaters.

FIG. 224 depicts an embodiment for generating electricity for subsurfaceheaters from an intermittent power source. The generated electricalpower may be used to power other equipment used to treat a subsurfaceformation such as, but not limited to, pumps, computers, or otherelectrical equipment. In certain embodiments, windmill 1068 is used togenerate electricity to power heaters 802. Windmill 1068 may representone or more windmills in a wind farm. The windmills convert wind to ausable mechanical form of motion. In some embodiments, the wind farm mayinclude advanced windmills as suggested by the National Renewable EnergyLaboratory (Golden, Colo., U.S.A.). In some embodiments, windmill 1068varies its power output during a 24 hour period (for example, thewindmill may generate the most power at night). Using windmill 1068 asthe power source may reduce the carbon dioxide footprint for supplyingpower to heaters 802. In some embodiments, windmill 1068 includes otherintermittent, time-variable, or power-variable power sources.

In some embodiments, gas turbine 1070 is used to generate electricity topower heaters 802. Windmill 1068 and/or gas turbine 1070 may be coupledto transformer 1072. Transformer 1072 may convert power from windmill1068 and/or gas turbine 1070 into electrical power with appropriateoperating parameters for heaters 802 (for example, AC or DC power withappropriate voltage, current, and/or frequency may be generated by thetransformer).

In certain embodiments, tap controller 1074 is coupled to transformer1072, control system 1076, and heaters 802. Tap controller 1074 maymonitor and control transformer 1072 to maintain a constant voltage toheaters 802, regardless of the load of the heaters. Tap controller 1074may control power output in a range from 5 MVA (megavolt amps) to 500MVA, from 10 MVA to 400 MVA, or from 20 MVA to 300 MVA. Tap controller1074 may be designed to meet selected design requirements such as, butnot limited to, load limitations of components (such as transformer1072, control system 1076, and/or heaters 802) and the expected fullload current in the electrical circuit. Tap controller 1074 may be anelectromechanical, mechanical, electrical, electromagnetic, or solidstate tap controller. In one embodiments, tap controller 1074 is a 32step (±16 steps) electromechanical tap controller obtained from ABB Ltd.(Asea Brown Boveri) (Zurich, Switzerland). Tap controller 1074 may be astep controller that changes power in steps over a period of time (forexample, 1 step per minute). Tap controller 1074 may operated over apercentage of the total range (for example, ±15% of the voltage or ±10%of the voltage).

As an example, during operation, an overload of voltage may be sent fromtransformer 1072. Tap controller 1074 may modify the load provided toheaters 802 and distribute the excess load to other heaters and/or otherequipment in need of power. In some embodiments, tap controller 1074 maystore the excess load for future use.

Control system 1076 may control tap controller 1074. Control system 1076may be, for example, a computer controller or an analog logic system.Control system 1076 may use data supplied from power sensors 1078 togenerate predictive algorithms and/or control tap controller 1074. Forexample, data may be an amount of power generated from windmill 1068,gas turbine 1070, and/or transformer 1072. Data may also include anamount of resistive load of heaters 802. Power sensors 1078 may betoroidal current sensors that output voltages that are proportional tothe currents in wires passing through the sensors.

Automatic voltage regulation for resistive load of a heater enhances thelife of the heaters and/or allows constant heat output from the heatersto a subsurface formation. Adjusting the load demands instead ofadjusting the power source allows enhanced control of power supplied toheaters and/or other equipment that requires electricity. Power suppliedto heaters 802 may be controlled within selected limits (for example, apower supplied and/or controlled to a heater within 1%, 5%, 10%, or 20%of power required by the heater). Control of power supplied fromalternative energy sources may allow output of prime power at itsrating, allow energy produced (for example, from an intermittent source,a subsurface formation, or a hydroelectric source) to be stored and usedlater, and/or allow use of power generated by intermittent power sourcesto be used as a constant source of energy.

Some hydrocarbon containing formations, such as oil shale formations,may include nahcolite, trona, dawsonite, and/or other minerals withinthe formation. In some embodiments, nahcolite is contained in partiallyunleached or unleached portions of the formation. Unleached portions ofthe formation are parts of the formation where minerals have not beenremoved by groundwater in the formation. For example, in the Piceancebasin in Colorado, U.S.A., unleached oil shale is found below a depth ofabout 500 m below grade. Deep unleached oil shale formations in thePiceance basin center tend to be relatively rich in hydrocarbons. Forexample, about 0.10 liters to about 0.15 liters of oil per kilogram(L/kg) of oil shale may be producible from an unleached oil shaleformation.

Nahcolite is a mineral that includes sodium bicarbonate (NaHCO₃).Nahcolite may be found in formations in the Green River lakebeds inColorado, U.S.A. In some embodiments, at least about 5 weight %, atleast about 10 weight %, or at least about 20 weight % nahcolite may bepresent in the formation. Dawsonite is a mineral that includes sodiumaluminum carbonate (NaAl(CO₃)(OH)₂). Dawsonite is typically present inthe formation at weight percents greater than about 2 weight % or, insome embodiments, greater than about 5 weight %. Nahcolite and/ordawsonite may dissociate at temperatures used in an in situ heattreatment process. The dissociation is strongly endothermic and mayproduce large amounts of carbon dioxide.

Nahcolite and/or dawsonite may be solution mined prior to, during,and/or following treatment of the formation in situ to avoiddissociation reactions and/or to obtain desired chemical compounds. Incertain embodiments, hot water or steam is used to dissolve nahcolite insitu to form an aqueous sodium bicarbonate solution before the in situheat treatment process is used to process hydrocarbons in the formation.Nahcolite may form sodium ions (Na+) and bicarbonate ions (HCO₃—) inaqueous solution. The solution may be produced from the formationthrough production wells, thus avoiding dissociation reactions duringthe in situ heat treatment process. In some embodiments, dawsonite isthermally decomposed to alumina during the in situ heat treatmentprocess for treating hydrocarbons in the formation. The alumina issolution mined after completion of the in situ heat treatment process.

Production wells and/or injection wells used for solution mining and/orfor in situ heat treatment processes may include smart well technology.The smart well technology allows the first fluid to be introduced at adesired zone in the formation. The smart well technology allows thesecond fluid to be removed from a desired zone of the formation.

Formations that include nahcolite and/or dawsonite may be treated usingthe in situ heat treatment process. A perimeter barrier may be formedaround the portion of the formation to be treated. The perimeter barriermay inhibit migration of water into the treatment area. During solutionmining and/or the in situ heat treatment process, the perimeter barriermay inhibit migration of dissolved minerals and formation fluid from thetreatment area. During initial heating, a portion of the formation to betreated may be raised to a temperature below the dissociationtemperature of the nahcolite. The temperature may be at most about 90°C., or in some embodiments, at most about 80° C. The temperature may beany temperature that increases the solvation rate of nahcolite in water,but is also below a temperature at which nahcolite dissociates (aboveabout 95° C. at atmospheric pressure).

A first fluid may be injected into the heated portion. The first fluidmay include water, brine, steam, or other fluids that form a solutionwith nahcolite and/or dawsonite. The first fluid may be at an increasedtemperature, for example, about 90° C., about 95° C., or about 100° C.The increased temperature may be similar to the temperature of theportion of the formation.

In some embodiments, the first fluid is injected at an increasedtemperature into a portion of the formation that has not been heated byheat sources. The increased temperature may be a temperature below aboiling point of the first fluid, for example, about 90° C. for water.Providing the first fluid at an increased temperature increases atemperature of a portion of the formation. In certain embodiments,additional heat may be provided from one or more heat sources in theformation during and/or after injection of the first fluid.

In other embodiments, the first fluid is or includes steam. The steammay be produced by forming steam in a previously heated portion of theformation (for example, by passing water through u-shaped wellbores thathave been used to heat the formation), by heat exchange with fluidsproduced from the formation, and/or by generating steam in standardsteam production facilities. In some embodiments, the first fluid may befluid introduced directly into a hot portion of the portion and producedfrom the hot portion of the formation. The first fluid may then be usedas the first fluid for solution mining.

In some embodiments, heat from a hot previously treated portion of theformation is used to heat water, brine, and/or steam used for solutionmining a new portion of the formation. Heat transfer fluid may beintroduced into the hot previously treated portion of the formation. Theheat transfer fluid may be water, steam, carbon dioxide, and/or otherfluids. Heat may transfer from the hot formation to the heat transferfluid. The heat transfer fluid is produced from the formation throughproduction wells. The heat transfer fluid is sent to a heat exchanger.The heat exchanger may heat water, brine, and/or steam used as the firstfluid to solution mine the new portion of the formation. The heattransfer fluid may be reintroduced into the heated portion of theformation to produce additional hot heat transfer fluid. In someembodiments, heat transfer fluid produced from the formation is treatedto remove hydrocarbons or other materials before being reintroduced intothe formation as part of a remediation process for the heated portion ofthe formation.

Steam injected for solution mining may have a temperature below thepyrolysis temperature of hydrocarbons in the formation. Injected steammay be at a temperature below 250° C., below 300° C., or below 400° C.The injected steam may be at a temperature of at least 150° C., at least135° C., or at least 125° C. Injecting steam at pyrolysis temperaturesmay cause problems as hydrocarbons pyrolyze and hydrocarbon fines mixwith the steam. The mixture of fines and steam may reduce permeabilityand/or cause plugging of production wells and the formation. Thus, theinjected steam temperature is selected to inhibit plugging of theformation and/or wells in the formation.

The temperature of the first fluid may be varied during the solutionmining process. As the solution mining progresses and the nahcolitebeing solution mined is farther away from the injection point, the firstfluid temperature may be increased so that steam and/or water thatreaches the nahcolite to be solution mined is at an elevated temperaturebelow the dissociation temperature of the nahcolite. The steam and/orwater that reaches the nahcolite is also at a temperature below atemperature that promotes plugging of the formation and/or wells in theformation (for example, the pyrolysis temperature of hydrocarbons in theformation).

A second fluid may be produced from the formation following injection ofthe first fluid into the formation. The second fluid may includematerial dissolved in the first fluid. For example, the second fluid mayinclude carbonic acid or other hydrated carbonate compounds formed fromthe dissolution of nahcolite in the first fluid. The second fluid mayalso include minerals and/or metals. The minerals and/or metals mayinclude sodium, aluminum, phosphorus, and other elements.

Solution mining the formation before the in situ heat treatment processallows initial heating of the formation to be provided by heat transferfrom the first fluid used during solution mining. Solution miningnahcolite or other minerals that decompose or dissociate by means ofendothermic reactions before the in situ heat treatment process avoidshaving energy supplied to heat the formation being used to support theseendothermic reactions. Solution mining allows for production of mineralswith commercial value. Removing nahcolite or other minerals before thein situ heat treatment process removes mass from the formation. Thus,less mass is present in the formation that needs to be heated to highertemperatures and heating the formation to higher temperatures may beachieved more quickly and/or more efficiently. Removing mass from theformation also may increase the permeability of the formation.Increasing the permeability may reduce the number of production wellsneeded for the in situ heat treatment process. In certain embodiments,solution mining before the in situ heat treatment process reduces thetime delay between startup of heating of the formation and production ofhydrocarbons by two years or more.

FIG. 225 depicts an embodiment of solution mining well 1080. Solutionmining well 1080 may include insulated portion 1082, input 1084, packer1086, and return 1088. Insulated portion 1082 may be adjacent tooverburden 482 of the formation. In some embodiments, insulated portion1082 is low conductivity cement. The cement may be low density, lowconductivity vermiculite cement or foam cement. Input 1084 may directthe first fluid to treatment area 1028. Perforations or other types ofopenings in input 1084 allow the first fluid to contact formationmaterial in treatment area 1028. Packer 1086 may be a bottom seal forinput 1084. First fluid passes through input 1084 into the formation.First fluid dissolves minerals and becomes second fluid. The secondfluid may be denser than the first fluid. An entrance into return 1088is typically located below the perforations or openings that allow thefirst fluid to enter the formation. Second fluid flows to return 1088.The second fluid is removed from the formation through return 1088.

FIG. 226 depicts a representation of an embodiment of solution miningwell 1080. Solution mining well 1080 may include input 1084 and return1088 in casing 1090. Inlet 1084 and/or return 1088 may be coiled tubing.

FIG. 227 depicts a representation of an embodiment of solution miningwell 1080. Insulating portions 1082 may surround return 1088. Input 1084may be positioned in return 1088. In some embodiments, input 1084 mayintroduce the first fluid into the treatment area below the entry pointinto return 1088. In some embodiments, crossovers may be used to directfirst fluid flow and second fluid flow so that first fluid is introducedinto the formation from input 1084 above the entry point of second fluidinto return 1088.

FIG. 228 depicts an elevational view of an embodiment of wells used forsolution mining and/or for an in situ heat treatment process. Solutionmining wells 1080 may be placed in the formation in an equilateraltriangle pattern. In some embodiments, the spacing between solutionmining wells 1080 may be about 36 m. Other spacings may be used. Heatsources 202 may also be placed in an equilateral triangle pattern.Solution mining wells 1080 substitute for certain heat sources of thepattern. In the shown embodiment, the spacing between heat sources 202is about 9 m. The ratio of solution mining well spacing to heat sourcespacing is 4. Other ratios may be used if desired. After solution miningis complete, solution mining wells 1080 may be used as production wellsfor the in situ heat treatment process.

In some formations, a portion of the formation with unleached mineralsmay be below a leached portion of the formation. The unleached portionmay be thick and substantially impermeable. A treatment area may beformed in the unleached portion. Unleached portion of the formation tothe sides, above and/or below the treatment area may be used as barriersto fluid flow into and out of the treatment area. A first treatment areamay be solution mined to remove minerals, increase permeability in thetreatment area, and/or increase the richness of the hydrocarbons in thetreatment area. After solution mining the first treatment area, in situheat treatment may be used to treat a second treatment area. In someembodiments, the second treatment area is the same as the firsttreatment area. In some embodiments, the second treatment has a smallervolume than the first treatment area so that heat provided by outermostheat sources to the formation do not raise the temperature of unleachedportions of the formation to the dissociation temperature of theminerals in the unleached portions.

In some embodiments, a leached or partially leached portion of theformation above an unleached portion of the formation may includesignificant amounts of hydrocarbon materials. An in situ heating processmay be used to produce hydrocarbon fluids from the unleached portionsand the leached or partially leached portions of the formation. FIG. 229depicts a representation of a formation with unleached zone 1092 belowleached zone 1094. Unleached zone 1092 may have an initial permeabilitybefore solution mining of less than 0.1 millidarcy. Solution miningwells 1080 may be placed in the formation. Solution mining wells 1080may include smart well technology that allows the position of firstfluid entrance into the formation and second flow entrance into thesolution mining wells to be changed. Solution mining wells 1080 may beused to form first treatment area 1028′ in unleached zone 1092.Unleached zone 1092 may initially be substantially impermeable.Unleached portions of the formation may form a top barrier and sidebarriers around first treatment area 1028′. After solution mining firsttreatment area 1028′, the portions of solution mining wells 1080adjacent to the first treatment area may be converted to productionwells and/or heater wells.

Heat sources 202 in first treatment area 1028′ may be used to heat thefirst treatment area to pyrolysis temperatures. In some embodiments, oneor more heat sources 202 are placed in the formation before firsttreatment area 1028′ is solution mined. The heat sources may be used toprovide initial heating to the formation to raise the temperature of theformation and/or to test the functionality of the heat sources. In someembodiments, one or more heat sources are installed during solutionmining of the first treatment area, or after solution mining iscompleted. After solution mining, heat sources 202 may be used to raisethe temperature of at least a portion of first treatment area 1028′above the pyrolysis and/or mobilization temperature of hydrocarbons inthe formation to result in the generation of mobile hydrocarbons in thefirst treatment area.

Barrier wells 200 may be introduced into the formation. Ends of barrierwells 200 may extend into and terminate in unleached zone 1092.Unleached zone 1092 may be impermeable. In some embodiments, barrierwells 200 are freeze wells. Barrier wells 200 may be used to form abarrier to fluid flow into or out of unleached zone 1094. Barrier wells200, overburden 482, and the unleached material above first treatmentarea 1028′ may define second treatment area 1028″. In some embodiments,a first fluid may be introduced into second treatment area 1028″ throughsolution mining wells 1080 to raise the initial temperature of theformation in second treatment area 1028″ and remove any residual solubleminerals from the second treatment area. In some embodiments, the topbarrier above first treatment area 1028′ may be solution mined to removeminerals and combine first treatment area 1028′ and second treatmentarea 1028″ into one treatment area. After solution mining, heat sourcesmay be activated to heat the treatment area to pyrolysis temperatures.

FIG. 230 depicts an embodiment for solution mining the formation.Barrier 1058 (for example, a frozen barrier and/or a grout barrier) maybe formed around a perimeter of treatment area 1028 of the formation.The footprint defined by the barrier may have any desired shape such ascircular, square, rectangular, polygonal, or irregular shape. Barrier1058 may be any barrier formed to inhibit the flow of fluid into or outof treatment area 1028. For example, barrier 1058 may include one ormore freeze wells that inhibit water flow through the barrier. Barrier1058 may be formed using one or more barrier wells 200. Formation ofbarrier 1058 may be monitored using monitor wells 1096 and/or bymonitoring devices placed in barrier wells 200.

Water inside treatment area 1028 may be pumped out of the treatment areathrough injection wells 788 and/or production wells 206. In certainembodiments, injection wells 788 are used as production wells 206 andvice versa (the wells are used as both injection wells and productionwells). Water may be pumped out until a production rate of water is lowor stops.

Heat may be provided to treatment area 1028 from heat sources 202. Heatsources may be operated at temperatures that do not result in thepyrolysis of hydrocarbons in the formation adjacent to the heat sources.In some embodiments, treatment area 1028 is heated to a temperature fromabout 90° C. to about 120° C. (for example, a temperature of about 90°C., 95° C., 100° C., 110° C., or 120° C.). In certain embodiments, heatis provided to treatment area 1028 from the first fluid injected intothe formation. The first fluid may be injected at a temperature fromabout 90° C. to about 120° C. (for example, a temperature of about 90°C., 95° C., 100° C., 110° C., or 120° C.). In some embodiments, heatsources 202 are installed in treatment area 1028 after the treatmentarea is solution mined. In some embodiments, some heat is provided fromheaters placed in injection wells 788 and/or production wells 206. Atemperature of treatment area 1028 may be monitored using temperaturemeasurement devices placed in monitoring wells 1096 and/or temperaturemeasurement devices in injection wells 788, production wells 206, and/orheat sources 202.

The first fluid is injected through one or more injection wells 788. Insome embodiments, the first fluid is hot water. The first fluid may mixand/or combine with non-hydrocarbon material that is soluble in thefirst fluid, such as nahcolite, to produce a second fluid. The secondfluid may be removed from the treatment area through injection wells788, production wells 206, and/or heat sources 202. Injection wells 788,production wells 206, and/or heat sources 202 may be heated duringremoval of the second fluid. Heating one or more wells during removal ofthe second fluid may maintain the temperature of the fluid duringremoval of the fluid from the treatment area above a desired value.After producing a desired amount of the soluble non-hydrocarbon materialfrom treatment area 1028, solution remaining within the treatment areamay be removed from the treatment area through injection wells 788,production wells 206, and/or heat sources 202. The desired amount of thesoluble non-hydrocarbon material may be less than half of the solublenon-hydrocarbon material, a majority of the soluble non-hydrocarbonmaterial, substantially all of the soluble non-hydrocarbon material, orall of the soluble non-hydrocarbon material. Removing solublenon-hydrocarbon material may produce a relatively high permeabilitytreatment area 1028.

Hydrocarbons within treatment area 1028 may be pyrolyzed and/or producedusing the in situ heat treatment process following removal of solublenon-hydrocarbon materials. The relatively high permeability treatmentarea allows for easy movement of hydrocarbon fluids in the formationduring in situ heat treatment processing. The relatively highpermeability treatment area provides an enhanced collection area forpyrolyzed and mobilized fluids in the formation. During the in situ heattreatment process, heat may be provided to treatment area 1028 from heatsources 202. A mixture of hydrocarbons may be produced from theformation through production wells 206 and/or heat sources 202. Incertain embodiments, injection wells 788 are used as either productionwells and/or heater wells during the in situ heat treatment process.

In some embodiments, a controlled amount of oxidant (for example, airand/or oxygen) is provided to treatment area 1028 at or near heatsources 202 when a temperature in the formation is above a temperaturesufficient to support oxidation of hydrocarbons. At such a temperature,the oxidant reacts with the hydrocarbons to provide heat in addition toheat provided by electrical heaters in heat sources 202. The controlledamount of oxidant may facilitate oxidation of hydrocarbons in theformation to provide additional heat for pyrolyzing hydrocarbons in theformation. The oxidant may more easily flow through treatment area 1028because of the increased permeability of the treatment area afterremoval of the non-hydrocarbon materials. The oxidant may be provided ina controlled manner to control the heating of the formation. The amountof oxidant provided is controlled so that uncontrolled heating of theformation is avoided. Excess oxidant and combustion products may flow toproduction wells in treatment area 1028.

Following the in situ heat treatment process, treatment area 1028 may becooled by introducing water to produce steam from the hot portion of theformation. Introduction of water to produce steam may vaporize somehydrocarbons remaining in the formation. Water may be injected throughinjection wells 788. The injected water may cool the formation. Theremaining hydrocarbons and generated steam may be produced throughproduction wells 206 and/or heat sources 202. Treatment area 1028 may becooled to a temperature near the boiling point of water. The steamproduced from the formation may be used to heat a first fluid used tosolution mine another portion of the formation.

Treatment area 1028 may be further cooled to a temperature at whichwater will condense in the formation. Water and/or solvent may beintroduced into and be removed from the treatment area. Removing thecondensed water and/or solvent from treatment area 1028 may remove anyadditional soluble material remaining in the treatment area. The waterand/or solvent may entrain non-soluble fluid present in the formation.Fluid may be pumped out of treatment area 1028 through production well206 and/or heat sources 202. The injection and removal of water and/orsolvent may be repeated until a desired water quality within treatmentarea 1028 is achieved. Water quality may be measured at the injectionwells, heat sources 202, and/or production wells. The water quality maysubstantially match or exceed the water quality of treatment area 1028prior to treatment.

In some embodiments, treatment area 1028 may include a leached zonelocated above an unleached zone. The leached zone may have been leachednaturally and/or by a separate leaching process. In certain embodiments,the unleached zone may be at a depth of at least about 500 m. Athickness of the unleached zone may be between about 100 m and about 500m. However, the depth and thickness of the unleached zone may varydepending on, for example, a location of treatment area 1028 and/or thetype of formation. In certain embodiments, the first fluid is injectedinto the unleached zone below the leached zone. Heat may also beprovided into the unleached zone.

In certain embodiments, a section of a formation may be left untreatedby solution mining and/or unleached. The unleached section may beproximate a selected section of the formation that has been leachedand/or solution mined by providing the first fluid as described above.The unleached section may inhibit the flow of water into the selectedsection. In some embodiments, more than one unleached section may beproximate a selected section.

Nahcolite may be present in the formation in layers or beds. Prior tosolution mining, such layers may have little or no permeability. Incertain embodiments, solution mining layered or bedded nahcolite fromthe formation causes vertical shifting in the formation. FIG. 231depicts an embodiment of a formation with nahcolite layers in theformation below overburden 482 and before solution mining nahcolite fromthe formation. Hydrocarbon layers 484A have substantially no nahcoliteand hydrocarbon layers 484B have nahcolite. FIG. 232 depicts theformation of FIG. 231 after the nahcolite has been solution mined.Layers 484B have collapsed due to the removal of the nahcolite from thelayers. The collapsing of layers 484B causes compaction of the layersand vertical shifting of the formation. The hydrocarbon richness oflayers 484B is increased after compaction of the layers. In addition,the permeability of layers 484B may remain relatively high aftercompaction due to removal of the nahcolite. The permeability may be morethan 5 darcy, more than 1 darcy, or more than 0.5 darcy after verticalshifting. The permeability may provide fluid flow paths to productionwells when the formation is treated using an in situ heat treatmentprocess. The increased permeability may allow for a large spacingbetween production wells. Distances between production wells for the insitu heat treatment system after solution mining may be greater than 10m, greater than 20 m, or greater than 30 meters. Heater wells may beplaced in the formation after removal of nahcolite and the subsequentvertical shifting. Forming heater wellbores and/or installing heaters inthe formation after the vertical shifting protects the heaters frombeing damaged due to the vertical shifting.

In certain embodiments, removing nahcolite from the formationinterconnects two or more wells in the formation. Removing nahcolitefrom zones in the formation may increase the permeability in the zones.Some zones may have more nahcolite than others and become more permeableas the nahcolite is removed. At a certain time, zones with the increasedpermeability may interconnect two or more wells (for example, injectionwells or production wells) in the formation.

FIG. 233 depicts an embodiment of two injection wells interconnected bya zone that has been solution mined to remove nahcolite from the zone.Solution mining wells 1080 are used to solution mine hydrocarbon layer484, which contains nahcolite. During the initial portion of thesolution mining process, solution mining wells 1080 are used to injectwater and/or other fluids, and to produce dissolved nahcolite fluidsfrom the formation. Each solution mining well 1080 is used to injectwater and produce fluid from a near wellbore region as the permeabilityof hydrocarbon layer is not sufficient to allow fluid to flow betweenthe injection wells. In certain embodiments, zone 1098 has morenahcolite than other portions of hydrocarbon layer 484. With increasednahcolite removal from zone 1098, the permeability of the zone mayincrease. The permeability increases from the wellbores outwards asnahcolite is removed from zone 1098. At some point during solutionmining of the formation, the permeability of zone 1098 increases toallow solution mining wells 1080 to become interconnected such thatfluid will flow between the wells. At this time, one solution miningwell 1080 may be used to inject water while the other solution miningwell is used to produce fluids from the formation in a continuousprocess. Injecting in one well and producing from a second well may bemore economical and more efficient in removing nahcolite, as compared toinjecting and producing through the same well. In some embodiments,additional wells may be drilled into zone 1098 and/or hydrocarbon layer484 in addition to solution mining wells 1080. The additional wells maybe used to circulate additional water and/or to produce fluids from theformation. The wells may later be used as heater wells and/or productionwells for the in situ heat treatment process treatment of hydrocarbonlayer 484.

In some embodiments, a treatment area has nahcolite beds above and/orbelow the treatment area. The nahcolite beds may be relatively thin (forexample, about 5 m to about 10 m in thickness). In an embodiment, thenahcolite beds are solution mined using horizontal solution mining wellsin the nahcolite beds. The nahcolite beds may be solution mined in ashort amount of time (for example, in less than 6 months). Aftersolution mining of the nahcolite beds, the treatment area and thenahcolite beds may be heated using one or more heaters. The heaters maybe placed either vertically, horizontally, or at other angles within thetreatment area and the nahcolite beds. The nahcolite beds and thetreatment area may then undergo the in situ heat treatment process.

In some embodiments, the solution mining wells in the nahcolite beds areconverted to production wells. The production wells may be used toproduce fluids during the in situ heat treatment process. Productionwells in the nahcolite bed above the treatment area may be used toproduce vapors or gas (for example, gas hydrocarbons) from theformation. Production wells in the nahcolite bed below the treatmentarea may be used to produce liquids (for example, liquid hydrocarbons)from the formation.

In some embodiments, the second fluid produced from the formation duringsolution mining is used to produce sodium bicarbonate. Sodiumbicarbonate may be used in the food and pharmaceutical industries, inleather tanning, in fire retardation, in wastewater treatment, and influe gas treatment (flue gas desulphurization and hydrogen chloridereduction). The second fluid may be kept pressurized and at an elevatedtemperature when removed from the formation. The second fluid may becooled in a crystallizer to precipitate sodium bicarbonate.

In some embodiments, the second fluid produced from the formation duringsolution mining is used to produce sodium carbonate, which is alsoreferred to as soda ash. Sodium carbonate may be used in the manufactureof glass, in the manufacture of detergents, in water purification,polymer production, tanning, paper manufacturing, effluentneutralization, metal refining, sugar extraction, and/or cementmanufacturing. The second fluid removed from the formation may be heatedin a treatment facility to form sodium carbonate (soda ash) and/orsodium carbonate brine. Heating sodium bicarbonate will form sodiumcarbonate according to the equation:

2NaHCO₃→Na₂CO₃+CO₂+H₂O.  (EQN. 6)

In certain embodiments, the heat for heating the sodium bicarbonate isprovided using heat from the formation. For example, a heat exchangerthat uses steam produced from the water introduced into the hotformation may be used to heat the second fluid to dissociationtemperatures of the sodium bicarbonate. In some embodiments, the secondfluid is circulated through the formation to utilize heat in theformation for further reaction. Steam and/or hot water may also be addedto facilitate circulation. The second fluid may be circulated through aheated portion of the formation that has been subjected to the in situheat treatment process to produce hydrocarbons from the formation. Atleast a portion of the carbon dioxide generated during sodium carbonatedissociation may be adsorbed on carbon that remains in the formationafter the in situ heat treatment process. In some embodiments, thesecond fluid is circulated through conduits previously used to heat theformation.

In some embodiments, higher temperatures are used in the formation (forexample, above about 120° C., above about 130° C., above about 150° C.,or below about 250° C.) during solution mining of nahcolite. The firstfluid is introduced into the formation under pressure sufficient toinhibit sodium bicarbonate from dissociating to produce carbon dioxide.The pressure in the formation may be maintained at sufficiently highpressures to inhibit such nahcolite dissociation but below pressuresthat would result in fracturing the formation. In addition, the pressurein the formation may be maintained high enough to inhibit steamformation if hot water is being introduced in the formation. In someembodiments, a portion of the nahcolite may begin to decompose in situ.In such cases, nahcolite is removed from the formation as soda ash. Ifsoda ash is produced from solution mining of nahcolite, the soda ash maybe transported to a separate facility for treatment. The soda ash may betransported through a pipeline to the separate facility.

As described above, in certain embodiments, following removal ofnahcolite from the formation, the formation is treated using the in situheat treatment process to produce formation fluids from the formation.In some embodiments, the formation is treating using the in situ heattreatment process before solution mining nahcolite from the formation.The nahcolite may be converted to sodium carbonate (from sodiumbicarbonate) during the in situ heat treatment process. The sodiumcarbonate may be solution mined as described above for solution miningnahcolite prior to the in situ heat treatment process.

In some formations, dawsonite is present in the formation. Dawsonitewithin the heated portion of the formation decomposes during heating ofthe formation to pyrolysis temperature. Dawsonite typically decomposesat temperatures above 270° C. according to the reaction:

2NaAl(OH)₂CO₃→Na₂CO₃+Al₂O₃+2H₂O+CO₂.  (EQN. 7)

Sodium carbonate may be removed from the formation by solution miningthe formation with water or other fluid into which sodium carbonate issoluble. In certain embodiments, alumina formed by dawsonitedecomposition is solution mined using a chelating agent. The chelatingagent may be injected through injection wells, production wells, and/orheater wells used for solution mining nahcolite and/or the in situ heattreatment process (for example, injection wells 788, production wells206, and/or heat sources 202 depicted in FIG. 230). The chelating agentmay be an aqueous acid. In certain embodiments, the chelating agent isEDTA (ethylenediaminetetraacetic acid). Other examples of possiblechelating agents include, but are not limited to, ethylenediamine,porphyrins, dimercaprol, nitrilotriacetic acid,diethylenetriaminepentaacetic acid, phosphoric acids, acetic acid,acetoxy benzoic acids, nicotinic acid, pyruvic acid, citric acid,tartaric acid, malonic acid, imidizole, ascorbic acid, phenols, hydroxyketones, sebacic acid, and boric acid. The mixture of chelating agentand alumina may be produced through production wells or other wells usedfor solution mining and/or the in situ heat treatment process (forexample, injection wells 788, production wells 206, and/or heat sources202, which are depicted in FIG. 230). The alumina may be separated fromthe chelating agent in a treatment facility. The recovered chelatingagent may be recirculated back to the formation to solution mine morealumina.

In some embodiments, alumina within the formation may be solution minedusing a basic fluid after the in situ heat treatment process. Basicfluids include, but are not limited to, sodium hydroxide, ammonia,magnesium hydroxide, magnesium carbonate, sodium carbonate, potassiumcarbonate, pyridine, and amines. In an embodiment, sodium carbonatebrine, such as 0.5 Normal Na₂CO₃, is used to solution mine alumina.Sodium carbonate brine may be obtained from solution mining nahcolitefrom the formation. Obtaining the basic fluid by solution mining thenahcolite may significantly reduce costs associated with obtaining thebasic fluid. The basic fluid may be injected into the formation througha heater well and/or an injection well. The basic fluid may combine withalumina to form an alumina solution that is removed from the formation.The alumina solution may be removed through a heater well, injectionwell, or production well.

Alumina may be extracted from the alumina solution in a treatmentfacility. In an embodiment, carbon dioxide is bubbled through thealumina solution to precipitate the alumina from the basic fluid. Carbondioxide may be obtained from dissociation of nahcolite, from the in situheat treatment process, or from decomposition of the dawsonite duringthe in situ heat treatment process.

In certain embodiments, a formation may include portions that aresignificantly rich in either nahcolite or dawsonite only. For example, aformation may contain significant amounts of nahcolite (for example, atleast about 20 weight %, at least about 30 weight %, or at least about40 weight %) in a depocenter of the formation. The depocenter maycontain only about 5 weight % or less dawsonite on average. However, inbottom layers of the formation, a weight percent of dawsonite may beabout 10 weight % or even as high as about 25 weight %. In suchformations, it may be advantageous to solution mine for nahcolite onlyin nahcolite-rich areas, such as the depocenter, and solution mine fordawsonite only in the dawsonite-rich areas, such as the bottom layers.This selective solution mining may significantly reduce fluid costs,heating costs, and/or equipment costs associated with operating thesolution mining process.

In certain formations, dawsonite composition varies between layers inthe formation. For example, some layers of the formation may havedawsonite and some layers may not. In certain embodiments, more heat isprovided to layers with more dawsonite than to layers with lessdawsonite. Tailoring heat input to provide more heat to certaindawsonite layers more uniformly heats the formation as the reaction todecompose dawsonite absorbs some of the heat intended for pyrolyzinghydrocarbons. FIG. 234 depicts an embodiment for heating a formationwith dawsonite in the formation. Hydrocarbon layer 484 may be cored toassess the dawsonite composition of the hydrocarbon layer. The mineralcomposition may be assessed using, for example, FTIR (Fourier transforminfrared spectroscopy) or x-ray diffraction. Assessing the corecomposition may also assess the nahcolite composition of the core. Afterassessing the dawsonite composition, heater 438 may be placed inwellbore 428. Heater 438 includes sections to provide more heat tohydrocarbon layers with more dawsonite in the layers (hydrocarbon layers484D). Hydrocarbon layers with less dawsonite (hydrocarbon layers 484C)are provided with less heat by heater 438. Heat output of heater 438 maybe tailored by, for example, adjusting the resistance of the heateralong the length of the heater. In one embodiment, heater 438 is atemperature limited heater, described herein, that has a highertemperature limit (for example, higher Curie temperature) in sectionsproximate layers 484D as compared to the temperature limit (Curietemperature) of sections proximate layers 484C. The resistance of heater438 may also be adjusted by altering the resistive conducting materialsalong the length of the heater to supply a higher energy input (wattsper meter) adjacent to dawsonite rich layers.

Solution mining dawsonite and nahcolite may be relatively simpleprocesses that produce alumina and soda ash from the formation. In someembodiments, hydrocarbons produced from the formation using the in situheat treatment process may be fuel for a power plant that producesdirect current (DC) electricity at or near the site of the in situ heattreatment process. The produced DC electricity may be used on the siteto produce aluminum metal from the alumina using the Hall process.Aluminum metal may be produced from the alumina by melting the aluminain a treatment facility on the site. Generating the DC electricity atthe site may save on costs associated with using hydrotreaters,pipelines, or other treatment facilities associated with transportingand/or treating hydrocarbons produced from the formation using the insitu heat treatment process.

In some embodiments, acid may be introduced into the formation throughselected wells to increase the porosity adjacent to the wells. Forexample, acid may be injected if the formation comprises limestone ordolomite. The acid used to treat the selected wells may be acid producedduring in situ heat treatment of a section of the formation (forexample, hydrochloric acid), or acid produced from byproducts of the insitu heat treatment process (for example, sulfuric acid produced fromhydrogen sulfide or sulfur).

In some embodiments, a saline rich zone is located at or near anunleached portion of the formation. The saline rich zone may be anaquifer in which water has leached out nahcolite and/or other minerals.A high flow rate may pass through the saline rich zone. Saline waterfrom the saline rich zone may be used to solution mine another portionof the formation. In certain embodiments, a steam and electricitycogeneration facility may be used to heat the saline water prior to usefor solution mining.

FIG. 235 depicts a representation of an embodiment for solution miningwith a steam and electricity cogeneration facility. Treatment area 1028may be formed in unleached portion 1092 of the formation (for example,an oil shale formation). Several treatment areas 1028 may be formed inunleached portion 1092 leaving top, side, and/or bottom walls ofunleached formation as barriers around the individual treatment areas toinhibit inflow and outflow of formation fluid during the in situ heattreatment process. The thickness of the walls surrounding the treatmentareas may be 10 m or more. For example, the side wall near closest tosaline zone 1100 may be 60 m or more thick, and the top wall may be 30 mor more thick.

Treatment area 1028 may have significant amounts of nahcolite. Salinezone 1100 is located at or near treatment area 1028. In certainembodiments, zone 1100 is located up dip from treatment area 1028. Zone1100 may be leached or partially leached such that the zone is mainlyfilled with saline water.

In certain embodiments, saline water is removed (pumped) from zone 1100using production well 206. Production well 206 may be located at or nearthe lowest portion of zone 1100 so that saline water flows into theproduction well. Saline water removed from zone 1100 is heated to hotwater and/or steam temperatures in facility 796. Facility 796 may burnhydrocarbons to run generators that produce electricity. Facility 796may burn gaseous and/or liquid hydrocarbons to make electricity. In someembodiments, pulverized coal is used to make electricity. Theelectricity generated may be used to provide electrical power forheaters or other electrical operations (for example, pumping). Wasteheat from the generators is used to make hot water and/or steam from thesaline water. After the in situ heat treatment process of one or moretreatment areas 1028 results in the production of hydrocarbons, at leasta portion of the produced hydrocarbons may be used as fuel for facility796.

The hot water and/or steam made by facility 796 is provided to solutionmining well 1080. Solution mining well 1080 is used to solution minetreatment area 1028. Nahcolite and/or other minerals are removed fromtreatment area 1028 by solution mining well 1080. The nahcolite may beremoved as a nahcolite solution from treatment area 1028. The solutionremoved from treatment area 1028 may be a brine solution with dissolvednahcolite. Heat from the removed nahcolite solution may be used infacility 796 to heat saline water from zone 1100 and/or other fluids.The nahcolite solution may then be injected through injection well 788into zone 1100. In some embodiments, injection well 788 injects thenahcolite solution into zone 1100 up dip from production well 206.Injection may occur a significant distance up dip so that nahcolitesolution may be continuously injected as saline water is removed fromthe zone without the two fluids substantially intermixing. In someembodiments, the nahcolite solution from treatment area 1028 is providedto injection well 788 without passing through facility 796 (thenahcolite solution bypasses the facility).

The nahcolite solution injected into zone 1100 may be left in the zonepermanently or for an extended period of time (for example, aftersolution mining, production well 206 may be shut in). In someembodiments, the nahcolite stored in zone 1100 is accessed at latertimes. The nahcolite may be produced by removing saline water from zone1100 and processing the saline water to make sodium bicarbonate and/orsoda ash.

Solution mining using saline water from zone 1100 and heat from facility796 to heat the saline water may be a high efficiency process forsolution mining treatment area 1028. Facility 796 is efficient atproviding heat to the saline water. Using the saline water to solutionmine decreases costs associated with pumping and/or transporting waterto the treatment site. Additionally, solution mining treatment area 1028preheats the treatment area for any subsequent heat treatment of thetreatment area, enriches the hydrocarbon content in the treatment areaby removing nahcolite, and/or creates more permeability in the treatmentarea by removing nahcolite.

In certain embodiments, treatment area 1028 is further treated using anin situ heat treatment process following solution mining of thetreatment area. A portion of the electricity generated in facility 796may be used to power heaters for the in situ heat treatment process.

In some embodiments, a perimeter barrier may be formed around theportion of the formation to be treated. The perimeter barrier mayinhibit migration of formation fluid into or out of the treatment area.The perimeter barrier may be a frozen barrier and/or a grout barrier.After formation of the perimeter barrier, the treatment area may beprocessed to produce desired products.

Formations that include non-hydrocarbon materials may be treated toremove and/or dissolve a portion of the non-hydrocarbon materials from asection of the formation before hydrocarbons are produced from thesection. In some embodiments, the non-hydrocarbon materials are removedby solution mining. Removing a portion of the non-hydrocarbon materialsmay reduce the carbon dioxide generation sources present in theformation. Removing a portion of the non-hydrocarbon materials mayincrease the porosity and/or permeability of the section of theformation. Removing a portion of the non-hydrocarbon materials mayresult in a raised temperature in the section of the formation.

After solution mining, some of the wells in the treatment may beconverted to heater wells, injection wells, and/or production wells. Insome embodiments, additional wells are formed in the treatment area. Thewells may be heater wells, injection wells, and/or production wells.Logging techniques may be employed to assess the physicalcharacteristics, including any vertical shifting resulting from thesolution mining, and/or the composition of material in the formation.Packing, baffles or other techniques may be used to inhibit formationfluid from entering the heater wells. The heater wells may be activatedto heat the formation to a temperature sufficient to support combustion.

One or more production wells may be positioned in permeable sections ofthe treatment area. Production wells may be horizontally and/orvertically oriented. For example, production wells may be positioned inareas of the formation that have a permeability of greater than 5 darcyor 10 darcy. In some embodiments, production wells may be positionednear a perimeter barrier. A production well may allow water andproduction fluids to be removed from the formation. Positioning theproduction well near a perimeter barrier enhances the flow of fluidsfrom the warmer zones of the formation to the cooler zones.

FIG. 236 depicts an embodiment of a process for treating a hydrocarboncontaining formation with a combustion front. Barrier 1058 (for example,a frozen barrier or a grout barrier) may be formed around a perimeter oftreatment area 1028 of the formation. The footprint defined by thebarrier may have any desired shape such as circular, square,rectangular, polygonal, or irregular shape. Barrier 1058 may be formedusing one or more barrier wells 200. The barrier may be any barrierformed to inhibit the flow of fluid into or out of treatment area 1028.In some embodiments, barrier 1058 may be a double barrier.

Heat may be provided to treatment area 1028 through heaters positionedin injection wells 788. In some embodiments, the heaters in injectionwells 788 heat formation adjacent to the injections wells totemperatures sufficient to support combustion. Heaters in injectionwells 788 may raise the formation near the injection wells totemperatures from about 90° C. to about 120° C. or higher (for example,a temperature of about 90° C., 95° C., 100° C., 110° C., or 120° C.).

Injection wells 788 may be used to introduce a combustion fuel, anoxidant, steam and/or a heat transfer fluid into treatment area 1028,either before, during, or after heat is provided to treatment area 1028from heaters. In some embodiments, injection wells 788 are incommunication with each other to allow the introduced fluid to flow fromone well to another. Injection wells 788 may be located at positionsthat are relatively far away from perimeter barrier 1058. Introducedfluid may cause combustion of hydrocarbons in treatment area 1028. Heatfrom the combustion may heat treatment area 1028 and mobilize fluidstoward production wells 206.

A temperature of treatment area 1028 may be monitored using temperaturemeasurement devices placed in monitoring wells and/or temperaturemeasurement devices in injection wells 788, production wells 206, and/orheater wells.

In some embodiments, a controlled amount of oxidant (for example, airand/or oxygen) is provided in injection wells 788 to advance a heatfront towards production wells 206. In some embodiments, the controlledamount of oxidant is introduced into the formation after solution mininghas established permeable interconnectivity between at least twoinjection wells. The amount of oxidant is controlled to limit theadvancement rate of the heat front and to limit the temperature of theheat front. The advancing heat front may pyrolyze hydrocarbons. The highpermeability in the formation allows the pyrolyzed hydrocarbons tospread in the formation towards production wells without being overtakenby the advancing heat front.

Vaporized formation fluid and/or gas formed during the combustionprocess may be removed through gas wells 1102 and/or injection wells788. Venting of gases through gas wells 1102 and/or injection wells 788may force the combustion front in a desired direction.

In some embodiments, the formation may be heated to a temperaturesufficient to cause pyrolysis of the formation fluid by the steam and/orheat transfer fluid. The steam and/or heat transfer fluid may be heatedto temperatures of about 300° C., about 400° C., about 500° C., or about600° C. In certain embodiments, the steam and/or heat transfer fluid maybe co-injected with the fuel and/or oxidant.

FIG. 237 depicts a representation of a cross-sectional view of anembodiment for treating a hydrocarbon containing formation with acombustion front. As the combustion front is initiated and/or fueledthrough injection wells 788, formation fluid near periphery 1104 of thecombustion front becomes mobile and flow towards production wells 206located proximate barrier 1058. Injection wells may include smart welltechnology. Combustion products and noncondensable formation fluid maybe removed from the formation through gas wells 1102. In someembodiments, no gas wells are formed in the formation. In suchembodiments, formation fluid, combustion products and noncondensableformation fluid are produced through production wells 206. Inembodiments that include gas wells 1102, condensable formation fluid maybe produced through production well 206. In some embodiments, productionwell 206 is located below injection well 788. Production well 206 may beabout 1 m, 5 m, 10 m or more below injection well 788. Production wellmay be a horizontal well. Periphery 1104 of the combustion front mayadvance from the toe of production well 206 towards the heel of theproduction well. Production well 206 may include a perforated liner thatallows hydrocarbons to flow into the production well. In someembodiments, a catalyst may be placed in production well 206. Thecatalyst may upgrade and/or stabilize formation fluid in the productionwell.

Gases may be produced during in situ heat treatment processes and duringmany conventional production processes. Some of the produced gases (forexample, carbon dioxide and/or hydrogen sulfide) when introduced intowater may change the pH of the water to less than 7. Such gases aretypically referred to as sour gas or acidic gas. Introducing sour gasfrom produced fluid into subsurface formations may reduce or eliminatethe need for or size of certain surface facilities (for example, a Clausplant or Scot gas treater). Introducing sour gas from produced formationfluid into subsurface formations may make the formation fluid moreacceptable for transportation, use, and/or processing. Removal of sourgas having a low heating value (for example, carbon dioxide) fromformation fluids may increase the caloric value of the gas streamseparated from the formation fluid.

Net release of sour gas to the atmosphere and/or conversion of sour gasto other compounds may be reduced by utilizing the produced sour gasand/or by storing the sour gas within subsurface formations. In someembodiments, the sour gas is stored in deep saline aquifers. Deep salineaquifers may be at depths of about 900 m or more below the surface. Thedeep saline aquifers may be relatively thick and permeable. A thick andrelatively impermeable formation strata may be located over deep salineaquifers. For example, 500 m or more of shale may be located above thedeep saline aquifer. The water in the deep saline aquifer may beunusable for agricultural or other common uses because of the highmineral content in the water. Over time, the minerals in the water mayreact with introduced sour gas to form precipitates in the deep salineaquifer. The deep saline aquifer used to store sour gas may be below thetreatment area, at another location in the same formation, or in anotherformation. If the deep saline aquifer is located at another location inthe same formation or in another formation, the sour gas may betransported to the deep saline aquifer by pipeline.

In some embodiments, injection wells used to inject sour gas may bevertical, slanted, and/or directionally steered wells with a significanthorizontal or near horizontal portion. The horizontal or near horizontalportion of the injection well may be located near or at the bottom ofthe deep saline aquifer. FIG. 238 depicts a representation of anembodiment of a system for injection of sour gases produced from the insitu heat treatment process into the deep saline aquifer. Formationfluids may be produced from hydrocarbon layer 484. In certainembodiments, formation fluids are produced using an in situ heattreatment process through production well 206. The sour gas (forexample, gas including at least carbon dioxide and hydrogen sulfide) maybe separated from the formation fluids in gas/liquid separator 1106using known gas/liquid separation techniques.

The separated sour gas may be transported to formation 1108 via conduit1110 (for example, a pipeline). Formation 1108 may include aquifer 1112(for example, a deep saline aquifer) and barrier portion 1114 (forexample, shale). The sour gas may be injected into deep saline aquifer1112 through injection well 1116. Injection well 1116 may have verticalportion 1118 and horizontal portion 1120. Horizontal portion 1120 may benear or at the bottom of deep saline aquifer 1112. The sour gas may beless dense than formation fluid in the deep saline aquifer. The sour gasmay diffuse upwards in the aquifer towards barrier layer 1114.Horizontal portion 1120 may allow injection of the sour gas in a largeportion of deep saline aquifer 1112. Openings in horizontal portion 1120may be critical flow orifices so that fluid is introduced substantiallyequally along the length of the horizontal portion.

Cement 1122 may be used to seal conduit 1110 in formation. Cement 1122used in injection wellbores to form seals at the surface and/or at aninterface of deep saline aquifer with barrier layer 1114 may be selectedso that the cement does not degrade due to the temperature, pressure andchemical environment due to exposure to sour gas.

The deep saline aquifer or aquifers used to store sour gas may be atsufficient depth such that the carbon dioxide in the sour gas isintroduced in the formation in a supercritical state. Supercriticalcarbon dioxide injection may maximize the density of the fluidintroduced into the formation. The depths of outlets of injection wellsused to introduce acidic gases in the formation may be 900 m or morebelow the surface.

Injection of sour gas into a non-producing formation and/or using sourgas as flooding agents are described in U.S. Pat. No. 7,128,150 toThomas et al.; RE 39,244 to Eaton; RE 39,077 to Eaton; U.S. Pat. No.6,755,251 to Thomas et al.; U.S. Pat. No. 6,283,230 to Peters, all ofwhich are incorporated by reference as if fully set forth herein.

During production of formation fluids from a subsurface formation,acidic gases may react with water in the formation and produce acids.For example, carbonic acid may be produced from the reaction of carbondioxide with water during heating of the formation. Portions of wellsmade of certain materials, such as carbon steel, may start todeteriorate or corrode in the presence of the produced acids. To inhibitcorrosion due to produced acids (for example, carbonic acid), fluidsand/or polymers (for example, corrosion inhibitors, foaming agents,surfactants, basic fluids, hydrocarbons, high density polyethylene, ormixtures thereof) may be introduced in the wellbore to neutralize and/ordissolve the acids.

In some embodiments, hydrogen sulfide and/or carbon dioxide areseparated from the produced gases and introduced into one or morewellbores in a subsurface formation. Water present in the gas introducedinto the formation may interact with hydrogen sulfide to form a sulfidelayer on metal surfaces of the injection well. Formation of the sulfidelayer may inhibit further corrosion of the metal surfaces of theinjection well by carbonic acid and/or other acids. The formation of thesulfide layer may allow for the use of carbon steel or other relativelyinexpensive alloys during the introduction of sour gas into subsurfaceformations.

In certain embodiments, a temperature measurement tool assesses theactive impedance of an energized heater. The temperature measurementtool may utilize the frequency domain analysis algorithm associated withPartial Discharge measurement technology (PD) coupled with timed domainreflectometer measurement technology (TDR). A set of frequency domainanalysis tools may be applied to a TDR signature. This process mayprovide unique information in the analysis of the energized heater suchas, but not limited to, an impedance log of the entire length of theheater per unit length. The temperature measurement tool may providecertain advantages for assessing the temperature of a downhole heater.

In certain embodiments, the temperature measurement tool assesses theimpedance per unit length and gives a profile on the entire length ofthe heated section of the heater. The impedance profile may be used inassociation with laboratory data for the heater (such as temperature andresistance profiles for heaters measured at various loads andfrequencies) to assess the temperature per unit length of the heatedsection. The impedance profile may also be used to assess variouscomputer models for heaters that are used in association with thereservoir simulations.

In certain embodiments, the temperature measurement tool assesses anaccurate impedance profile of a heater in a specific formation after anumber of heater wells have been installed and energized in the specificformation. The accurate impedance profile may assess the actual reactiveand real power consumption for each heater that is used similarly. Thisinformation may be used to properly size surface electrical distributionequipment and/or eliminate any extra capacity designed to accommodateany anticipated heater impedance turndown ratio or any unknown powerfactor or reactive power consumption for the heaters.

In certain embodiments, the temperature measurement tool is used totroubleshoot malfunctioning heaters and assess the impedance profile ofthe length of the heated section. The impedance profile may be able toaccurately predict the location of a faulted section and its relativeimpedance to ground. This information may be used to accurately assessthe appropriate reduction in surface voltage to allow the heater tocontinue to operate in a limited capacity. This method may be morepreferable than abandoning the heater in the formation.

In certain embodiments, frequency domain PD testing offers an improvedset of PD characterization tools. A basic set of frequency domain PDtesting tools are described in “The Case for Frequency Domain PD TestingIn The Context Of Distribution Cable”, Steven Boggs, ElectricalInsulation Magazine, IEEE, Vol. 19, Issue 4, July-August 2003, pages13-19, which is incorporated by reference as if fully set forth herein.Frequency domain PD detection sensitivity under field conditions may beone to two orders of magnitude greater than for time domain testing as aresult of there not being a need to trigger on the first PD pulse abovethe broadband noise, and the filtering effect of the cable between thePD detection site and the terminations. As a result of this greatlyincreased sensitivity and the set of characterization tools, frequencydomain PD testing has been developed into a highly sensitive andreliable tool for characterizing the condition of distribution cableduring normal operation while the cable is energized, the sensitivityand accuracy of which have been confirmed through independent testing.

In some embodiments, a method of treating formation that has previouslyundergone an in situ heat treatment process includes providing arecovery fluid to the formation. The recovery fluid may include, but isnot limited to, water, steam, air, oxygen, carbon dioxide, methaneand/or other non-condensable hydrocarbon gases, and/or mixtures thereof.Heat from one or more heat sources may provide heat to a section of theformation. In some embodiments, contact of formation fluid with therecovery fluid may generate heat through oxidation of the formationfluid and/or solid hydrocarbons in the formation (for example, coke).The formation may be heated or allowed to heat to temperatures rangingfrom about 200° C. to about 1200° C., or from about 300° C. to about1000° C., or from about 500° C. to about 800° C. Heating of theformation in the presence of the recovery fluid may reduce coke in theformation and produce gas. Once the recovery process has been completed,one or more heated portions of the formation may be used as an in situreactor and/or reaction zone to treat formation fluid, and/orhydrocarbons from surface facilities. Using one or more heated portionsof the formation to treat such hydrocarbons may reduce or eliminate theneed for surface facilities that treat such fluids (for example, cokingunits and/or delayed coking units).

A catalyst system may be introduced to the heated portion of theformation. In some embodiments, the portion of the formation is heatedafter and/or during introduction of the catalyst system. The catalystsystem may be provided to the formation by injection of the catalystsystem into an injection well and/or a production well in the section ofthe formation to be treated. In some embodiments, the catalyst systemmay be positioned in a well bore proximate the section of the formationto be treated.

The catalyst system may be provided to the formation with a carrierfluid. The carrier fluid may include, but is not limited, tohydrocarbons, water, steam, in situ heat treatment process gas,hydrogen, or mixtures thereof. In some embodiments, the catalyst systemis slurried with the carrier fluid and/or another fluid and the slurryis introduced to the heated portion of the formation. In someembodiments, carrier fluid is a liquid and the formation may havesufficient heat to vaporize at least a portion of the carrier fluid.Vaporization of the carrier fluid may leave at least a portion of thecatalyst system in the formation and/or in a well bore.

The catalyst system may include one or more catalysts. The catalysts maybe supported or unsupported catalysts. Catalysts include, but are notlimited to, alkali metal carbonates, alkali metal hydroxides, alkalimetal hydrides, alkali metal amides, alkali metal sulfides, alkali metalacetates, alkali metal oxalates, alkali metal formates, alkali metalpyruvates, alkaline-earth metal carbonates, alkaline-earth metalhydroxides, alkaline-earth metal hydrides, alkaline-earth metal amides,alkaline-earth metal sulfides, alkaline-earth metal acetates,alkaline-earth metal oxalates, alkaline-earth metal formates,alkaline-earth metal pyruvates, or commercially available fluidcatalytic cracking catalysts, dolomite, any catalyst that promotesformation of aromatic hydrocarbons, or mixtures thereof.

Hydrocarbons may be introduced into the heated portion of the formation.In some embodiments, the catalyst system is slurried with a portion ofthe hydrocarbons and the slurry is introduced to the heated portion ofthe formation. The introduced hydrocarbons may be hydrocarbons information fluid from an adjacent portion of the formation, condensablehydrocarbons that have been previously produced or created in surfacefacilities that would need to be further treated to produce desirableproducts. Such hydrocarbons may be introduced into the formation throughone or more injection wells. Such hydrocarbons may include residue,asphaltenes, bitumen or other types of hydrocarbons. The hydrocarbonsmay contact the catalyst system to produce desirable products (forexample, visbroken hydrocarbons and/or cracked hydrocarbons). Thedesirable products may be removed from the formation.

In some embodiments, the desirable products may include aromatics. Thearomatics may solubilize a portion of the heavy hydrocarbons in theformation. The mixture of desirable products and heavy hydrocarbons maybe produced from the formation. In some embodiments, the mixture ofhydrocarbons and formation fluid may drain to a bottom portion of alayer and solubilize additional hydrocarbons at the bottom of the layer.The resulting mixture may be produced from production wells positionedat the bottom of the layer.

Heating the formation in the presence of the hydrocarbons may mobilizeformation fluids in the heated first portion to allow the formationfluid to contact the catalyst system. In some embodiments, heating thefirst portion may increase permeability of the formation and allowformation fluid (for example, bitumen) from a second portion of theformation to flow into the heated first portion and contact the catalystsystem. In some embodiments, the fluids may be driven to the heatedportion of the formation using a drive fluid (for example, carbondioxide and/or steam).

In some embodiments, a portion of the formation may be heated to atemperature to mobilize formation fluids (for example, temperatures ofat least 200° C.). At least a portion of the mobilized fluids may beproduced from the formation. The catalyst system may be introduced aftera portion of the mobilized fluids have been removed. The catalyst systemmay be introduced in a carrier fluid and/or as a slurry. Contact of thecatalyst system with at least a portion of the mobilized fluids mayproduce hydrocarbons having a lower API gravity than the mobilizedfluids.

The fluid mixture produced from contact of hydrocarbons, formation fluidand/or mobilized fluids with the catalyst system may be produced fromthe formation. In certain embodiments, the fluid mixture may be producedthrough a production well. The liquid hydrocarbon portion of the fluidmixture may have an API gravity between 10° and 25°, between 12° and 23°or between 15° and 20°. In some embodiments, the produce mixture has atmost 0.25 grams of aromatics per gram of total hydrocarbons. In someembodiments, the produced mixture includes some of the catalysts and/orused catalysts.

During contacting, impurities (for example, coke, nitrogen containingcompounds, sulfur containing compounds, and/or metals such as nickeland/or vanadium) may form on the catalyst. Removal of the impurities onthe catalyst in situ may enhance catalyst life. In situ removal of theimpurities may be performed through combustion of the catalyst. In someembodiments, an oxidant (for example, air, oxygen, and/or synthesis gasgenerating fluid) may be introduced into the formation and the formationis heated to a temperature sufficient to allow combustion of impuritieson the catalyst to occur.

Contact of the hydrocarbons with catalyst system may produce coke. Theamount of coke may be reduced by introduction of an oxidant (forexample, air and/or synthesis gas generating fluid). Oxidation of thecoke may produce gases. In some embodiments, the formation may be heatedto initiate oxidation of the coke. The produced gases may be removedfrom the formation through one or more production wells.

Additional catalysts may be introduced into the formation during thecontacting process, after a portion of the coke has been removed fromthe existing catalyst, and/or after reduction of coke in the formationto continue the treatment process.

During or after solution mining and/or the in situ heat treatmentprocess, some existing cased heater wells and/or some existing casedmonitor wells may be converted into production wells and/or injectionwells. Existing cased wells may be converted to production and/orinjection wells by perforating a portion of the well casing withperforation devices that utilize explosives. Also, some production wellsmay be perforated at one or more cased locations to facilitate removalof formation fluid through newly opened sections in the productionwells. In some embodiments, perforation devices may be used in openwellbores to fracture formation adjacent to the wellbore.

In some embodiments, pre-perforated portions of wells are installed.Coverings may initially be placed over the perforations. At a desiredtime, the covering of the perforations may be removed to open additionalportions of the wells or to convert the wells to production wells and/orinjections wells. Knowing which wells will need to be converted toproduction wells and/or injection wells may not be apparent at the timeof well installation. Using pre-perforated wells for all wells may beprohibitively expensive.

Perforation devices may be used to form openings in a well. Perforationdevices may be obtained from, for example, Schlumberger USA (Sugar Land,Tex., USA). Perforation devices may include, but are not limited to,capsule guns and/or hollow carrier guns. Perforation devices may useexplosives to form openings in a well. The well may need to be at arelatively cool temperature to inhibit premature detonation of theexplosives. Temperature exposure limits of some explosives commonly usedfor perforation devices are a maximum exposure of 1 hour to atemperature of about 260° C., and a maximum exposure of 10 hours to atemperature of about 210° C. In some embodiments, the well is cooledbefore use of the perforation device. In some embodiments, theperforation device is insulated to inhibit heat transfer to theperforation device. The use of insulation may not be suitable for wellswith portions that are at high temperature (for example, above 300° C.).

In some embodiments, the perforation device is equipped with acirculated fluid cooling system. The circulated fluid cooling system maykeep the temperature of the perforation device below a desired value.Keeping the temperature of the perforation device below a selectedtemperature may inhibit premature denotation of explosives in theperforation device.

One or more temperature sensing devices may be included in thecirculated fluid cooling system to allow temperatures in the well and/ornear the perforating device to be observed. After insertion into thewell, the perforation device may be activated to form openings in thewell. The openings may be of sufficient size to allow fluid to be pumpedthrough the well after removal of the perforation device positioningapparatus.

FIG. 239 represents a perspective view of circulated fluid coolingsystem 1124 that provides continuous and/or semi-continuous coolingfluid to perforating device 1126. Circulated fluid cooling system 1124may include outer tubing 1128, inner tubing 1130, connectors 1132,sleeve 1134, support 1136, perforating device 1126, temperature sensor1138, and control cable 1140.

Sleeve 1134 may be coupled to outer tubing 1128 by connector 1132. Insome embodiments, outer tubing 1128 is a coiled tubing string, andconnector 1132 is a threaded connection. Sleeve 1134 may be a thinwalled sleeve. In some embodiments, sleeve 1134 is made of a polymer.Sleeve 1134 may have minimal thickness to maximize explosive performanceof perforation device 1126, yet still be sufficiently strong to supportthe forces applied to the sleeve by the hydrostatic column andcirculation of cooling fluid.

Inner tubing 1130 may be positioned inside of outer tubing 1128. In someembodiments, inner tubing 1130 is a coiled tubing string. Support 1136may be coupled to inner tubing by connector 1132. In some embodiments,support 1136 is a pipe and connector 1132 and is a threaded connection.Perforation device 1126 may be secured to the outside of support 1136. Anumber of perforation devices may be secured to the outside of thesupport in series. Using a number of perforation devices may allow along length of perforations to be formed in the well on a single trip ofcirculated fluid cooling system 1124 into the well.

Temperature sensor 1138 and control cable 1140 may be positioned throughinner tubing 1130 and support 1136. Temperature sensor may be a fiberoptic cable or plurality of thermocouples that are capable of sensingtemperature at various locations in circulated fluid cooling system1124. Control cable 1140 may be coupled to perforation device 1126. Asignal may be sent through control cable to detonate explosives inperforation device 1126.

Cooling fluid 1142 may flow downwards through inner tubing 1130 andsupport 1136 and return to the surface past perforation device 1126 inthe space between the support and sleeve 1134 and in the space betweenthe inner tubing and outer tubing 1128. Cooling fluid 1142 may be water,glycol, or any other suitable heat transfer fluid.

In some embodiments, a long length of support 1136 and sleeve 1134 maybe left below perforation device 1126 as a dummy section. Temperaturemeasurements taken by temperature sensor 1138 in the dummy section maybe used to monitor the temperature rise of the leading portion ofcirculated fluid cooling system 1124 as the circulated fluid coolingsystem is introduced into the well. The dummy section may also be atemperature buffer for perforation device 1126 that inhibits rapidtemperature rise in the perforation device. In other embodiments, thecirculated fluid cooling system may be introduced into the well withoutperforation devices to determine so that the temperature increase theperforation device will be exposed to will be known before theperforation device is placed in the well.

To use circulated fluid cooling system 1124, the circulated fluidcooling system is lowered into the well. Cooling fluid 1142 keeps thetemperature of perforation device 1126 below temperatures that mayresult in the premature detonation of explosives of the perforationdevice. After the perforation device is positioned at the desiredlocation in the well, circulation of cooling fluid 1142 is stopped. Insome embodiments, cooling fluid 1142 is removed from circulated fluidcooling system 1124. Then, control cable 1140 may be used to detonatethe explosives of perforation device 1126 to form openings in the well.Outer tubing 1128 and inner tubing 1130 may be removed from the well,and the remaining portions of sleeve 1134 and/or support 1136 may bedisconnected from the outer tubing and the inner tubing.

To perforate another well, a new perforation device may be secured tothe support if the support is reusable. The support may be coupled toinner tubing, and a new sleeve may be coupled to the outer tubing. Thenewly reformed circulated fluid cooling system 1124 may be deployed inthe well to be perforated.

Many wells may be used to treat the hydrocarbon formation using the insitu heat treatment process. In some embodiments, vertical and/orsubstantially vertical wells are formed in the formation. In someembodiments, horizontal and/or U-shaped wells are formed in theformation. In some embodiments, combinations of horizontal and verticalwells are formed in the formation. Horizontal and/or vertical wells mayextend through the overburden of the formation. Heat from eitherhorizontal and/or vertical wells may be lost to the overburden. Surfaceand/or overburden infrastructures used to support heaters and/orproduction wells in horizontal wellbores may be large in size and/ornumerous. Positioning heaters, heater power sources, productionequipment, supply lines, and/or other heater or production supportequipment in substantially horizontal tunnels and/or inclined tunnelsmay reduce allow reductions in size of heaters and/or other equipmentused to treat the formation, reduce energy costs for treating theformation, reduce emissions from the treatment process, facilitateheating system installation, and/or reduce heat loss to the overburden,as compared to conventional hydrocarbon recovery processes that utilizesurface based equipment. U.S. Published Patent Application Nos.2007-0044957 to Watson et al.; 2008-0017416 to Watson et al.; and2008-0078552 to Donnelly et al., all of which are incorporated herein byreference, describe methods of drilling from a shaft for undergroundrecovery of hydrocarbons and methods of underground recovery ofhydrocarbons.

FIGS. 240-245 depict representations of underground treatment systems.FIG. 240 depicts a perspective exploded view of an underground treatmentsystem. FIG. 241 depicts a perspective view of tunnels in an undergroundtreatment system. FIG. 242 depicts a perspective view of undergroundtreatment systems having heat sources connected to two tunnels. FIG. 243depicts a representation of a portion of an underground system.Wellbores extending from the surface intersect tunnels of theunderground system. FIG. 244 depicts a schematic of tunnel sections inan underground treatment system. FIG. 245 depicts a schematic of anunderground treatment system in combination with surface production.Underground heater system 1144 may include shafts 1146, utility shafts1148, tunnels 1150, heat sources 202, supply lines 204, collectionpiping 208, production wells 206, or combinations thereof. Shafts 1146connect with tunnels 1150 in overburden 482 to form an undergroundworkspace. Shafts 1146 may also extend into hydrocarbon layer 484.Shafts 1146 and utility shafts 1148 may have openings that allowmovement to and from the shafts and tunnels 1150.

The underground workspace may be sealed from the formation pressure andformation fluids. For example, the underground workspace may have animpermeable barrier to seal the workspace from the formation. In someembodiments, the impermeable barrier is a cement barrier. Theunderground workspace may have at least one entry point to surface 568.

Shafts 1146 may be sunk or formed in overburden 482 and/or hydrocarbonlayer 484 using methods known in the art for drilling and/or sinkingmine shafts. Shafts 1146 may connect surface 568 with overburden 482and/or hydrocarbon layer 484. In certain embodiments, shafts 1146 aresubstantially vertical, have a circular cross-section, and havedimensions suitable to allow ventilation, materials, vehicles andpersonnel access. In some embodiments, shafts 1146 have a diameter of atleast 1 m or greater. A distance between two shafts may be at least 100m or greater. In some embodiments, shafts 1146 proximate to heatertunnels 1152 are sealed (for example, filled with cement) after heatinghas been initiated in hydrocarbon layer 484 to inhibit gas or otherfluids from entering the shaft 1146.

In some embodiments, utility shafts 1148 are placed between two shafts.A distance between utility shafts 1148 may be about 200 m, 500 m, or1000 m. Utility shafts 1148 may include equipment or structures such as,but not limited to, power supply legs, production risers, and/orventilation openings.

In certain embodiments, tunnels 1150 extend outward from shafts 1146.Tunnels may be located in the overburden of the formation, hydrocarbonlayer of the formation and/or in the underburden of the formation. Insome embodiments, tunnels are located in an impermeable portion of thehydrocarbon formation. For example, tunnels may be located in a portionof the formation having permeability of about 1 millidarcy. Tunnels 1150may be substantially horizontal or inclined. Tunnels 1150 may connect atleast two shafts 1146. A shape of ends of tunnels 1150 may berectangular, circular, elliptical, or horseshoe-shaped. Ends andportions of the lengths of tunnels 1150 may have cross-sections largeenough for personnel, equipment, and/or vehicles to pass through theends of the tunnels. Tunnels 1150 may include heater tunnels 1152 and/orutilities tunnels 1154.

In certain embodiments, wellbores 428 are formed substantiallyvertically, substantially horizontally, or inclined in hydrocarbon layer484 by drilling into the hydrocarbon layer from tunnels 1150. In someembodiments, injection wells and monitoring wells are extended fromtunnels 1150. Drilling wellbores 428 from tunnels 1150 may increasedrilling efficiency and decrease drilling time and length because thewellbores do not have to be drilled through overburden 482. Drillingfrom tunnels 1150 and subsequent placement of equipment in the tunnelsmay reduce a surface equipment footprint as compared to conventionalsurface drilling methods. In some embodiments, heater wellbores 428interconnect with utility tunnels 1154. In some embodiments, utilitiestunnel 1154 is positioned between two heater tunnels 1152. It should beunderstood that the any number of tunnels and/or any order of tunnelsmay be used as contemplated or desired. Using shafts and tunnels incombination with in situ treatment to produce hydrocarbons from theformation may be beneficial because the overburden section is eliminatedfrom both heater construction and drilling requirements. In someembodiments, a least a portion of the shafts and tunnels are locatedbelow the aquifers in or above the hydrocarbon containing formation.Locating the shafts and tunnels in such a manner may reducecontamination risk to the aquifers, and may simplify abandonment of theshafts and tunnels after production.

In some embodiments, wellbores 428 are directionally drilled to utilitytunnels 1154 as shown in FIG. 243. Directional drilling to intersectutility tunnel 1154 can be easier than directional drilling to intersectanother wellbore in the formation. Drilling equipment such as, but notlimited to, magnetic transmission equipment, magnetic sensing equipment,acoustic transmission equipment, and acoustic sensing equipment may belocated in the utility tunnels and used for directional drilling of theheater wellbores. The drilling equipment may be removed from the utilitytunnel after directional drilling is completed.

In certain embodiments, subsurface end connections for heaters and/orsubsurface connections between heater elements are made in utilitytunnels 1154. Physical connections between heater elements may be madein the utility tunnels 1154. For example, physical connections may bemade between heater elements and a bus bar located in the utilitytunnel. The bus bar may be used to provide electrical connection to theends of the heater elements.

In some embodiments, the physical connections are made manually in theutility tunnel 1154. In some embodiments, utilities tunnel 1154 includespower equipment necessary to operate heat sources and productionequipment (for example, transformers 1156 and voltage regulators 1158depicted in FIG. 241). In certain embodiments, voltage regulators arelocated in power chamber 1160. Power chamber 1160 may connect to utilityshaft 1148. Supply lines 204, depicted in FIG. 245, in utility shaft1148 may supply power to heat sources 202 through voltage regulators1158 and transformers 1156 in utility tunnels 1154. Utility tunnels 1154may allow for easier, quicker, and/or more effective maintenance,repair, and/or replacement of the subsurface connections.

In some embodiments, heat sources are located in wellbores 428 thatextend from heater tunnels 1152 and/or interconnect with utility tunnels1154 as depicted in FIG. 240 and FIG. 242. Examples of heat sourcesinclude, but are not limited to, molten salts, closed looped molten saltcirculating systems, insulated conductors, temperature limited heaters,induction heaters, fluid transport systems, and/or pulverized coalsystems.

Introduction of heat sources through heater tunnels 1152 allowshydrocarbon layer 484 to be heated without significant heat losses tooverburden 482. Being able to provide heat mainly to hydrocarbon layer484 with low heat losses in the overburden may enhance heaterefficiency. For example, the savings in heating costs may be at least15%. By using tunnels to provide heaters only in the hydrocarbon layer,and not requiring significant heater wellbore sections in the overburdenmay decrease heater costs by at least 30%, at least 50%, at least 60%,or at least 70% as compared to heater costs using heaters that havesections passing through the overburden. Providing heaters throughtunnels may allow optimal heater density to be obtained, thus resultingin faster production from the formation. Closer spacing of heaters maybe economically beneficial due to a significantly lower cost peradditional heater. For example, heaters located in the hydrocarbon layerby drilling through the overburden are typically spaced about 11 mapart. Using tunnels to space heaters, the heaters may be spaced about6.5 m apart in the hydrocarbon layer. The closer spacing may acceleratefirst production by 4 to 5 years, as compared to the years for firstproduction obtained from heaters that are spaced 11 m apart. Thisacceleration in first production may reduce the heating requirement byat least 15%.

In some embodiments, heat sources of various lengths providing differentamounts of heata at different locations may be used in wellbores 428proximate heater tunnels 1152 instead of pumps to control viscosity offormation fluids in production wells 206.

In some embodiments, at least two tunnels may connect to one shaft. Twoor more heater wellbores may extend from the first tunnel to the secondtunnel. Heated fluid may flow through the wellbores from the firsttunnel to the second tunnel. The second tunnel may include a productionsystem that is capable of removing the heated fluids from the formationto the surface of the formation. The second tunnel may include equipmentthat collects heated fluids from at least two of the heater wellbores.The heated fluids may be moved to the surface through a verticalproduction wellbore using a lift system.

As shown in FIG. 244, heater tunnels 1152 may include heat sourcesection 1162, connecting section 1164, and/or drilling section 1166. Inheat source section 1162, heat sources 202 may be introduced intowellbores 428. In some embodiments, heat source section 1162 isconsidered a hazardous confined space. Heat source section 1162 may beisolated from other sections in heater tunnel 1152 and/or utility tunnel1154 with material impermeable to hydrocarbon gases and/or hydrogensulfide. For example, cement or another impermeable material may be usedto seal off heat source section 1162 from heater tunnel 1152 and/orutility tunnel 1154. In some embodiments, impermeable material is usedto seal off heat source section 1162 from the heated portion of theformation to inhibit formation fluids or other hazardous fluids fromentering the heat source section. In some embodiments, at least 30 m, atleast 40 m, or at least 50 m of wellbore is between heat sources 202 andthe heater tunnel. In some embodiments, shafts 1146 proximate to heatertunnels 1152 are sealed (for example, filled with cement) after heatinghas been initiated in hydrocarbon layer 484 to inhibit gas or otherfluids from entering the shaft.

Connecting section 1164 may separate heat source section 1162 anddrilling section 1166. Connecting section 1164 may include space forperforming operations necessary for production processing. In someembodiments, heaters controls may be located in connecting section 1164.In some embodiments, connecting section 1164 includes electricalconnections, combustors, tanks, and/or pumps necessary to supportheaters and/or heat transport systems. In some embodiments, exhaust fromcombustors and/or other equipment is introduced to the hydrocarbon layerto provide additional heat.

In drilling section 1166, additional wellbores may be dug and/or thetunnel may be extended. In certain embodiments, operations in heatsource section 1162, connecting section 1164, and/or production section1166 are independent of each other. Heat source section 1162, connectingsection 1164, and/or production section 1166 may have dedicatedventilation systems and/or connections to utilities tunnel 1154.

Sections of heater tunnels 1152 and utilities tunnel 1154 may beinterconnected by connecting tunnels 1168. Connecting tunnels 1168 mayallow access and egress to heat source section 1162, connecting section1164, and/or production section 1166. Connecting tunnels 1168 andtunnels 1150 may be formed using tunneling methods known in the art.

In certain embodiments, connecting tunnels 1168 include airlocks 1170.Airlocks 1170 may help regulate the relative pressures such that thepressure in heat source section 1162 is less than the air pressure inconnecting section 1164, which is less than the air pressure inproduction section 1166. Air flow may move into heat source section 1162(the most hazardous area) to reduce the probability of a flammableatmosphere in utilities tunnel 1154, connecting section 1164, and/orproduction section 1166. Airlocks 1170 may include suitable gasdetection and alarms to ensure transformers or other electricalequipment are de-energized in the event that an unsafe flammable limitis encountered in the utilities tunnel 1154 (for example, less thanone-half of the lower flammable limit).

Heat from heat sources 202 may mobilize hydrocarbons in the hydrocarbonlayer towards production wells. Production wells may be are positionedin hydrocarbon layer below, adjacent, or above tunnels 1150. In someembodiments, production systems may be installed in one or more tunnels.The tunnel production systems may be operated from surface facilitiesand/or facilities in the tunnel. As shown in FIG. 243 production well206 is positioned in hydrocarbon layer below tunnels 1150. In someembodiments, production wells 206 connect to surface facilities, asshown in FIG. 245. As shown in FIG. 241, pipelines 208 may be located inportions of heater tunnels 1154. Pumps and associated equipment 1172 forproduction of formation fluids may be located in production chambers1174. Production chambers 1174 may be isolated from heater tunnels 1154.Risers and/or pumps in production chambers 1174 may be located inutility shafts 1148 that connect to surface 568.

In some embodiments, formation fluids may gravity drain into a piping,holding facilities and/or vertical production wells located in aproduction portion of the tunnels 1150. The production portion of thetunnel may be sealed with an impervious material (for example, cement,or a steel liner as described above). The formation fluids may be pumpedto the surface through a riser and/or vertical production well locatedin the tunnels. For example, formation fluids from four horizontalproduction wellbores spaced 60 m apart may drain into one verticalproduction well located in tunnel. The formation fluids are produced tothe surface through the vertical production well.

EXAMPLES

Non-restrictive examples are set forth below.

Temperature Limited Heater Experimental Data

FIGS. 246-261 depict experimental data for temperature limited heaters.FIG. 246 depicts electrical resistance (Ω) versus temperature (° C.) atvarious applied electrical currents for a 446 stainless steel rod with adiameter of 2.5 cm and a 410 stainless steel rod with a diameter of 2.5cm. Both rods had a length of 1.8 m. Curves 1176-1182 depict resistanceprofiles as a function of temperature for the 446 stainless steel rod at440 amps AC (curve 1176), 450 amps AC (curve 1178), 500 amps AC (curve1180), and 10 amps DC (curve 1182). Curves 1184-1190 depict resistanceprofiles as a function of temperature for the 410 stainless steel rod at400 amps AC (curve 1184), 450 amps AC (curve 1186), 500 amps AC (curve1188), 10 amps DC (curve 1190). For both rods, the resistance graduallyincreased with temperature until the Curie temperature was reached. Atthe Curie temperature, the resistance fell sharply. Above the Curietemperature, the resistance decreased slightly with increasingtemperature. Both rods show a trend of decreasing resistance withincreasing AC current. Accordingly, the turndown ratio decreased withincreasing current. Thus, the rods provide a reduced amount of heat nearand above the Curie temperature of the rods. In contrast, the resistancegradually increased with temperature through the Curie temperature withthe applied DC current.

FIG. 247 shows electrical resistance (Ω) profiles as a function oftemperature (° C.) at various applied electrical currents for a copperrod contained in a conduit of Sumitomo HCM12A (a high strength 410stainless steel). The Sumitomo conduit had a diameter of 5.1 cm, alength of 1.8 m, and a wall thickness of about 0.1 cm. Curves 1192-1202show that at all applied currents (1192: 300 amps AC; 1194: 350 amps AC;1196: 400 amps AC; 1198: 450 amps AC; 1200: 500 amps AC; 1202: 550 ampsAC), resistance increased gradually with temperature until the Curietemperature was reached. At the Curie temperature, the resistance fellsharply. As the current increased, the resistance decreased, resultingin a smaller turndown ratio.

FIG. 248 depicts electrical resistance (Ω) versus temperature (° C.) atvarious applied electrical currents for a temperature limited heater.The temperature limited heater included a 4/0 MGT-1000 furnace cableinside an outer conductor of ¾″ Schedule 80 Sandvik (Sweden) 4C54 (446stainless steel) with a 0.30 cm thick copper sheath welded onto theoutside of the Sandvik 4C54 and a length of 1.8 m. Curves 1204 through1222 show resistance profiles as a function of temperature for ACapplied currents ranging from 40 amps to 500 amps (1204: 40 amps; 1206:80 amps; 1208: 120 amps; 1210: 160 amps; 1212: 250 amps; 1214: 300 amps;1216: 350 amps; 1218: 400 amps; 1220: 450 amps; 1222: 500 amps). FIG.249 depicts the raw data for curve 1218. FIG. 250 depicts the data forselected curves 1214, 1216, 1218, 1220, 1222, and 1224. At lowercurrents (below 250 amps), the resistance increased with increasingtemperature up to the Curie temperature. At the Curie temperature, theresistance fell sharply. At higher currents (above 250 amps), theresistance decreased slightly with increasing temperature up to theCurie temperature. At the Curie temperature, the resistance fellsharply. Curve 1224 shows resistance for an applied DC electricalcurrent of 10 amps. Curve 1224 shows a steady increase in resistancewith increasing temperature, with little or no deviation at the Curietemperature.

FIG. 251 depicts power (watts per meter (W/m)) versus temperature (° C.)at various applied electrical currents for a temperature limited heater.The temperature limited heater included a 4/0 MGT-1000 furnace cableinside an outer conductor of ¾″ Schedule 80 Sandvik (Sweden) 4C54 (446stainless steel) with a 0.30 cm thick copper sheath welded onto theoutside of the Sandvik 4C54 and a length of 1.8 m. Curves 1226-1234depict power versus temperature for AC applied currents of 300 amps to500 amps (1226: 300 amps; 1228: 350 amps; 1230: 400 amps; 1232: 450amps; 1234: 500 amps). Increasing the temperature gradually decreasedthe power until the Curie temperature was reached. At the Curietemperature, the power decreased rapidly.

FIG. 252 depicts electrical resistance (mΩ) versus temperature (° C.) atvarious applied electrical currents for a temperature limited heater.The temperature limited heater included a copper rod with a diameter of1.3 cm inside an outer conductor of 2.5 cm Schedule 80 410 stainlesssteel pipe with a 0.15 cm thick copper Everdur™ (DuPont Engineering,Wilmington, Del., U.S.A.) welded sheath over the 410 stainless steelpipe and a length of 1.8 m. Curves 1236-1246 show resistance profiles asa function of temperature for AC applied currents ranging from 300 ampsto 550 amps (1236: 300 amps; 1238: 350 amps; 1240: 400 amps; 1242: 450amps; 1244: 500 amps; 1246: 550 amps). For these AC applied currents,the resistance gradually increases with increasing temperature up to theCurie temperature. At the Curie temperature, the resistance fallssharply. In contrast, curve 1248 shows resistance for an applied DCelectrical current of 10 amps. This resistance shows a steady increasewith increasing temperature, and little or no deviation at the Curietemperature.

FIG. 253 depicts data of electrical resistance (mΩ) versus temperature(° C.) for a solid 2.54 cm diameter, 1.8 m long 410 stainless steel rodat various applied electrical currents. Curves 1250, 1252, 1254, 1256,and 1258 depict resistance profiles as a function of temperature for the410 stainless steel rod at 40 amps AC (curve 1256), 70 amps AC (curve1258), 140 amps AC (curve 1250), 230 amps AC (curve 1252), and 10 ampsDC (curve 1254). For the applied AC currents of 140 amps and 230 amps,the resistance increased gradually with increasing temperature until theCurie temperature was reached. At the Curie temperature, the resistancefell sharply. In contrast, the resistance showed a gradual increase withtemperature through the Curie temperature for the applied DC current.

FIG. 254 depicts data of electrical resistance (mΩ) versus temperature(° C.) for a composite 1.75 inch (1.9 cm) diameter, 6 foot (1.8 m) longAlloy 42-6 rod with a 0.375 inch diameter copper core (the rod has anoutside diameter to copper diameter ratio of 2:1) at various appliedelectrical currents. Curves 1260, 1262, 1264, 1266, 1268, 1270, 1272,and 1274 depict resistance profiles as a function of temperature for thecopper cored alloy 42-6 rod at 300 A AC (curve 1260), 350 A AC (curve1262), 400 A AC (curve 1264), 450 A AC (curve 1266), 500 A AC (curve1268), 550 A AC (curve 1270), 600 A AC (curve 1272), and 10 A DC (curve1274). For the applied AC currents, the resistance decreased graduallywith increasing temperature until the Curie temperature was reached. Asthe temperature approaches the Curie temperature, the resistancedecreased more sharply. In contrast, the resistance showed a gradualincrease with temperature for the applied DC current.

FIG. 255 depicts data of power output (watts per foot (W/ft)) versustemperature (° C.) for a composite 1.75 inch (1.9 cm) diameter, 6 foot(1.8 m) long Alloy 42-6 rod with a 0.375 inch diameter copper core (therod has an outside diameter to copper diameter ratio of 2:1) at variousapplied electrical currents. Curves 1276, 1278, 1280, 1282, 1284, 1286,1288, and 1290 depict power as a function of temperature for the coppercored alloy 42-6 rod at 300 A AC (curve 1276), 350 A AC (curve 1278),400 A AC (curve 1280), 450 A AC (curve 1282), 500 A AC (curve 1284), 550A AC (curve 1286), 600 A AC (curve 1288), and 10 A DC (curve 1290). Forthe applied AC currents, the power output decreased gradually withincreasing temperature until the Curie temperature was reached. As thetemperature approaches the Curie temperature, the power output decreasedmore sharply. In contrast, the power output showed a relatively flatprofile with temperature for the applied DC current.

FIG. 256 depicts data for values of skin depth (cm) versus temperature(° C.) for a solid 2.54 cm diameter, 1.8 m long 410 stainless steel rodat various applied AC electrical currents. The skin depth was calculatedusing EQN. 8:

δ=R ₁ −R ₁×(1−(1/R _(AC) /R _(DC)))^(1/2);  (EQN. 8)

where δ is the skin depth, R₁ is the radius of the cylinder, R_(AC) isthe AC resistance, and R_(DC) is the DC resistance. In FIG. 256, curves1292-1310 show skin depth profiles as a function of temperature forapplied AC electrical currents over a range of 50 amps to 500 amps(1292: 50 amps; 1294: 100 amps; 1296: 150 amps; 1298: 200 amps; 1300:250 amps; 1302: 300 amps; 1304: 350 amps; 1306: 400 amps; 1380: 450amps; 1310: 500 amps). For each applied AC electrical current, the skindepth gradually increased with increasing temperature up to the Curietemperature. At the Curie temperature, the skin depth increased sharply.

FIG. 257 depicts temperature (° C.) versus time (hrs) for a temperaturelimited heater. The temperature limited heater was a 1.83 m long heaterthat included a copper rod with a diameter of 1.3 cm inside a 2.5 cmSchedule XXH 410 stainless steel pipe and a 0.325 cm copper sheath. Theheater was placed in an oven for heating. Alternating current wasapplied to the heater when the heater was in the oven. The current wasincreased over two hours and reached a relatively constant value of 400amps for the remainder of the time. Temperature of the stainless steelpipe was measured at three points at 0.46 m intervals along the lengthof the heater. Curve 1314 depicts the temperature of the pipe at a point0.46 m inside the oven and closest to the lead-in portion of the heater.Curve 1316 depicts the temperature of the pipe at a point 0.46 m fromthe end of the pipe and furthest from the lead-in portion of the heater.Curve 1318 depicts the temperature of the pipe at about a center pointof the heater. The point at the center of the heater was furtherenclosed in a 0.3 m section of 2.5 cm thick Fiberfrax® (Unifrax Corp.,Niagara Falls, N.Y., U.S.A.) insulation. The insulation was used tocreate a low thermal conductivity section on the heater (a section whereheat transfer to the surroundings is slowed or inhibited (a “hotspot”)). The temperature of the heater increased with time as shown bycurves 1318, 1316, and 1314. Curves 1318, 1316, and 1314 show that thetemperature of the heater increased to about the same value for allthree points along the length of the heater. The resulting temperatureswere substantially independent of the added Fiberfrax® insulation. Thus,the operating temperatures of the temperature limited heater weresubstantially the same despite the differences in thermal load (due tothe insulation) at each of the three points along the length of theheater. Thus, the temperature limited heater did not exceed the selectedtemperature limit in the presence of a low thermal conductivity section.

FIG. 258 depicts temperature (° C.) versus log time (hrs) data for a 2.5cm solid 410 stainless steel rod and a 2.5 cm solid 304 stainless steelrod. At a constant applied AC electrical current, the temperature ofeach rod increased with time. Curve 1320 shows data for a thermocoupleplaced on an outer surface of the 304 stainless steel rod and under alayer of insulation. Curve 1322 shows data for a thermocouple placed onan outer surface of the 304 stainless steel rod without a layer ofinsulation. Curve 1324 shows data for a thermocouple placed on an outersurface of the 410 stainless steel rod and under a layer of insulation.Curve 1326 shows data for a thermocouple placed on an outer surface ofthe 410 stainless steel rod without a layer of insulation. A comparisonof the curves shows that the temperature of the 304 stainless steel rod(curves 1320 and 1322) increased more rapidly than the temperature ofthe 410 stainless steel rod (curves 1324 and 1326). The temperature ofthe 304 stainless steel rod (curves 1320 and 1322) also reached a highervalue than the temperature of the 410 stainless steel rod (curves 1324and 1326). The temperature difference between the non-insulated sectionof the 410 stainless steel rod (curve 1326) and the insulated section ofthe 410 stainless steel rod (curve 1324) was less than the temperaturedifference between the non-insulated section of the 304 stainless steelrod (curve 1322) and the insulated section of the 304 stainless steelrod (curve 1320). The temperature of the 304 stainless steel rod wasincreasing at the termination of the experiment (curves 1320 and 1322)while the temperature of the 410 stainless steel rod had leveled out(curves 1324 and 1326). Thus, the 410 stainless steel rod (thetemperature limited heater) provided better temperature control than the304 stainless steel rod (the non-temperature limited heater) in thepresence of varying thermal loads (due to the insulation).

A 6 foot temperature limited heater element was placed in a 6 foot 347Hstainless steel canister. The heater element was connected to thecanister in a series configuration. The heater element and canister wereplaced in an oven. The oven was used to raise the temperature of theheater element and the canister. At varying temperatures, a series ofelectrical currents were passed through the heater element and returnedthrough the canister. The resistance of the heater element and the powerfactor of the heater element were determined from measurements duringpassing of the electrical currents.

FIG. 259 depicts experimentally measured electrical resistance (mΩ)versus temperature (° C.) at several currents for a temperature limitedheater with a copper core, a carbon steel ferromagnetic conductor, and a347H stainless steel support member. The ferromagnetic conductor was alow-carbon steel with a Curie temperature of 770° C. The ferromagneticconductor was sandwiched between the copper core and the 347H supportmember. The copper core had a diameter of 0.5″. The ferromagneticconductor had an outside diameter of 0.765″. The support member had anoutside diameter of 1.05″. The canister was a 3″ Schedule 160 347Hstainless steel canister.

Data 1328 depicts electrical resistance versus temperature for 300 A at60 Hz AC applied current. Data 1330 depicts resistance versustemperature for 400 A at 60 Hz AC applied current. Data 1332 depictsresistance versus temperature for 500 A at 60 Hz AC applied current.Curve 1334 depicts resistance versus temperature for 10 A DC appliedcurrent. The resistance versus temperature data indicates that the ACresistance of the temperature limited heater linearly increased up to atemperature near the Curie temperature of the ferromagnetic conductor.Near the Curie temperature, the AC resistance decreased rapidly untilthe AC resistance equaled the DC resistance above the Curie temperature.The linear dependence of the AC resistance below the Curie temperatureat least partially reflects the linear dependence of the AC resistanceof 347H at these temperatures. Thus, the linear dependence of the ACresistance below the Curie temperature indicates that the majority ofthe current is flowing through the 347H support member at thesetemperatures.

FIG. 260 depicts experimentally measured electrical resistance (mΩ)versus temperature (° C.) data at several currents for a temperaturelimited heater with a copper core, an iron-cobalt ferromagneticconductor, and a 347H stainless steel support member. The iron-cobaltferromagnetic conductor was an iron-cobalt conductor with 6% cobalt byweight and a Curie temperature of 834° C. The ferromagnetic conductorwas sandwiched between the copper core and the 347H support member. Thecopper core had a diameter of 0.465″. The ferromagnetic conductor had anoutside diameter of 0.765″. The support member had an outside diameterof 1.05″. The canister was a 3″ Schedule 160 347H stainless steelcanister.

Data 1336 depicts resistance versus temperature for 100 A at 60 Hz ACapplied current. Data 1338 depicts resistance versus temperature for 400A at 60 Hz AC applied current. Curve 1340 depicts resistance versustemperature for 10 A DC. The AC resistance of this temperature limitedheater turned down at a higher temperature than the previous temperaturelimited heater. This was due to the added cobalt increasing the Curietemperature of the ferromagnetic conductor. The AC resistance wassubstantially the same as the AC resistance of a tube of 347H steelhaving the dimensions of the support member. This indicates that themajority of the current is flowing through the 347H support member atthese temperatures. The resistance curves in FIG. 260 are generally thesame shape as the resistance curves in FIG. 259.

FIG. 261 depicts experimentally measured power factor (y-axis) versustemperature (° C.) at two AC currents for the temperature limited heaterwith the copper core, the iron-cobalt ferromagnetic conductor, and the347H stainless steel support member. Curve 1342 depicts power factorversus temperature for 100 A at 60 Hz AC applied current. Curve 1344depicts power factor versus temperature for 400 A at 60 Hz AC appliedcurrent. The power factor was close to unity (1) except for the regionaround the Curie temperature. In the region around the Curietemperature, the non-linear magnetic properties and a larger portion ofthe current flowing through the ferromagnetic conductor produceinductive effects and distortion in the heater that lowers the powerfactor. FIG. 261 shows that the minimum value of the power factor forthis heater remained above 0.85 at all temperatures in the experiment.Because only portions of the temperature limited heater used to heat asubsurface formation may be at the Curie temperature at any given pointin time and the power factor for these portions does not go below 0.85during use, the power factor for the entire temperature limited heaterwould remain above 0.85 (for example, above 0.9 or above 0.95) duringuse.

From the data in the experiments for the temperature limited heater withthe copper core, the iron-cobalt ferromagnetic conductor, and the 347Hstainless steel support member, the turndown ratio (y-axis) wascalculated as a function of the maximum power (W/m) delivered by thetemperature limited heater. The results of these calculations aredepicted in FIG. 262. The curve in FIG. 262 shows that the turndownratio (y-axis) remains above 2 for heater powers up to approximately2000 W/m. This curve is used to determine the ability of a heater toeffectively provide heat output in a sustainable manner. A temperaturelimited heater with the curve similar to the curve in FIG. 262 would beable to provide sufficient heat output while maintaining temperaturelimiting properties that inhibit the heater from overheating ormalfunctioning.

A theoretical model has been used to predict the experimental results.The theoretical model is based on an analytical solution for the ACresistance of a composite conductor. The composite conductor has a thinlayer of ferromagnetic material, with a relative magnetic permeabilityμ₂/μ₀>>1, sandwiched between two non-ferromagnetic materials, whoserelative magnetic permeabilities, μ₁/μ₀ and μ₃/μ₀, are close to unityand within which skin effects are negligible. An assumption in the modelis that the ferromagnetic material is treated as linear. In addition,the way in which the relative magnetic permeability, μ₂/μ₀, is extractedfrom magnetic data for use in the model is far from rigorous.

Magnetic data was obtained for carbon steel as a ferromagnetic material.B versus H curves, and hence relative permeabilities, were obtained fromthe magnetic data at various temperatures up to 1100° F. and magneticfields up to 200 Oe (oersteds). A correlation was found that fitted thedata well through the maximum permeability and beyond. FIG. 263 depictsexamples of relative magnetic permeability (y-axis) versus magneticfield (Oe) for both the found correlations and raw data for carbonsteel. Data 1346 is raw data for carbon steel at 400° F. Data 1348 israw data for carbon steel at 1000° F. Curve 1350 is the foundcorrelation for carbon steel at 400° F. Curve 1352 is the foundcorrelation for carbon steel at 1000° F.

For the dimensions and materials of the copper/carbon steel/347H heaterelement in the experiments above, theoretical calculations were carriedout to calculate magnetic field at the outer surface of the carbon steelas a function of skin depth. Results of the theoretical calculationswere presented on the same plot as skin depth versus magnetic field fromthe correlations applied to the magnetic data from FIG. 263. Thetheoretical calculations and correlations were made for fourtemperatures (200° F., 500° F., 800° F., and 1100° F.) and five totalroot-mean-square (RMS) currents (100 A, 200 A, 300 A, 400 A, and 500 A).

FIG. 264 shows the resulting plots of skin depth (in) versus magneticfield (Oe) for all four temperatures and 400 A current. Curve 1354 isthe correlation from magnetic data at 200° F. Curve 1356 is thecorrelation from magnetic data at 500° F. Curve 1358 is the correlationfrom magnetic data at 800° F. Curve 1360 is the correlation frommagnetic data at 1100° F. Curve 1362 is the theoretical calculation atthe outer surface of the carbon steel as a function of skin depth at200° F. Curve 1364 is the theoretical calculation at the outer surfaceof the carbon steel as a function of skin depth at 500° F. Curve 1366 isthe theoretical calculation at the outer surface of the carbon steel asa function of skin depth at 800° F. Curve 1368 is the theoreticalcalculation at the outer surface of the carbon steel as a function ofskin depth at 1100° F.

The skin depths obtained from the intersections of the same temperaturecurves in FIG. 264 were input into equations based on theory and the ACresistance per unit length was calculated. The total AC resistance ofthe entire heater, including that of the canister, was subsequentlycalculated. A comparison between the experimental and numerical(calculated) results is shown in FIG. 265 for currents of 300 A(experimental data 1370 and numerical curve 1372), 400 A (experimentaldata 1374 and numerical curve 1376), and 500 A (experimental data 1378and numerical curve 1380). Though the numerical results exhibit asteeper trend than the experimental results, the theoretical modelcaptures the close bunching of the experimental data, and the overallvalues are quite reasonable given the assumptions involved in thetheoretical model. For example, one assumption involved the use of apermeability derived from a quasistatic B-H curve to treat a dynamicsystem.

One feature of the theoretical model describing the flow of alternatingcurrent in the three-part temperature limited heater is that the ACresistance does not fall off monotonically with increasing skin depth.FIG. 266 shows the AC resistance (mΩ) per foot of the heater element asa function of skin depth (in.) at 1100° F. calculated from thetheoretical model. The AC resistance may be maximized by selecting theskin depth that is at the peak of the non-monotonical portion of theresistance versus skin depth profile (for example, at about 0.23 in. inFIG. 266).

FIG. 267 shows the power generated per unit length (W/ft) in each heatercomponent (curve 1382 (copper core), curve 1384 (carbon steel), curve1386 (347H outer layer), and curve 1388 (total)) versus skin depth(in.). As expected, the power dissipation in the 347H falls off whilethe power dissipation in the copper core increases as the skin depthincreases. The maximum power dissipation in the carbon steel occurs atthe skin depth of about 0.23 inches and is expected to correspond to theminimum in the power factor, as shown in FIG. 261. The current densityin the carbon steel behaves like a damped wave of wavelength λ=2π

and the effect of this wavelength on the boundary conditions at thecopper/carbon steel and carbon steel/347H interface may be behind thestructure in FIG. 266. For example, the local minimum in AC resistanceis close to the value at which the thickness of the carbon steel layercorresponds to λ/4. Formulae may be developed that describe the shapesof the AC resistance versus temperature profiles of temperature limitedheaters for use in simulating the performance of the heaters in aparticular embodiment. The data in FIGS. 259 and 260 show that theresistances initially rise linearly, then drop off increasingly steeplytowards the DC lines.

FIGS. 268A-C compare the results of the theoretical calculations withexperimental data at 300 A (FIG. 268A), 400 A (FIG. 268B) and 500 A(FIG. 268C). FIG. 268A depicts electrical resistance (mΩ) versustemperature (° F.) at 300 A. Data 1390 is the experimental data at 300A. Curve 1392 is the theoretical calculation at 300 A. Curve 1394 is aplot of resistance versus temperature at 10 A DC. FIG. 268B depictselectrical resistance (mΩ) versus temperature (° F.) at 400 A. Data 1396is the experimental data at 400 A. Curve 1398 is the theoreticalcalculation at 400 A. Curve 1400 is a plot of resistance versustemperature at 10 A DC. FIG. 268C depicts electrical resistance (mΩ)versus temperature (° F.) at 500 A. Data 1402 is the experimental dataat 500 A. Curve 1404 is the theoretical calculation at 500 A. Curve 1406is a plot of resistance versus temperature at 10 A DC.

Temperature Limited Heater Simulations

A numerical simulation (FLUENT available from Fluent USA, Lebanon, N.H.,U.S.A.) was used to compare operation of temperature limited heaterswith three turndown ratios. The simulation was done for heaters in anoil shale formation (Green River oil shale). Simulation conditions were:

-   -   61 m length conductor-in-conduit temperature limited heaters        (center conductor (2.54 cm diameter), conduit outer diameter 7.3        cm)    -   downhole heater test field richness profile for an oil shale        formation    -   16.5 cm (6.5 inch) diameter wellbores at 9.14 m spacing between        wellbores on triangular spacing    -   200 hours power ramp-up time to 820 watts/m initial heat        injection rate    -   constant current operation after ramp up    -   Curie temperature of 720.6° C. for heater    -   formation will swell and touch the heater canisters for oil        shale richnesses at least 0.14 L/kg (35 gals/ton)

FIG. 269 displays temperature (° C.) of a center conductor of aconductor-in-conduit heater as a function of formation depth (m) for atemperature limited heater with a turndown ratio of 2:1. Curves1408-1430 depict temperature profiles in the formation at various timesranging from 8 days after the start of heating to 675 days after thestart of heating (1408: 8 days, 1410: 50 days, 1412: 91 days, 1414: 133days, 1416: 216 days, 1418: 300 days, 1420: 383 days, 1422: 466 days,1424: 550 days, 1426: 591 days, 1428: 633 days, 1430: 675 days). At aturndown ratio of 2:1, the Curie temperature of 720.6° C. was exceededafter 466 days in the richest oil shale layers. FIG. 270 shows thecorresponding heater heat flux (W/m) through the formation for aturndown ratio of 2:1 along with the oil shale richness (1/kg) profile(curve 1432). Curves 1434-1466 show the heat flux profiles at varioustimes from 8 days after the start of heating to 633 days after the startof heating (1434: 8 days; 1436: 50 days; 1438: 91 days; 1440: 133 days;1444: 175 days; 1446: 216 days; 1448: 258 days; 1450: 300 days; 1442:341 days; 1452: 383 days; 1454: 425 days; 1456: 466 days; 1458: 508days; 1460: 550 days; 1462: 591 days; 1464: 633 days; 1466: 675 days).

At a turndown ratio of 2:1, the center conductor temperature exceededthe Curie temperature in the richest oil shale layers.

FIG. 271 displays heater temperature (° C.) as a function of formationdepth (m) for a turndown ratio of 3:1. Curves 1468-1490 show temperatureprofiles through the formation at various times ranging from 12 daysafter the start of heating to 703 days after the start of heating (1468:12 days; 1470: 33 days; 1472: 62 days; 1474: 102 days; 1476: 146 days;1478: 205 days; 1480: 271 days; 1482: 354 days; 1484: 467 days; 1486:605 days; 1488: 662 days; 1490: 703 days). At a turndown ratio of 3:1,the Curie temperature was approached after 703 days. FIG. 272 shows thecorresponding heater heat flux (W/m) through the formation for aturndown ratio of 3:1 along with the oil shale richness (1/kg) profile(curve 1492). Curves 1494-1514 show the heat flux profiles at varioustimes from 12 days after the start of heating to 605 days after thestart of heating (1494: 12 days, 1496: 32 days, 1498: 62 days, 1500: 102days, 1502: 146 days, 1504: 205 days, 1506: 271 days, 1508: 354 days,1510: 467 days, 1512: 605 days, 1514: 749 days). The center conductortemperature never exceeded the Curie temperature for the turndown ratioof 3:1. The center conductor temperature also showed a relatively flattemperature profile for the 3:1 turndown ratio.

FIG. 273 shows heater temperature (° C.) as a function of formationdepth (m) for a turndown ratio of 4:1. Curves 1516-1536 show temperatureprofiles through the formation at various times ranging from 12 daysafter the start of heating to 467 days after the start of heating (1516:12 days; 1518: 33 days; 1520: 62 days; 1522: 102 days, 1524: 147 days;1526: 205 days; 1528: 272 days; 1530: 354 days; 1532: 467 days; 1534:606 days, 1536: 678 days).

At a turndown ratio of 4:1, the Curie temperature was not exceeded evenafter 678 days. The center conductor temperature never exceeded theCurie temperature for the turndown ratio of 4:1. The center conductorshowed a temperature profile for the 4:1 turndown ratio that wassomewhat flatter than the temperature profile for the 3:1 turndownratio. These simulations show that the heater temperature stays at orbelow the Curie temperature for a longer time at higher turndown ratios.For this oil shale richness profile, a turndown ratio of at least 3:1may be desirable.

Simulations have been performed to compare the use of temperaturelimited heaters and non-temperature limited heaters in an oil shaleformation. Simulation data was produced for conductor-in-conduit heatersplaced in 16.5 cm (6.5 inch) diameter wellbores with 12.2 m (40 feet)spacing between heaters using a formation simulator (for example, STARS)and a near wellbore simulator (for example, ABAQUS from ABAQUS, Inc.,Providence, R.I., U.S.A.). Standard conductor-in-conduit heatersincluded 304 stainless steel conductors and conduits. Temperaturelimited conductor-in-conduit heaters included a metal with a Curietemperature of 760° C. for conductors and conduits. Results from thesimulations are depicted in FIGS. 274-276.

FIG. 274 depicts heater temperature (° C.) at the conductor of aconductor-in-conduit heater versus depth (m) of the heater in theformation for a simulation after 20,000 hours of operation. Heater powerwas set at 820 watts/meter until 760° C. was reached, and the power wasreduced to inhibit overheating. Curve 1538 depicts the conductortemperature for standard conductor-in-conduit heaters. Curve 1538 showsthat a large variance in conductor temperature and a significant numberof hot spots developed along the length of the conductor. Thetemperature of the conductor had a minimum value of 490° C. Curve 1540depicts conductor temperature for temperature limitedconductor-in-conduit heaters. As shown in FIG. 274, temperaturedistribution along the length of the conductor was more controlled forthe temperature limited heaters. In addition, the operating temperatureof the conductor was 730° C. for the temperature limited heaters. Thus,more heat input would be provided to the formation for a similar heaterpower using temperature limited heaters.

FIG. 275 depicts heater heat flux (W/m) versus time (yrs) for theheaters used in the simulation for heating oil shale. Curve 1542 depictsheat flux for standard conductor-in-conduit heaters. Curve 1544 depictsheat flux for temperature limited conductor-in-conduit heaters. As shownin FIG. 275, heat flux for the temperature limited heaters wasmaintained at a higher value for a longer period of time than heat fluxfor standard heaters. The higher heat flux may provide more uniform andfaster heating of the formation.

FIG. 276 depicts cumulative heat input (kJ/m) (kilojoules per meter)versus time (yrs) for the heaters used in the simulation for heating oilshale. Curve 1546 depicts cumulative heat input for standardconductor-in-conduit heaters. Curve 1548 depicts cumulative heat inputfor temperature limited conductor-in-conduit heaters. As shown in FIG.276, cumulative heat input for the temperature limited heaters increasedfaster than cumulative heat input for standard heaters. The fasteraccumulation of heat in the formation using temperature limited heatersmay decrease the time needed for retorting the formation. Onset ofretorting of the oil shale formation may begin around an averagecumulative heat input of 1.1×10⁸ kJ/meter. This value of cumulative heatinput is reached around 5 years for temperature limited heaters andbetween 9 and 10 years for standard heaters.

High Voltage Insulated Conductors

Simulations (using STARS) were carried out to simulate heating aformation using the heater embodiments shown in FIGS. 61 and 63. Thesimulation used insulated conductor heaters with Alloy 180 cores withvarious diameters inside jackets with a diameter of 0.625″ and magnesiumoxide insulation between the cores and jackets (for example, core 542,electrical insulator 534, and jacket 540 in FIGS. 61 and 63). Thevarious core diameters used were 0.125″, 0.115″, 0.1084″, and 0.1016″.The various core diameters produced selected amounts of heater power inthe heater (using three insulated conductors in the conduit for theheater). FIG. 277 depicts a plot of heater power (W/ft) versus corediameter (in.). As shown in FIG. 277, core diameters of 0.1016″ providesa heater power of about 220 W/ft; core diameters of 0.1084″ provides aheater power of about 250 W/ft; core diameters of 0.115″ provides aheater power of about 280 W/ft; and core diameters of 0.125″ provides aheater power of about 333 W/ft.

For the simulation, the insulated conductor heaters were placed in aconduit (for example, conduit 570 in FIGS. 61 and 63) with an outsidediameter of 1.75″. The conduit with the insulated conductors was placedin another outside conduit (an outside tubular) that had an outsidediameter of 3.5″ and an inside diameter of 3.094″. The entire heaterassembly was placed in a 6″ wellbore in the formation.

The simulation was used to simulate heating of 2000 feet of formationdepth (target zone) below an overburden of 1225 feet. The voltageprovided to the heaters was a constant voltage of 4160 V. The formationproperties used were for a typical tar sands formation in the PeaceRiver field in Alberta, Canada. The heater spacing was 40 feet.

FIG. 278 depicts power, resistance, and current versus temperature (°F.) for a heater with core diameters of 0.105″. Plot 1550 depicts power(W/ft)(left axis) versus temperature. Plot 1552 depicts current (I) inamps (right axis) versus temperature. Plot 1554 depicts resistance (R)in ohms (right axis) versus temperature. As shown in FIG. 278, heaterpower decreased linearly with increasing temperature with resistance andcurrent varying slightly over the temperature range.

FIG. 279 depicts actual heater power (W/ft) versus time (days) duringthe simulation for three different heater designs (three power outputsbased on three core diameters). Plot 1556 depicts power for a heaterwith a designed heater output of 220 W/ft (0.1016″ core diameters). Plot1558 depicts power for a heater with a designed heater output of 250W/ft (0.1084″ core diameters). Plot 1560 depicts power for a heater witha designed heater output of 280 W/ft (0.115″ core diameters). As shownin FIG. 279, the heater power outputs decrease slightly with time butremain relatively constant over the duration of the simulation.

FIG. 280 depicts heater element temperature (core temperature) (° F.)and average formation temperature (° F.) versus time (days) for threedifferent heater designs (three power outputs based on three corediameters). Plot 1562 depicts heater temperature for the heater with thedesigned heater output of 220 W/ft (0.1016″ core diameters). Plot 1564depicts heater temperature for the heater with the designed heateroutput of 250 W/ft (0.1084″ core diameters). Plot 1566 depicts heatertemperature for the heater with the designed heater output of 280 W/ft(0.115″ core diameters). As shown by plots 1566, 1564, and 1562, theheater temperatures increased relatively linearly over time.

Plot 1568 depicts average formation temperature using the heater withthe designed heater output of 220 W/ft (0.1016″ core diameters). Plot1570 depicts average formation temperature using the heater with thedesigned heater output of 250 W/ft (0.1084″ core diameters). Plot 1572depicts average formation temperature using the heater with the designedheater output of 280 W/ft (0.115″ core diameters). Plot 1574 depicts thetarget temperature for the formation of 527° F. As shown by plots 1572,1570, and 1568, the average formation temperatures increased relativelylinearly over time. In addition, time to reach the target formationtemperature decreased with the higher powered heaters. For the 220 W/ftheater, the time to reach the target formation temperature was about1322 days. For the 250 W/ft heater, the time to reach the targetformation temperature was about 1145 days. For the 280 W/ft heater, thetime to reach the target formation temperature was about 1055 days. Thesimulation shows that heater embodiments shown in FIGS. 61 and 63 haverelatively linear heating properties and may be used to heat subsurfaceformations to desired temperatures.

Tubular Induction Heater

Non-linear analysis was used to calculate power versus temperaturecurves at three values of currents for a tubular induction heater. Thetubular was a 6″ Schedule 80 carbon steel tubular. The tubular was usedin heater similar to the heater depicted in FIG. 115. FIG. 281 depictsplots of power versus temperature at the three currents. Plot 1576depicts power versus temperature for a current of 750 A. Plot 1578depicts power versus temperature for a current of 1000 A. Plot 1580depicts power versus temperature for a current of 1250 A. As shown bythe plots in FIG. 281, the turndown ratio for the tubular inductionheater is relatively sharp. The plots also show the effect of current onthe power output for the tubular induction heater.

Insulated Conductor In Conduit With Fluid Between The Conductor And TheConduit Simulations

Simulations were performed for a heater including a vertical insulatedconductor in a cylindrical conduit (for example, the heater depicted inFIG. 68) with either air, solar salt, or tin between the insulatedconductor and the conduit. The simulation used a vertical steady state,two dimensional axi-symmetric system with a temperature boundarycondition and a constant power injection rate by the insulated conductorof 300 watts per foot. Values of the temperature boundary condition(temperature of the outside surface of the conduit) were set at 300° C.,500° C. or 700° C. Air was assumed to be an ideal gas. Somerepresentative properties of the solar salt and the tin are given inTable 2. The software used for the simulations was ANSYS CFX 11. Theturbulence model was a shear stress transport model, which is anaccurate model to solve the heat transfer rate in the near wall region.Table 3 shows the heat transfer modes used for each material.

TABLE 2 Molten solar salt Molten tin Density (kg/m³) 1794 6800 Dynamicviscosity (Pa s) 2.10 × 10⁻³ 0.001 Specific heat capacity (J/kg K) 15493180 Thermal conductivity (W/m K) 0.5365 33.5 Thermal expansivity (1/K)2.50 × 10⁻⁴ 2.00 × 10⁻⁴

TABLE 3 Material Heat Transfer Modes Air Radiation, convection, andconduction Solar salt Radiation, convection, and conduction TinConvection and conduction

The simulations were used to examine three different insulated conduitand conduit embodiments. Table 4 shows the sizes of the insulatedconductors and conduits used in the simulations.

TABLE 4 Insulated conductor: Case 1 Case 2 Case 3 core radius (cm): 0.50.25 0.25 insulation thickness (cm) 0.3 0.15 0.15 jacket thickness (cm)0.1 0.05 0.05 Nominal conduit size (inches) 2 2 3.5

FIGS. 282-284 depict temperature profiles for case 1 heaters with theboundary condition temperature set at 500° C. The temperature axis ofthe three figures is different to emphasize the shape of the curves.FIG. 282 depicts temperature versus radial distance for the heater withair between the insulated conductor and the conduit. FIG. 283 depictstemperature versus radial distance for the heater with molten solar saltbetween the insulated conductor and the conduit. FIG. 284 depictstemperature versus radial distance for the heater with molten tinbetween the insulated conductor and the conduit. As shown by the shapeof the curves in FIGS. 282-284, the effect of natural convection for themolten salt is much stronger than the effect of natural convection forair or molten tin. Table 5 shows calculated values of the Prandtl number(Pr), Grashof number (Gr) and Rayleigh number (Ra) for the solar saltand tin when the boundary condition was set at 500° C.

TABLE 5 Material Pr Gr Ra Solar Salt 6.06 4.33 × 10⁵ 2.63 × 10⁶ Tin 0.092.98 × 10⁵ 2.83 × 10⁵

FIG. 285 depicts simulation results for case 1 heaters with the threedifferent materials between the insulated conductors and the conduits,and with boundary conditions of 700° C., 500° C. and 300° C. Region A isthe distance from the center of the insulated conductor to the outsidesurface of the insulated conductor. Region B is the distance from theoutside of the insulated conductor to the inside surface of the conduit.Region C is the distance from the inside surface of the conduit to theoutside surface of the conduit. Curve 1582 depicts the temperatureprofile for air between the insulated conductor and the conduit with theboundary condition for the outer surface of the conduit set at 700° C.Curve 1584 depicts the temperature profile for molten solar salt betweenthe insulated conductor and the conduit with the boundary condition forthe outer surface of the conduit set at 700° C. Curve 1586 depicts thetemperature profile for molten tin between the insulated conductor andthe conduit with the boundary condition for the outer surface of theconduit set at 700° C. Curves 1588, 1590, and 1592 depict thetemperature profiles for air, molten salt, and molten tin respectivelywith the boundary condition for the outer surface of the conduit set at500° C. Curves 1594, 1596, and 1598 depict the temperature profiles forair, molten salt, and molten tin respectively with the boundarycondition for the outer surface of the conduit set at 300° C.

Having air in the gap between the insulated conductor and the conduitresults in the largest temperature difference between the insulatedconductor and the conduit for a given boundary condition temperature,especially for the lower boundary condition of 300° C. For boundarycondition temperatures of 500° C. and 700° C., the temperaturedifference between the insulated conductor and the conduit for themolten salt and air is significantly reduced because of the increase inradiative heat transfer with increasing temperature.

FIG. 286 depicts simulation results for case 2 heaters with the threedifferent materials between the insulated conductors and the conduits,and with boundary conditions of 700° C., 500° C. and 300° C. Region A isthe distance from the center of the insulated conductor to the outsidesurface of the insulated conductor. Region B is the distance from theoutside of the insulated conductor to the inside surface of the conduit.Region C is the distance from the inside surface of the conduit to theoutside surface of the conduit. Curves 1582, 1584, and 1586 depict thetemperature profiles for air, molten salt, and molten tin, respectively,with the boundary condition for the outer surface of the conduit set at700° C. Curves 1588, 1590, and 1592 depict the temperature profiles forair, molten salt, and molten tin, respectively, with the boundarycondition for the outer surface of the conduit set at 500° C. Curves1594, 1596, and 1598 depict the temperature profiles for air, moltensalt, and molten tin, respectively, with the boundary condition for theouter surface of the conduit set at 300° C. As can be seen by comparingFIG. 285 with FIG. 286, decreasing the heater radius results in higherinsulated conductor temperature and therefore larger temperaturedifferences between the insulated conductor and the conduit. As seen inFIG. 285 and in FIG. 286, the temperature profile in the materialbetween the insulated conductor and the conduit falls rapidly for themolten salt and is only slightly higher in temperature than thetemperature profile established when the material is molten metal. Therapid temperature fall for the molten salt may be due to naturalconvection in the molten salt.

FIG. 287 depicts simulation results for case 3 heaters with the threedifferent materials between the insulated conductors and the conduits,and with boundary conditions of 700° C., 500° C. and 300° C. Region A isthe distance from the center of the insulated conductor to the outsidesurface of the insulated conductor. Region B is the distance from theoutside of the insulated conductor to the inside surface of the conduit.Region C is the distance from the inside surface of the conduit to theoutside surface of the conduit. Curves 1582, 1584, and 1586 depict thetemperature profiles for air, molten salt, and molten tin, respectively,with the boundary condition for the outer surface of the conduit set at700° C. Curves 1588, 1590, and 1592 depict the temperature profiles forair, molten salt, and molten tin, respectively, with the boundarycondition for the outer surface of the conduit set at 500° C. Curves1594, 1596, and 1598 depict the temperature profiles for air, moltensalt, and molten tin, respectively, with the boundary condition for theouter surface of the conduit set at 300° C. As can be seen by comparingFIG. 286 with FIG. 287, increasing the size of the conduit results in alower insulated conductor temperature, and a lower and more uniformtemperature in Region B.

FIG. 288 depicts simulation results of temperature (° C.) versus radialdistance (mm) for the three cases examined in the simulation with moltensalt between the insulated conductors and the conduits, and where theboundary condition was set at 500° C. Curve 1600 depicts the results forcase 1, curve 1602 depicts the results for case 2, and curve 1604depicts the results for case 3. The lower insulated conductortemperature (for example, when r=0) for curve 1600 may result from thelarger size of the insulated conductor.

The temperature of insulated conductor (for example, at r=0) is lowerfor curve 1604 than for curve 1602. Also, the temperature of the moltensalt away from the near insulated conductor and near conduit regions islower for curve 1604 than for curves 1600, 1602. The Rayleigh number isproportional to x³, where x is the radial thickness of the fluid. Forthe large conduit (i.e., case 3 and curve 1604), the Rayleigh number isabout 8 times that of the small conduit (i.e., case 2 and curve 1602).The larger Rayleigh number implies that natural convection for the saltin the large conduit is much stronger than the natural convection in thesmaller conduit. The stronger natural convection may increase the heattransfer through the molten salt and reduce the temperature of theinsulated conductor.

Tar Sands Simulation

A STARS simulation was used to simulate heating of a tar sands formationusing the heater well pattern depicted in FIG. 159. The heaters had ahorizontal length in the tar sands formation of 600 m. The heating rateof the heaters was about 750 W/m. Production well 206B, depicted in FIG.159, was used at the production well in the simulation. The bottom holepressure in the horizontal production well was maintained at about 690kPa. The tar sands formation properties were based on Athabasca tarsands. Input properties for the tar sands formation simulation included:initial porosity equals 0.28; initial oil saturation equals 0.8; initialwater saturation equals 0.2; initial gas saturation equals 0.0; initialvertical permeability equals 250 millidarcy; initial horizontalpermeability equals 500 millidarcy; initial K_(v)/K_(h) equals 0.5;hydrocarbon layer thickness equals 28 m; depth of hydrocarbon layerequals 587 m; initial reservoir pressure equals 3771 kPa; distancebetween production well and lower boundary of hydrocarbon layer equals2.5 meter; distance of topmost heaters and overburden equals 9 meter;spacing between heaters equals 9.5 meter; initial hydrocarbon layertemperature equals 18.6° C.; viscosity at initial temperature equals 53Pa·s (53000 cp); and gas to oil ratio (GOR) in the tar equals 50standard cubic feet/standard barrel. The heaters were constant wattageheaters with a highest temperature of 538° C. at the sand face and aheater power of 755 W/m. The heater wells had a diameter of 15.2 cm.

FIG. 289 depicts a temperature profile in the formation after 360 daysusing the STARS simulation. The hottest spots are at or near heaters438. The temperature profile shows that portions of the formationbetween the heaters are warmer than other portions of the formation.These warmer portions create more mobility between the heaters andcreate a flow path for fluids in the formation to drain downwardstowards the production wells.

FIG. 290 depicts an oil saturation profile in the formation after 360days using the STARS simulation. Oil saturation is shown on a scale of0.00 to 1.00 with 1.00 being 100% oil saturation. The oil saturationscale is shown in the sidebar. Oil saturation, at 360 days, is somewhatlower at heaters 438 and production well 206B. FIG. 291 depicts the oilsaturation profile in the formation after 1095 days using the STARSsimulation. Oil saturation decreased overall in the formation with agreater decrease in oil saturation near the heaters and in between theheaters after 1095 days. FIG. 292 depicts the oil saturation profile inthe formation after 1470 days using the STARS simulation. The oilsaturation profile in FIG. 292 shows that the oil is mobilized andflowing towards the lower portions of the formation. FIG. 293 depictsthe oil saturation profile in the formation after 1826 days using theSTARS simulation. The oil saturation is low in a majority of theformation with some higher oil saturation remaining at or near thebottom of the formation in portions below production well 206B. This oilsaturation profile shows that a majority of oil in the formation hasbeen produced from the formation after 1826 days.

FIG. 294 depicts the temperature profile in the formation after 1826days using the STARS simulation. The temperature profile shows arelatively uniform temperature profile in the formation except atheaters 438 and in the extreme (corner) portions of the formation. Thetemperature profile shows that a flow path has been created between theheaters and to production well 206B.

FIG. 295 depicts oil production rate 1606 (bbl/day)(left axis) and gasproduction rate 1608 (ft³/day)(right axis) versus time (years). The oilproduction and gas production plots show that oil is produced at earlystages (0-1.5 years) of production with little gas production. The oilproduced during this time was most likely heavier mobilized oil that isunpyrolyzed. After about 1.5 years, gas production increased sharply asoil production decreased sharply. The gas production rate quicklydecreased at about 2 years. Oil production then slowly increased up to amaximum production around about 3.75 years. Oil production then slowlydecreased as oil in the formation was depleted.

From the STARS simulation, the ratio of energy out (produced oil and gasenergy content) versus energy in (heater input into the formation) wascalculated to be about 12 to 1 after about 5 years. The total recoverypercentage of oil in place was calculated to be about 60% after about 5years. Thus, producing oil from a tar sands formation using anembodiment of the heater and production well pattern depicted in FIG.159 may produce high oil recoveries and high energy out to energy inratios.

Tar Sands Example

A STARS simulation was used in combination with experimental analysis tosimulate an in situ heat treatment process of a tar sands formation.Heating conditions for the experimental analysis were determined fromreservoir simulations. The experimental analysis included heating a cellof tar sands from the formation to a selected temperature and thenreducing the pressure of the cell (blow down) to 100 psig. The processwas repeated for several different selected temperatures. While heatingthe cells, formation and fluid properties of the cells were monitoredwhile producing fluids to maintain the pressure below an optimumpressure of 12 MPa before blow down and while producing fluids afterblow down (although the pressure may have reached higher pressures insome cases, the pressure was quickly adjusted and does not affect theresults of the experiments). FIGS. 296-303 depict results from thesimulation and experiments.

FIG. 296 depicts weight percentage of original bitumen in place (OBIP)(left axis) and volume percentage of OBIP (right axis) versustemperature (° C.). The term “OBIP” refers, in these experiments, to theamount of bitumen that was in the laboratory vessel with 100% being theoriginal amount of bitumen in the laboratory vessel. Plot 1610 depictsbitumen conversion (correlated to weight percentage of OBIP). Plot 1610shows that bitumen conversion began to be significant at about 270° C.and ended at about 340° C. The bitumen conversion was relatively linearover the temperature range.

Plot 1612 depicts barrels of oil equivalent from producing fluids andproduction at blow down (correlated to volume percentage of OBIP). Plot1614 depicts barrels of oil equivalent from producing fluids (correlatedto volume percentage of OBIP). Plot 1616 depicts oil production fromproducing fluids (correlated to volume percentage of OBIP). Plot 1618depicts barrels of oil equivalent from production at blow down(correlated to volume percentage of OBIP). Plot 1620 depicts oilproduction at blow down (correlated to volume percentage of OBIP). Asshown in FIG. 296, the production volume began to significantly increaseas bitumen conversion began at about 270° C. with a significant portionof the oil and barrels of oil equivalent (the production volume) comingfrom producing fluids and only some volume coming from the blow down.

FIG. 297 depicts bitumen conversion percentage (weight percentage of(OBIP)) (left axis) and oil, gas, and coke weight percentage (as aweight percentage of OBIP) (right axis) versus temperature (° C.). Plot1622 depicts bitumen conversion (correlated to weight percentage ofOBIP). Plot 1624 depicts oil production from producing fluids correlatedto weight percentage of OBIP (right axis). Plot 1626 depicts cokeproduction correlated to weight percentage of OBIP (right axis). Plot1628 depicts gas production from producing fluids correlated to weightpercentage of OBIP (right axis). Plot 1630 depicts oil production fromblow down production correlated to weight percentage of OBIP (rightaxis). Plot 1632 depicts gas production from blow down productioncorrelated to weight percentage of OBIP (right axis). FIG. 297 showsthat coke production begins to increase at about 280° C. and maximizesaround 340° C. FIG. 297 also shows that the majority of oil and gasproduction is from produced fluids with only a small fraction from blowdown production.

FIG. 298 depicts API gravity (°) (left axis) of produced fluids, blowdown production, and oil left in place along with pressure (psig) (rightaxis) versus temperature (° C.). Plot 1634 depicts API gravity ofproduced fluids versus temperature. Plot 1636 depicts API gravity offluids produced at blow down versus temperature. Plot 1638 depictspressure versus temperature. Plot 1640 depicts API gravity of oil(bitumen) in the formation versus temperature. FIG. 298 shows that theAPI gravity of the oil in the formation remains relatively constant atabout 100 API and that the API gravity of produced fluids and fluidsproduced at blow down increases slightly at blow down.

FIGS. 299A-D depict gas-to-oil ratios (GOR) in thousand cubic feet perbarrel (Mcf/bbl) (y-axis) versus temperature (° C.) (x-axis) fordifferent types of gas at a low temperature blow down (about 277° C.)and a high temperature blow down (at about 290° C.). FIG. 299A depictsthe GOR versus temperature for carbon dioxide (CO₂). Plot 1642 depictsthe GOR for the low temperature blow down. Plot 1644 depicts the GOR forthe high temperature blow down. FIG. 299B depicts the GOR versustemperature for hydrocarbons. FIG. 299C depicts the GOR for hydrogensulfide (H₂S). FIG. 299D depicts the GOR for hydrogen (H₂). In FIGS.299B-D, the GORs were approximately the same for both the lowtemperature and high temperature blow downs. The GORs for CO₂ (shown inFIG. 299) was different for the high temperature blow down and the lowtemperature blow down. The reason for the difference in the GORs for CO₂may be that CO₂ was produced early (at low temperatures) by the hydrousdecomposition of dolomite and other carbonate minerals and clays. Atthese low temperatures, there was hardly any produced oil so the GOR isvery high because the denominator in the ratio is practically zero. Theother gases (hydrocarbons, H₂S, and H₂) were produced concurrently withthe oil either because they were all generated by the upgrading ofbitumen (for example, hydrocarbons, H₂, and oil) or because they weregenerated by the decomposition of minerals (such as pyrite) in the sametemperature range as that of bitumen upgrading. Thus, when the GOR wascalculated, the denominator (oil) was non zero for hydrocarbons, H₂S,and H₂.

FIG. 300 depicts coke yield (weight percentage) (y-axis) versustemperature (° C.) (x-axis). Plot 1646 depicts bitumen and kerogen cokeas a weight percent of original mass in the formation. Plot 1648 depictsbitumen coke as a weight percent of original bitumen in place (OBIP) inthe formation. FIG. 300 shows that kerogen coke is already present at atemperature of about 260° C. (the lowest temperature cell experiment)while bitumen coke begins to form at about 280° C. and maximizes atabout 340° C.

FIGS. 301A-D depict assessed hydrocarbon isomer shifts in fluidsproduced from the experimental cells as a function of temperature andbitumen conversion. Bitumen conversion and temperature increase fromleft to right in the plots in FIGS. 301A-D with the minimum bitumenconversion being 10%, the maximum bitumen conversion being 100%, theminimum temperature being 277° C., and the maximum temperature being350° C. The arrows in FIGS. 301A-D show the direction of increasingbitumen conversion and temperature.

FIG. 301A depicts the hydrocarbon isomer shift of n-butane-δ¹³C₄percentage (y-axis) versus propane-δ¹³C₃ percentage (x-axis). FIG. 301Bdepicts the hydrocarbon isomer shift of n-pentane-δ¹³C₅ percentage(y-axis) versus propane-δ¹³C₃ percentage (x-axis). FIG. 301C depicts thehydrocarbon isomer shift of n-pentane-δ¹³C₅ percentage (y-axis) versusn-butane-δ¹³C₄ percentage (x-axis). FIG. 301D depicts the hydrocarbonisomer shift of i-pentane-δ¹³C₅ percentage (y-axis) versusi-butane-δ¹³C₄ percentage (x-axis). FIGS. 301A-D show that there is arelatively linear relationship between the hydrocarbon isomer shifts andboth temperature and bitumen conversion. The relatively linearrelationship may be used to assess formation temperature and/or bitumenconversion by monitoring the hydrocarbon isomer shifts in fluidsproduced from the formation.

FIG. 302 depicts weight percentage (Wt %)(y-axis) of saturates from SARAanalysis of the produced fluids versus temperature (° C.)(x-axis). Thelogarithmic relationship between the weight percentage of saturates andtemperature may be used to assess formation temperature by monitoringthe weight percentage of saturates in fluids produced from theformation.

FIG. 303 depicts weight percentage (Wt %) (y-axis) of n-C₇ of theproduced fluids versus temperature (° C.) (x-axis). The linearrelationship between the weight percentage of n-C₇ and temperature maybe used to assess formation temperature by monitoring the weightpercentage of n-C₇ in fluids produced from the formation.

Pre-Heating Using Heaters For Injectivity Before Steam Drive Example

An example uses the embodiment depicted in FIGS. 163 and 164 to preheat.Injection wells 788 and production wells 206 are substantially verticalwells. Heaters 438 are long substantially horizontal heaters positionedso that the heaters pass in the vicinity of injection wells 788. Heaters438 intersect the vertical well patterns slightly displaced from thevertical wells.

The following conditions were assumed for purposes of this example:

(a) heater well spacing; s=330 ft;(b) formation thickness; h=100 ft;(c) formation heat capacity; ρc=35 BTU/cu. ft.-° F.(d) formation thermal conductivity; λ=1.2 BTU/ft-hr-° F.;(e) electric heating rate; q_(h)=200 watts/ft;(f) steam injection rate; q_(s)=500 bbls/day;(g) enthalpy of steam; h_(s)=1000 BTU/lb;(h) time of heating; t=1 year;(i) total electric heat injection; Q_(E)=BTU/pattern/year;(j) radius of electric heat; r=ft; and(k) total steam heat injected; Q_(s)=BTU/pattern/year.

Electric heating for one well pattern for one year is given by:

Q _(E) =q _(h) ·t·s(BTU/pattern/year);  (EQN. 9)

with Q_(E)=(200 watts/ft)[0.001 kw/watt](1 yr)[365 day/yr][24hr/day][3413 BTU/kw·hr](330 ft)=1.9733×10⁹ BTU/pattern/year.

Steam heating for one well pattern for one year is given by:

Q _(s) =q _(s) ·t·h _(s)(BTU/pattern/year);  (EQN. 10)

with Q_(s)=(500 bbls/day)(1 yr) [365 day/yr][1000 BTU/lb][350lbs/bbl]=63.875×10⁹ BTU/pattern/year.

Thus, electric heat divided by total heat is given by:

Q _(E)/(Q _(E) +Q _(E))×100=3% of the total heat.  (EQN. 11)

Thus, the electrical energy is only a small fraction of the total heatinjected into the formation.

The actual temperature of the region around a heater is described by anexponential integral function. The integrated form of the exponentialintegral function shows that about half the energy injected is nearlyequal to about half of the injection well temperature. The temperaturerequired to reduce viscosity of the heavy oil is assumed to be 500° F.The volume heated to 500° F. by an electric heater in one year is givenby:

V_(E)=πr².  (EQN. 12)

The heat balance is given by:

Q _(E)=(πr _(E) ²)(s)(ρc)(ΔT).  (EQN. 13)

Thus, r_(E) can be solved for and is found to be 10.4 ft. For anelectric heater operated at 1000° F., the diameter of a cylinder heatedto half that temperature for one year would be about 23 ft. Depending onthe permeability profile in the injection wells, additional horizontalwells may be stacked above the one at the bottom of the formation and/orperiods of electric heating may be extended. For a ten year heatingperiod, the diameter of the region heated above 500° F. would be about60 ft.

If all the steam were injected uniformly into the steam injectors overthe 100 ft. interval for a period of one year, the equivalent volume offormation that could be heated to 500° F. would be give by:

Q _(s)=(πr _(s) ²)(s)(ρc)(ΔT).  (EQN. 14)

Solving for r_(s) gives an r_(s) of 107 ft. This amount of heat would besufficient to heat about ¾ of the pattern to 500° F.

Tar Sands Oil Recovery Example

A STARS simulation was used in combination with experimental analysis tosimulate an in situ heat treatment process of a tar sands formation. Theexperiments and simulations were used to determine oil recovery(measured by volume percentage (vol %) of oil in place (bitumen inplace)) versus API gravity of the produced fluid as affected by pressurein the formation. The experiments and simulations also were used todetermine recovery efficiency (percentage of oil (bitumen) recovered)versus temperature at different pressures.

FIG. 304 depicts oil recovery (volume percentage bitumen in place (vol %BIP)) versus API gravity (°) as determined by the pressure (MPa) in theformation. As shown in FIG. 304, oil recovery decreases with increasingAPI gravity and increasing pressure up to a certain pressure (about 2.9MPa in this experiment). Above that pressure, oil recovery and APIgravity decrease with increasing pressure (up to about 10 MPa in theexperiment). Thus, it may be advantageous to control the pressure in theformation below a selected value to get higher oil recovery along with adesired API gravity in the produced fluid.

FIG. 305 depicts recovery efficiency (%) versus temperature (° C.) atdifferent pressures. Curve 1650 depicts recovery efficiency versustemperature at 0 MPa. Curve 1652 depicts recovery efficiency versustemperature at 0.7 MPa. Curve 1654 depicts recovery efficiency versustemperature at 5 MPa. Curve 1656 depicts recovery efficiency versustemperature at 10 MPa. As shown by these curves, increasing the pressurereduces the recovery efficiency in the formation at pyrolysistemperatures (temperatures above about 300° C. in the experiment). Theeffect of pressure may be reduced by reducing the pressure in theformation at higher temperatures, as shown by curve 1658. Curve 1658depicts recovery efficiency versus temperature with the pressure being 5MPa up until about 380° C., when the pressure is reduced to 0.7 MPa. Asshown by curve 1658, the recovery efficiency can be increased byreducing the pressure even at higher temperatures. The effect of higherpressures on the recovery efficiency is reduced when the pressure isreduced before hydrocarbons (oil) in the formation have been convertedto coke.

In this patent, certain U.S. patents, U.S. patent applications, andother materials (for example, articles) have been incorporated byreference. The text of such U.S. patents, U.S. patent applications, andother materials is, however, only incorporated by reference to theextent that no conflict exists between such text and the otherstatements and drawings set forth herein. In the event of such conflict,then any such conflicting text in such incorporated by reference U.S.patents, U.S. patent applications, and other materials is specificallynot incorporated by reference in this patent.

Further modifications and alternative embodiments of various aspects ofthe invention may be apparent to those skilled in the art in view ofthis description. Accordingly, this description is to be construed asillustrative only and is for the purpose of teaching those skilled inthe art the general manner of carrying out the invention. It is to beunderstood that the forms of the invention shown and described hereinare to be taken as the presently preferred embodiments. Elements andmaterials may be substituted for those illustrated and described herein,parts and processes may be reversed, and certain features of theinvention may be utilized independently, all as would be apparent to oneskilled in the art after having the benefit of this description of theinvention. Changes may be made in the elements described herein withoutdeparting from the spirit and scope of the invention as described in thefollowing claims. In addition, it is to be understood that featuresdescribed herein independently may, in certain embodiments, be combined.

1-1411. (canceled)
 1412. A heating system for a subsurface formation,comprising: an electrical conductor; an insulation layer at leastpartially surrounding the electrical conductor; and a jacket comprisingferromagnetic material, the jacket at least partially surrounding theinsulation layer, wherein the outside surface of the jacket isconfigured to be at little or no electric potential while the electricalconductor is conducting electricity and while the jacket is attemperatures below the Curie temperature of the ferromagnetic material.1413. The heating system of claim 1412, wherein the jacket has athickness of at least 2 times the skin depth of the ferromagneticmaterial at 50° C. below the Curie temperature of the ferromagneticmaterial.
 1414. The heating system of claim 1412, wherein the jacket hasa thickness of at least 3 times the skin depth of the ferromagneticmaterial at 50° C. below the Curie temperature of the ferromagneticmaterial.
 1415. The heating system of claim 1412, wherein the heatingsystem is configured such that a majority of electrical current passesthrough the jacket on the inside diameter of the jacket.
 1416. Theheating system of claim 1412, wherein the jacket and the electricalconductor are electrically coupled at distal ends of the jacket and theelectrical conductor.
 1417. The heating system of claim 1412, whereinthe electrical conductor is copper.
 1418. The heating system of claim1412, wherein the jacket is formed from multiple layers of material.1419. The heating system of claim 1412, wherein a majority of the heatgenerated by the heating system is generated in the jacket.
 1420. Theheating system of claim 1412, wherein the heating system is located in awellbore such that the heating system provides heat to mobilizehydrocarbons in the subsurface formation.
 1421. A heating system for asubsurface formation, comprising: an electrical conductor; an insulationlayer at least partially surrounding the electrical conductor; and ajacket comprising ferromagnetic material, the jacket at least partiallysurrounding the insulation layer, wherein the jacket is configured togenerate a majority of the heat in the heating system when atime-varying electrical current is applied to the heating system. 1422.The heating system of claim 1421, wherein the jacket has a thickness ofat least 2 times the skin depth of the ferromagnetic material at 50° C.below the Curie temperature of the ferromagnetic material.
 1423. Theheating system of claim 1421, wherein the jacket has a thickness of atleast 3 times the skin depth of the ferromagnetic material at 50° C.below the Curie temperature of the ferromagnetic material.
 1424. Theheating system of claim 1421, wherein the heating system is configuredsuch that a majority of electrical current passes through the jacket onthe inside diameter of the jacket.
 1425. The heating system of claim1421, wherein the jacket and the electrical conductor are electricallycoupled at distal ends of the jacket and the electrical conductor. 1426.The heating system of claim 1421, wherein the electrical conductor iscopper.
 1427. The heating system of claim 1421, wherein the jacket isformed from multiple layers of material.
 1428. The heating system ofclaim 1421, wherein a majority of the heat generated by the heatingsystem is generated in the jacket.
 1429. The heating system of claim1421, wherein the heating system is located in a wellbore such that theheating system provides heat to mobilize hydrocarbons in the subsurfaceformation.
 1430. A method for heating a subsurface formation,comprising: providing electrical power to a heater located in an openingin the formation, the heater comprising: an electrical conductor; aninsulation layer at least partially surrounding the electricalconductor; and a jacket comprising ferromagnetic material, the jacket atleast partially surrounding the insulation layer, wherein the outsidesurface of the jacket is configured to be at little or no electricalpotential while the electrical conductor is conducting electricity andwhile the jacket is at temperatures below the Curie temperature of theferromagnetic material; and allowing heat to transfer from the heater toat least a portion of the subsurface formation.
 1431. The method ofclaim 1430, wherein the jacket has a thickness of at least 2 times theskin depth of the ferromagnetic material.
 1432. The method of claim1430, wherein the jacket has a thickness of at least 3 times the skindepth of the ferromagnetic material.
 1433. The method of claim 1430,wherein a majority of electrical current passes through the jacket onthe inside diameter of the jacket while electrical power is beingprovided to the heater.
 1434. The method of claim 1430, wherein thejacket and the electrical conductor are electrically coupled at distalends of the jacket and the electrical conductor.
 1435. The method ofclaim 1430, wherein the electrical conductor is copper.
 1436. The methodof claim 1430, wherein the jacket is formed from multiple layers ofmaterial.
 1437. The method of claim 1430, further comprising generatinga majority of the heat in the jacket.
 1438. The method of claim 1430,further comprising using heat from the heater to mobilize hydrocarbonsin the subsurface formation.
 1439. The method of claim 1430, furthercomprising using heat from the heater to mobilize hydrocarbons in thesubsurface formation, and producing hydrocarbons from the subsurfaceformation. 1440-1936. (canceled)